ピーク情報

ポプラ, 幼植物, 地上部

pos

Peak #8599 MN MID: SE205_S08_M90

m/z: 433.16481, RT: 83.22, 強度: 6944, ログ強度: 0.24, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 1

DB検索結果: (4 names) Artocommunol CA;(+)-6-Hydroxy-11-methoxy-3,3-dimethyl-8-(2-methyl-1-propenyl)-3H,7H,8H-bis[1]benzopyrano[4,3-b:6',5'-e]pyran-7-one;Methyltetrapterol A;5,7,2'-Trihydroxy-6-methyl-6'',6''-dimethyl-4'',5...

DBごとのヒット数: ALL 2 KN 2

FlavonoidSearch最大スコア MS2: -, MS3: 0.091

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C26H24O6	432.15729	0.577	Artocommunol CA	FlavonoidViewer: FL3FRNNP0009 KNApSAcK: C00013499 LipidMAPS: LMPK12111534
C26H24O6	432.15729	0.577	Methyltetrapterol A	KNApSAcK: C00018994

MSnスペクトル情報

Level: 2, プリカーサーm/z: 433.16428

Splash: splash10-0002-0091000000-30efbe6239a144f2577f

m/z	Int.	NL	Rel.Int.
299.06	27212	134	1000
339.18	6199	94	227
204.97	1445	228	53

FlavonoidSearch結果

Symbolized Name	MSMS-Category	MSMS-Aglycone
[Flavone]-A(3OMe)-B(4OMe)	Flavone	Agehoustin B
[Flavone]-A(4OMe)-B(3OMe)	Flavone	5,6,7,8,3',4',5'-Heptamethoxyflavone
[Flavone]-A(4OMe)-B(3OMe)	Flavone	Agecorynin C
[Flavone]-A(2OH, 1(C-Glu))-B(1OH)	Flavone	Neovitexin
[Flavone]-A(2OH, 1(C-Glu))-B(1OH)	Flavone	Vitexin
[Flavone]-A(2OH, 1(C-Glu))-B(1OH)	Flavone	Isovitexin
[Flavonol]-A(1OH, 1(C-Glu))-B(1OH)	Flavonol	8-C-Glucosylresokaempferol
[Isoflavone]-A(1OH, 1(C-Glu))-B(2OH)	Isoflavone	8-Glucosyl 3'-hydroxydaidzein
[Isoflavone]-A(2OH, 1(C-Glu))-B(1OH)	Isoflavone	Genistein 8-C-glucoside
[Chalcone]-A(2OMe, 1([@@]-Methylenedioxy))-B(4OMe)	Chalcone	2,3,4,5,2',6'-Hexamethoxy-3',4'-methylenedioxychalcone
[Flavanone]-A(1OH, 1([2,3:@@]-(4-(p-Hydroxyphenyl)-6-oxodihydropyrano)))-B(1OMe)	Flavanone	Calomelanol G
[Flavone]-A(2OH, 1(C-Galactosyl))-B(1OH)	Flavone	8-C-beta-D-Galactopyranosylapigenin
[Flavone]-A(2OH, 1(C-Galactosyl))-B(1OH)	Flavone	6-C-beta-D-Galactosylapigenin
[Flavone]-A(2OH, 1(C-Chinovosyl))-B(2OH)	Flavone	6-C-Chinovopyranosylluteolin
[Flavone]-A(2OH, 1(C-Fucosyl))-B(2OH)	Flavone	6-C-Fucopyranosylluteolin
[Flavone]-A(2OH, 1(C-Rhamnosyl))-B(2OH)	Flavone	8-C-Rhamnopyranosylluteolin
[Flavone]-A(2OH, 1(C-Xylosyl))-B(1OH, 1OMe)	Flavone	5,7,4'-Trihydroxy-3'-methoxyflavone-8-C-beta-D-xylopyranoside
[CCS-type derivative / [2',3]-Prenyloxidoflavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OMe)	CCS-type derivative / [2',3]-Prenyloxidoflavone	Artocommunol CA
[Flavonol (3-OMe)]-A(3OMe)-B(3OMe)	Flavonol	3,5,6,7,3',4',5'-Heptamethoxyflavone
[Flavonol (3-OMe)]-A(3OMe)-B(3OMe)	Flavonol	Benthamitin
[Flavonol (3-OMe)]-A(3OMe)-B(3OMe)	Flavonol	Hibiscetin heptamethyl ether
[Flavonol (3-OMe)]-A(4OMe)-B(2OMe)	Flavonol	3,5,6,7,8,3',4'-Heptamethoxyflavone
[Flavonol (3-OMe)]-A(2OMe, 1([@@]-Methylenedioxy))-B(1OH, 2OMe)	Flavonol	3'-Hydroxy-3,5,8,4',5'-pentamethoxy-6,7-methylenedioxyflavone

Level: 3, プリカーサーm/z: 299.05914

Splash: splash10-0udi-0390000000-7ff44a6f82d3fd3fed25

m/z	Int.	NL	Rel.Int.
204.98	10679	94	1000
178.92	2789	120	261
192.96	1150	106	107
257.11	617	42	57

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.053	[Flavonol]-A(2OMe)-B(none)	Flavonol	Galangin 5,7-dimethyl ether
0.050	[Isoflavone]-A(1OH, 1OMe)-B(1OH)	Isoflavone	8-O-Methylretusin
0.043	[Isoflavone]-A(1OH, 1OMe)-B(1OMe)	Isoflavone	Afrormosin
0.043	[Isoflavone]-A(1OH, 1OMe)-B(1OMe)	Isoflavone	Alfalone
0.043	[Isoflavone]-A(1OH, 1OMe)-B(1OMe)	Isoflavone	5-O-Methylbiochanin A
0.000	[Flavone]-A(1OH)-B(2OMe)	Flavone	7-Hydroxy-3',4'-dimethoxyflavone
0.000	[Flavone]-A(1OMe)-B(1OH, 1OMe)	Flavone	Tithonine
0.000	[Flavone]-A(1OH, 1OMe)-B(1OMe)	Flavone	5-Hydroxy-6,2'-dimethoxyflavone
0.000	[Flavone]-A(1OH, 1OMe)-B(1OMe)	Flavone	5-Hydroxy-7,2'-dimethoxyflavone
0.000	[Flavone]-A(1OH, 1OMe)-B(1OMe)	Flavone	Apigenin 5,4'-dimethyl ether
0.000	[Flavone]-A(2OMe)-B(1OH)	Flavone	Apigenin 5,7-dimethyl ether
0.000	[Flavone]-A(1OH, 1OMe)-B(1OMe)	Flavone	Apigenin 7,4'-dimethyl ether
0.000	[Flavone]-A(1OH, 2OMe)-B(none)	Flavone	Baicalein 5,6-dimethyl ether
0.000	[Flavone]-A(1OH, 2OMe)-B(none)	Flavone	Mosloflavone
0.000	[Flavone]-A(1OH, 2OMe)-B(none)	Flavone	Norwogonin 5,8-dimethyl ether
0.000	[Flavone]-A(1OH, 2OMe)-B(none)	Flavone	Moslosooflavone
0.000	[Isoflavone]-A(1OH)-B(2OMe)	Isoflavone	Cladrin
0.000	[Isoflavone]-A(1OMe)-B(1OH, 1OMe)	Isoflavone	Sayanedine
0.000	[Coumestan]-A(1OH)-B(1OH, 1OMe)	Coumestan	8-Methoxycoumestrol
0.000	[Coumestan]-A(1OH)-B(1OH, 1OMe)	Coumestan	Trifoliol
0.000	[Coumestan]-A(1OH, 1OMe)-B(1OH)	Coumestan	Sativol
0.000	[Chalcone]-A(1OH, 1OMe, 1Formyl)-B(1OH)	Chalcone	Isoneobavachalcone
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1Formyl)-B(1OH)	2'-Hydroxychalcone	Neobavachalcone
0.000	[2'-Hydroxychalcone]-A(1OH, 2OMe, 1Methyl)-B(none)	2'-Hydroxychalcone	Aurentiacin
0.000	[2'-Hydroxychalcone]-A(2OH, 1OMe, 2Methyl)-B(none)	2'-Hydroxychalcone	2',4'-Dihydroxy-6'-methoxy-3',5'-dimethylchalcone
0.000	[UBR-type derivative / 2'-Oxocyclohexa-3',6'-dienyl-type Chalcone]-A(1OH, 1OMe, 2Methyl)-B(none)	UBR-type derivative / 2'-Oxocyclohexa-3',6'-dienyl-type Chalcone	Ceroptene
0.000	[UBR-type derivative / 2'-Oxo-3'-enyl-0-hydroxy-type Chalcone]-A(1Methoxycarbonylmethyl)-B(none)	UBR-type derivative / 2'-Oxo-3'-enyl-0-hydroxy-type Chalcone	Infectocaryone
0.000	[Flavanone]-A(1OMe, 1Methyl)-B(1OMe)	Flavanone	7,4'-Dimethoxy-6-C-methylflavanone
0.000	[Flavanone]-A(2OMe, 1Methyl)-B(none)	Flavanone	5,7-Dimethoxy-6-C-methylflavanone
0.000	[Flavanone]-A(1OH, 1OMe, 2Methyl)-B(none)	Flavanone	5-Hydroxy-7-methoxy-6,8-di-C-methylflavanone
0.000	[Flavanone]-A(1OH, 1OMe, 2Methyl)-B(none)	Flavanone	6,8-Di-C-methylpinocembrin 5-methyl ether
0.000	[Flavanone]-A(2OH, 1Formyl, 1Methyl)-B(none)	Flavanone	Lawinal
0.000	[Flavone]-A(1OH, 1OMe, 1Methyl)-B(1OH)	Flavone	8-Demethylsideroxylin
0.000	[Flavone]-A(2OH, 2Methyl)-B(1OH)	Flavone	Syzalterin
0.000	[Flavone]-A(1OH, 1([@@]-Methylenedioxy))-B(1OH)	Flavone	Kanzakiflavone 2
0.000	[Flavonol (3-OMe)]-A(1OH, 1OMe)-B(none)	Flavonol	Galangin 3,7-dimethyl ether
0.000	[Flavonol (3-OMe)]-A(2OH, 1Methyl)-B(none)	Flavonol	5,7-Dihydroxy-3-methoxy-8-methylflavone
0.000	[Flavonol]-A(1OH, 1OMe, 1Methyl)-B(none)	Flavonol	3,5-Dihydroxy-7-methoxy-8-methylflavone
0.000	[Flavonol]-A(2OH, 2Methyl)-B(none)	Flavonol	6,8-Dimethylgalangin
0.000	[CCS-type derivative / [3,2']-Epoxymethanoflavone]-A(1OH)-B(2OH)	CCS-type derivative / [3,2']-Epoxymethanoflavone	Peltogynin
0.000	[CCS-type derivative / [3,2']-Epoxymethanoflavone]-A(1OH)-B(2OH)	CCS-type derivative / [3,2']-Epoxymethanoflavone	Mopanin
0.000	[3-DehydroxyAnthocyanidin]-A(2OH, 1OMe)-B(1OMe)	3-DehydroxyAnthocyanidin	Carajurin
0.000	[Isoflavone]-A(1OH)-B(1OH, 1([@@]-Methylenedioxy))	Isoflavone	2-Hydroxypseudobaptigenin
0.000	[Isoflavone]-A(1OH)-B(1OH, 1([@@]-Methylenedioxy))	Isoflavone	Glyzaglabrin
0.000	[Isoflavone]-A(2OH)-B(1([@@]-Methylenedioxy))	Isoflavone	5-Hydroxypseudobaptigenin
0.000	[Isoflavone]-A(1OH, 1([@@]-Methylenedioxy))-B(1OH)	Isoflavone	Irisone B
0.000	[Isoflavone]-A(1OH, 1([@@]-Methylenedioxy))-B(1OH)	Isoflavone	Irilone
0.000	[UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavone]-A(1OH)-B(1OMe)	UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavone	Bowdichione
0.000	[Pterocarpan]-A(1OMe)-B(1([@@]-Methylenedioxy))	Pterocarpan	Pterocarpin
0.000	[3-Phenylcoumarin]-A(1OH)-B(1OH, 1([@@]-Methylenedioxy))	3-Phenylcoumarin	7,2'-Dihydroxy-4',5'-methylenedioxy-3-phenylcoumarin
0.000	[4-phenylcoumarin]-A(1OH, 2OMe)-B(none)	4-phenylcoumarin	Kuhlmannin
0.000	[4-phenylcoumarin]-A(2OMe)-B(1OH)	4-phenylcoumarin	4'-Hydroxy-5,7-dimethoxy-4-phenylcoumarin
0.000	[4-phenylcoumarin]-A(1OH, 1OMe)-B(1OMe)	4-phenylcoumarin	5-Hydroxy-7,4'-dimethoxy-4-phenylcoumarin
0.000	[CCS-type derivative / [5,2']-Epoxy-4-phenylcoumarin]-A(1OMe)-B(2OH)	CCS-type derivative / [5,2']-Epoxy-4-phenylcoumarin	4',5'-Dihydroxy-7-methoxy-5,2'-oxido-4-phenylcoumarin

Level: 3, プリカーサーm/z: 339.18152

Splash: splash10-0udi-0090000000-fd3e787382a01ecab093

m/z	Int.	NL	Rel.Int.
204.96	5611	134	1000

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.091	[Pterocarpan]-A(1OH)-B(1OMe, 1(C-Prenyl))	Pterocarpan	Sandwicensin
0.045	[Flavonol]-A(2OH, 1(C-Prenyl))-B(none)	Flavonol	3,5,7-Trihydroxy-8-prenylflavone
0.045	[Flavonol]-A(2OH, 1(C-Prenyl))-B(none)	Flavonol	3,5,7-Trihydroxy-6-prenylflavone
0.000	[Isoflavone]-A(2OH, 1(C-Prenyl))-B(1OH)	Isoflavone	Wighteone
0.000	[Isoflavone]-A(2OH, 1(C-Prenyl))-B(1OH)	Isoflavone	Lupiwighteone
0.000	[Isoflavone]-A(2OH)-B(1OH, 1(C-Prenyl))	Isoflavone	Isowighteone
0.000	[Flavone]-A(2OH)-B(1OH, 1(C-Prenyl))	Flavone	Yinyanghuo D
0.000	[Flavone]-A(2OH, 1(C-Prenyl))-B(1OH)	Flavone	5,7,4'-Trihydroxy-6-prenylflavone
0.000	[Flavone]-A(2OH, 1(C-Prenyl))-B(1OH)	Flavone	Licoflavone C
0.000	[Chalcone]-A(1OH)-B(1OH, 1OMe, 1(C-Prenyl))	Chalcone	Licochalcone C
0.000	[Flavanone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH)	Flavanone	Citflavanone
0.000	[Flavanone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH)	Flavanone	Paratocarpin K
0.000	[Flavanone]-A(1OH, 1OMe, 1(C-Prenyl))-B(none)	Flavanone	5-Methoxy-7-hydroxy-8-C-prenylflavanone
0.000	[Flavanone]-A(1OH, 1OMe, 1(C-Prenyl))-B(none)	Flavanone	Tephrinone
0.000	[Flavanone]-A(1OH, 1OMe, 1(C-Prenyl))-B(none)	Flavanone	5-Hydroxy-7-methoxy-6-C-prenylflavanone
0.000	[Flavanone]-A(1OMe, 1(C-Prenyl))-B(1OH)	Flavanone	4'-Hydroxyisoderricin
0.000	[Flavanone]-A(1OMe, 1(C-Prenyl))-B(1OH)	Flavanone	Bavachinin
0.000	[2'-Hydroxychalcone]-A(3OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(none)	2'-Hydroxychalcone	Mallotus A
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1(C-Prenyl))-B(1OH)	2'-Hydroxychalcone	4-Hydroxyderricin
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1(C-Prenyl))-B(1OH)	2'-Hydroxychalcone	Bavachalcone
0.000	[2'-Hydroxychalcone]-A(2OH, 1OMe, 1(C-Prenyl))-B(none)	2'-Hydroxychalcone	Isoxanthohumol(Helichrysum)
0.000	[2'-Hydroxychalcone]-A(2OH, 1OMe, 1(C-Prenyl))-B(none)	2'-Hydroxychalcone	2',4'-Dihydroxy-6'-methoxy-3'-prenylchalcone
0.000	[2'-Hydroxychalcone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OH)	2'-Hydroxychalcone	3,4,2'-Trihydroxy-6'',6''-dimethylpyrano[2'',3'':4',3']chalcone
0.000	[Auronol (2-OMe)]-A(1([2,3:@@]-Furano))-B(1([@@]-Methylenedioxy))	Auronol	Castillene D
0.000	[Chalcone]-A(1OH)-B(1OH, 1OMe, 1(1,1-Dimethylallyl))	Chalcone	Licochalcone A
0.000	[Chalcone]-A(1OH, 1OMe, 1([2,3:@@]-Furano))-B(1([@@]-Methylenedioxy))	Chalcone	5'-Hydroxy-2'-methoxy-3,4-methylenedioxyfurano[2'',3'':4',3']chalcone
0.000	[beta-Hydroxy(or Oxodihydro)chalcone]-A(1OMe, 1Oxo, 1([2,3:@@]-Furano))-B(1([@@]-Methylenedioxy))	beta-Hydroxy(or Oxodihydro)chalcone	Ovalitenone
0.000	[beta-Hydroxy(or Oxodihydro)chalcone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH)	beta-Hydroxy(or Oxodihydro)chalcone	Glyinflanin B
0.000	[Dihydrochalcone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OMe)	Dihydrochalcone	Crotaramin
0.000	[Flavanone]-A(1OMe, 1(2-Hydroxy-1,1-dimethylallyl))-B(none)	Flavanone	Falciformin
0.000	[Flavanone]-A(2OH, 1(C-Prenyl), 1Methyl)-B(none)	Flavanone	6-C-Prenyl-8-C-methylpinocembrin
0.000	[Flavanone]-A(2OH, 1(C-Prenyl), 1Methyl)-B(none)	Flavanone	5,7-Dihydroxy-6-methyl-8-prenylflavanone
0.000	[Flavanone]-A(2OH, 1(4-Oxoprenyl))-B(none)	Flavanone	5,7-Dihydroxy-8-C-(4-oxoprenyl)flavanone
0.000	[Flavonol]-A(2OH, 1(1,1-Dimethylallyl))-B(none)	Flavonol	8-(1,1-Dimethylallyl)galangin
0.000	[Flavan 4-ol]-A(1OMe, 1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(none)	Flavan 4-ol	Hildgardtol A
0.000	[Flavan 4-ol]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(none)	Flavan 4-ol	Hildgardtol B
0.000	[Flavan]-A(2OMe, 1(C-Prenyl))-B(none)	Flavan	5,7-Dimethoxy-8-prenylflavan
0.000	[CCS-type derivative / [2,3,4:5,4a,4]-(6-Carboxypyrano)anthocyanidin]-A(1OH)-B(1OH)	CCS-type derivative / [2,3,4:5,4a,4]-(6-Carboxypyrano)anthocyanidin	5-Carboxypyranopelargonidin
0.000	[Isoflavone]-A(1OH)-B(1([2,3:@@]-(6,6-Dimethyl-5-hydroxydihydropyrano)))	Isoflavone	Psoralenol
0.000	[Isoflavone]-A(2OH, 1(1,1-Dimethylallyl))-B(1OH)	Isoflavone	6-(1,1-Dimethylallyl)genistein
0.000	[Isoflavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethyldihydropyrano)))-B(1OH)	Isoflavone	Crotalarin
0.000	[Isoflavanone]-A(1([2,3:@@]-Furano))-B(1OMe, 1([@@]-Methylenedioxy))	Isoflavanone	Neotenone
0.000	[Isoflavan]-A(1OH)-B(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))	Isoflavan	2'-O-Methylphaseollinisoflavan
0.000	[Isoflavan]-A(1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH, 1OMe)	Isoflavan	4'-O-Methylglabridin
0.000	[Pterocarpan]-A(1OMe, 1([2,3:@@]-Furano))-B(1([@@]-Methylenedioxy))	Pterocarpan	Ficinin
0.000	[Pterocarpan]-A(1OH, 1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(1OH)	Pterocarpan	Apiocarpin
0.000	[Pterocarpan-6a-ol]-A(1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(1OH)	Pterocarpan-6a-ol	Glyceollin III
0.000	[Pterocarpan-6a-ol]-A(1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH)	Pterocarpan-6a-ol	Glyceollin I
0.000	[Pterocarpan-6a-ol]-A(1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH)	Pterocarpan-6a-ol	Glyceollin II
0.000	[Pterocarpan-6a-ol]-A(1OH)-B(1([2,3:@@]-(6,6-Dimethylpyrano)))	Pterocarpan-6a-ol	Tuberosin
0.000	[2-Phenylbenzofuran]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OH)	2-Phenylbenzofuran	Neoraufurane