ピーク情報

イネ　玄米　コシヒカリ

pos

Peak #3862 MN MID: SE199_S11_M90

m/z: 317.17459, RT: 55.77, 強度: 1026, ログ強度: -0.42, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 2

DB検索結果: (25 names) 6beta-Isobutyryloxy-9,10-didehydrofuranoeremophilan-1-one;Gibberellin A9;Capillartemisin B;Nagilactone F;Antrocinnamomin D;11beta,13-Dihydroxy-3-oxo-13,17-secoandrosta-1,4-dien-17-oic acid, delta-lact...

DBごとのヒット数: ALL 23 KG 6 KN 14 HM 3

FlavonoidSearch最大スコア MS2: 0.182, MS3: -

DB検索結果

ppm

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C19H24O4	316.16746	-0.448	6beta-Isobutyryloxy-9,10-didehydrofuranoeremophilan-1-one	KNApSAcK: C00017435
C19H24O4	316.16746	-0.448	Gibberellin A9	HMDB: HMDB0303451 KEGG: C11863 KNApSAcK: C00000009 LipidMAPS: LMPR0104170020
C19H24O4	316.16746	-0.448	Capillartemisin B	KEGG: C17795, C17789
C19H24O4	316.16746	-0.448	Nagilactone F	KNApSAcK: C00000273
C19H24O4	316.16746	-0.448	Antrocinnamomin D	KNApSAcK: C00038472
C19H24O4	316.16746	-0.448	11beta,13-Dihydroxy-3-oxo-13,17-secoandrosta-1,4-dien-17-oic acid, delta-lactone	KEGG: C15456
C19H24O4	316.16746	-0.448	Isopulegone caffeate	HMDB: HMDB0029566
C19H24O4	316.16746	-0.448	Eurotirumin	KNApSAcK: C00030240
C19H24O4	316.16746	-0.448	Adenostylone	KNApSAcK: C00017424
C19H24O4	316.16746	-0.448	Chaetopyranin	KNApSAcK: C00029928
C19H24O4	316.16746	-0.448	t-Crotonin	KNApSAcK: C00043062
C19H24O4	316.16746	-0.448	Perrottetin C	KNApSAcK: C00015842
C19H24O4	316.16746	-0.448	Ethuliaconyzophenone	KNApSAcK: C00044161
C19H24O4	316.16746	-0.448	1-Dehydro-15alpha-hydroxytestololactone	KEGG: C14946
C19H24O4	316.16746	-0.448	Isoadenostylone	KNApSAcK: C00017421
C19H24O4	316.16746	-0.448	Bisphenol A bis(2-hydroxyethyl)ether	HMDB: HMDB0247634 KEGG: C14347
C19H24O4	316.16746	-0.448	Zaluzanin C isobutyrate	KNApSAcK: C00045462
C19H24O4	316.16746	-0.448	estradiol alone	HMDB: HMDB0251960
C19H24O4	316.16746	-0.448	6beta-(2-Methylacryloyloxy)-9-oxofuranoeremophilane	KNApSAcK: C00017419
C19H24O4	316.16746	-0.448	3,4-dihydroxy-9,10-secoandrosta-1,3,5(10)-triene-9,17-dione	KEGG: C04793 LipidMAPS: LMST02020062
C19H24O4	316.16746	-0.448	Acronyculatin E	KNApSAcK: C00044500
C19H24O4	316.16746	-0.448	[1aR-(1aalpha,4beta,4abeta,5beta,9aS*)]-1a,2,4,4a,5,9-Hexahydro-4,4a,6-trimethyl-3H-oxireno[8,8a]naphtho[2,3-b]furan-5-yl ester 2-methyl-2-propenoic acid	KNApSAcK: C00017320
C20H20N4	316.16880	-4.678	Porphyrinogen	HMDB: HMDB0256709

MSnスペクトル情報

Level: 2, プリカーサーm/z: 317.17462

Splash: splash10-001j-0190000000-640a5bf09e055df70343

m/z	Int.	NL	Rel.Int.
281.23	670	36	1000
299.06	491	18	732
187.14	87	130	130
133.08	42	184	63
271.19	42	46	62
106.98	42	210	62

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.182	[Dihydroflavonol]-A(1OH, 1OMe)-B(1OMe)	Dihydroflavonol	Aromadendrin 7,4'-dimethyl ether
0.182	[Dihydroflavonol]-A(2OMe)-B(1OH)	Dihydroflavonol	Aromadendrin 5,7-dimethyl ether
0.154	[Isoflavanone]-A(1OH)-B(1OH, 2OMe)	Isoflavanone	7,4'-Dihydroxy-3',5'-dimethoxyisoflavanone
0.154	[Isoflavanone]-A(1OH)-B(1OH, 2OMe)	Isoflavanone	Violanone
0.154	[Isoflavanone]-A(1OH)-B(1OH, 2OMe)	Isoflavanone	Lespedeol C
0.154	[Isoflavanone]-A(2OH)-B(2OMe)	Isoflavanone	Homoferreirin
0.154	[Isoflavanone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Isoflavanone	Cajanol
0.154	[Isoflavanone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Isoflavanone	7,4'-Dihydroxy-5,2'-dimethoxyisoflavanone
0.133	[Flavanone]-A(2OH, 1OMe)-B(1OMe)	Flavanone	7,8-Dihydroxy-6,4'-dimethoxyflavanone
0.133	[Flavanone]-A(2OH, 1OMe)-B(1OMe)	Flavanone	5,7-Dihydroxy-8,2'-dimethoxyflavanone
0.133	[Flavanone]-A(2OH, 1OMe)-B(1OMe)	Flavanone	5,7-Dihydroxy-8,4'-dimethoxyflavanone
0.125	[Dihydroflavonol (3-OMe)]-A(1OMe)-B(2OH)	Dihydroflavonol	Fustin 3,7-dimethyl ether
0.125	[Dihydrochalcone]-A(1OH, 3OMe)-B(none)	Dihydrochalcone	2'-Hydroxy-3',4',6'-trimethoxydihydrochalcone
0.111	[Flavonol]-A(3OH)-B(1OMe)	Flavonol	3,5,6,7-Tetrahydroxy-4'-methoxyflavone
0.111	[Flavonol]-A(3OH)-B(1OMe)	Flavonol	Herbacetin 4'-methyl ether
0.095	[Isoflavone]-A(2OH)-B(2OH, 1OMe)	Isoflavone	Junipegenin A
0.095	[Isoflavone]-A(3OH, 1OMe)-B(1OH)	Isoflavone	5,6,7,4'-Tetrahydroxy-8-methoxyisoflavone
0.095	[Isoflavone]-A(3OH)-B(1OH, 1OMe)	Isoflavone	5,6,7,4'-Tetrahydroxy-3'-methoxyisoflavone
0.071	[2'-Hydroxychalcone]-A(3OH, 2OMe)-B(none)	2'-Hydroxychalcone	3',4',6'-Trihydroxy-2',5'-dimethoxychalcone
0.071	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OH, 1OMe)	2'-Hydroxychalcone	2',4',4-Trihydroxy-3',3-methoxychalcone
0.071	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OH, 1OMe)	2'-Hydroxychalcone	3,4',6'-Trihydroxy-4,2'-dimethoxychalcone
0.071	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OH, 1OMe)	2'-Hydroxychalcone	4,2',6'-Trihydroxy-3,4'-dimethoxychalcone
0.071	[2'-Hydroxychalcone]-A(3OH)-B(2OMe)	2'-Hydroxychalcone	Okanin 3,4-dimethyl ether
0.063	[Flavanone]-A(2OH)-B(2OMe)	Flavanone	Eriodictyol 3',4'-dimethyl ether
0.063	[Flavanone]-A(1OH, 2OMe)-B(1OH)	Flavanone	5,4'-Dihydroxy-6,7-dimethoxyflavanone
0.063	[Flavanone]-A(1OH, 2OMe)-B(1OH)	Flavanone	Dihydroskullcap flavone I
0.063	[Flavanone]-A(1OH, 2OMe)-B(1OH)	Flavanone	5,4'-Dihydroxy-7,8-dimethoxyflavanone
0.063	[Flavanone]-A(2OH, 2OMe)-B(none)	Flavanone	Didymocarpin A
0.063	[Flavanone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavanone	7,4'-Dihydroxy-8,3'-dimethoxyflavanone
0.063	[Flavanone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavanone	5,2'-Dihydroxy-7,5'-dimethoxyflavanone
0.063	[Flavanone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavanone	5,3'-Dihydroxy-7,2'-dimethoxyflavanone
0.063	[Flavanone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavanone	Eriodictyol 5,4'-dimethyl ether
0.063	[Flavanone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavanone	Eriodictyol 7,3'-dimethyl ether
0.063	[Flavanone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavanone	Persicogenin
0.063	[Flavanone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavanone	5,2'-Dihydroxy-7,4'-dimethoxyflavanone
0.059	[Anthocyanidin]-A(2OH)-B(2OH, 1OMe)	Anthocyanidin	Petunidin
0.059	[Anthocyanidin]-A(1OH, 1OMe)-B(3OH)	Anthocyanidin	Pulchellidin
0.053	[Flavonol]-A(1OH, 1OMe)-B(2OH)	Flavonol	7-Methoxy-3,6,3',4'-tetrahydroxyflavone
0.053	[Flavonol]-A(1OH, 1OMe)-B(2OH)	Flavonol	3,7,3',4'-Tetrahydroxy-8-methoxyflavone
0.053	[Flavonol]-A(1OH, 1OMe)-B(2OH)	Flavonol	Azaleatin
0.053	[Flavonol]-A(1OH, 1OMe)-B(2OH)	Flavonol	Rhamnetin
0.053	[Flavonol]-A(2OH, 1OMe)-B(1OH)	Flavonol	Vogeletin
0.053	[Flavonol]-A(2OH, 1OMe)-B(1OH)	Flavonol	6-Methoxykaempferol
0.053	[Flavonol]-A(2OH, 1OMe)-B(1OH)	Flavonol	3,5,6,4'-Tetrahydroxy-7-methoxyflavone
0.053	[Flavonol]-A(2OH, 1OMe)-B(1OH)	Flavonol	3,5,8,2'-Tetrahydroxy-7-methoxyflavone
0.053	[Flavonol]-A(2OH, 1OMe)-B(1OH)	Flavonol	Pollenitin
0.053	[Flavonol]-A(2OH, 1OMe)-B(1OH)	Flavonol	Sexangularetin
0.053	[Flavonol]-A(2OH)-B(1OH, 1OMe)	Flavonol	3'-O-Methylmelanoxetin
0.053	[Flavonol]-A(2OH)-B(1OH, 1OMe)	Flavonol	Isorhamnetin
0.053	[Flavonol]-A(2OH)-B(1OH, 1OMe)	Flavonol	Tamarixetin
0.053	[Flavonol]-A(2OH)-B(1OH, 1OMe)	Flavonol	Milimorin
0.000	[Flavone]-A(2OH)-B(2OH, 1OMe)	Flavone	Tricetin 3'-methyl ether
0.000	[Flavone]-A(2OH)-B(2OH, 1OMe)	Flavone	Tricetin 4'-methyl ether
0.000	[Flavone]-A(1OH, 1OMe)-B(3OH)	Flavone	Tricetin 7-methyl ether
0.000	[Flavone]-A(3OH)-B(1OH, 1OMe)	Flavone	Nodifloretin
0.000	[Flavone]-A(3OH)-B(1OH, 1OMe)	Flavone	6-Hydroxyluteolin 4'-methyl ether
0.000	[Flavone]-A(2OH, 1OMe)-B(2OH)	Flavone	Carajuflavone
0.000	[Flavone]-A(2OH, 1OMe)-B(2OH)	Flavone	Nepetin
0.000	[Flavone]-A(2OH, 1OMe)-B(2OH)	Flavone	Pedalitin
0.000	[Flavone]-A(3OH)-B(1OH, 1OMe)	Flavone	Hypolaetin 3'-methyl ether
0.000	[Flavone]-A(3OH)-B(1OH, 1OMe)	Flavone	Hypolaetin 4'-methyl ether
0.000	[Flavone]-A(2OH, 1OMe)-B(2OH)	Flavone	Onopordin
0.000	[Dihydrochalcone]-A(1OH, 2OMe)-B(1OMe)	Dihydrochalcone	Flavokawin A
0.000	[Dihydrochalcone]-A(none)-B(1OH, 3OMe)	Dihydrochalcone	2-Hydroxy-3,4,6-trimethoxydihydrochalcone
0.000	[Dihydrochalcone]-A(none)-B(1OH, 3OMe)	Dihydrochalcone	2-Hydroxy-4,5,6-trimethoxydihydrochalcone
0.000	[Dihydrochalcone]-A(3OMe)-B(1OH)	Dihydrochalcone	4-Hydroxy-2',4',6'-trimethoxydihydrochalcone
0.000	[Dihydrochalcone]-A(1OH)-B(3OMe)	Dihydrochalcone	Loureirin B
0.000	[Pterocarpan]-A(1OH)-B(1OH, 2OMe)	Pterocarpan	Philenopteran
0.000	[Pterocarpan]-A(1OH, 1OMe)-B(1OH, 1OMe)	Pterocarpan	2,8-Dihydroxy-3,9-dimethoxypterocarpan
0.000	[Pterocarpan]-A(1OH, 1OMe)-B(1OH, 1OMe)	Pterocarpan	Mucronucarpan
0.000	[Pterocarpan]-A(1OH, 1OMe)-B(1OH, 1OMe)	Pterocarpan	Nissolicarpin
0.000	[Pterocarpan]-A(1OH, 1OMe)-B(1OH, 1OMe)	Pterocarpan	Melilotocarpan D
0.000	[Pterocarpan]-A(1OH, 1OMe)-B(1OH, 1OMe)	Pterocarpan	Melilotocarpan E
0.000	[Aurone]-A(1OH, 1OMe)-B(3OH)	Aurone	Bracteatin 4-Methyl ether
0.000	[Dihydrochalcone]-A(2OH, 1OMe, 2Methyl)-B(1OH)	Dihydrochalcone	4,2',6'-Trihydroxy-4'-methoxy-3',5'-dimethyldihydrochalcone
0.000	[Dihydrochalcone]-A(2OH, 1OMe)-B(1([@@]-Methylenedioxy))	Dihydrochalcone	2',4'-Dihydroxy-6'-methoxy-3,4-methylenedioxydihydrochalcone
0.000	[Dihydrochalcone alpha-ol]-A(2OMe)-B(1OMe)	Dihydrochalcone alpha-ol	O-Methylodoratol
0.000	[Flavanone]-A(1OH, 1OMe, 1Methyl)-B(2OH)	Flavanone	7,3',4'-Trihydroxy-5-methoxy-6-C-methylflavanone
0.000	[Flavanone]-A(2OH, 2Methyl)-B(2OH)	Flavanone	Cyrtominetin
0.000	[Flavanone]-A(1OH, 1([@@]-Methylenedioxy))-B(2OH)	Flavanone	5,2',3'-Trihydroxy-6,7-methylenedioxyflavanone
0.000	[2-Hydroxyflavanone]-A(1OH, 2OMe, 1Methyl)-B(none)	2-Hydroxyflavanone	Mosloflavanone
0.000	[Dihydroflavonol]-A(2OH, 1Methyl)-B(1OMe)	Dihydroflavonol	3,5,7-Trihydroxy-4'-methoxy-6-methylflavanone
0.000	[Dihydroflavonol]-A(1OH, 1OMe, 1Methyl)-B(1OH)	Dihydroflavonol	3,7,4'-Trihydroxy-5-methoxy-6-methylflavanone
0.000	[CCS-type derivative / [3,2']-Epoxymethanodihydroflavanone]-A(2OH)-B(2OH)	CCS-type derivative / [3,2']-Epoxymethanodihydroflavanone	Crombeone
0.000	[Flavonol (3-OMe)]-A(2OH)-B(2OH)	Flavonol	3-Methoxy-6,7,3',4'-tetrahydroxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH)-B(2OH)	Flavonol	Transilitin
0.000	[Flavonol (3-OMe)]-A(2OH)-B(2OH)	Flavonol	Quercetin 3-methyl ether
0.000	[Flavonol]-A(2OH, 1Methyl)-B(2OH)	Flavonol	Pinoquercetin
0.000	[Flavonol]-A(2OH, 1Methyl)-B(2OH)	Flavonol	8-C-Methylquercetin
0.000	[Flavonol (3-OMe)]-A(3OH)-B(1OH)	Flavonol	5,6,7,4'-Tetrahydroxy-3-methoxyflavone
0.000	[Flavonol (3-OMe)]-A(3OH)-B(1OH)	Flavonol	3-Methylherbacetin
0.000	[Flavan 4-ol]-A(2OMe)-B(1OMe)	Flavan 4-ol	4-Hydroxy-5,7,4'-trimethoxyflavan
0.000	[Flavan 4-ol]-A(2OH, 2Methyl)-B(1OMe)	Flavan 4-ol	4,5,7-Trihydroxy-4'-methoxy-6,8-dimethylflavan
0.000	[CCS-type derivative / [3,2']-Epoxymethanoflavan 4-ol]-A(1OMe)-B(2OH)	CCS-type derivative / [3,2']-Epoxymethanoflavan 4-ol	7-O-Methylpeltogynol
0.000	[Flavan]-A(1OH, 1OMe)-B(2OMe)	Flavan	2-(3,5-Dimethoxyphenyl)-3,4-dihydro-7-methoxy-2H-1-benzopyran-5-ol
0.000	[Flavan]-A(1OH, 1OMe)-B(2OMe)	Flavan	5-Hydroxy-7,3',4'-trimethoxyflavan
0.000	[Flavan]-A(2OMe)-B(1OH, 1OMe)	Flavan	4'-Hydroxy-5,7,3'-trimethoxyflavan
0.000	[Isoflavanone]-A(1OH, 1OMe, 1Methyl)-B(2OH)	Isoflavanone	Ougenin
0.000	[UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavan]-A(1OH)-B(2OMe)	UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavan	Pendulone
0.000	[UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavan]-A(1OH, 1OMe)-B(1OMe)	UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavan	Mucroquinone
0.000	[isoflavan-4-ol]-A(1OH, 1OMe, 1([@@]-Methylenedioxy))-B(none)	isoflavan-4-ol	Lapathinol
0.000	[isoflavene]-A(2OH)-B(1OH, 2OMe)	isoflavene	6,7,3'-Trihydroxy-2',4'-dimethoxyisoflavene
0.000	[Pterocarpan-6a-ol]-A(1OH)-B(1OH, 1([@@]-Methylenedioxy))	Pterocarpan-6a-ol	6a,7-Dihydroxymaackiain
0.000	[12a-Hydroxyrotenone]-A(2OH)-B(1OH)	12a-Hydroxyrotenone	4,9,11,12a-Tetrahydroxyrotenoid
0.000	[4-phenylcoumarin]-A(1OH, 1OMe)-B(3OH)	4-phenylcoumarin	5,2',4',5'-Tetrahydroxy-7-methoxy-4-phenylcoumarin
0.000	[Dalbergiquinol]-A(1OH, 3OMe)-B(1OH)	Dalbergiquinol	Kuhlmanniquinol

Level: 3, プリカーサーm/z: 281.17789

Splash: splash10-000i-0900000000-7fc7aafe4a88cb28e965

m/z	Int.	NL	Rel.Int.
187.16	215	94	1000
133.06	105	148	490
147.00	105	134	487
263.20	30	18	140
106.96	19	174	87
161.13	16	120	74