ピーク情報
|
（しょうが類） しょうが 根茎 生
pos
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| Peak #5361 MN MID: SE115_S061031_M90 |
| m/z: 405.21206, RT: 53.49, 強度: 138173, ログ強度: 1.67, アダクト: [M+CH3OH+Na]+, [M+Na]+, 共有数（同様のピークを含むサンプル数）: 1 |
| DB検索結果: |
| DBごとのヒット数: |
| FlavonoidSearch最大スコア MS2: 0.188, MS3: 0.154 |
DB検索結果
ppm
ヒットなし
MSnスペクトル情報
| Level: 2, プリカーサーm/z: 405.21146 |
| Splash: splash10-000i-0593000000-42d6d57f465a52d44bf8 |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 288.89 | 5526 | 116 | 1000 |
| 270.94 | 4012 | 134 | 726 |
| 126.98 | 3777 | 278 | 683 |
| 303.05 | 3022 | 102 | 546 |
| 186.97 | 2248 | 218 | 406 |
| 387.06 | 905 | 18 | 163 |
| 253.05 | 583 | 152 | 105 |
| 144.81 | 532 | 260 | 96 |
| 369.29 | 304 | 36 | 54 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.188 | [Flavanone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1([2,3:@@]-(6,6-Dimethylpyrano))) | Flavanone | Euchrenone a1 |
| 0.125 | [Dihydroflavonol]-A(1([2,3:@@]-(6,6-Dimethylpyrano)))-B(none) | Dihydroflavonol | MS II |
| 0.111 | [Flavanone]-A(3OMe)-B(3OMe) | Flavanone | 5,6,7,3',4',5'-Hexamethoxyflavanone |
| 0.100 | [2'-Hydroxychalcone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano))) | 2'-Hydroxychalcone | Glyinflanin G |
| 0.059 | [Chalcone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH) | Chalcone | Laxichalcone |
| 0.000 | [Flavone]-A(1OH, 2OMe)-B(1OH, 3OMe) | Flavone | Psiadiarabicin |
| 0.000 | [Flavone]-A(1OH, 3OMe)-B(1OH, 2OMe) | Flavone | Gardenin C |
| 0.000 | [Flavone]-A(1OH, 3OMe)-B(1OH, 2OMe) | Flavone | 5,4'-Dihydroxy-6,7,8,3',5'-pentamethoxyflavone |
| 0.000 | [Flavone]-A(1OH, 3OMe)-B(1OH, 2OMe) | Flavone | Agehoustin F |
| 0.000 | [Flavonol]-A(1OH, 3OMe)-B(2OMe) | Flavonol | 3,5-Dihydroxy-6,7,8,3',4'-pentamethoxyflavone |
| 0.000 | [2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(6-Methyl-6-(4-Hydroxy-4-methyl-2-pentenyl)pyrano)))-B(none) | 2'-Hydroxychalcone | Boesenbergin A |
| 0.000 | [2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(6-Methyl-6-(4-Hydroxy-4-methyl-2-pentenyl)pyrano)))-B(none) | 2'-Hydroxychalcone | Boesenbergin B |
| 0.000 | [2'-Hydroxychalcone]-A(1OH, 1OMe, 1([@@]-Methylenedioxy))-B(1OH, 3OMe) | 2'-Hydroxychalcone | 2,2'-Dihydroxy-3,4,5,6'-tetramethoxy-3',4'-methylenedioxychalcone |
| 0.000 | [beta-Hydroxy(or Oxodihydro)chalcone]-A(1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano))) | beta-Hydroxy(or Oxodihydro)chalcone | Glyinflanin D |
| 0.000 | [Dihydrochalcone]-A(2OH, 1([2,3:@@]-(4-(p-Hydroxyphenyl)-6-oxodihydropyrano)))-B(none) | Dihydrochalcone | Calomelanol C |
| 0.000 | [Dihydrochalcone]-A(2OH, 1([2,3:@@]-(4-Phenyl-4,5-dihydro-6-oxopyrano)))-B(1OH) | Dihydrochalcone | Calomelanol B |
| 0.000 | [Flavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)), 1(3-Hydroxy-3-methyl-1-butenyl))-B(none) | Flavone | Fulvinervin C |
| 0.000 | [Flavone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH) | Flavone | Laxifolin |
| 0.000 | [Flavone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH) | Flavone | Isolaxifolin |
| 0.000 | [Flavonol]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(none) | Flavonol | Sericetin |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH, 2OMe) | Flavonol | Apuleirin |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH, 2OMe) | Flavonol | Murrayanol |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH, 2OMe) | Flavonol | 5,3'-Dihydroxy-3,6,7,4',5'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(3OMe)-B(2OH, 1OMe) | Flavonol | Apulein |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH, 2OMe) | Flavonol | 6,5'-Dihydroxy-3,5,7,2',4'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH, 2OMe) | Flavonol | 6,2'-Dihydroxy-3,5,7,4',5'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH, 2OMe) | Flavonol | 5,5'-Dihidroxy-3,6,7,2',4'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH, 2OMe) | Flavonol | Brickellin |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1OMe)-B(3OMe) | Flavonol | Distemonatin |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1OMe)-B(3OMe) | Flavonol | Conyzatin |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1OMe)-B(3OMe) | Flavonol | 5,8-Dihydroxy-3,7,2',3',4'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 3OMe)-B(1OH, 1OMe) | Flavonol | 5,4'-Dihydroxy-3,6,7,8,3'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 3OMe)-B(1OH, 1OMe) | Flavonol | 5,3'-Dihydroxy-3,6,7,8,4'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 2OMe)-B(2OMe) | Flavonol | 5,7-Dihydroxy-3,6,8,3',4'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 3OMe)-B(1OH, 1OMe) | Flavonol | 5,4'-Dihydroxy-3,6,7,8,2'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 3OMe)-B(1OH, 1OMe) | Flavonol | 5,2'-Dihydroxy-3,6,7,8,4'-pentamethoxyflavone |
| 0.000 | [4-substituted Flavan (4-(4-Hydroxystyryl))]-A(2OMe)-B(1OH) | 4-substituted Flavan | 4'-Hydroxy-4-(4-hydroxystyryl)-5,7-dimethoxyflavan |
| 0.000 | [Isoflavone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH) | Isoflavone | Osajin |
| 0.000 | [Isoflavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH, 1(C-Prenyl)) | Isoflavone | Chandalone |
| 0.000 | [Isoflavone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH) | Isoflavone | Warangalone |
| 0.000 | [Isoflavone]-A(2OH, 1(C-Prenyl))-B(1([2,3:@@]-(6,6-Dimethylpyrano))) | Isoflavone | Isochandalone |
| 0.000 | [Isoflavone]-A(2OH, 1(C-Prenyl))-B(1([2,3:@@]-(6,6-Dimethylpyrano))) | Isoflavone | Ulexone A |
| 0.000 | [Coumestan]-A(1OH, 1Geranyl)-B(1OH) | Coumestan | Puerarol |
| 0.000 | [4-phenylcoumarin]-A(1([2,3:@@]-(6,6-Dimethylpyrano)), 1([2,3:@@]-(5,6-Dimethyl-4-hydroxydihydropyrano)))-B(none) | 4-phenylcoumarin | Inophyllolide chromanol |
| 0.000 | [4-phenylcoumarin]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(5,6-Dimethyl-4-oxodihydropyrano)))-B(none) | 4-phenylcoumarin | 5-Hydroxy-10-prenyl-7,8-dihydro-7,8-trans-dimethyl-4-phenyl-2H,6H-benzo[1,2-b:5,4-b']dipyran-2,6-dione |
| 0.000 | [4-phenylcoumarin]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)), 1Isovaleryl)-B(none) | 4-phenylcoumarin | Mammeigin |
| 0.000 | [4-phenylcoumarin]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)), 1(2-Methylbutyroyl))-B(none) | 4-phenylcoumarin | 5-Hydroxy-6'',6''-dimethyl-6-(2-methylbutyryl)-4-phenylpyrano[2'',3'':7,8]coumarin |
| Level: 3, プリカーサーm/z: 270.94305 |
| Splash: splash10-0ufr-0690000000-5793c220f9dd551026e5 |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 252.95 | 764 | 18 | 1000 |
| 126.97 | 443 | 144 | 580 |
| 192.98 | 66 | 78 | 86 |
| 108.86 | 54 | 162 | 70 |
| 234.94 | 50 | 36 | 65 |
| 135.32 | 45 | 136 | 58 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.250 | [Isoflavanone]-A(1OH)-B(1OMe) | Isoflavanone | Dihydroformononetin |
| 0.154 | [2'-Hydroxychalcone]-A(2OH, 1OMe)-B(none) | 2'-Hydroxychalcone | Flemichapparin |
| 0.154 | [2'-Hydroxychalcone]-A(2OH, 1OMe)-B(none) | 2'-Hydroxychalcone | Larrein |
| 0.154 | [2'-Hydroxychalcone]-A(2OH, 1OMe)-B(none) | 2'-Hydroxychalcone | Cardamonin |
| 0.154 | [2'-Hydroxychalcone]-A(2OH, 1OMe)-B(none) | 2'-Hydroxychalcone | 2',6'-Dihydroxy-4'-methoxychalcone |
| 0.133 | [Flavanone]-A(1OH)-B(1OMe) | Flavanone | 4'-Methylliquiritigenin |
| 0.133 | [Flavanone]-A(1OH, 1OMe)-B(none) | Flavanone | 7-Hydroxy-8-methoxyflavanone |
| 0.133 | [Flavanone]-A(1OH, 1OMe)-B(none) | Flavanone | Alpinetin |
| 0.133 | [Flavanone]-A(1OH, 1OMe)-B(none) | Flavanone | Pinostrobin |
| 0.091 | [Pterocarpan]-A(1OMe)-B(1OH) | Pterocarpan | Isomedicarpin |
| 0.071 | [2'-Hydroxychalcone]-A(1OH, 1OMe)-B(1OH) | 2'-Hydroxychalcone | Isoliquiritigenin 4'-methyl ether |
| 0.071 | [2'-Hydroxychalcone]-A(2OH)-B(1OMe) | 2'-Hydroxychalcone | Isoliquiritigenin 4-methyl ether |
| 0.071 | [2'-Hydroxychalcone]-A(2OH)-B(1OMe) | 2'-Hydroxychalcone | 2',5'-Dihydroxy-4-methoxychalcone |
| 0.063 | [Flavone]-A(2OH)-B(1OH) | Flavone | 5,8,2'-Trihydroxyflavone |
| 0.063 | [Flavone]-A(2OH)-B(1OH) | Flavone | 5,7,2'-Trihydroxyflavone |
| 0.063 | [Flavone]-A(2OH)-B(1OH) | Flavone | Apigenin |
| 0.063 | [Flavone]-A(3OH)-B(none) | Flavone | Baicalein |
| 0.063 | [Flavone]-A(3OH)-B(none) | Flavone | Norwogonin |
| 0.063 | [Flavone]-A(1OH)-B(2OH) | Flavone | 7,3',4'-Trihydroxyflavone |
| 0.063 | [Flavone]-A(1OH)-B(2OH) | Flavone | 5,2',5'-Trihydroxyflavone |
| 0.063 | [Chalcone]-A(1OH)-B(1OH, 1OMe) | Chalcone | Echinatin |
| 0.063 | [Chalcone]-A(1OH, 1OMe)-B(1OH) | Chalcone | Isoliquiritigenin 2'-methy ether |
| 0.063 | [Anthocyanidin]-A(2OH)-B(1OH) | Anthocyanidin | Pelargonidin |
| 0.063 | [Flavanone]-A(1OMe)-B(1OH) | Flavanone | Methyl-liquiritigenin |
| 0.059 | [Isoflavone]-A(2OH)-B(1OH) | Isoflavone | Demethyltexasin |
| 0.059 | [Isoflavone]-A(2OH)-B(1OH) | Isoflavone | 8-Hydroxydaidzein |
| 0.059 | [Isoflavone]-A(2OH)-B(1OH) | Isoflavone | 5,7,2'-Trihydroxyisoflavone |
| 0.059 | [Isoflavone]-A(2OH)-B(1OH) | Isoflavone | 5,7,3'-Trihydroxyisoflavone |
| 0.059 | [Isoflavone]-A(2OH)-B(1OH) | Isoflavone | Genistein |
| 0.059 | [Isoflavone]-A(1OH)-B(2OH) | Isoflavone | 3'-Hydroxydaidzein |
| 0.059 | [Isoflavone]-A(1OH)-B(2OH) | Isoflavone | 2'-Hydroxydaidzein |
| 0.045 | [Flavonol]-A(2OH)-B(none) | Flavonol | Galangin |
| 0.043 | [Flavonol]-A(1OH)-B(1OH) | Flavonol | Resokaempferol |
| 0.000 | [Pterocarpan]-A(1OH)-B(1OMe) | Pterocarpan | Medicarpin |
| 0.000 | [Aurone]-A(1OH)-B(2OH) | Aurone | Sulfuretin |
| 0.000 | [Aurone]-A(2OH)-B(1OH) | Aurone | 4,6,4'-Trihydroxyaurone |
| 0.000 | [UBR-type derivative / 2',5'-Dioxo-3'-cyclopentenyl-type Calcone (alpha-OMe)]-A(1OMe)-B(none) | UBR-type derivative / 2',5'-Dioxo-3'-cyclopentenyl-type Calcone | Methyllucidone |
| 0.000 | [UBR-type derivative / 3',5'-Dioxo-1'-cyclopentenyl-type Dihydrocalcone]-A(3Methyl)-B(none) | UBR-type derivative / 3',5'-Dioxo-1'-cyclopentenyl-type Dihydrocalcone | 4-Hydrocinnamoyl-2,2,5-trimethyl-4-cyclopentene-1,3-dione |
| 0.000 | [Flavanone]-A(2OH, 1Methyl)-B(none) | Flavanone | Strobopinin |
| 0.000 | [Flavanone]-A(2OH, 1Methyl)-B(none) | Flavanone | Cryptostrobin |
| 0.000 | [Flavan]-A(1OMe, 1Methyl)-B(1OH) | Flavan | 4'-Hydroxy-7-methoxy-8-methylflavan |
| 0.000 | [Flavan]-A(1OH)-B(1([@@]-Methylenedioxy)) | Flavan | 7-Hydroxy-3',4'-methylenedioxyflavan |
| 0.000 | [Flavan]-A(2OMe)-B(none) | Flavan | Tephrowatsin E |
| 0.000 | [Flavan]-A(1OH, 1OMe, 1Methyl)-B(none) | Flavan | 7-Hydroxy-5-methoxy-6-methylflavan |
| 0.000 | [3-DehydroxyAnthocyanidin]-A(2OH)-B(2OH) | 3-DehydroxyAnthocyanidin | Luteolinidin |
| 0.000 | [isoflavene]-A(1OH)-B(1OH, 1OMe) | isoflavene | Haginin B |
| 0.000 | [2-Phenylbenzofuran]-A(1OMe)-B(1OH, 1OMe) | 2-Phenylbenzofuran | Vignafuran |
| 0.000 | [2-Phenylbenzofuran]-A(1([@@]-Methylenedioxy))-B(2OH) | 2-Phenylbenzofuran | 2',4'-Dihydroxy-5,6-methylenedioxy-2-phenylbenzofuran |
| 0.000 | [Dalbergiquinol]-A(1OH, 2OMe)-B(none) | Dalbergiquinol | 5-Hydroxy-2,4-dimethoxydalbergiquinol |
| 0.000 | [UBR-type derivative / [2,5]-Benzoquinonyl-type Dalbergiquinol]-A(1OMe)-B(1OH) | UBR-type derivative / [2,5]-Benzoquinonyl-type Dalbergiquinol | 4'-Hydroxy-4-methoxydalbergione |
| Level: 3, プリカーサーm/z: 288.88837 |
| Splash: splash10-00dr-0890000000-dc69bb48465368d02082 |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 270.88 | 214 | 18 | 1000 |
| 187.16 | 118 | 102 | 550 |
| 126.90 | 95 | 162 | 444 |
| 72.97 | 18 | 216 | 83 |
| 145.01 | 17 | 144 | 80 |
| 204.43 | 14 | 84 | 67 |
| 253.32 | 12 | 36 | 56 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.154 | [Dihydroflavonol]-A(2OH)-B(1OH) | Dihydroflavonol | Aromadendrin |
| 0.143 | [2'-Hydroxychalcone]-A(3OH)-B(2OH) | 2'-Hydroxychalcone | 3,4,2',4',6'-Pentahydroxychalcone |
| 0.133 | [Flavanone]-A(2OH)-B(2OH) | Flavanone | 5,7,2',6'-Tetrahydroxyflavanone |
| 0.133 | [Flavanone]-A(2OH)-B(2OH) | Flavanone | 5,7,2',5'-Tetrahydroxyflavanone |
| 0.133 | [Flavanone]-A(2OH)-B(2OH) | Flavanone | Eriodictyol |
| 0.133 | [Flavanone]-A(2OH)-B(2OH) | Flavanone | Steppogenin |
| 0.133 | [Flavanone]-A(3OH)-B(1OH) | Flavanone | Carthamidin |
| 0.133 | [Flavanone]-A(3OH)-B(1OH) | Flavanone | Isocarthamidin |
| 0.118 | [2'-Hydroxychalcone]-A(2OH)-B(3OH) | 2'-Hydroxychalcone | Robtein |
| 0.118 | [2'-Hydroxychalcone]-A(3OH)-B(2OH) | 2'-Hydroxychalcone | Neoplathymenin |
| 0.118 | [2'-Hydroxychalcone]-A(3OH)-B(2OH) | 2'-Hydroxychalcone | Okanin |
| 0.111 | [Dihydrochalcone]-A(3OH)-B(1OMe) | Dihydrochalcone | 2',4',6'-Trihydroxy-4-methoxydihydrochalcone |
| 0.111 | [Flavanone]-A(2OH)-B(2OH) | Flavanone | Plathymenin |
| 0.111 | [Flavanone]-A(2OH)-B(2OH) | Flavanone | Isookanin |
| 0.100 | [Dihydroflavonol]-A(1OH)-B(2OH) | Dihydroflavonol | Fustin |
| 0.100 | [Dihydroflavonol]-A(2OH)-B(1OH) | Dihydroflavonol | 3,5,7,2'-Tetrahydroxyflavanone |
| 0.067 | [Isoflavanone]-A(2OH)-B(2OH) | Isoflavanone | Dalbergioidin |
| 0.000 | [Dihydrochalcone]-A(1OH)-B(2OH, 1OMe) | Dihydrochalcone | Loureirin D |
| 0.000 | [Dihydrochalcone]-A(2OH, 1OMe)-B(1OH) | Dihydrochalcone | Asebogenin |
| 0.000 | [Dihydrochalcone]-A(2OH, 1OMe)-B(1OH) | Dihydrochalcone | 4,2',4'-Trihydroxy-6'-methoxydihydrochalcone |
| 0.000 | [Dihydrochalcone]-A(1OH, 1OMe)-B(2OH) | Dihydrochalcone | Dihydrocalythropsin |
| 0.000 | [Dihydrochalcone]-A(2OH)-B(1OH, 1OMe) | Dihydrochalcone | 4,2',4'-Trihydroxy-3-methoxydihydrochalcone |
| 0.000 | [Auronol]-A(1OH)-B(2OH) | Auronol | 2,6,3',4'-Tetrahydroxy-2-benzylcoumaranone |
| 0.000 | [Auronol]-A(2OH)-B(1OH) | Auronol | Maesopsin |
| 0.000 | [alpha-Hydroxychalcone]-A(2OH)-B(2OH) | alpha-Hydroxychalcone | 3,4,2',4',alpha-Pentahydroxychalcone |
| 0.000 | [Dihydrochalcone alpha-ol]-A(1OH, 1OMe)-B(1OH) | Dihydrochalcone alpha-ol | 4,4',alpha-Trihydroxy-2'-methoxydihydrochalcone |
| 0.000 | [Dihydrochalcone alpha-ol]-A(2OH)-B(1OMe) | Dihydrochalcone alpha-ol | 2',4',alpha-Trihydroxy-4-methoxydihydrochalcone |
| 0.000 | [2-Hydroxyflavanone]-A(2OH)-B(1OH) | 2-Hydroxyflavanone | 2,5,7,4'-Tetrahydroxyflavanone |
| 0.000 | [CCS-type derivative / [4,2']-Epoxyflavan 3-ol]-A(2OH)-B(1OH) | CCS-type derivative / [4,2']-Epoxyflavan 3-ol | Cyanomaclurin |
| 0.000 | [CCS-type derivative / [4,2']-Epoxyflavan 3-ol]-A(1OH)-B(2OH) | CCS-type derivative / [4,2']-Epoxyflavan 3-ol | 6,12-Mehthano-6H,12H-dibenzo[b,f][1,5]dioxocin-2,3,9,13-tetrol |
| 0.000 | [Flavan]-A(1OH)-B(2OH, 1OMe) | Flavan | 7,3',5'-Trihydroxy-4'-methoxyflavan |