ピーク情報

はつか大根　葉

pos

Peak #669 MN MID: SE202_S21_M90

m/z: 478.83618, RT: 11.24, 強度: 5135, ログ強度: 0.26, アダクト: [M+K]+, 共有数（同様のピークを含むサンプル数）: 4

DB検索結果:

DBごとのヒット数:

FlavonoidSearch最大スコア MS2: 0.071, MS3: 0.167

MSnスペクトル情報

Level: 2, プリカーサーm/z: 478.83575

Splash: splash10-0006-0009100000-e23533f537b828fb8fa0

m/z	Int.	NL	Rel.Int.
342.83	671	136	1000
394.72	569	84	848
410.71	167	68	249
358.79	138	120	206
326.85	135	152	200
274.84	56	204	83
258.85	53	220	79
374.90	44	104	66
432.13	39	47	58

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.071	[Flavonol]-A(1OH, 1OMe, 1(C-Glu))-B(2OH)	Flavonol	Keyakinin B
0.000	[Dihydrochalcone]-A(3OH)-B(1OH, 1(C-Prenyl), 1Geranyl)	Dihydrochalcone	3-Geranyl-4,2',4',6'-tetrahydroxy-5-prenyldihydrochalcone
0.000	[Flavonol]-A(1OH, 1OMe, 1(C-Rhamnosyl))-B(3OH)	Flavonol	8-C-Rhamnosyleuropetin

Level: 3, プリカーサーm/z: 394.71860

Splash: splash10-00di-0090000000-16314a4ddc33ceeb6b0f

m/z	Int.	NL	Rel.Int.
274.85	407	120	1000
258.80	152	136	373
290.79	34	104	84

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.167	[Flavan 3-ol]-A(2OH)-B(2OH)-C(1(O-Benzoyl))	Flavan 3-ol	Catechin 3-O-benzoate
0.000	[Isoflavone]-A(1([2,3:@@]-(6,6-Dimethylpyrano)))-B(3OMe)	Isoflavone	Barbigerone
0.000	[Flavanone]-A(1([2,3:@@]-(5,5-Dimethyl-4-acetoxy-4,5,3a,6a-tetrahydro-furo[2,3-b]furano)))-B(none)	Flavanone	Purpurin
0.000	[Flavanone]-A(1OMe, 1(C-Prenyl), 1([2,3:@@]-Furano))-B(2OH)	Flavanone	3',4'-Dihydroxy-7-methoxy-8-prenyl-[2'',3'':5,6]furanoflavanone
0.000	[Flavone]-A(1OH, 1([2,3:@@]-(4-Methyl-5-hydoxy-3a,6a-dihydro-6-oxocyclopenta[b]furano)))-B(2OH)	Flavone	Demethyltorosaflavone C
0.000	[Flavone]-A(1OH, 1OMe, 2Methyl)-B(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))	Flavone	Muxiangrin I
0.000	[Dihydroflavonol]-A(2OH, 1(p-Hydroxybenzyl))-B(1OH)	Dihydroflavonol	Gericudranin E
0.000	[Flavonol (3-OMe)]-A(1OMe, 1Methyl, 1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(1OH)	Flavonol	8-C-Methylvellokaempferol 3,5-dimethyl ether
0.000	[Rotenone]-A(1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(2OMe)	Rotenone	Rotenone
0.000	[Rotenone]-A(1OH, 1(Penta-1,4-dienyl))-B(2OMe)	Rotenone	Myriconol
0.000	[Rotenone]-A(1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OMe)	Rotenone	Deguelin
0.000	[12a-Hydroxyrotenone]-A(1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(1([@@]-Methylenedioxy))	12a-Hydroxyrotenone	12a-Hydroxyisomillettone
0.000	[12a-Hydroxyrotenone]-A(1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1([@@]-Methylenedioxy))	12a-Hydroxyrotenone	Millettosin
0.000	[Dehydrorotenone]-A(1([2,3:@@]-(5-Isopropyldihydrofurano)))-B(2OMe)	Dehydrorotenone	Dehydrodihydrorotenone
0.000	[4-Hydroxy-3-phenylcoumarin (4-OMe)]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OMe)	4-Hydroxy-3-phenylcoumarin	Robustic acid methyl ether
0.000	[4-Hydroxy-3-phenylcoumarin]-A(1OMe, 1([@@]-Methylenedioxy))-B(1([2,3:@@]-(6,6-Dimethylpyrano)))	4-Hydroxy-3-phenylcoumarin	Robustin
0.000	[4-Hydroxy-3-phenylcoumarin]-A(1OMe, 1([@@]-Methylenedioxy))-B(1([2,3:@@]-(6,6-Dimethylpyrano)))	4-Hydroxy-3-phenylcoumarin	Isorobustin

Level: 3, プリカーサーm/z: 342.83337

Splash: splash10-0a4i-0090000000-ff3af1b8e512e8d722f6

m/z	Int.	NL	Rel.Int.
258.88	221	84	1000
206.83	161	136	729
274.87	37	68	169
290.96	19	52	88
223.03	19	120	86
122.80	13	220	60
174.92	13	168	60

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.125	[Isoflavone]-A(2OMe)-B(2OMe)	Isoflavone	6,7,3',4'-Tetramethoxyisoflavone
0.080	[Isoflavone]-A(1OMe)-B(3OMe)	Isoflavone	7,2',4',5'-Tetramethoxyisoflavone
0.000	[Flavone]-A(1OH)-B(3OH)	Flavone	7,2',4',5'-Tetrahydroxyflavone
0.000	[Flavone]-A(2OMe)-B(2OMe)	Flavone	Zapotin
0.000	[Flavone]-A(2OMe)-B(2OMe)	Flavone	Cerrosillin
0.000	[Flavone]-A(2OMe)-B(2OMe)	Flavone	5,7,2',5'-tetramethoxyflavone
0.000	[Flavone]-A(2OMe)-B(2OMe)	Flavone	Luteolin 5,7,3',4'-tetramethyl ether
0.000	[Flavone]-A(2OMe)-B(2OMe)	Flavone	Norartocarpetin 5,7,2',4'-tetramethyl ether
0.000	[Flavone]-A(3OMe)-B(1OMe)	Flavone	Scutellarein 5,6,7,4'-tetramethyl ether
0.000	[Flavone]-A(3OMe)-B(1OMe)	Flavone	4',5,7,8-Tetramethoxyflavone
0.000	[Flavone]-A(4OMe)-B(none)	Flavone	5,6,7,8-Tetramethoxyflavone
0.000	[Aurone]-A(2OMe)-B(2OMe)	Aurone	4,6,3',4'-Tetramethoxyaurone
0.000	[Chalcone]-A(3OMe)-B(1([@@]-Methylenedioxy))	Chalcone	3,4-Methylenedioxy-2',4',6'-trimethoxychalcone
0.000	[alpha-Methyl-beta-oxodihydrochalcone]-A(2OMe)-B(1Oxo, 1Methyl, 1([@@]-Methylenedioxy))	alpha-Methyl-beta-oxodihydrochalcone	Tinosporinone
0.000	[Flavanone]-A(1OH, 1(3-hydroxy-3-methylbutyl))-B(1OH)	Flavanone	Brosimacutin C
0.000	[Flavone]-A(1OH, 2OMe)-B(1([@@]-Methylenedioxy))	Flavone	2-(1,3-Benzodioxol-5-yl)-5-hydroxy-6,8-dimethoxy-4H-1-benzopyran-4-one
0.000	[Flavone]-A(2OH, 2Methyl)-B(2OMe)	Flavone	5,7-Dihydroxy-3',4'-dimethoxy-6,8-dimethylflavone
0.000	[Flavonol (3-OMe)]-A(1OMe)-B(2OMe)	Flavonol	Fisetin tetramethyl ether
0.000	[Flavonol (3-OMe)]-A(2OMe)-B(1OMe)	Flavonol	Tetramethylkaempferol
0.000	[Flavonol (3-OMe)]-A(1OH, 1OMe, 1Methyl)-B(1OMe)	Flavonol	8-Desmethylkalmiatin
0.000	[Flavonol (3-OMe)]-A(1OH, 1OMe, 2Methyl)-B(1OH)	Flavonol	6,8-Di-C-methylkaempferol 3,7-dimethyl ether
0.000	[Flavonol (3-OMe)]-A(1OH, 1OMe)-B(1([@@]-Methylenedioxy))	Flavonol	5-Hydroxy-3,7-dimethoxy-3',4'-methylenedioxyflavone
0.000	[Flavonol (3-OMe)]-A(3OMe)-B(none)	Flavonol	3,5,6,7-Tetramethoxyflavone
0.000	[Flavonol]-A(1OMe, 1([@@]-Methylenedioxy))-B(1OMe)	Flavonol	3-Hydroxy-5,4'-dimethoxy-6,7-methylenedioxyflavone
0.000	[Flavonol (3-OMe)]-A(3OMe)-B(none)	Flavonol	3,5,7,8-Tetramethoxyflavone
0.000	[Flavan 3-ol]-A(1OH, 1([2,3:@@]-(6-Oxopyrano)))-B(2OH)	Flavan 3-ol	Phyllocoumarin
0.000	[Isoflavone]-A(1OH, 1OMe)-B(1OMe, 1([@@]-Methylenedioxy))	Isoflavone	6-Hydroxy-7,2'-dimethoxy-4',5'-methylenedioxyisoflavone
0.000	[Isoflavone]-A(1OH, 1OMe)-B(1OMe, 1([@@]-Methylenedioxy))	Isoflavone	Dalpatein
0.000	[Isoflavone]-A(1OH, 1OMe)-B(1OMe, 1([@@]-Methylenedioxy))	Isoflavone	Maximaisoflavone F
0.000	[Isoflavone]-A(1OH, 1OMe, 1Methyl)-B(2OMe)	Isoflavone	5-Hydroxy-7,3',4'-trimethoxy-8-methylisoflavone
0.000	[Isoflavone]-A(1OMe, 1([@@]-Methylenedioxy))-B(1OH, 1OMe)	Isoflavone	Isoiriskashmirianin
0.000	[Isoflavone]-A(1OH, 2OMe)-B(1([@@]-Methylenedioxy))	Isoflavone	Dipteryxine
0.000	[Isoflavone]-A(1OH, 1([@@]-Methylenedioxy))-B(2OMe)	Isoflavone	Squarrosin
0.000	[Isoflavone]-A(1OMe, 1([@@]-Methylenedioxy))-B(1OH, 1OMe)	Isoflavone	Iriskashmirianin
0.000	[Isoflavone]-A(1OMe, 1([@@]-Methylenedioxy))-B(1OH, 1OMe)	Isoflavone	Iriskumaonin
0.000	[Isoflavone]-A(1OH, 2OMe)-B(1([@@]-Methylenedioxy))	Isoflavone	Platycarpanetin
0.000	[Pterocarpene]-A(1OH, 2OMe)-B(1([@@]-Methylenedioxy))	Pterocarpene	Leiocalycin
0.000	[Pterocarpene]-A(1OMe)-B(3OMe)	Pterocarpene	Bryacarpene 3
0.000	[Rotenone]-A(1OMe)-B(2OMe)	Rotenone	Munduserone
0.000	[4-phenylcoumarin]-A(1OH, 1OMe, 1Formyl)-B(1OH, 1OMe)	4-phenylcoumarin	7,3'-Dihydroxy-5,4'-dimethoxy-6-formyl-4-phenylcoumarin
0.000	[4-phenylcoumarin]-A(1OH, 1OMe, 1Formyl)-B(1OH, 1OMe)	4-phenylcoumarin	Sisafolin