ピーク情報

ポプラ, 幼植物, 地上部

pos

Peak #8877 MN MID: SE205_S08_M90

m/z: 363.25299, RT: 91.69, 強度: 6822, ログ強度: 0.24, アダクト: [M-H2O+H]+, 共有数（同様のピークを含むサンプル数）: 1

DB検索結果: (26 names) 20a,20b-dihomo-9-oxo-11R,15S-dihydroxy-5Z,13E-prostadienoic acid;Sartol acetate B;15-Hydroxy-16-acetoxy-ent-clerod-3-en-18-oic acid;16,16-Dimethylprostaglandin E2;1a,1b-dihomo-9-oxo-11R,15S-dihydroxy-...

DBごとのヒット数: ALL 23 KN 9 HM 4 LM 10

FlavonoidSearch最大スコア MS2: 0.083, MS3: 0.120

DB検索結果

ppm

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C22H36O5	380.25627	0.012	20a,20b-dihomo-9-oxo-11R,15S-dihydroxy-5Z,13E-prostadienoic acid	HMDB: HMDB0245563 LipidMAPS: LMFA03010174
C22H36O5	380.25627	0.012	Sartol acetate B	KNApSAcK: C00049581
C22H36O5	380.25627	0.012	15-Hydroxy-16-acetoxy-ent-clerod-3-en-18-oic acid	KNApSAcK: C00029400
C22H36O5	380.25627	0.012	16,16-Dimethylprostaglandin E2	HMDB: HMDB0244730 LipidMAPS: LMFA03010065
C22H36O5	380.25627	0.012	1a,1b-dihomo-9-oxo-11R,15S-dihydroxy-5Z,13E-prostadienoic acid	LipidMAPS: LMFA03010155
C22H36O5	380.25627	0.012	ent-3alpha-acetoxy-16beta,17,18-trihydroxyatisane	LipidMAPS: LMPR0104150007
C22H36O5	380.25627	0.012	Pacificin G	KNApSAcK: C00042819
C22H36O5	380.25627	0.012	19-Acetoxy-12,20-dihydroxygeranylnerol	KNApSAcK: C00022101
C22H36O5	380.25627	0.012	Prostalene	HMDB: HMDB0256858
C22H36O5	380.25627	0.012	24-dinor-3alpha,7alpha,16alpha-trihydroxy-5beta-cholan-22-oic acid	LipidMAPS: LMST04050016
C22H36O5	380.25627	0.012	7-[(1R,2R,3R)-3-Hydroxy-2-[(3R)-3-hydroxy-4,4-dimethyloct-1-enyl]-5-oxocyclopentyl]hept-2-enoic acid	HMDB: HMDB0247164
C22H36O5	380.25627	0.012	1a,1b-dihomo-9S,15S-dihydroxy-11-oxo-5Z,13E-prostadienoic acid	LipidMAPS: LMFA03010156
C22H36O5	380.25627	0.012	Membrenone A	KNApSAcK: C00039747
C22H36O5	380.25627	0.012	Cycloschkuhriadiol acetate	KNApSAcK: C00022215
C22H36O5	380.25627	0.012	5beta-pregnane-11beta,17alpha,20beta,21-tetrol-3-one	LipidMAPS: LMST02030273, LMST02030274
C22H36O5	380.25627	0.012	Limaprost	HMDB: HMDB0254093
C22H36O5	380.25627	0.012	24-dinor-3alpha,6beta,7beta-trihydroxy-5beta-cholan-22-oic acid	LipidMAPS: LMST04050009, LMST04050012, LMST04050013, LMST04050014
C22H36O5	380.25627	0.012	Pacificin H	KNApSAcK: C00042820
C22H36O5	380.25627	0.012	Bisnorcholic acid	HMDB: HMDB0002082 LipidMAPS: LMST04050005
C22H36O5	380.25627	0.012	Divaricatic acid (Pteronia)	KNApSAcK: C00022039
C22H36O5	380.25627	0.012	6,9S-epoxy-11R,15S-dihydoxy-5Z,13E-1a,1b-dihomo-prostadienoic acid	LipidMAPS: LMFA03010195
C22H36O5	380.25627	0.012	9S,15S-dihydroxy-11-oxo-16,16-dimethyl-5Z,13E-prostadienoic acid	LipidMAPS: LMFA03010052
C22H36O5	380.25627	0.012	Cordobic acid 18-acetate	KNApSAcK: C00022247
C22H36O5	380.25627	0.012	Enisoprost	HMDB: HMDB0251811

MSnスペクトル情報

Level: 2, プリカーサーm/z: 363.25262

Splash: splash10-0uds-0912000000-b353feb0982ec411a6b1

m/z	Int.	NL	Rel.Int.
152.86	4053	210	1000
345.19	2855	18	704
193.04	1940	170	478
138.91	1522	224	375
127.00	981	236	242
219.13	955	144	235
181.05	921	182	227
237.19	587	126	144
176.93	402	186	99
149.10	285	214	70
205.05	258	158	63
164.95	234	198	57
207.12	219	156	54
191.05	215	172	52
279.13	205	84	50

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.083	[Flavanone]-A(2OH, 1OMe)-B(1OH, 2OMe)	Flavanone	5,7,3'-Trihydroxy-6,4',5'-trimethoxyflavanone
0.053	[Isoflavan]-A(1OH, 2OMe)-B(1OH, 2OMe)	Isoflavan	Machaerol B
0.033	[Flavonol]-A(2OH, 1OMe)-B(2OH, 1OMe)	Flavonol	3,5,7,3',5'-Pentahydroxy-6,4'-dimethoxyflavone
0.033	[Flavonol]-A(2OH, 1OMe)-B(2OH, 1OMe)	Flavonol	Hibiscetin 8,3'-dimethyl ether
0.000	[Flavonol]-A(2OH, 2OMe)-B(2OH)	Flavonol	3,5,7,3',4'-Pentahydroxy-6,8-dimethoxyflavone
0.000	[Flavanone]-A(2OH, 1(2-hydroxybenzyl))-B(none)	Flavanone	Isochamanetin
0.000	[Flavanone]-A(2OH, 1(2-hydroxybenzyl))-B(none)	Flavanone	Chamanetin
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(3OH)	Flavonol	5,7,3',4',5'-Pentahydroxy-3,6-dimethoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(3OH)	Flavonol	5,7,2',3',4'-Pentahydroxy-3,6-dimethoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(3OH)	Flavonol	5,8,3',4',5'-Pentahydroxy-3,7-dimethoxyflavone
0.000	[Flavonol (3-OMe)]-A(3OH, 1OMe)-B(2OH)	Flavonol	5,7,8,3',4'-Pentahydroxy-3,6-dimethoxyflavone
0.000	[Flavan 3-ol]-A(2OH, 1OMe)-B(2OH)-C(1(O-Acetyl))	Flavan 3-ol	3,7,8,3',4'-Pentahydroxy-5-methoxyflavan 3-O-acetate

Level: 3, プリカーサーm/z: 345.18579

Splash: splash10-002u-0920000000-9228342007434cbba6ce

m/z	Int.	NL	Rel.Int.
138.96	347	206	1000
191.00	239	154	689
176.94	234	168	675
219.08	111	126	321
205.11	104	140	301
123.10	71	222	204
303.48	67	42	192
162.98	66	182	191
277.12	54	68	155
189.02	43	156	125
152.83	38	192	110
165.02	36	180	104
249.16	33	96	96
263.14	29	82	83
149.12	25	196	73
317.24	19	28	55
179.01	18	166	52

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.167	[Flavanone]-A(2OMe)-B(2OMe)	Flavanone	5,7,2',5'-Tetramethoxyflavanone
0.167	[Flavanone]-A(2OMe)-B(2OMe)	Flavanone	Arjunone
0.100	[Flavonol]-A(1OH, 1OMe)-B(2OMe)	Flavonol	3,7-Dihydroxy-5,3',4'-trimethoxyflavone
0.100	[Flavonol]-A(1OH, 1OMe)-B(2OMe)	Flavonol	Quercetin 7,3',4'-trimethyl ether
0.088	[Isoflavone]-A(1OH, 1OMe)-B(1OH, 2OMe)	Isoflavone	Derrugenin
0.083	[2'-Hydroxychalcone]-A(1OH, 2OMe)-B(2OMe)	2'-Hydroxychalcone	Okanin 3,4,3',4'-tetramethyl ether
0.083	[2'-Hydroxychalcone]-A(1OH, 2OMe)-B(2OMe)	2'-Hydroxychalcone	2'-Hydroxy-2,3,4',6'-tetramethoxychalcone
0.083	[2'-Hydroxychalcone]-A(1OH, 2OMe)-B(2OMe)	2'-Hydroxychalcone	2'-Hydroxy-3,4,4',6'-tetramethoxychalcone
0.083	[2'-Hydroxychalcone]-A(1OH, 2OMe)-B(2OMe)	2'-Hydroxychalcone	Cerasidin
0.065	[Flavonol]-A(1OMe)-B(1OH, 2OMe)	Flavonol	3,4'-Dihydroxy-7,3',5'-trimethoxyflavone
0.057	[Isoflavone]-A(2OH)-B(3OMe)	Isoflavone	Panchovillin
0.057	[Isoflavone]-A(1OH, 2OMe)-B(1OH, 1OMe)	Isoflavone	5,3'-Dihydroxy-7,8,2'-trimethoxyisoflavone
0.040	[2'-Hydroxychalcone]-A(1OH, 3OMe)-B(1OMe)	2'-Hydroxychalcone	6'-Hydroxy-4,2',3',4'-tetramethoxychalcone
0.040	[2'-Hydroxychalcone]-A(2OH, 3OMe)-B(none)	2'-Hydroxychalcone	3'-Hydroxy-2',4',5',6'-tetramethoxychalcone
0.040	[2'-Hydroxychalcone]-A(1OH, 4OMe)-B(none)	2'-Hydroxychalcone	Kanakugiol
0.037	[Flavanone]-A(4OMe)-B(none)	Flavanone	Kanakugin
0.037	[Flavanone]-A(3OMe)-B(1OMe)	Flavanone	5,6,7,4'-Tetramethoxyflavanone
0.028	[Isoflavone]-A(2OH, 1OMe)-B(2OMe)	Isoflavone	Junipegenin B
0.028	[Isoflavone]-A(2OH, 1OMe)-B(2OMe)	Isoflavone	5,7-Dihydroxy-8,3',4'-trimethoxyisoflavone
0.000	[Flavone]-A(2OH)-B(3OMe)	Flavone	Prosogerin E
0.000	[Flavone]-A(1OH, 1OMe)-B(1OH, 2OMe)	Flavone	8,3'-Dihydroxy-7,4',5'-trimethoxyflavone
0.000	[Flavone]-A(1OH, 1OMe)-B(1OH, 2OMe)	Flavone	5,5'-Dihydroxy-8,3',4'-trimethoxyflavone
0.000	[Flavone]-A(2OH)-B(3OMe)	Flavone	Tricetin 3',4',5'-trimethyl ether
0.000	[Flavone]-A(1OH, 1OMe)-B(1OH, 2OMe)	Flavone	Lethedocin
0.000	[Flavone]-A(1OH, 1OMe)-B(1OH, 2OMe)	Flavone	5,4'-dihydroxy-7,3',5'-trimethoxyflavone
0.000	[Flavone]-A(3OMe)-B(2OH)	Flavone	3',4'-Dihydroxy-5,6,7-trimethoxyflavone
0.000	[Flavone]-A(2OH, 1OMe)-B(2OMe)	Flavone	Eupatilin
0.000	[Flavone]-A(1OH, 2OMe)-B(1OH, 1OMe)	Flavone	Cirsilineol
0.000	[Flavone]-A(1OH, 2OMe)-B(1OH, 1OMe)	Flavone	Eupatorin
0.000	[Flavone]-A(2OH, 1OMe)-B(2OMe)	Flavone	6-Hydroxyluteolin 7,3',4'-trimethyl ether
0.000	[Flavone]-A(1OH, 2OMe)-B(1OH, 1OMe)	Flavone	Wightin
0.000	[Flavone]-A(1OH, 2OMe)-B(1OH, 1OMe)	Flavone	Rivularin (flavone)
0.000	[Flavone]-A(2OH, 1OMe)-B(2OMe)	Flavone	5,7-Dihydroxy-8,2',6'-trimethoxyflavone
0.000	[Flavone]-A(2OH, 1OMe)-B(2OMe)	Flavone	5,7-Dihydroxy-8,3',5'trimethoxyflavone
0.000	[Flavone]-A(1OH, 2OMe)-B(1OH, 1OMe)	Flavone	8,3'-Dihydroxy-5,7,4'-trimethoxyflavone
0.000	[Flavone]-A(2OH, 1OMe)-B(2OMe)	Flavone	Hypolaetin 8,3',4'-trimethyl ether
0.000	[Flavone]-A(1OH, 3OMe)-B(1OH)	Flavone	Tenaxin I
0.000	[Flavone]-A(2OH, 2OMe)-B(1OMe)	Flavone	Pedunculin
0.000	[Flavone]-A(1OH, 3OMe)-B(1OH)	Flavone	Xanthomicrol
0.000	[Flavone]-A(2OH, 2OMe)-B(1OMe)	Flavone	Nevadensin
0.000	[Flavone]-A(2OH, 2OMe)-B(1OMe)	Flavone	5,6-Dihydroxy-7,8,4'-trimethoxyflavone
0.000	[Anthocyanidin]-A(1OH, 1OMe)-B(1OH, 2OMe)	Anthocyanidin	3,7,4'-Trihydroxy-5,3',5'-trimethoxyflavylium
0.000	[Anthocyanidin]-A(1OH, 1OMe)-B(1OH, 2OMe)	Anthocyanidin	Hirsutidin
0.000	[Flavonol]-A(1OH, 2OMe)-B(1OMe)	Flavonol	Mikanin
0.000	[Flavonol]-A(1OH, 2OMe)-B(1OMe)	Flavonol	Tambulin
0.000	[Flavonol]-A(1OH, 3OMe)-B(none)	Flavonol	3,5-Dihydroxy-6,7,8-trimethoxyflavone
0.000	[Flavonol]-A(3OMe)-B(1OH)	Flavonol	Candidol
0.000	[Aurone]-A(3OMe)-B(2OH)	Aurone	Hamiltrone
0.000	[2'-Hydroxychalcone]-A(2OH, 2OMe)-B(1([@@]-Methylenedioxy))	2'-Hydroxychalcone	Agestricin A
0.000	[Dihydrochalcone]-A(3OMe)-B(1([@@]-Methylenedioxy))	Dihydrochalcone	2',4',6'-Trimethoxy-3,4-methylenedioxydihydrochalcone
0.000	[Dihydrochalcone beta-ol (2-OMe)]-A(1([@@]-Methylenedioxy))-B(2OMe)	Dihydrochalcone beta-ol	Dihydroisomilletenone methyl ether
0.000	[Dihydrochalcone beta-ol (beta-OMe)]-A(2OMe)-B(1([@@]-Methylenedioxy))	Dihydrochalcone beta-ol	Dihydromilletenone methyl ether
0.000	[Flavanone]-A(1OH, 1OMe, 1Methyl)-B(2OMe)	Flavanone	5-Hydroxy-7,3',4'-trimethoxy-6-C-methylflavanone
0.000	[Flavanone]-A(2OMe, 1Methyl)-B(1OH, 1OMe)	Flavanone	3'-Hydroxy-5,7,4'-trimethoxy-8-C-methylflavanone
0.000	[Flavanone]-A(1OH, 2OMe)-B(1([@@]-Methylenedioxy))	Flavanone	Agestricin B
0.000	[UBR-type derivative / [2',5']-Benzoquinonyl-type Flavanone]-A(1OH, 1OMe, 1Methyl)-B(1OMe)	UBR-type derivative / [2',5']-Benzoquinonyl-type Flavanone	Breverin
0.000	[Flavone]-A(1([2,3:@@]-(6,6-Dimethylpyrano)), 1([2,3:@@]-Furano))-B(none)	Flavone	Sanaganone
0.000	[Dihydroflavonol]-A(2OH)-B(1OMe)-C(1(O-Acetyl))	Dihydroflavonol	Aromadendrin 4'-methyl ether 3-O-acetate
0.000	[Dihydroflavonol]-A(1OH, 1OMe)-B(1OH)-C(1(O-Acetyl))	Dihydroflavonol	Aromadendrin 7-methyl ether 3-O-acetate
0.000	[Flavonol (3-OMe)]-A(1OMe)-B(2OH, 1OMe)	Flavonol	4',5'-Dihydroxy-3,7,3'-trimethoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH)-B(2OMe)	Flavonol	Quercetin 3,3',4'-trimethyl ether
0.000	[Flavonol (3-OMe)]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavonol	Quercetin 3,5,3'-trimethyl ether
0.000	[Flavonol (3-OMe)]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavonol	Pachypodol
0.000	[Flavonol (3-OMe)]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavonol	Ayanin
0.000	[Flavonol (3-OMe)]-A(2OH, 1Methyl)-B(1OH, 1OMe)	Flavonol	6-C-Methylquercetin 3,3'-dimethyl ether
0.000	[Flavonol (3-OMe)]-A(1OH, 1OMe, 1Methyl)-B(2OH)	Flavonol	2-(3,4-Dihydroxyphenyl)-5-hydroxy-3,7-dimethoxy-6-methyl-4H-1-benzopyran-4-one
0.000	[Flavonol (3-OMe)]-A(2OH, 2Methyl)-B(2OH)	Flavonol	2-(3,4-Dihydroxyphenyl)-5,7-dihydroxy-3-methoxy-6,8-dimethyl-4H-1-benzopyran-4-one
0.000	[Flavonol (3-OMe)]-A(2OH)-B(2OMe)	Flavonol	Morin 3,2',4'-trimethyl ether
0.000	[Flavonol (3-OMe)]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavonol	Morin 3,7,4'-trimethyl ether
0.000	[Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH)	Flavonol	6-Hydroxykaempferol 3,5,7-trimethyl ether
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(1OMe)	Flavonol	Santin
0.000	[Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH)	Flavonol	Penduletin
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(1OMe)	Flavonol	Tanetin
0.000	[Flavonol (3-OMe)]-A(1OH, 1([@@]-Methylenedioxy))-B(2OH)	Flavonol	5,3',4'-Trihydroxy-3-methoxy-6,7-methylenedioxyflavone
0.000	[Flavonol]-A(1OH, 1([@@]-Methylenedioxy))-B(1OH, 1OMe)	Flavonol	3,5,3'-Trihydroxy-4'-methoxy-6,7-methylenedioxyflavone
0.000	[Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH)	Flavonol	5,2'-Dihydroxy-3,7,8-trimethoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(1OMe)	Flavonol	Herbacetin 3,7,4'-trimethyl ether
0.000	[Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH)	Flavonol	Herbacetin 3,7,8-trimethyl ether
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(1OMe)	Flavonol	Herbacetin 3,8,4'-trimethyl ether
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe, 1Methyl)-B(1OH)	Flavonol	5,8,4'-Trihydroxy-3,7-dimethoxy-6-methylflavone
0.000	[Flavonol (3-OMe)]-A(1OH, 1([@@]-Methylenedioxy))-B(2OH)	Flavonol	Wharangin
0.000	[Flavonol (3-OMe)]-A(2OH, 2OMe)-B(none)	Flavonol	5,8-Dihydroxy-3,6,7-trimethoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH, 2OMe)-B(none)	Flavonol	Araneol
0.000	[CCS-type derivative / [3,2']-Epoxymethanoflavone]-A(2OH, 1OMe)-B(2OH)	CCS-type derivative / [3,2']-Epoxymethanoflavone	Benthamianin
0.000	[Flavan]-A(1OH, 1OMe, 2Methyl)-B(1OH, 1([@@]-Methylenedioxy))	Flavan	5,2'-Dihydroxy-7-methoxy-6,8-dimethyl-4',5'-methylenedioxyflavan
0.000	[Pterocarpan]-A(1OH, 2OMe)-B(1([@@]-Methylenedioxy))	Pterocarpan	2-Hydroxy-4-methoxypterocarpin
0.000	[Pterocarpan-6a-ol]-A(2OMe)-B(1([@@]-Methylenedioxy))	Pterocarpan-6a-ol	Lathycarpin
0.000	[Pterocarpene]-A(1OH, 1OMe)-B(1OH, 2OMe)	Pterocarpene	Bryacarpene 1
0.000	[12a-Hydroxyrotenone]-A(1OH, 1OMe, 1Methyl)-B(1OH)	12a-Hydroxyrotenone	Boeravinone C
0.000	[4-phenylcoumarin]-A(1OH, 2OMe)-B(1OH, 1OMe)	4-phenylcoumarin	8,3'-Dihydroxy-5,7,4'-trimethoxy-4-phenylcoumarin

Level: 3, プリカーサーm/z: 152.86273

Splash: splash10-014i-9600000000-c5465ecf88aec72dea11

m/z	Int.	NL	Rel.Int.
68.98	21	84	1000
124.94	8	28	363
110.85	7	42	320

ピーク番号	保持時間 (min)	m/z	m/z差分	ログ強度	アダクト	DB検索結果	ヒット数	MSn	FS2	FS3	共有数
	91.66	381.26356	18.0106	1.62	[M+H]+	(26 names) 20a,20b-dihomo-9-oxo-11R,15S-dihydroxy-5Z,13E-prostadienoic acid; Sartol acetate B; 15-Hydroxy-16-acetoxy-ent-clerod-3-en-18-oic acid; 16,16-Dimethylprostaglandin E2; 1a,1b-dihomo-9-oxo-11R,15S-dihydroxy-...	ALL 23 KN 9 HM 4 LM 10	MS2 MS3 x 2		0.250	2
8877	91.69	363.25299	0.0000	0.24	[M-H2O+H]+	(26 names) 20a,20b-dihomo-9-oxo-11R,15S-dihydroxy-5Z,13E-prostadienoic acid; Sartol acetate B; 15-Hydroxy-16-acetoxy-ent-clerod-3-en-18-oic acid; 16,16-Dimethylprostaglandin E2; 1a,1b-dihomo-9-oxo-11R,15S-dihydroxy-...	ALL 23 KN 9 HM 4 LM 10	MS2 MS3 x 2	0.083	0.120	1

ピーク情報

DB検索結果

MSnスペクトル情報

FlavonoidSearch結果

FlavonoidSearch結果

FlavonoidSearch結果

関連ピーク情報