ピーク情報
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パセリ 葉
pos
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| Peak #10321 MN MID: SE61_S21_M90 |
| m/z: 477.15457, RT: 94.70, 強度: 21808, ログ強度: 0.75, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 2 |
| DB検索結果: (2 names) Guangsangon L;(-)-Guangsangon L |
| DBごとのヒット数: ALL 1 KN 1 |
| FlavonoidSearch最大スコア MS2: 0.115, MS3: - |
DB検索結果
ppm
| 組成式 | 分子量 | 誤差(Δppm） | 候補化合物名（代表で最短名を記載） | 化合物ID |
|---|---|---|---|---|
| C27H24O8 | 476.14712 | 0.372 | Guangsangon L | KNApSAcK: C00031834 |
MSnスペクトル情報
| Level: 2, プリカーサーm/z: 477.15384 |
| Splash: splash10-0002-0563900000-7fdc0216d52e875bb0d2 |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 449.25 | 5855 | 28 | 1000 |
| 163.03 | 2811 | 314 | 480 |
| 287.20 | 2629 | 190 | 448 |
| 299.18 | 1615 | 178 | 275 |
| 315.17 | 1060 | 162 | 181 |
| 459.40 | 1047 | 18 | 178 |
| 393.24 | 950 | 84 | 162 |
| 191.11 | 820 | 286 | 140 |
| 392.32 | 667 | 85 | 113 |
| 173.05 | 571 | 304 | 97 |
| 217.10 | 525 | 260 | 89 |
| 215.16 | 480 | 262 | 81 |
| 391.15 | 381 | 86 | 65 |
| 245.18 | 369 | 232 | 63 |
| 458.68 | 351 | 18 | 59 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.115 | [Flavanone]-A(2OH, 2(C-Prenyl))-B(1OH, 1(C-Prenyl)) | Flavanone | Amorilin |
| 0.074 | [Flavanone]-A(2OH, 1(C-Prenyl))-B(1OH, 2(C-Prenyl)) | Flavanone | Hydroxysophoranone |
| 0.050 | [Flavone]-A(1OH, 1OMe, 1(C-Glu))-B(1OH, 1OMe) | Flavone | Isoorientin 7,3'-dimethyl ether |
| 0.050 | [Flavone]-A(1OH, 1OMe, 1(C-Glu))-B(1OH, 1OMe) | Flavone | 6-C-Glucopyranosylpilloin |
| 0.050 | [Flavone]-A(2OMe, 1(C-Glu))-B(2OH) | Flavone | Parkinsonin B |
| 0.050 | [Flavone]-A(1OH, 1OMe, 1(C-Glu))-B(1OH, 1OMe) | Flavone | Orientin 7,3'-dimethyl ether |
| 0.050 | [Flavone]-A(1OH, 2OMe, 1(C-Glu))-B(1OH) | Flavone | Abrusin |
| 0.050 | [Flavone]-A(1OH, 2OMe, 1(C-Glu))-B(1OH) | Flavone | Precatorin I |
| 0.050 | [Isoflavone]-A(2OH, 1OMe, 1(C-Glu))-B(1OMe) | Isoflavone | Volubilinin |
| 0.043 | [Dihydroflavonol]-A(1OH, 1(C-Prenyl))-B(1OH, 2(C-Prenyl)) | Dihydroflavonol | 8,3',5'-Triprenylgarbanzol |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1(C-Rhamnosyl))-B(1OH, 1OMe) | Flavonol | 5,7,3'-Trihydroxy-3,4'-dimethoxyflavone 8-C-rhamnopyranoside |
| 0.000 | [CCS-type derivative / [2,3,4:5,4a,4]-(6-Phenylpyrano)anthocyanidin (4'-Hydroxy-3'-methoxy)]-A(1OH)-B(1OH, 2OMe) | CCS-type derivative / [2,3,4:5,4a,4]-(6-Phenylpyrano)anthocyanidin | Malvidin 4-vinylguaiacol |
| 0.000 | [Isoflavanone]-A(2OH, 1(C-Prenyl))-B(1OH, 1Geranyl) | Isoflavanone | Sophoraisoflavanone C |
| 0.000 | [UBR-type derivative / 7-Oxocyclohexa-5,8a-dienyl-type 4-Phenylcoumarin]-A(1OH, 2(C-Prenyl), 1(2-Methylbutyroyl))-B(none) | UBR-type derivative / 7-Oxocyclohexa-5,8a-dienyl-type 4-Phenylcoumarin | Calofloride |
| Level: 3, プリカーサーm/z: 449.25153 |
| Splash: splash10-0300-0029300000-69173c1951b6203724c2 |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 364.20 | 399 | 85 | 1000 |
| 365.27 | 370 | 84 | 926 |
| 421.17 | 364 | 28 | 911 |
| 363.17 | 256 | 86 | 641 |
| 349.22 | 220 | 100 | 549 |
| 215.10 | 186 | 234 | 466 |
| 431.28 | 180 | 18 | 451 |
| 331.10 | 149 | 118 | 373 |
| 337.27 | 127 | 112 | 317 |
| 417.22 | 118 | 32 | 294 |
| 216.97 | 113 | 232 | 281 |
| 189.07 | 84 | 260 | 209 |
| 335.32 | 80 | 114 | 199 |
| 333.05 | 72 | 116 | 179 |
| 336.13 | 71 | 113 | 178 |
| 377.18 | 69 | 72 | 171 |
| 175.12 | 65 | 274 | 163 |
| 273.18 | 61 | 176 | 152 |
| 235.12 | 55 | 214 | 138 |
| 319.26 | 55 | 130 | 138 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.107 | [Chalcone]-A(4OMe)-B(4OMe) | Chalcone | 2,3,4,5,2',3',4',6'-Octamethoxychalcone |
| 0.040 | [Flavone]-A(2OH, 1(C-Glu))-B(2OH) | Flavone | Isoorientin |
| 0.040 | [Flavone]-A(2OH, 1(C-Glu))-B(2OH) | Flavone | Orientin |
| 0.040 | [Flavonol]-A(1OH, 1(C-Glu))-B(2OH) | Flavonol | Fisetin 8-C-glucoside |
| 0.040 | [Flavonol]-A(2OH, 1(C-Glu))-B(1OH) | Flavonol | 6-C-Glucopyranosylkaempferol |
| 0.040 | [Flavonol]-A(2OH, 1(C-Glu))-B(1OH) | Flavonol | 8-C-beta-D-Glucopyranosylkaempferol |
| 0.040 | [Isoflavone]-A(2OH, 1(C-Glu))-B(2OH) | Isoflavone | 6-C-Glucosylorobol |
| 0.040 | [Isoflavone]-A(2OH, 1(C-Glu))-B(2OH) | Isoflavone | 8-C-Glucosylorobol |
| 0.040 | [Anthocyanidin]-A(2OH, 1(C-Glu))-B(2OH) | Anthocyanidin | 8-C-Glucosylcyanidin |
| 0.000 | [Flavone]-A(4OMe)-B(1OH, 3OMe) | Flavone | Agehoustin C |
| 0.000 | [Flavone]-A(2OH, 1(C-Galactosyl))-B(2OH) | Flavone | 6-C-Galactosylluteolin |
| 0.000 | [Flavone]-A(2OH, 1(C-Galactosyl))-B(2OH) | Flavone | 8-C-Galactosylluteolin |
| 0.000 | [Flavone]-A(3OH, 1(C-Galactosyl))-B(1OH) | Flavone | 6-C-Galactosylisoscutellarein |
| 0.000 | [CCS-type derivative / [2',3]-Prenyloxidoflavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH, 1OMe) | CCS-type derivative / [2',3]-Prenyloxidoflavone | Cycloartomunin |
| 0.000 | [CCS-type derivative / [2',3]-Isopropenylethanoflavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OH, 1OMe) | CCS-type derivative / [2',3]-Isopropenylethanoflavone | Artomunoxanthone |
| 0.000 | [CCS-type derivative / [2',3]-Isopropenylethanoflavone]-A(1OH, 1OMe)-B(2OH, 1([2,3:@@]-(6,6-Dimethylpyrano))) | CCS-type derivative / [2',3]-Isopropenylethanoflavone | Artonol E |
| 0.000 | [CCS-type derivative / [2,2a,5:3',2',3]-7,7-Dimethyltetrahydroisobenzofuranoflavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH, 1OMe) | CCS-type derivative / [2,2a,5:3',2',3]-7,7-Dimethyltetrahydroisobenzofuranoflavone | Cycloartomunoxanthone |
| 0.000 | [UBR-type derivative / 3',6'-Oxo-4'-enyl-[1',2']-epoxy-type [2',3]-Isopropenylethanoflavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH) | UBR-type derivative / 3',6'-Oxo-4'-enyl-[1',2']-epoxy-type [2',3]-Isopropenylethanoflavone | Artonin P |
| 0.000 | [Flavonol (3-OMe)]-A(4OMe)-B(1OH, 2OMe) | Flavonol | 3'-Hydroxy-3,5,6,7,8,4',5'-heptamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 3OMe)-B(3OMe) | Flavonol | 5-Hydroxy-3,6,7,8,3',4',5'-heptamethoxyflavone |
| 0.000 | [4-Hydroxy-3-phenylcoumarin]-A(1OMe, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OMe) | 4-Hydroxy-3-phenylcoumarin | Lonchocarpenin |