ピーク情報

はつか大根　葉

pos

Peak #3094 MN MID: SE202_S21_M90

m/z: 448.19445, RT: 32.92, 強度: 18365, ログ強度: 0.81, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 13

DB検索結果: (2 names) Glycoerysodin;Hydromorphone-3-glucoside

DBごとのヒット数: ALL 2 KN 1 HM 1

FlavonoidSearch最大スコア MS2: -, MS3: 0.111

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C23H29O8N	447.18932	-4.787	Glycoerysodin	KNApSAcK: C00019516
C23H29O8N	447.18932	-4.787	Hydromorphone-3-glucoside	HMDB: HMDB0061144

MSnスペクトル情報

Level: 2, プリカーサーm/z: 448.19431

Splash: splash10-0a59-0096600000-97f63218e37e6efae69a

m/z	Int.	NL	Rel.Int.
259.22	13825	189	1000
301.20	9512	147	688
284.11	6876	164	497
406.25	6870	42	496
430.28	6760	18	488
319.23	4423	129	319
431.24	1655	17	119
277.18	1241	171	89
388.27	1220	60	88
302.13	1033	146	74

Level: 3, プリカーサーm/z: 301.16733

Splash: splash10-0a59-0090000000-987a01b3a6e899e10937

m/z	Int.	NL	Rel.Int.
259.12	4261	42	1000
284.21	2298	17	539
216.19	215	85	50

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.111	[Dihydroflavonol]-A(2OMe)-B(none)	Dihydroflavonol	5,7-Di-O-methylpinobanksin
0.091	[2'-Hydroxychalcone]-A(2OH, 2OMe)-B(none)	2'-Hydroxychalcone	Pashanone
0.091	[2'-Hydroxychalcone]-A(2OH, 2OMe)-B(none)	2'-Hydroxychalcone	2',4'-Dihydroxy-3',6'-dimethoxychalcone
0.091	[2'-Hydroxychalcone]-A(2OH, 2OMe)-B(none)	2'-Hydroxychalcone	2',3'-Dihydroxy-4',6'-dimethoxychalcone
0.091	[2'-Hydroxychalcone]-A(2OH)-B(2OMe)	2'-Hydroxychalcone	2',4'-Dihydroxy-3,4-dimethoxychalcone
0.091	[2'-Hydroxychalcone]-A(1OH, 2OMe)-B(1OH)	2'-Hydroxychalcone	Heliannone A
0.091	[2'-Hydroxychalcone]-A(1OH, 2OMe)-B(1OH)	2'-Hydroxychalcone	Flavokawin C
0.091	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OMe)	2'-Hydroxychalcone	Kukulkanin A
0.091	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OMe)	2'-Hydroxychalcone	Gymnogrammene
0.091	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OMe)	2'-Hydroxychalcone	2',4'-Dihydroxy-4,6'-dimethoxychalcone
0.077	[Flavanone]-A(2OMe)-B(1OH)	Flavanone	Naringenin 5,7-dimethyl ether
0.077	[Flavanone]-A(1OH, 2OMe)-B(none)	Flavanone	6-Hydroxy-5,7-dimethoxyflavanone
0.077	[Flavanone]-A(1OH, 2OMe)-B(none)	Flavanone	Onysilin
0.077	[Flavanone]-A(1OH, 2OMe)-B(none)	Flavanone	8-Hydroxy-5,7-dimethoxyflavanone
0.077	[Flavanone]-A(1OH, 2OMe)-B(none)	Flavanone	5-Hydroxy-7,8-dimethoxyflavanone
0.077	[Flavanone]-A(1OH, 1OMe)-B(1OMe)	Flavanone	Tsugafolin
0.077	[Flavanone]-A(1OH, 1OMe)-B(1OMe)	Flavanone	Naringenin 7,4'-dimethyl ether
0.077	[Chalcone]-A(1OH, 2OMe)-B(1OH)	Chalcone	4,4'-Dihydroxy-2',6'-dimethoxychalcone
0.077	[Chalcone]-A(1OMe)-B(2OH, 1OMe)	Chalcone	2,4-Dihydroxy-6,4'-dimethoxychalcone
0.000	[Flavone]-A(1OH, 1OMe)-B(2OH)	Flavone	7,3',4'-Trihydroxy-6-methoxyflavone
0.000	[Flavone]-A(2OH)-B(1OH, 1OMe)	Flavone	5,7,2'-Trihydroxy-6'-methoxyflavone
0.000	[Flavone]-A(1OH, 1OMe)-B(2OH)	Flavone	5,2',6'-Trihydroxy-7-methoxyflavone
0.000	[Flavone]-A(2OH)-B(1OH, 1OMe)	Flavone	Chrysoeriol
0.000	[Flavone]-A(2OH)-B(1OH, 1OMe)	Flavone	Diosmetin
0.000	[Flavone]-A(1OH, 1OMe)-B(2OH)	Flavone	Luteolin 5-methyl ether
0.000	[Flavone]-A(1OH, 1OMe)-B(2OH)	Flavone	Luteolin 7-methyl ether
0.000	[Flavone]-A(1OH, 1OMe)-B(2OH)	Flavone	Artocarpetin
0.000	[Flavone]-A(2OH, 1OMe)-B(1OH)	Flavone	5,7,2'-Trihydroxy-6-methoxyflavone
0.000	[Flavone]-A(3OH)-B(1OMe)	Flavone	Scutellarein 4'-methyl ether
0.000	[Flavone]-A(2OH, 1OMe)-B(1OH)	Flavone	Hispidulin
0.000	[Flavone]-A(2OH, 1OMe)-B(1OH)	Flavone	Sorbifolin
0.000	[Flavone]-A(2OH, 1OMe)-B(1OH)	Flavone	5,8,2'-Trihydroxy-7-methoxyflavone
0.000	[Flavone]-A(2OH, 1OMe)-B(1OH)	Flavone	Scutevulin
0.000	[Flavone]-A(3OH)-B(1OMe)	Flavone	Takakin
0.000	[Flavone]-A(2OH, 1OMe)-B(1OH)	Flavone	Isocutellarein 7-methyl ether
0.000	[Flavone]-A(2OH, 1OMe)-B(1OH)	Flavone	Isoscutellarein 8-methyl ether
0.000	[Anthocyanidin]-A(2OH)-B(1OH, 1OMe)	Anthocyanidin	Peonidin
0.000	[Anthocyanidin]-A(1OH, 1OMe)-B(2OH)	Anthocyanidin	5-Methoxycyanidin
0.000	[Isoflavone]-A(1OH)-B(2OH, 1OMe)	Isoflavone	Gliricidin
0.000	[Isoflavone]-A(1OH)-B(2OH, 1OMe)	Isoflavone	7,2',4'-Trihydroxy-3'-methoxyisoflavone
0.000	[Isoflavone]-A(1OH)-B(2OH, 1OMe)	Isoflavone	Koparin
0.000	[Isoflavone]-A(2OH, 1OMe)-B(1OH)	Isoflavone	7,8,4'-Trihydroxy-6-methoxyisoflavone
0.000	[Isoflavone]-A(2OH, 1OMe)-B(1OH)	Isoflavone	Tectorigenin
0.000	[Isoflavone]-A(2OH, 1OMe)-B(1OH)	Isoflavone	Isotectorigenin
0.000	[Isoflavone]-A(1OH, 1OMe)-B(2OH)	Isoflavone	Santal
0.000	[Isoflavone]-A(1OH, 1OMe)-B(2OH)	Isoflavone	Cajanin
0.000	[Isoflavone]-A(2OH)-B(1OH, 1OMe)	Isoflavone	7,8,3'-Trihydroxy-4'-methoxyisoflavone
0.000	[Isoflavone]-A(2OH)-B(1OH, 1OMe)	Isoflavone	3'-O-Methylorobol
0.000	[Isoflavone]-A(2OH)-B(1OH, 1OMe)	Isoflavone	Pratensein
0.000	[Isoflavone]-A(2OH)-B(1OH, 1OMe)	Isoflavone	2'-Hydroxybiochanin A
0.000	[Coumestan]-A(2OH)-B(2OH)	Coumestan	Demethylwedelolactone
0.000	[Flavonol]-A(1OH, 1OMe)-B(1OH)	Flavonol	Datin
0.000	[Flavonol]-A(1OH, 1OMe)-B(1OH)	Flavonol	Kaempferol 5-methyl ether
0.000	[Flavonol]-A(1OH, 1OMe)-B(1OH)	Flavonol	Rhamnocitrin
0.000	[Flavonol]-A(2OH, 1OMe)-B(none)	Flavonol	Alnusin
0.000	[Flavonol]-A(2OH, 1OMe)-B(none)	Flavonol	8-Hydroxygalangin 7-methyl ether
0.000	[Flavonol]-A(2OH, 1OMe)-B(none)	Flavonol	8-Methoxygalangin
0.000	[Flavonol]-A(1OH)-B(1OH, 1OMe)	Flavonol	Geraldol
0.000	[Flavonol]-A(1OH)-B(1OH, 1OMe)	Flavonol	Fisetin 4'-methyl ether
0.000	[Flavonol]-A(2OH)-B(1OMe)	Flavonol	3,6,7-Trihydroxy-4'-methoxyflavone
0.000	[Flavonol]-A(2OH)-B(1OMe)	Flavonol	Ptaeroxylol
0.000	[Flavonol]-A(2OH)-B(1OMe)	Flavonol	Kaempferide
0.000	[Pterocarpan]-A(1OH, 1OMe)-B(1OMe)	Pterocarpan	2-Methoxymedicarpin
0.000	[Pterocarpan]-A(1OH, 1OMe)-B(1OMe)	Pterocarpan	Melilotocarpan A
0.000	[Pterocarpan]-A(1OH, 1OMe)-B(1OMe)	Pterocarpan	4-Methoxymedicarpin
0.000	[Pterocarpan]-A(1OH)-B(2OMe)	Pterocarpan	Methylnissolin
0.000	[Pterocarpan]-A(2OMe)-B(1OH)	Pterocarpan	Sparticarpin
0.000	[Pterocarpan]-A(1OMe)-B(1OH, 1OMe)	Pterocarpan	8-Hydroxy-3,9-dimethoxypterocarpan
0.000	[Pterocarpan]-A(1OMe)-B(1OH, 1OMe)	Pterocarpan	Fruticarpin
0.000	[Isoflavanone]-A(1OH)-B(2OMe)	Isoflavanone	3'-Methoxydihydroformononetin
0.000	[Isoflavanone]-A(1OH)-B(2OMe)	Isoflavanone	Sativanone
0.000	[Isoflavanone]-A(1OMe)-B(1OH, 1OMe)	Isoflavanone	Isosativanone
0.000	[Aurone]-A(1OH, 1OMe)-B(2OH)	Aurone	Leptosidin
0.000	[Aurone]-A(1OH, 1OMe)-B(2OH)	Aurone	Rengasin
0.000	[Aurone]-A(2OH, 1Methyl)-B(2OH)	Aurone	4,6,3',4'-Tetrahydroxy-5-methylaurone
0.000	[Aurone]-A(2OH, 1Methyl)-B(2OH)	Aurone	4,6,3',4'-Tetrahydroxy-7-methylaurone
0.000	[CCS-type derivative / [alpha,2]-Epoxymethanochalcone]-A(2OH)-B(2OH)	CCS-type derivative / [alpha,2]-Epoxymethanochalcone	Peltochalcone
0.000	[CCS-type derivative / [alpha,2]-Epoxymethanochalcone]-A(2OH)-B(2OH)	CCS-type derivative / [alpha,2]-Epoxymethanochalcone	Mopachalcone
0.000	[UBR-type derivative / [2',5']-Benzoquinonyl-type chalcone]-A(2OH, 1OMe)-B(none)	UBR-type derivative / [2',5']-Benzoquinonyl-type chalcone	Pedicinin
0.000	[UBR-type derivative / 2',5'-Dioxo-3'-cyclopentenyl-type Calcone (alpha-OMe)]-A(2OMe)-B(none)	UBR-type derivative / 2',5'-Dioxo-3'-cyclopentenyl-type Calcone	Methylliderone
0.000	[Dihydrochalcone]-A(1OH, 2OMe, 1Methyl)-B(none)	Dihydrochalcone	2'-Hydroxy-4',6'-dimethoxy-3'-methyldihydrochalcone
0.000	[Dihydrochalcone]-A(2OH, 1OMe, 2Methyl)-B(none)	Dihydrochalcone	Myrigalon B
0.000	[Dihydrochalcone]-A(2OH, 1OMe, 2Methyl)-B(none)	Dihydrochalcone	Angoletin
0.000	[Dihydrochalcone]-A(3OH, 1Formyl, 1Methyl)-B(none)	Dihydrochalcone	3'-Formyl-2',4',6'-trihydroxy-5'-methyldihydrochalcone
0.000	[UBR-type derivative / 2',4',6'-trioxocyclohexanyl-type Dihydrochalcone]-A(3Methyl)-B(none)	UBR-type derivative / 2',4',6'-trioxocyclohexanyl-type Dihydrochalcone	2,2,4-Trimethyl-6-(1-oxo-3-phenylpropyl)-1,3,5-cyclohexanetrione
0.000	[Flavanone]-A(1OH, 1OMe, 1Methyl)-B(1OH)	Flavanone	5,4'-Dihydroxy-7-methoxy-6-methylflavanone
0.000	[Flavanone]-A(2OH, 1Methyl)-B(1OMe)	Flavanone	5,7-Dihydroxy-4'-methoxy-8-methylflavanone
0.000	[Flavanone]-A(1OH, 1OMe, 1Methyl)-B(1OH)	Flavanone	5,4'-Dihydroxy-7-methoxy-8-methylflavanone
0.000	[Flavanone]-A(2OH, 2Methyl)-B(1OH)	Flavanone	Farrerol
0.000	[Flavanone]-A(1OH, 1([@@]-Methylenedioxy))-B(1OH)	Flavanone	5,2'-Dihydroxy-6,7-methylenedioxyflavanone
0.000	[2-Hydroxyflavanone]-A(1OH, 1OMe, 1Methyl)-B(none)	2-Hydroxyflavanone	2,5-Dihydroxy-7-methoxy-6-methylflavanone
0.000	[2-Hydroxyflavanone]-A(1OH, 1OMe, 1Methyl)-B(none)	2-Hydroxyflavanone	2,5-Dihydroxy-7-methoxy-8-methylflavanone
0.000	[3-substituted Flavone (3-Methyl)]-A(2OH)-B(2OH)	3-substituted Flavone	3-C-Methylluteolin
0.000	[Flavone]-A(2OH, 1Methyl)-B(2OH)	Flavone	6-Methylluteolin
0.000	[Dihydroflavonol]-A(1OH, 1([@@]-Methylenedioxy))-B(none)	Dihydroflavonol	3,5-Dihydroxy-6,7-methylenedioxyflavanone
0.000	[CCS-type derivative / [3,2']-Epoxymethanodihydroflavanone]-A(1OH)-B(2OH)	CCS-type derivative / [3,2']-Epoxymethanodihydroflavanone	Peltogynone
0.000	[CCS-type derivative / [3,2']-Epoxymethanodihydroflavanone]-A(1OH)-B(2OH)	CCS-type derivative / [3,2']-Epoxymethanodihydroflavanone	Mopanone
0.000	[Flavonol (3-OMe)]-A(1OH)-B(2OH)	Flavonol	Fisetin 3-methyl ether
0.000	[Flavonol (3-OMe)]-A(2OH)-B(1OH)	Flavonol	6,7,4'-Trihydroxy-3-methoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH)-B(1OH)	Flavonol	7,8,4'-Trihydroxy-3-methoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH)-B(1OH)	Flavonol	Isokaempferide
0.000	[Flavonol]-A(2OH, 1Methyl)-B(1OH)	Flavonol	6-C-Methylkaempferol
0.000	[Flavonol]-A(2OH, 1Methyl)-B(1OH)	Flavonol	8-C-Methylkaempferol
0.000	[Flavonol]-A(3OH, 1Methyl)-B(none)	Flavonol	Isoplatanin
0.000	[Flavonol (3-OMe)]-A(3OH)-B(none)	Flavonol	8-Hydroxygalangin 3-methyl ether
0.000	[Flavonol]-A(3OH, 1Methyl)-B(none)	Flavonol	Platanin
0.000	[Flavan]-A(1OMe)-B(1OH, 1([@@]-Methylenedioxy))	Flavan	2'-Hydroxy-7-methoxy-4',5'-methylenedioxyflavan
0.000	[Flavan]-A(2OMe)-B(1OMe)	Flavan	5,7,4'-Trimethoxyflavan
0.000	[Flavan]-A(2OMe, 1Methyl)-B(1OH)	Flavan	4'-Hydroxy-5,7-dimethoxy-8-methylflavan
0.000	[3-DehydroxyAnthocyanidin]-A(2OH, 1OMe)-B(2OH)	3-DehydroxyAnthocyanidin	5-Methyl-6-hydroxyluteolinidin
0.000	[Isoflavanone]-A(1OH)-B(1OH, 1([@@]-Methylenedioxy))	Isoflavanone	Sophorol
0.000	[Isoflavan]-A(1OH)-B(1OMe, 1([@@]-Methylenedioxy))	Isoflavan	Astraciceran
0.000	[isoflavene]-A(1OH)-B(1OH, 2OMe)	isoflavene	2'-O-Methylsepiol
0.000	[isoflavene]-A(1OH)-B(1OH, 2OMe)	isoflavene	Haginin A
0.000	[isoflavene]-A(1OH)-B(1OH, 2OMe)	isoflavene	Odoriflavene
0.000	[isoflavene]-A(1OH, 1OMe)-B(1OH, 1OMe)	isoflavene	7,2'-Dihydroxy-8,4'-dimethoxyisoflav-3-ene
0.000	[Pterocarpan]-A(2OH)-B(1([@@]-Methylenedioxy))	Pterocarpan	2-Hydroxymaackiain
0.000	[Pterocarpan]-A(2OH)-B(1([@@]-Methylenedioxy))	Pterocarpan	4-Hydroxymaackiain
0.000	[Pterocarpan-6a-ol]-A(1OMe)-B(1OMe)	Pterocarpan-6a-ol	Homopisatin
0.000	[Pterocarpan-6a-ol]-A(1OH)-B(1([@@]-Methylenedioxy))	Pterocarpan-6a-ol	6a-Hydroxymaackiain
0.000	[Pterocarpan-6-ol (6-OMe)]-A(1OH)-B(1OMe)	Pterocarpan-6-ol	Sophoracarpan A
0.000	[2-Phenylbenzofuran]-A(1OH, 1OMe)-B(2OMe)	2-Phenylbenzofuran	Methylsainfuran
0.000	[2-Phenylbenzofuran]-A(1([@@]-Methylenedioxy))-B(2OH, 1OMe)	2-Phenylbenzofuran	Sophorafuran A
0.000	[4-phenylcoumarin]-A(1OH, 1OMe)-B(2OH)	4-phenylcoumarin	5,3',4'-Trihydroxy-7-methoxy-4-phenylcoumarin
0.000	[4-phenylcoumarin]-A(1OH, 1OMe)-B(2OH)	4-phenylcoumarin	7,3',4'-Trihydroxy-5-methoxy-4-phenylcoumarin
0.000	[Dalbergiquinol]-A(3OMe)-B(1OH)	Dalbergiquinol	5-O-Methyllatifolin
0.000	[UBR-type derivative / [2,5]-Benzoquinonyl-type Dalbergiquinol]-A(1OH)-B(2OMe)	UBR-type derivative / [2,5]-Benzoquinonyl-type Dalbergiquinol	4'-Hydroxy-3,4-dimethoxydalbergione
0.000	[UBR-type derivative / [2,5]-Benzoquinonyl-type Dalbergiquinol]-A(1OMe)-B(1OH, 1OMe)	UBR-type derivative / [2,5]-Benzoquinonyl-type Dalbergiquinol	3'-Hydroxy-4,4'-dimethoxydalbergione

Level: 3, プリカーサーm/z: 259.12732

Splash: splash10-001i-0090000000-c03a16e77b8949c5b575

m/z	Int.	NL	Rel.Int.
230.02	3863	29	1000
202.11	2195	57	568
232.21	679	27	175
216.07	506	43	130
120.02	404	139	104
231.09	275	28	71
242.11	231	17	59
132.04	213	127	55

Symbolized Name	MSMS-Category	MSMS-Aglycone
[Isoflavan]-A(1OH)-B(2OH)	Isoflavan	Demethylvestitol
[Dihydrochalcone]-A(2OH)-B(1OH)	Dihydrochalcone	Davidigenin
[Dihydrochalcone]-A(3OH)-B(none)	Dihydrochalcone	2',4',6'-Trihydroxydihydrochalcone
[Dihydrochalcone]-A(1OH)-B(2OH)	Dihydrochalcone	2,4,4'-Trihydroxydihydrochalcone
[Flavan 3-ol]-A(2OH)-B(none)	Flavan 3-ol	Distenin
[Flavan 3-ol]-A(1OH)-B(1OH)	Flavan 3-ol	Guibourtinidol
[2-Benzyldihydrobenzofuran]-A(1OH)-B(1OH)	2-Benzyldihydrobenzofuran	3,6,4'-Trihydroxy-2-benzyldihydrobenzofuran
[Flavan]-A(2OH)-B(1OH)	Flavan	Apigeniflavan