ピーク情報
|
パセリ 葉
pos
|
| Peak #11378 MN MID: SE61_S21_M90 |
| m/z: 435.28986, RT: 103.79, 強度: 90813, ログ強度: 1.37, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 9 |
| DB検索結果: |
| DBごとのヒット数: |
| FlavonoidSearch最大スコア MS2: 0.042, MS3: 0.034 |
DB検索結果
ppm
ヒットなし
MSnスペクトル情報
| Level: 2, プリカーサーm/z: 435.28983 |
| Splash: splash10-014j-0396700000-b60e9d16a04fc65bcc6e |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 417.26 | 5506 | 18 | 1000 |
| 399.36 | 1741 | 36 | 316 |
| 377.35 | 1397 | 58 | 253 |
| 233.18 | 1260 | 202 | 228 |
| 299.25 | 991 | 136 | 179 |
| 167.13 | 962 | 268 | 174 |
| 159.04 | 945 | 276 | 171 |
| 295.12 | 687 | 140 | 124 |
| 209.22 | 597 | 226 | 108 |
| 235.14 | 556 | 200 | 100 |
| 359.37 | 553 | 76 | 100 |
| 289.26 | 540 | 146 | 98 |
| 277.16 | 537 | 158 | 97 |
| 223.11 | 494 | 212 | 89 |
| 343.24 | 479 | 92 | 86 |
| 249.04 | 431 | 186 | 78 |
| 301.29 | 429 | 134 | 77 |
| 195.10 | 424 | 240 | 76 |
| 215.10 | 416 | 220 | 75 |
| 197.17 | 413 | 238 | 75 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.036 | [2'-Hydroxychalcone]-A(1OH, 3OMe)-B(4OMe) | 2'-Hydroxychalcone | 6'-Hydroxy-2,3,4,5,2',3',4'-heptamethoxychalcone |
| 0.033 | [Flavanone]-A(3OMe)-B(4OMe) | Flavanone | 5,6,7,2',3',4',5'-Heptamethoxyflavanone |
| 0.033 | [Flavanone]-A(4OMe)-B(3OMe) | Flavanone | 5,6,7,8,3',4',5'-Heptamethoxyflavanone |
| 0.000 | [Flavone]-A(1OH, 3OMe)-B(1OH, 3OMe) | Flavone | Agehoustin D |
| 0.000 | [beta-Hydroxy(or Oxodihydro)chalcone]-A(3OMe)-B(4OMe) | beta-Hydroxy(or Oxodihydro)chalcone | beta-Hydroxy-2,3,4,5,2',4',5'-heptamethoxychalcone |
| 0.000 | [Flavanone]-A(1OH, 1(C-Galactosyl))-B(2OH) | Flavanone | Palodulcin B |
| 0.000 | [Flavanone]-A(2OH, 1(C-Glu))-B(1OH) | Flavanone | Hemiphloin |
| 0.000 | [Flavanone]-A(2OH, 1(C-Glu))-B(1OH) | Flavanone | Isohemiphloin |
| 0.000 | [Flavone]-A(2OH)-B(1([2,3:@@]-(5-Hydroxymethyl-6-(p-hydroxyphenyl)-dihydro[1,4]dioxinyl))) | Flavone | Sinaticin |
| 0.000 | [CCS-type derivative / [2',3]-Prenyloxidoflavone]-A(2OH, 1(3-Methyl-1-butenyl))-B(1OMe) | CCS-type derivative / [2',3]-Prenyloxidoflavone | Cycloartocarpin A |
| 0.000 | [CCS-type derivative / [2',3]-Prenyloxidoflavone]-A(1OH, 1OMe, 1(C-Prenyl))-B(1OH) | CCS-type derivative / [2',3]-Prenyloxidoflavone | Cycloartocarpin |
| 0.000 | [CCS-type derivative / [2',3]-Isopropenylethanoflavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(3OH) | CCS-type derivative / [2',3]-Isopropenylethanoflavone | Artobiloxanthone |
| 0.000 | [CCS-type derivative / [2,2a,5:3',2',3]-7,7-Dimethyltetrahydroisobenzofuranoflavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OH) | CCS-type derivative / [2,2a,5:3',2',3]-7,7-Dimethyltetrahydroisobenzofuranoflavone | Cycloartobiloxanthone |
| 0.000 | [Flavonol (3-OMe)]-A(1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OH) | Flavonol | Macaflavone II |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1(1-(p-Hydroxyphenyl)ethyl))-B(1OMe) | Flavonol | Haplopappin |
| 0.000 | [Flavonol]-A(1OH, 1OMe, 1(1-(p-Hydroxyphenyl)ethyl))-B(1OMe) | Flavonol | Haplopappin A |
| 0.000 | [Flavonol (3-OMe)]-A(4OMe)-B(2OH, 1OMe) | Flavonol | 3',5'-Dihydroxy-3,5,6,7,8,4'-hexamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 3OMe)-B(1OH, 2OMe) | Flavonol | Digicitrin |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 2OMe)-B(3OMe) | Flavonol | 5,7-Dihydroxy-3,6,8,3',4',5'-hexamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 3OMe)-B(1OH, 2OMe) | Flavonol | 5,2'-Dihydroxy-3,6,7,8,4',5'-hexamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 2OMe)-B(3OMe) | Flavonol | 5,7-Dihydroxy-3,6,8,2',4',5'-hexamethoxyflavone |
| 0.000 | [Isoflavone]-A(1([2,3:@@]-(6,6-Dimethyl-5-hydroxydihydropyrano)))-B(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano))) | Isoflavone | Mundulone |
| 0.000 | [Isoflavone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH, 1OMe) | Isoflavone | Auriculin |
| 0.000 | [4-Hydroxy-3-phenylcoumarin]-A(1OMe, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH) | 4-Hydroxy-3-phenylcoumarin | Scandenin |
| 0.000 | [4-Hydroxy-3-phenylcoumarin]-A(1OMe, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH) | 4-Hydroxy-3-phenylcoumarin | Lonchocarpic acid |
| Level: 3, プリカーサーm/z: 417.31165 |
| Splash: splash10-052b-0049000000-32c9fa8292860cffa1aa |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 399.44 | 346 | 18 | 1000 |
| 359.37 | 152 | 58 | 438 |
| 259.06 | 100 | 158 | 288 |
| 375.42 | 91 | 42 | 262 |
| 315.33 | 76 | 102 | 219 |
| 233.15 | 68 | 184 | 197 |
| 343.04 | 68 | 74 | 195 |
| 281.16 | 67 | 136 | 193 |
| 261.29 | 64 | 156 | 184 |
| 366.52 | 53 | 51 | 152 |
| 267.13 | 52 | 150 | 150 |
| 273.07 | 51 | 144 | 146 |
| 253.31 | 47 | 164 | 136 |
| 341.32 | 47 | 76 | 135 |
| 329.38 | 46 | 88 | 134 |
| 349.20 | 46 | 68 | 133 |
| 274.97 | 44 | 142 | 126 |
| 373.79 | 42 | 44 | 120 |
| 325.30 | 41 | 92 | 118 |
| 303.15 | 41 | 114 | 117 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.152 | [Isoflavone]-A(1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano))) | Isoflavone | Munetone |
| 0.040 | [Flavone]-A(1OH, 1(C-Glu))-B(1OH) | Flavone | Bayin |
| 0.040 | [Flavone]-A(2OH, 1(C-Glu))-B(none) | Flavone | Chrysin 6-C-beta-D-glucopyranoside |
| 0.040 | [Flavone]-A(2OH, 1(C-Glu))-B(none) | Flavone | Chrysin 8-C-beta-D-glucopyranoside |
| 0.040 | [Isoflavone]-A(1OH, 1(C-Glu))-B(1OH) | Isoflavone | 8-Glucosyldaidzein |
| 0.000 | [Flavone]-A(1OH, 1OMe, 1(C-Arabinosyl))-B(1OH) | Flavone | Isomolludistin |
| 0.000 | [Flavone]-A(1OH, 1OMe, 1(C-Arabinosyl))-B(1OH) | Flavone | Molludistin |
| 0.000 | [Flavone]-A(2OH, 1(C-Rhamnosyl))-B(1OH) | Flavone | Isofurcatain |
| 0.000 | [Flavone]-A(4OMe)-B(1OMe, 1([@@]-Methylenedioxy)) | Flavone | Eupalestin |
| 0.000 | [Flavonol]-A(1OH, 1([2,3:@@]-(4-(p-Hydroxyphenyl)-6-oxodihydropyrano)))-B(1OH) | Flavonol | Calomelanol D |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1OMe)-B(1OH, 1(3-hydroxy-3-methylbutyl)) | Flavonol | Aliarin |
| 0.000 | [Flavonol]-A(1OH, 2OMe)-B(1OH, 1(4-hydroxy-3-methylbutyl)) | Flavonol | 3,7-Dihydroxy-2-[4-hydroxy-3-(4-hydroxy-3-methylbutyl)phenyl]-5,6-dimethoxy-4H-1-benzopyran-4-one |
| 0.000 | [Flavonol (3-OMe)]-A(4OMe)-B(1([@@]-Methylenedioxy)) | Flavonol | Melibentin |
| 0.000 | [Flavonol (3-OMe)]-A(2OMe, 1([@@]-Methylenedioxy))-B(2OMe) | Flavonol | Melicophyllin |
| 0.000 | [6-Hydroxyrotenone]-A(1OH, 1OMe)-B(2OMe)-C(1(O-Acetyl)) | 6-Hydroxyrotenone | Dihydrostemonal 6-O-acetate |
| 0.000 | [4-phenylcoumarin]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)), 1Tiglyl)-B(none) | 4-phenylcoumarin | Apetalolide |
| Level: 3, プリカーサーm/z: 399.29889 |
| Splash: splash10-05i4-0298000000-902ca6d01f6507e01b42 |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 341.35 | 86 | 58 | 1000 |
| 357.38 | 81 | 42 | 942 |
| 299.41 | 58 | 100 | 670 |
| 273.23 | 53 | 126 | 619 |
| 329.14 | 45 | 70 | 523 |
| 315.26 | 43 | 84 | 493 |
| 381.38 | 38 | 18 | 434 |
| 221.39 | 36 | 178 | 420 |
| 287.55 | 33 | 112 | 386 |
| 275.19 | 33 | 124 | 383 |
| 265.23 | 28 | 134 | 319 |
| 251.23 | 27 | 148 | 318 |
| 143.44 | 22 | 256 | 255 |
| 149.30 | 21 | 250 | 237 |
| 161.27 | 20 | 238 | 236 |
| 263.21 | 18 | 136 | 209 |
| 343.47 | 17 | 56 | 201 |
| 223.58 | 16 | 176 | 190 |
| 173.30 | 14 | 226 | 162 |
| 293.27 | 14 | 106 | 157 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.250 | [Isoflavone]-A(2OH)-B(1OH, 2OMe, 1(C-Prenyl)) | Isoflavone | 2'-Hydroxypiscerythrinetin |
| 0.222 | [Isoflavone]-A(2OH, 1(C-Prenyl))-B(1OH, 2OMe) | Isoflavone | Viridiflorin |
| 0.139 | [Flavonol]-A(1OH, 1OMe, 1(C-Prenyl))-B(1OH, 1OMe) | Flavonol | Isorhynchospermin |
| 0.139 | [Flavonol]-A(1OH, 1OMe, 1(C-Prenyl))-B(1OH, 1OMe) | Flavonol | Rhynchospermin |
| 0.071 | [Flavone]-A(2OH, 1(C-Prenyl))-B(1OH, 2OMe) | Flavone | Baohuosu |
| 0.000 | [Flavone]-A(1OH, 1OMe, 1(4,5-Dihydroxy-6-methyltetrahydropyran-2-yl))-B(none) | Flavone | Hoslunddiol |
| 0.000 | [3-substituted Flavone (3-C-Prenyl)]-A(1OH, 1OMe)-B(2OH, 1OMe) | 3-substituted Flavone | Artoindonesianin Q |
| 0.000 | [3-substituted Flavone (3-C-Prenyl)]-A(2OH)-B(1OH, 2OMe) | 3-substituted Flavone | Artoindonesianin R |
| 0.000 | [Dihydroflavonol (3-OMe)]-A(2OMe, 1([2,3:@@]-Furano))-B(1([@@]-Methylenedioxy)) | Dihydroflavonol | 3,5,6-Trimethoxy-3',4'-methylene-dioxyfurano[2'',3'':7,8]flavanone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 1OMe, 1(C-Prenyl))-B(2OH) | Flavonol | 5,3',4'-Trihydroxy-3,7-dimethoxy-6-prenylflavone |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1OMe, 1(C-Prenyl))-B(1OH) | Flavonol | 5,7,4'-Trihydroxy-3,8-dimethoxy-6-prenylflavone |
| 0.000 | [Flavan 3,4-diol]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH) | Flavan 3,4-diol | 3beta,4beta,5-Trimethoxy-4'-hydroxy- (6:7)-2,2-dimethylpyranoflavan |
| 0.000 | [CCS-type derivative / [2,3,4:5,4a,4]-(6-Carboxypyrano)anthocyanidin]-A(1OH)-B(1OH, 2OMe) | CCS-type derivative / [2,3,4:5,4a,4]-(6-Carboxypyrano)anthocyanidin | 5-Carboxypyranomalvidin |
| 0.000 | [Pterocarpan-6a-ol]-A(1OMe)-B(2OMe, 1(C-Prenyl)) | Pterocarpan-6a-ol | Sphenostylin A |