ピーク情報

はつか大根　葉

pos

Peak #10541 MN MID: SE202_S21_M90

m/z: 703.40408, RT: 96.14, 強度: 94442, ログ強度: 1.52, アダクト: [M+Na]+, 共有数（同様のピークを含むサンプル数）: 4

DB検索結果: (3 names) 2alpha,3beta,24,29-tetrahydroxyolean-12-en-28-oic acid 28-O-beta-d-glucopyranside;Beesioside D;(+)-Beesioside D

DBごとのヒット数: ALL 2 KN 1 LM 1

FlavonoidSearch最大スコア MS2: -, MS3: 0.130

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C37H60O11	680.41356	1.908	2alpha,3beta,24,29-tetrahydroxyolean-12-en-28-oic acid 28-O-beta-d-glucopyranside	LipidMAPS: LMPR0106150047
C37H60O11	680.41356	1.908	Beesioside D	KNApSAcK: C00045229

MSnスペクトル情報

Level: 2, プリカーサーm/z: 703.40411

Splash: splash10-00or-0000960000-c8ef8ab7bd1fb79eadb6

m/z	Int.	NL	Rel.Int.
425.25	9726	278	1000
519.36	6988	184	718

Level: 3, プリカーサーm/z: 425.27869

Splash: splash10-06r6-0090000000-f3ac772d50672f0c5377

m/z	Int.	NL	Rel.Int.
243.14	155	182	1000
263.13	120	162	774
207.15	97	218	620
240.99	67	184	427
259.11	57	166	363
277.24	53	148	339
203.10	42	222	268
397.39	28	28	178
185.02	26	240	166
303.11	16	122	100
407.56	11	18	71
335.29	11	90	69

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.130	[Isoflavanone]-A(2OH, 1(C-Prenyl))-B(2OH, 1(C-Prenyl))	Isoflavanone	3'-Dimethylallylkievitone
0.091	[Dihydroflavonol]-A(2OH, 1(C-Prenyl))-B(1OH, 1(C-Prenyl))	Dihydroflavonol	Lespedezaflavanone C
0.083	[Flavanone]-A(2OH, 1(C-Prenyl))-B(2OH, 1(C-Prenyl))	Flavanone	Gancaonin E
0.083	[Flavanone]-A(2OH, 1(C-Prenyl))-B(2OH, 1(C-Prenyl))	Flavanone	5,7,3',4'-Tetrahydroxy-6,5'-di-C-prenylflavanone
0.083	[Flavanone]-A(2OH, 1(C-Prenyl))-B(2OH, 1(C-Prenyl))	Flavanone	Lespedezaflavanone D
0.043	[Dihydroflavonol]-A(2OH, 2(C-Prenyl))-B(1OH)	Dihydroflavonol	6,8-diprenylaromadendrin
0.040	[Flavanone]-A(2OH, 2(C-Prenyl))-B(2OH)	Flavanone	Monotesone B
0.040	[Flavanone]-A(2OH, 2(C-Prenyl))-B(2OH)	Flavanone	6,8-Diprenyleriodictyol
0.040	[Flavanone]-A(2OH, 2(C-Prenyl))-B(2OH)	Flavanone	Kushenol E
0.040	[Flavanone]-A(2OH)-B(2OH, 2(C-Prenyl))	Flavanone	Sigmoidin A
0.040	[Flavanone]-A(2OH)-B(2OH, 2(C-Prenyl))	Flavanone	Abyssinin III
0.000	[Flavone]-A(2OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OMe)	Flavone	7,8,3',4'-Tetramethoxy-6'',6''-dimethylpyrano[2'',3'':5,6]flavone
0.000	[2'-Hydroxychalcone]-A(2OH, 1(2-hydroxy-3-methyl-3-butenyl))-B(1OH, 1(2-hydroxy-3-methyl-3-butenyl))	2'-Hydroxychalcone	Angusticornin B
0.000	[2'-Hydroxychalcone]-A(2OH, 1(C-Prenyl))-B(1([2,3:@@]-(4-Hydroxy-5-(hydroxyisopropanyl)dihydrofurano)))	2'-Hydroxychalcone	Paratocarpin G
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(5,5-Dimethyl-4-acetoxy-4,5,3a,6a-tetrahydro-furo[2,3-b]furano)))-B(none)	2'-Hydroxychalcone	Tephropurpurin
0.000	[beta-Hydroxy(or Oxodihydro)chalcone]-A(2OH, 1(C-Prenyl))-B(1OH, 1(2-hydroxy-3-methyl-3-butenyl))	beta-Hydroxy(or Oxodihydro)chalcone	Glyinflanin E
0.000	[beta-Hydroxy(or Oxodihydro)chalcone]-A(1OH, 1([2,3:@@]-(5-(hydroxyisopropanyl)dihydrofurano)))-B(1OH, 1(C-Prenyl))	beta-Hydroxy(or Oxodihydro)chalcone	Glyinflanin F
0.000	[Dihydrochalcone]-A(1OH, 1OMe, 1([2,3:@@]-(4-Ispropyl-7-methyl-7-hydroxy-3a,4,5,6,7,7a-hexahydrobenzofurano)))-B(none)	Dihydrochalcone	Adunctin E
0.000	[UBR-type derivative / 2'-Oxocyclohexa-4',6'-dienyl-type Dihydrochalcone]-A(2OH, 1OMe, 2(C-Prenyl))-B(none)	UBR-type derivative / 2'-Oxocyclohexa-4',6'-dienyl-type Dihydrochalcone	Helihumulone
0.000	[Flavanone]-A(2OH, 1Lavandulyl)-B(2OH)	Flavanone	Exiguaflavanone A
0.000	[Flavanone]-A(1OH, 1([2,3:@@]-(6,6-Dimethyl-5-prenyl-4,5-dihydropyrano)))-B(2OH)	Flavanone	Exiguaflavanone L
0.000	[Flavanone]-A(2OH, 1(C-Prenyl), 1(2-hydroxy-3-methyl-3-butenyl))-B(1OH)	Flavanone	Lupiniol A1
0.000	[Flavanone]-A(2OH, 1(C-Prenyl))-B(1OH, 1(2-hydroxy-3-methyl-3-butenyl))	Flavanone	Lupiniol B
0.000	[Flavanone]-A(2OH, 1(C-Prenyl))-B(1OH, 1(3-Methyl-2,3-epoxybutyl))	Flavanone	Flemiflavanone D
0.000	[Flavanone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(5-(hydroxyisopropanyl)dihydrofurano)))-B(1OH)	Flavanone	Lonchocarpol C
0.000	[Flavanone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(5-(hydroxyisopropanyl)dihydrofurano)))-B(1OH)	Flavanone	Lonchocarpol D
0.000	[Flavanone]-A(2OH, 1Geranyl)-B(2OH)	Flavanone	Diplacone
0.000	[Flavanone]-A(2OH)-B(2OH, 1Geranyl)	Flavanone	Propolin D
0.000	[Flavanone]-A(2OH)-B(2OH, 1Geranyl)	Flavanone	Isonymphaeol B
0.000	[Flavanone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethyldihydropyrano)))-B(2OH)	Flavanone	Dorsmanin J
0.000	[Flavanone]-A(2([2,3:@@]-(6,6-Dimethyldihydropyrano)))-B(2OH)	Flavanone	Dorsmanin E
0.000	[Flavanone]-A(2OH, 1(C-Prenyl))-B(2OH, 1(1,1-Dimethylallyl))	Flavanone	2',4'-Dihydroxy-5'-(1'',1''-dimethylallyl)-6-C-prenylpinocembrin
0.000	[Flavanone]-A(2OH, 1(C-Prenyl))-B(2OH, 1(1,1-Dimethylallyl))	Flavanone	5,7,2',4'-Tetrahydroxy-8-prenyl-5'-(1,1-dimethylallyl)flavanone
0.000	[Flavanone]-A(2OH)-B(2OH, 1Geranyl)	Flavanone	Sanggenol A
0.000	[Flavanone]-A(2OH)-B(2OH, 1Geranyl)	Flavanone	5'-Geranylsteppogenin
0.000	[Flavanone]-A(2OH, 1Geranyl)-B(2OH)	Flavanone	Sophoraflavanone C
0.000	[Flavanone]-A(2OH, 1Lavandulyl)-B(2OH)	Flavanone	Kushenol F
0.000	[Flavanone]-A(2OH, 1Lavandulyl)-B(2OH)	Flavanone	Sophoraflavanone G
0.000	[Flavanone]-A(2OH, 1(2-Isopropenyl-5-methyl-5-hexenyl))-B(2OH)	Flavanone	Remangiflavanone B
0.000	[Flavanone]-A(1OH, 1([2,3:@@]-(6,6-Dimethyl-5-prenyl-4,5-dihydropyrano)))-B(2OH)	Flavanone	Leachianone F
0.000	[Dihydroflavonol]-A(2OH, 1Geranyl)-B(1OH)	Dihydroflavonol	Bonanniol A
0.000	[Dihydroflavonol]-A(2OH)-B(1OH, 1(5-Carboxy-2-hydroxyphenyl))	Dihydroflavonol	Hypnum acid
0.000	[Flavonol (3-OMe)]-A(1OMe, 1Methyl, 1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(1OH, 1OMe)	Flavonol	8-C-Methylvelloquercetin 3,5,3'-trimethyl ether
0.000	[Flavan 3-ol]-A(1OH)-B(2OH)	Flavan 3-ol	6-(3,4-Dihydroxyphenyl)-6a,12b-dihydro-3,10,11,12-tetrahydroxy-[2]benzopyrano[3,4-c]benzopyran-8(6H)-one
0.000	[Isoflavanone]-A(2OH, 1Geranyl)-B(2OH)	Isoflavanone	6-Geranyldalbergioidin
0.000	[Isoflavan]-A(1OH, 1OMe, 1(C-Prenyl))-B(2OH, 1(C-Prenyl))	Isoflavan	Licoricidin
0.000	[Rotenone]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OMe)	Rotenone	Erythynone
0.000	[12a-Hydroxyrotenone (3-OMe)]-A(1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(2OMe)	12a-Hydroxyrotenone	12a-Methoxyrotenone
0.000	[6-Hydroxydehydrorotenone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OMe)	6-Hydroxydehydrorotenone	6-Hydroxy-6a,12a-dehydro-alpha-toxicarol

Level: 3, プリカーサーm/z: 519.41711

Splash: splash10-0006-0291000000-f3ac3011a6d2b9d46ec6

m/z	Int.	NL	Rel.Int.
241.04	70	278	1000
243.16	66	276	946
185.10	37	334	524
357.44	15	162	210
203.01	11	316	161
301.14	10	218	144
259.05	8	260	120
463.89	8	56	110

ピーク番号	保持時間 (min)	m/z	m/z差分	ログ強度	アダクト	DB検索結果	ヒット数	MSn	FS3	共有数
	96.16	719.37821	15.9741	1.78	[M+K]+	(3 names) 2alpha,3beta,24,29-tetrahydroxyolean-12-en-28-oic acid 28-O-beta-d-glucopyranside; Beesioside D; (+)-Beesioside D	ALL 2 KN 1 LM 1			2
10541	96.14	703.40408	0.0000	1.52	[M+Na]+	(3 names) 2alpha,3beta,24,29-tetrahydroxyolean-12-en-28-oic acid 28-O-beta-d-glucopyranside; Beesioside D; (+)-Beesioside D	ALL 2 KN 1 LM 1	MS2 MS3 x 2	0.130	4
	96.15	698.44812	-4.9560	2.59	[M+NH4]+	(3 names) 2alpha,3beta,24,29-tetrahydroxyolean-12-en-28-oic acid 28-O-beta-d-glucopyranside; Beesioside D; (+)-Beesioside D	ALL 2 KN 1 LM 1	MS2 MS3		8

ピーク情報

DB検索結果

MSnスペクトル情報

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