ピーク情報
|
ポプラ, 幼植物, 地上部
pos
|
| Peak #8645 MN MID: SE205_S08_M90 |
| m/z: 271.09659, RT: 84.43, 強度: 4672, ログ強度: 0.07, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 1 |
| DB検索結果: (56 names) Isoimperatorin;Cryptostrobin;3-(4-Methoxyphenyl)-8-hydroxydihydroisocoumarin;Hydrangenol monomethyl ether;4'-Methylliquiritigenin;7-Hydroxy-3',4'-methylenedioxyflavan;Dimethyl [1,1'-biphenyl]-4,4'-dic... |
| DBごとのヒット数: ALL 50 KG 9 KN 39 HM 2 |
| FlavonoidSearch最大スコア MS2: 0.583, MS3: - |
DB検索結果
ppm
| 組成式 | 分子量 | 誤差(Δppm） | 候補化合物名（代表で最短名を記載） | 化合物ID |
|---|---|---|---|---|
| C16H14O4 | 270.08921 | 0.389 | 8-Methylpinocembrin | FlavonoidViewer: FL2FA9NM0004 KNApSAcK: C00008166 LipidMAPS: LMPK12140190 |
| C16H14O4 | 270.08921 | 0.389 | Isoimperatorin | HMDB: HMDB0253646 KEGG: C16976 KNApSAcK: C00030532 |
| C16H14O4 | 270.08921 | 0.389 | 3-(4-Methoxyphenyl)-8-hydroxydihydroisocoumarin | KNApSAcK: C00015276 |
| C16H14O4 | 270.08921 | 0.389 | 4'-Methylliquiritigenin | FlavonoidViewer: FL2F1ANS0003 KNApSAcK: C00008429 LipidMAPS: LMPK12140063 |
| C16H14O4 | 270.08921 | 0.389 | 7-Hydroxy-3',4'-methylenedioxyflavan | FlavonoidViewer: FL6F1CNS0005 KNApSAcK: C00008773 LipidMAPS: LMPK12020248 |
| C16H14O4 | 270.08921 | 0.389 | Dimethyl [1,1'-biphenyl]-4,4'-dicarboxylate | HMDB: HMDB0247395 |
| C16H14O4 | 270.08921 | 0.389 | Vignafuran | FlavonoidViewer: FLII1ANS0001 HMDB: HMDB0033940 KEGG: C08993 KNApSAcK: C00002414 LipidMAPS: LMPK12160036 |
| C16H14O4 | 270.08921 | 0.389 | Methyl-liquiritigenin | FlavonoidViewer: FL2F1ANS0002 KNApSAcK: C00008198 LipidMAPS: LMPK12140062 |
| C16H14O4 | 270.08921 | 0.389 | Nudol | KNApSAcK: C00015898 |
| C16H14O4 | 270.08921 | 0.389 | Haginin B | FlavonoidViewer: FLICWXNS0002 KNApSAcK: C00009749 LipidMAPS: LMPK12080063 |
| C16H14O4 | 270.08921 | 0.389 | Bauhiniastatin 4 | KNApSAcK: C00041373 |
| C16H14O4 | 270.08921 | 0.389 | Strobopinin | FlavonoidViewer: FL2FA9NM0001 KEGG: C09939 KNApSAcK: C00001006 LipidMAPS: LMPK12140187 |
| C16H14O4 | 270.08921 | 0.389 | 3-Hydroxy-5-methoxystilbene-2-carboxylic acid | HMDB: HMDB0040868 KNApSAcK: C00015521 |
| C16H14O4 | 270.08921 | 0.389 | Cardamomin | FlavonoidViewer: FL1CA9NS0003 KNApSAcK: C00006935, C00031536 LipidMAPS: LMPK12120245 |
| C16H14O4 | 270.08921 | 0.389 | 2',6'-Dihydroxy-4'-methoxychalcone | FlavonoidViewer: FL1CA9NS0002 HMDB: HMDB0033702 KNApSAcK: C00006934 LipidMAPS: LMPK12120244 |
| C16H14O4 | 270.08921 | 0.389 | Lantalucratin A | KNApSAcK: C00043655 |
| C16H14O4 | 270.08921 | 0.389 | [(1S,2S)-2-[[2,2-Dimethylpropyl(nonyl)carbamoyl]amino]cyclohexyl] 3-[[(4R)-2,2,5,5-tetramethyl-1,3-dioxane-4-carbonyl]amino]propanoate | HMDB: HMDB0252152 |
| C16H14O4 | 270.08921 | 0.389 | 2',5'-Dihydroxy-4-methoxychalcone | FlavonoidViewer: FL1C9ANS0002 KNApSAcK: C00006930 LipidMAPS: LMPK12120194 |
| C16H14O4 | 270.08921 | 0.389 | Stemofuran D | KNApSAcK: C00046421 |
| C16H14O4 | 270.08921 | 0.389 | Saprionide | KNApSAcK: C00045393 |
| C16H14O4 | 270.08921 | 0.389 | Pacharin | KNApSAcK: C00015833 |
| C16H14O4 | 270.08921 | 0.389 | 6,7-Dihydroxy-2,4-dimethoxyphenanthrene | KNApSAcK: C00015609 |
| C16H14O4 | 270.08921 | 0.389 | Flemichapparin | FlavonoidViewer: FL1C29NS0001 KNApSAcK: C00006932 LipidMAPS: LMPK12120136 |
| C16H14O4 | 270.08921 | 0.389 | 7-Hydroxy-8-methoxyflavanone | FlavonoidViewer: FL2F39NS0001 KNApSAcK: C00008128 LipidMAPS: LMPK12140089 |
| C16H14O4 | 270.08921 | 0.389 | 3,7-Dihydroxy-2,4-dimethoxyphenanthrene | KNApSAcK: C00015404 |
| C16H14O4 | 270.08921 | 0.389 | Isomedicarpin | FlavonoidViewer: FLID1ANS0003 HMDB: HMDB0033305 KNApSAcK: C00009611 LipidMAPS: LMPK12070030 |
| C16H14O4 | 270.08921 | 0.389 | Isoliquiritigenin 4-methyl ether | FlavonoidViewer: FL1C1ANS0002 KNApSAcK: C00006926 LipidMAPS: LMPK12120097 |
| C16H14O4 | 270.08921 | 0.389 | (S)-4'-Hydroxy-4-methoxydalbergione | FlavonoidViewer: FLND2ANS0001 KNApSAcK: C00010253 LipidMAPS: LMPK12100073 |
| C16H14O4 | 270.08921 | 0.389 | Dihydroformononetin | FlavonoidViewer: FLIB1ANS0002 HMDB: HMDB0033759 KNApSAcK: C00009534 LipidMAPS: LMPK12050448 |
| C16H14O4 | 270.08921 | 0.389 | 3,5-Dihydroxy-2,4-dimethoxyphenanthrene | KNApSAcK: C00015900 |
| C16H14O4 | 270.08921 | 0.389 | Amoenumin | KNApSAcK: C00015735 |
| C16H14O4 | 270.08921 | 0.389 | Hyperolactone C | KNApSAcK: C00043593 |
| C16H14O4 | 270.08921 | 0.389 | (+)-Medicarpin | FlavonoidViewer: FLID1ANS0001 HMDB: HMDB0254403 KEGG: C01729, C10503 KNApSAcK: C00002547, C00018987 LipidMAPS: LMPK12070028 |
| C16H14O4 | 270.08921 | 0.389 | Imbricatin | KNApSAcK: C00015790 |
| C16H14O4 | 270.08921 | 0.389 | Larrein | FlavonoidViewer: FL1C39NS0001 KNApSAcK: C00006931 LipidMAPS: LMPK12120145 |
| C16H14O4 | 270.08921 | 0.389 | Alloimperatorin | HMDB: HMDB0301848 KEGG: C09053 KNApSAcK: C00002448 |
| C16H14O4 | 270.08921 | 0.389 | Cepacin A | KNApSAcK: C00018582 |
| C16H14O4 | 270.08921 | 0.389 | Bolusanthin III | KNApSAcK: C00020664 |
| C16H14O4 | 270.08921 | 0.389 | 2'-O-Methylisoliquiritigenin | FlavonoidViewer: FL1C1ANS0003 HMDB: HMDB0037319 KEGG: C15531 KNApSAcK: C00006927, C00038229 LipidMAPS: LMPK12120098 |
| C16H14O4 | 270.08921 | 0.389 | 2,7-Dihydroxy-3,5-dimethoxyphenanthrene. | HMDB: HMDB0031612 KNApSAcK: C00015260 |
| C16H14O4 | 270.08921 | 0.389 | Imperatorin | HMDB: HMDB0034376 KEGG: C09269 KNApSAcK: C00002477 |
| C16H14O4 | 270.08921 | 0.389 | Stemanthraquinone | KNApSAcK: C00034283 |
| C16H14O4 | 270.08921 | 0.389 | Methyllucidone | FlavonoidViewer: FL1CUNNS0004 KNApSAcK: C00007170 LipidMAPS: LMPK12120440 |
| C16H14O4 | 270.08921 | 0.389 | Isoliquiritigenin 4'-methyl ether | FlavonoidViewer: FL1C1ANS0004 KNApSAcK: C00006928 LipidMAPS: LMPK12120099 |
| C16H14O4 | 270.08921 | 0.389 | 4,7-Dihydroxy-2,3-dimethoxyphenanthrene | KNApSAcK: C00015543 |
| C16H14O4 | 270.08921 | 0.389 | Pinostrobin | FlavonoidViewer: FL2FA9NS0003 HMDB: HMDB0242619 KEGG: C16419 KNApSAcK: C00008144 LipidMAPS: LMPK12140216 |
| C16H14O4 | 270.08921 | 0.389 | 3,4 | KNApSAcK: C00015304 |
| C16H14O4 | 270.08921 | 0.389 | Alpinetin | FlavonoidViewer: FL2FA9NS0002 HMDB: HMDB0248258 KNApSAcK: C00008143 LipidMAPS: LMPK12140215 |
| C16H14O4 | 270.08921 | 0.389 | Echinatin | FlavonoidViewer: FL1CRTNS0001 KNApSAcK: C00006922 LipidMAPS: LMPK12120431 |
| C11H15O2N4Cl | 270.08835 | 3.555 | Nitenpyram | HMDB: HMDB0255630 KEGG: C18511 |
MSnスペクトル情報
| Level: 2, プリカーサーm/z: 271.09656 |
| Splash: splash10-0159-0900000000-55fb7f12da872e32ed65 |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 167.01 | 8776 | 104 | 1000 |
| 130.88 | 6071 | 140 | 691 |
| 172.97 | 1249 | 98 | 142 |
| 253.08 | 979 | 18 | 111 |
| 229.06 | 752 | 42 | 85 |
| 102.89 | 545 | 168 | 62 |
| 192.95 | 504 | 78 | 57 |
| 164.94 | 456 | 106 | 51 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.583 | [Flavanone]-A(1OH, 1OMe)-B(none) | Flavanone | 7-Hydroxy-8-methoxyflavanone |
| 0.583 | [Flavanone]-A(1OH, 1OMe)-B(none) | Flavanone | Alpinetin |
| 0.583 | [Flavanone]-A(1OH, 1OMe)-B(none) | Flavanone | Pinostrobin |
| 0.545 | [2'-Hydroxychalcone]-A(2OH, 1OMe)-B(none) | 2'-Hydroxychalcone | Flemichapparin |
| 0.545 | [2'-Hydroxychalcone]-A(2OH, 1OMe)-B(none) | 2'-Hydroxychalcone | Larrein |
| 0.545 | [2'-Hydroxychalcone]-A(2OH, 1OMe)-B(none) | 2'-Hydroxychalcone | Cardamonin |
| 0.545 | [2'-Hydroxychalcone]-A(2OH, 1OMe)-B(none) | 2'-Hydroxychalcone | 2',6'-Dihydroxy-4'-methoxychalcone |
| 0.214 | [2'-Hydroxychalcone]-A(1OH, 1OMe)-B(1OH) | 2'-Hydroxychalcone | Isoliquiritigenin 4'-methyl ether |
| 0.214 | [2'-Hydroxychalcone]-A(2OH)-B(1OMe) | 2'-Hydroxychalcone | Isoliquiritigenin 4-methyl ether |
| 0.214 | [2'-Hydroxychalcone]-A(2OH)-B(1OMe) | 2'-Hydroxychalcone | 2',5'-Dihydroxy-4-methoxychalcone |
| 0.190 | [Flavonol]-A(2OH)-B(none) | Flavonol | Galangin |
| 0.188 | [Flavanone]-A(1OH)-B(1OMe) | Flavanone | 4'-Methylliquiritigenin |
| 0.188 | [Flavanone]-A(1OMe)-B(1OH) | Flavanone | Methyl-liquiritigenin |
| 0.130 | [Flavonol]-A(1OH)-B(1OH) | Flavonol | Resokaempferol |
| 0.118 | [Flavone]-A(2OH)-B(1OH) | Flavone | 5,8,2'-Trihydroxyflavone |
| 0.118 | [Flavone]-A(2OH)-B(1OH) | Flavone | 5,7,2'-Trihydroxyflavone |
| 0.118 | [Flavone]-A(2OH)-B(1OH) | Flavone | Apigenin |
| 0.118 | [Flavone]-A(3OH)-B(none) | Flavone | Baicalein |
| 0.118 | [Flavone]-A(3OH)-B(none) | Flavone | Norwogonin |
| 0.118 | [Flavone]-A(1OH)-B(2OH) | Flavone | 7,3',4'-Trihydroxyflavone |
| 0.118 | [Flavone]-A(1OH)-B(2OH) | Flavone | 5,2',5'-Trihydroxyflavone |
| 0.118 | [Anthocyanidin]-A(2OH)-B(1OH) | Anthocyanidin | Pelargonidin |
| 0.118 | [Chalcone]-A(1OH)-B(1OH, 1OMe) | Chalcone | Echinatin |
| 0.118 | [Chalcone]-A(1OH, 1OMe)-B(1OH) | Chalcone | Isoliquiritigenin 2'-methy ether |
| 0.063 | [Isoflavanone]-A(1OH)-B(1OMe) | Isoflavanone | Dihydroformononetin |
| 0.053 | [Isoflavone]-A(2OH)-B(1OH) | Isoflavone | Demethyltexasin |
| 0.053 | [Isoflavone]-A(2OH)-B(1OH) | Isoflavone | 8-Hydroxydaidzein |
| 0.053 | [Isoflavone]-A(2OH)-B(1OH) | Isoflavone | 5,7,2'-Trihydroxyisoflavone |
| 0.053 | [Isoflavone]-A(2OH)-B(1OH) | Isoflavone | 5,7,3'-Trihydroxyisoflavone |
| 0.053 | [Isoflavone]-A(2OH)-B(1OH) | Isoflavone | Genistein |
| 0.053 | [Isoflavone]-A(1OH)-B(2OH) | Isoflavone | 3'-Hydroxydaidzein |
| 0.053 | [Isoflavone]-A(1OH)-B(2OH) | Isoflavone | 2'-Hydroxydaidzein |
| 0.000 | [Pterocarpan]-A(1OH)-B(1OMe) | Pterocarpan | Medicarpin |
| 0.000 | [Pterocarpan]-A(1OMe)-B(1OH) | Pterocarpan | Isomedicarpin |
| 0.000 | [Aurone]-A(1OH)-B(2OH) | Aurone | Sulfuretin |
| 0.000 | [Aurone]-A(2OH)-B(1OH) | Aurone | 4,6,4'-Trihydroxyaurone |
| 0.000 | [UBR-type derivative / 2',5'-Dioxo-3'-cyclopentenyl-type Calcone (alpha-OMe)]-A(1OMe)-B(none) | UBR-type derivative / 2',5'-Dioxo-3'-cyclopentenyl-type Calcone | Methyllucidone |
| 0.000 | [UBR-type derivative / 3',5'-Dioxo-1'-cyclopentenyl-type Dihydrocalcone]-A(3Methyl)-B(none) | UBR-type derivative / 3',5'-Dioxo-1'-cyclopentenyl-type Dihydrocalcone | 4-Hydrocinnamoyl-2,2,5-trimethyl-4-cyclopentene-1,3-dione |
| 0.000 | [Flavanone]-A(2OH, 1Methyl)-B(none) | Flavanone | Strobopinin |
| 0.000 | [Flavanone]-A(2OH, 1Methyl)-B(none) | Flavanone | Cryptostrobin |
| 0.000 | [Flavan]-A(1OMe, 1Methyl)-B(1OH) | Flavan | 4'-Hydroxy-7-methoxy-8-methylflavan |
| 0.000 | [Flavan]-A(1OH)-B(1([@@]-Methylenedioxy)) | Flavan | 7-Hydroxy-3',4'-methylenedioxyflavan |
| 0.000 | [Flavan]-A(2OMe)-B(none) | Flavan | Tephrowatsin E |
| 0.000 | [Flavan]-A(1OH, 1OMe, 1Methyl)-B(none) | Flavan | 7-Hydroxy-5-methoxy-6-methylflavan |
| 0.000 | [3-DehydroxyAnthocyanidin]-A(2OH)-B(2OH) | 3-DehydroxyAnthocyanidin | Luteolinidin |
| 0.000 | [isoflavene]-A(1OH)-B(1OH, 1OMe) | isoflavene | Haginin B |
| 0.000 | [2-Phenylbenzofuran]-A(1OMe)-B(1OH, 1OMe) | 2-Phenylbenzofuran | Vignafuran |
| 0.000 | [2-Phenylbenzofuran]-A(1([@@]-Methylenedioxy))-B(2OH) | 2-Phenylbenzofuran | 2',4'-Dihydroxy-5,6-methylenedioxy-2-phenylbenzofuran |
| 0.000 | [Dalbergiquinol]-A(1OH, 2OMe)-B(none) | Dalbergiquinol | 5-Hydroxy-2,4-dimethoxydalbergiquinol |
| 0.000 | [UBR-type derivative / [2,5]-Benzoquinonyl-type Dalbergiquinol]-A(1OMe)-B(1OH) | UBR-type derivative / [2,5]-Benzoquinonyl-type Dalbergiquinol | 4'-Hydroxy-4-methoxydalbergione |