ピーク情報

（しょうが類）しょうが根茎生

pos

Peak #13278 MN MID: SE115_S061031_M90

m/z: 377.26894, RT: 104.36, 強度: 15883, ログ強度: 0.73, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 2

DB検索結果: (13 names) MG(0:0/20:5(5Z,8Z,11Z,14Z,17Z)/0:0);Broussonetone C;(-)-Broussonetone C;5alpha-Androstane-3beta,17beta-diol diacetate;3beta,17beta-Diacetoxy-5alpha-androstane;Andavadoic acid;(+)-Andavadoic acid;;[12]...

DBごとのヒット数: ALL 10 KG 2 KN 3 HM 3 LM 2

FlavonoidSearch最大スコア MS2: 0.143, MS3: -

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C23H36O4	376.26136	0.801	MG(0:0/20:5(5Z,8Z,11Z,14Z,17Z)/0:0)	HMDB: HMDB0011550 LipidMAPS: LMGL01010026
C23H36O4	376.26136	0.801	Broussonetone C	KNApSAcK: C00038652
C23H36O4	376.26136	0.801	5alpha-Androstane-3beta,17beta-diol diacetate	KEGG: C15346
C23H36O4	376.26136	0.801	Andavadoic acid	KNApSAcK: C00044517
C23H36O4	376.26136	0.801	[12]-Gingerdione	HMDB: HMDB0039278
C23H36O4	376.26136	0.801		LipidMAPS: LMPK13070017
C23H36O4	376.26136	0.801	MG(20:5(5Z,8Z,11Z,14Z,17Z)/0:0/0:0)	HMDB: HMDB0011580
C23H36O4	376.26136	0.801	Ardisiphenol B	KNApSAcK: C00032722
C23H36O4	376.26136	0.801	3-Acetyl-5alpha-androstane-3beta,17beta-diol 3-acetate	KEGG: C15157
C23H36O4	376.26136	0.801	9'-Carboxy-gamma-chromanol	HMDB: HMDB0012868

MSnスペクトル情報

Level: 2, プリカーサーm/z: 377.26831

Splash: splash10-0a4i-0409000000-1fd3bdeafbdbf0874432

m/z	Int.	NL	Rel.Int.
359.15	1240	18	1000
177.02	253	200	203
178.06	192	199	154
144.95	109	232	88
179.14	80	198	64

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.143	[Flavanone]-A(1OH, 3OMe)-B(1OH, 1OMe)	Flavanone	5,2'-Dihydroxy-6,7,8,6'-tetramethoxyflavanone
0.143	[Flavanone]-A(1OH, 2OMe)-B(1OH, 2OMe)	Flavanone	5,3'-Dihydroxy-6,7,4',5'-tetramethoxyflavanone
0.048	[Flavanone]-A(1OH, 2(C-Prenyl))-B(none)	Flavanone	Ovaliflavanone A
0.048	[2'-Hydroxychalcone]-A(2OH, 2(C-Prenyl))-B(none)	2'-Hydroxychalcone	Spinochalcone A
0.000	[Flavone]-A(2OH, 2OMe)-B(2OH, 1OMe)	Flavone	5,7,3',6'-Tetrahydroxy-6,8,2'-trimethoxyflavone
0.000	[Flavone]-A(2OH, 2OMe)-B(2OH, 1OMe)	Flavone	5,7,3',4'-Tetrahydroxy-6,8,5'-trimethoxyflavone
0.000	[Flavone]-A(2OH, 2OMe)-B(2OH, 1OMe)	Flavone	5,7,2',4'-Tetrahydroxy-6,8,5'-trimethoxyflavone
0.000	[Flavonol]-A(2OH, 2OMe)-B(1OH, 1OMe)	Flavonol	Limocitrol
0.000	[Flavonol]-A(2OH, 2OMe)-B(1OH, 1OMe)	Flavonol	3,5,7,3'-Tetrahydroxy-6,8,4'-trimethoxyflavone
0.000	[Flavonol]-A(1OH, 3OMe)-B(2OH)	Flavonol	3,5,3',4'-Tetrahydroxy-6,7,8-trimethoxyflavone
0.000	[Flavonol]-A(2OH, 1OMe)-B(1OH, 2OMe)	Flavonol	3,5,7,4'-Tetrahydroxy-6,3',5'-trimethoxyflavone
0.000	[Flavonol]-A(2OH, 1OMe)-B(1OH, 2OMe)	Flavonol	3,5,7,3'-Tetrahydroxy-6,4',5'-trimethoxyflavone
0.000	[Flavonol]-A(2OH, 1OMe)-B(1OH, 2OMe)	Flavonol	Hibiscetin 8,3',5'-trimethyl ether
0.000	[Pterocarpan]-A(1OH, 2OMe)-B(1OH, 2OMe)	Pterocarpan	2,8-Dihydroxy-3,4,9,10-tetramethoxypterocarpan
0.000	[Flavanone]-A(1OH, 1OMe, 1(2-hydroxybenzyl))-B(none)	Flavanone	5-O-Methylchamanetin
0.000	[Dihydroflavonol]-A(2OH)-B(none)-C(1(O-Benzoyl))	Dihydroflavonol	Pinobanksin 3-O-benzoate
0.000	[Dihydroflavonol]-A(2OH, 1OMe)-B(2OH)-C(1(O-Acetyl))	Dihydroflavonol	3,5,7,3',4'-Pentahydroxy-6-methoxyflavanone 3-O-acetate
0.000	[Dihydroflavonol]-A(1OH, 1OMe, 1([@@]-Methylenedioxy))-B(1OH, 1OMe)	Dihydroflavonol	Plumbaginol
0.000	[Flavonol (3-OMe)]-A(3OH)-B(1OH, 2OMe)	Flavonol	5,6,7,4'-Tetrahydroxy-3,3',5'-trimethoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(2OH, 1OMe)	Flavonol	5,7,3',5'-Tetrahydroxy-3,6,4'-trimethoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(2OH, 1OMe)	Flavonol	5,7,3',4'-Tetrahydroxy-3,6,5'-trimethoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(2OH, 1OMe)	Flavonol	Apuleisin
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(2OH, 1OMe)	Flavonol	5,7,4',5'-Tetrahydroxy-3,6,2'-trimethoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(2OH, 1OMe)	Flavonol	5,7,2',5'-Tetrahydroxy-3,6,4'-trimethoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(2OH, 1OMe)	Flavonol	5,7,2',4'-Tetrahydroxy-3,6,5'-trimethoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(2OH, 1OMe)	Flavonol	Hibiscetin 3,7,4'-trimethyl ether
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(2OH, 1OMe)	Flavonol	Hibiscetin 3,8,4'-trimethyl ether
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(2OH, 1OMe)	Flavonol	5,7,2',4'-Tetrahydroxy-3,8,5'-trimethoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH, 2OMe)-B(2OH)	Flavonol	5,7,3',4'-Tetrahydroxy-3,6,8-trimethoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH, 2OMe)-B(2OH)	Flavonol	5,6,3',4'-Tetrahydroxy-3,7,8-trimethoxyflavone
0.000	[UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavan]-A(1OH, 2OMe)-B(2OMe)	UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavan	Abruquinone C
0.000	[Dehydrorotenone]-A(1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1([@@]-Methylenedioxy))	Dehydrorotenone	Dehydromillettone

Level: 3, プリカーサーm/z: 359.14816

Splash: splash10-004i-0900000000-4719b7058a936c46a9c9

m/z	Int.	NL	Rel.Int.
177.05	366	182	1000
183.04	150	176	409
174.97	23	184	62

FlavonoidSearch結果

Symbolized Name	MSMS-Category	MSMS-Aglycone
[Flavone]-A(1OH, 1OMe)-B(3OMe)	Flavone	Prosogerin D
[Flavone]-A(2OMe)-B(1OH, 2OMe)	Flavone	3'-Hydroxy-7,8,4',5'-tetramethoxyflavone
[Flavone]-A(1OH, 1OMe)-B(3OMe)	Flavone	Corymbosin
[Flavone]-A(1OH, 1OMe)-B(3OMe)	Flavone	Isoetin 7,2',4',5'-tetramethyl ether
[Flavone]-A(1OH, 2OMe)-B(2OMe)	Flavone	6-Hydroxyluteolin 5,6,3',4'-tetramethyl ether
[Flavone]-A(3OMe)-B(1OH, 1OMe)	Flavone	Ageconyflavone B
[Flavone]-A(3OMe)-B(1OH, 1OMe)	Flavone	6-Hydroxyluteolin 5,6,7,4'-tetramethyl ether
[Flavone]-A(1OH, 2OMe)-B(2OMe)	Flavone	6-Hydroxyluteolin 6,7,3',4'-tetramethyl ethe
[Flavone]-A(1OH, 2OMe)-B(2OMe)	Flavone	5-Hydroxy-2',3',7,8-tetramethoxyflavone
[Flavone]-A(1OH, 2OMe)-B(2OMe)	Flavone	5-Hydroxy-2',3',7,8-tetramethoxyflavone
[Flavone]-A(1OH, 2OMe)-B(2OMe)	Flavone	5-hydroxy-7,8,2',5'-tetramethoxyflavone
[Flavone]-A(1OH, 2OMe)-B(2OMe)	Flavone	Altisin
[Flavone]-A(1OH, 2OMe)-B(2OMe)	Flavone	Hypolaetin 7,8,3',4'-tetramethyl ether
[Flavone]-A(1OH, 2OMe)-B(2OMe)	Flavone	2-(2,4-dimethoxyphenyl)-5-hydroxy-7,8-dimethoxyflavone
[Flavone]-A(4OMe)-B(1OH)	Flavone	4'-Hydroxy-5,6,7,8-tetramethoxyflavone
[Flavone]-A(1OH, 3OMe)-B(1OMe)	Flavone	7-Hydroxy-5,6,8,4'-tetramethoxyflavone
[Flavone]-A(1OH, 3OMe)-B(1OMe)	Flavone	Gardenin B
[Chalcone]-A(5OMe)-B(none)	Chalcone	Pedicellin
[Isoflavone]-A(1OH, 1OMe)-B(3OMe)	Isoflavone	7-Hydroxy-6,2',4',5'-tetramethoxyisoflavone
[Isoflavone]-A(1OH, 1OMe)-B(3OMe)	Isoflavone	Robustigenin
[Isoflavone]-A(1OH, 2OMe)-B(2OMe)	Isoflavone	Belamcandin
[Flavonol]-A(2OMe)-B(2OMe)	Flavonol	Quercetin 5,7,3',4'-tetramethyl ether
[Aurone]-A(2OH, 1Methyl)-B(3OMe)	Aurone	4,6-Dihydroxy-5-methyl-3',4',5'-trimethoxyaurone
[Aurone]-A(2OH, 1Methyl)-B(3OMe)	Aurone	4,6-Dihydroxy-7-methyl-3',4',5'-trimethoxyaurone
[beta-Hydroxy(or Oxodihydro)chalcone]-A(3OMe)-B(1([@@]-Methylenedioxy))	beta-Hydroxy(or Oxodihydro)chalcone	Ponganone X
[Flavanone]-A(1OH, 1(2,3-Dihydroxy-3-methylbutyl))-B(1OH)	Flavanone	Brosimacutin A
[Flavanone]-A(2OMe, 1Methyl)-B(2OMe)	Flavanone	2',4',5,7-Tetramethoxy-8-methylflavanone
[UBR-type derivative / [2',5']-Benzoquinonyl-type Flavanone]-A(1OH, 1OMe, 2Methyl)-B(1OMe)	UBR-type derivative / [2',5']-Benzoquinonyl-type Flavanone	Scaberin
[Flavone]-A(2OH, 2Methyl)-B(1OH, 2OMe)	Flavone	5,7,3'-Trihydroxy-4',5'-dimethoxy-6,8-dimethylflavone
[Flavone]-A(2OH, 2OMe)-B(1([@@]-Methylenedioxy))	Flavone	Linderoflavone A
[UBR-type derivative / [3',6']-Benzoquinonyl-type Flavone]-A(1OH, 1OMe)-B(2OMe)	UBR-type derivative / [3',6']-Benzoquinonyl-type Flavone	5-Hydroxy-7,2',4'-trimethoxy-3',6'-diketoflavone
[Dihydroflavonol]-A(2OH)-B(1OH)-C(1(O-Isobutyroyl))	Dihydroflavonol	3,5,7,3'-Tetrahydroxyflavanone 3-O-Isobutyrate
[Flavonol (3-OMe)]-A(1OMe)-B(1OH, 2OMe)	Flavonol	4'-Hydroxy-3,7,3',5'-tetramethoxyflavone
[Flavonol (3-OMe)]-A(1OH, 1OMe)-B(2OMe)	Flavonol	Santoflavone
[Flavonol (3-OMe)]-A(1OH, 1OMe)-B(2OMe)	Flavonol	Quercetin 3,5,3',4'-tetramethyl ether
[Flavonol (3-OMe)]-A(2OMe)-B(1OH, 1OMe)	Flavonol	Quercetin 3,5,7,3'-tetramethyl ether
[Flavonol (3-OMe)]-A(2OMe)-B(1OH, 1OMe)	Flavonol	Quercetin 3,5,7,4'-tetramethyl ether
[Flavonol (3-OMe)]-A(1OH, 1OMe)-B(2OMe)	Flavonol	Retusin(Ariocarpus)
[Flavonol (3-OMe)]-A(1OH, 1OMe, 1Methyl)-B(1OH, 1OMe)	Flavonol	6-C-Methylquercetin 3,7,3'-trimethyl ether
[Flavonol (3-OMe)]-A(1OH, 1OMe, 1Methyl)-B(1OH, 1OMe)	Flavonol	5,4'-Dihydroxy-3,7,3'-trimethoxy-8-methylflavone
[Flavonol (3-OMe)]-A(1OH, 1OMe, 2Methyl)-B(2OH)	Flavonol	2-(3,4-Dihydroxyphenyl)-5-hydroxy-3,7-dimethoxy-6,8-dimethyl-4H-1-benzopyran-4-one
[Flavonol (3-OMe)]-A(2OH, 2Methyl)-B(1OH, 1OMe)	Flavonol	5,7,4'-Trihydroxy-3,3'-dimethoxy-6,8-dimethylflavone
[Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OMe)	Flavonol	6-Hydroxykaempferol 3,5,7,4'-tetramethyl ether
[Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OMe)	Flavonol	Penduletin 4'-methyl ether
[Flavonol (3-OMe)]-A(1OH, 2OMe, 1Methyl)-B(1OH)	Flavonol	8-C-Methyl-6-hydroxykaempferol 3,6,7-trimethyl ether
[Flavonol (3-OMe)]-A(1OH, 1([@@]-Methylenedioxy))-B(1OH, 1OMe)	Flavonol	5,4'-Dihydroxy-3,3'-dimethoxy-6,7-methylenedioxyflavone
[Flavonol]-A(1OMe, 1([@@]-Methylenedioxy))-B(1OH, 1OMe)	Flavonol	3,3'-Dihydroxy-5,4'-dimethoxy-6,7-methylenedioxyflavone
[Flavonol]-A(1OH, 2OMe)-B(1([@@]-Methylenedioxy))	Flavonol	3,7-Dihydroxy-5,6-dimethoxy-3',4'-methylenedioxyflavone
[Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OMe)	Flavonol	5-Hydroxy-3,7,8,2'-tetramethoxyflavone
[Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OMe)	Flavonol	Flindulatin
[Flavonol (3-OMe)]-A(1OH, 2OMe, 1Methyl)-B(1OH)	Flavonol	5-Hydroxy-2-(4-hydroxyphenyl)-3,7,8-trimethoxy-6-methyl-4H-1-benzopyran-4-one
[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(1([@@]-Methylenedioxy))	Flavonol	3,8-Dimethoxy-5,7-dihydroxy-3',4'-methylenedioxyflavone
[Flavonol (3-OMe)]-A(1OH, 3OMe)-B(none)	Flavonol	5-Hydroxy-3,6,7,8-tetramethoxyflavone
[CCS-type derivative / [3,2']-Formyloxidoflavone]-A(2OH, 1OMe)-B(2OH)	CCS-type derivative / [3,2']-Formyloxidoflavone	Distemonanthin
[Flavan 3-ol]-A(2OH, 1(C-Prenyl))-B(2OH)	Flavan 3-ol	6-Prenylcatechin
[Flavan 3-ol]-A(2OH, 1(C-Prenyl))-B(2OH)	Flavan 3-ol	8-Prenylcatechin
[Isoflavone]-A(1OH, 1([@@]-Methylenedioxy))-B(1OH, 2OMe)	Isoflavone	5,3'-Dihydroxy-4',5'-dimethoxy-6,7-methylenedioxyisoflavone
[Isoflavone]-A(2OH, 1OMe)-B(1OMe, 1([@@]-Methylenedioxy))	Isoflavone	Dalpalatin
[Isoflavanone]-A(1OH, 1(3-hydroxy-3-methylbutyl))-B(2OH)	Isoflavanone	7,2',4'-Trihydroxy-8-(3-hydroxy-3-methylbutyl)isoflavanone
[Rotenone]-A(1OH, 1OMe)-B(2OMe)	Rotenone	Sermundone
[12a-Hydroxyrotenone]-A(1OMe)-B(2OMe)	12a-Hydroxyrotenone	12a-Hydroxymunduserone
[4-phenylcoumarin]-A(1OH, 2OMe)-B(2OMe)	4-phenylcoumarin	8-Hydroxy-5,7,3',4'-tetramethoxy-4-phenylcoumarin
[4-phenylcoumarin]-A(3OMe)-B(1OH, 1OMe)	4-phenylcoumarin	3'-Hydroxy-5,7,8,4'-tetramethoxy-4-phenylcoumarin