ピーク情報
|
ポプラ, 幼植物, 地上部
pos
|
| Peak #8419 MN MID: SE205_S08_M90 |
| m/z: 303.12258, RT: 79.62, 強度: 128553, ログ強度: 1.51, アダクト: [M+CH3OH+H]+, 共有数（同様のピークを含むサンプル数）: 1 |
| DB検索結果: (57 names) Isoimperatorin;Cryptostrobin;3-(4-Methoxyphenyl)-8-hydroxydihydroisocoumarin;Hydrangenol monomethyl ether;4'-Methylliquiritigenin;7-Hydroxy-3',4'-methylenedioxyflavan;Dimethyl [1,1'-biphenyl]-4,4'-dic... |
| DBごとのヒット数: ALL 51 KG 10 KN 39 HM 2 |
| FlavonoidSearch最大スコア MS2: 1.000, MS3: - |
DB検索結果
ppm
| 組成式 | 分子量 | 誤差(Δppm） | 候補化合物名（代表で最短名を記載） | 化合物ID |
|---|---|---|---|---|
| C16H14O4 | 270.08921 | -0.455 | 8-Methylpinocembrin | FlavonoidViewer: FL2FA9NM0004 KNApSAcK: C00008166 LipidMAPS: LMPK12140190 |
| C16H14O4 | 270.08921 | -0.455 | Isoimperatorin | HMDB: HMDB0253646 KEGG: C16976 KNApSAcK: C00030532 |
| C16H14O4 | 270.08921 | -0.455 | 3-(4-Methoxyphenyl)-8-hydroxydihydroisocoumarin | KNApSAcK: C00015276 |
| C16H14O4 | 270.08921 | -0.455 | 4'-Methylliquiritigenin | FlavonoidViewer: FL2F1ANS0003 KNApSAcK: C00008429 LipidMAPS: LMPK12140063 |
| C16H14O4 | 270.08921 | -0.455 | 7-Hydroxy-3',4'-methylenedioxyflavan | FlavonoidViewer: FL6F1CNS0005 KNApSAcK: C00008773 LipidMAPS: LMPK12020248 |
| C16H14O4 | 270.08921 | -0.455 | Dimethyl [1,1'-biphenyl]-4,4'-dicarboxylate | HMDB: HMDB0247395 |
| C16H14O4 | 270.08921 | -0.455 | Vignafuran | FlavonoidViewer: FLII1ANS0001 HMDB: HMDB0033940 KEGG: C08993 KNApSAcK: C00002414 LipidMAPS: LMPK12160036 |
| C16H14O4 | 270.08921 | -0.455 | Methyl-liquiritigenin | FlavonoidViewer: FL2F1ANS0002 KNApSAcK: C00008198 LipidMAPS: LMPK12140062 |
| C16H14O4 | 270.08921 | -0.455 | Nudol | KNApSAcK: C00015898 |
| C16H14O4 | 270.08921 | -0.455 | Haginin B | FlavonoidViewer: FLICWXNS0002 KNApSAcK: C00009749 LipidMAPS: LMPK12080063 |
| C16H14O4 | 270.08921 | -0.455 | Bauhiniastatin 4 | KNApSAcK: C00041373 |
| C16H14O4 | 270.08921 | -0.455 | Strobopinin | FlavonoidViewer: FL2FA9NM0001 KEGG: C09939 KNApSAcK: C00001006 LipidMAPS: LMPK12140187 |
| C16H14O4 | 270.08921 | -0.455 | 3-Hydroxy-5-methoxystilbene-2-carboxylic acid | HMDB: HMDB0040868 KNApSAcK: C00015521 |
| C16H14O4 | 270.08921 | -0.455 | Cardamomin | FlavonoidViewer: FL1CA9NS0003 KNApSAcK: C00006935, C00031536 LipidMAPS: LMPK12120245 |
| C16H14O4 | 270.08921 | -0.455 | 2',6'-Dihydroxy-4'-methoxychalcone | FlavonoidViewer: FL1CA9NS0002 HMDB: HMDB0033702 KNApSAcK: C00006934 LipidMAPS: LMPK12120244 |
| C16H14O4 | 270.08921 | -0.455 | Lantalucratin A | KNApSAcK: C00043655 |
| C16H14O4 | 270.08921 | -0.455 | [(1S,2S)-2-[[2,2-Dimethylpropyl(nonyl)carbamoyl]amino]cyclohexyl] 3-[[(4R)-2,2,5,5-tetramethyl-1,3-dioxane-4-carbonyl]amino]propanoate | HMDB: HMDB0252152 |
| C16H14O4 | 270.08921 | -0.455 | 2',5'-Dihydroxy-4-methoxychalcone | FlavonoidViewer: FL1C9ANS0002 KNApSAcK: C00006930 LipidMAPS: LMPK12120194 |
| C16H14O4 | 270.08921 | -0.455 | Stemofuran D | KNApSAcK: C00046421 |
| C16H14O4 | 270.08921 | -0.455 | Saprionide | KNApSAcK: C00045393 |
| C16H14O4 | 270.08921 | -0.455 | Pacharin | KNApSAcK: C00015833 |
| C16H14O4 | 270.08921 | -0.455 | 6,7-Dihydroxy-2,4-dimethoxyphenanthrene | KNApSAcK: C00015609 |
| C16H14O4 | 270.08921 | -0.455 | Flemichapparin | FlavonoidViewer: FL1C29NS0001 KNApSAcK: C00006932 LipidMAPS: LMPK12120136 |
| C16H14O4 | 270.08921 | -0.455 | 7-Hydroxy-8-methoxyflavanone | FlavonoidViewer: FL2F39NS0001 KNApSAcK: C00008128 LipidMAPS: LMPK12140089 |
| C16H14O4 | 270.08921 | -0.455 | 3,7-Dihydroxy-2,4-dimethoxyphenanthrene | KNApSAcK: C00015404 |
| C16H14O4 | 270.08921 | -0.455 | Isomedicarpin | FlavonoidViewer: FLID1ANS0003 HMDB: HMDB0033305 KNApSAcK: C00009611 LipidMAPS: LMPK12070030 |
| C16H14O4 | 270.08921 | -0.455 | Isoliquiritigenin 4-methyl ether | FlavonoidViewer: FL1C1ANS0002 KNApSAcK: C00006926 LipidMAPS: LMPK12120097 |
| C16H14O4 | 270.08921 | -0.455 | (S)-4'-Hydroxy-4-methoxydalbergione | FlavonoidViewer: FLND2ANS0001 KNApSAcK: C00010253 LipidMAPS: LMPK12100073 |
| C16H14O4 | 270.08921 | -0.455 | Dihydroformononetin | FlavonoidViewer: FLIB1ANS0002 HMDB: HMDB0033759 KNApSAcK: C00009534 LipidMAPS: LMPK12050448 |
| C16H14O4 | 270.08921 | -0.455 | 3,5-Dihydroxy-2,4-dimethoxyphenanthrene | KNApSAcK: C00015900 |
| C16H14O4 | 270.08921 | -0.455 | Amoenumin | KNApSAcK: C00015735 |
| C16H14O4 | 270.08921 | -0.455 | Hyperolactone C | KNApSAcK: C00043593 |
| C16H14O4 | 270.08921 | -0.455 | (+)-Medicarpin | FlavonoidViewer: FLID1ANS0001 HMDB: HMDB0254403 KEGG: C01729, C10503 KNApSAcK: C00002547, C00018987 LipidMAPS: LMPK12070028 |
| C16H14O4 | 270.08921 | -0.455 | Imbricatin | KNApSAcK: C00015790 |
| C16H14O4 | 270.08921 | -0.455 | Larrein | FlavonoidViewer: FL1C39NS0001 KNApSAcK: C00006931 LipidMAPS: LMPK12120145 |
| C16H14O4 | 270.08921 | -0.455 | Alloimperatorin | HMDB: HMDB0301848 KEGG: C09053 KNApSAcK: C00002448 |
| C16H14O4 | 270.08921 | -0.455 | Cepacin A | KNApSAcK: C00018582 |
| C16H14O4 | 270.08921 | -0.455 | Bolusanthin III | KNApSAcK: C00020664 |
| C16H14O4 | 270.08921 | -0.455 | 2'-O-Methylisoliquiritigenin | FlavonoidViewer: FL1C1ANS0003 HMDB: HMDB0037319 KEGG: C15531 KNApSAcK: C00006927, C00038229 LipidMAPS: LMPK12120098 |
| C16H14O4 | 270.08921 | -0.455 | 2,7-Dihydroxy-3,5-dimethoxyphenanthrene. | HMDB: HMDB0031612 KNApSAcK: C00015260 |
| C16H14O4 | 270.08921 | -0.455 | Imperatorin | HMDB: HMDB0034376 KEGG: C09269 KNApSAcK: C00002477 |
| C16H14O4 | 270.08921 | -0.455 | Stemanthraquinone | KNApSAcK: C00034283 |
| C16H14O4 | 270.08921 | -0.455 | Methyllucidone | FlavonoidViewer: FL1CUNNS0004 KNApSAcK: C00007170 LipidMAPS: LMPK12120440 |
| C16H14O4 | 270.08921 | -0.455 | Isoliquiritigenin 4'-methyl ether | FlavonoidViewer: FL1C1ANS0004 KNApSAcK: C00006928 LipidMAPS: LMPK12120099 |
| C16H14O4 | 270.08921 | -0.455 | 4,7-Dihydroxy-2,3-dimethoxyphenanthrene | KNApSAcK: C00015543 |
| C16H14O4 | 270.08921 | -0.455 | Pinostrobin | FlavonoidViewer: FL2FA9NS0003 HMDB: HMDB0242619 KEGG: C16419 KNApSAcK: C00008144 LipidMAPS: LMPK12140216 |
| C16H14O4 | 270.08921 | -0.455 | 3,4 | KNApSAcK: C00015304 |
| C16H14O4 | 270.08921 | -0.455 | Alpinetin | FlavonoidViewer: FL2FA9NS0002 HMDB: HMDB0248258 KNApSAcK: C00008143 LipidMAPS: LMPK12140215 |
| C16H14O4 | 270.08921 | -0.455 | Echinatin | FlavonoidViewer: FL1CRTNS0001 KNApSAcK: C00006922 LipidMAPS: LMPK12120431 |
| C11H15O2N4Cl | 270.08835 | 2.711 | Nitenpyram | HMDB: HMDB0255630 KEGG: C18511 |
MSnスペクトル情報
| Level: 2, プリカーサーm/z: 303.12225 |
| Splash: splash10-00dl-0900000000-a11a77fa3c2a620c7de7 |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 120.93 | 273660 | 182 | 1000 |
| 140.93 | 155647 | 162 | 568 |
| 163.00 | 52581 | 140 | 192 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 1.000 | [Dihydrochalcone]-A(2OH, 1OMe)-B(1OMe) | Dihydrochalcone | Lusianin |
| 1.000 | [Dihydrochalcone]-A(2OH, 1OMe)-B(1OMe) | Dihydrochalcone | Calomelanone |
| 1.000 | [Dihydrochalcone]-A(2OH, 1OMe)-B(1OMe) | Dihydrochalcone | 2',4'-Dihydroxy-4,6'-dimethoxydihydrochalcone |
| 0.333 | [Flavan 3-ol]-A(1OH, 1OMe)-B(1OMe) | Flavan 3-ol | Afzelechin 5,4'-dimethyl ether |
| 0.200 | [Isoflavanone]-A(1OH)-B(2OH, 1OMe) | Isoflavanone | 7,2',3'-Trihydroxy-4'-methoxyisoflavanone |
| 0.143 | [Isoflavan]-A(1OH, 1OMe)-B(1OH, 1OMe) | Isoflavan | 5-Methoxyvestitol |
| 0.091 | [2'-Hydroxychalcone]-A(2OH, 1OMe)-B(2OH) | 2'-Hydroxychalcone | Lanceoletin |
| 0.077 | [Flavanone]-A(1OH, 1OMe)-B(2OH) | Flavanone | 8-Methoxybutin |
| 0.077 | [Flavanone]-A(1OH, 1OMe)-B(2OH) | Flavanone | 7,2',6'-Trihydroxy-5-methoxyflavanone |
| 0.077 | [Flavanone]-A(1OH, 1OMe)-B(2OH) | Flavanone | Scutamoenin |
| 0.077 | [Flavanone]-A(1OH, 1OMe)-B(2OH) | Flavanone | 5,2',3'-Trihydroxy-7-methoxyflavanone |
| 0.077 | [Flavanone]-A(1OH, 1OMe)-B(2OH) | Flavanone | Eriodictyol 5-methyl ether |
| 0.077 | [Flavanone]-A(1OH, 1OMe)-B(2OH) | Flavanone | Sternbin |
| 0.077 | [Flavanone]-A(1OH, 1OMe)-B(2OH) | Flavanone | Artocarpanone |
| 0.077 | [Chalcone]-A(2OH)-B(2OH, 1OMe) | Chalcone | 3,4,3',4'-Tetrahydroxy-2-methoxychalcone |
| 0.077 | [Flavanone]-A(2OH, 1OMe)-B(1OH) | Flavanone | 5,7,4'-Trihydroxy-6-methoxyflavanone |
| 0.077 | [Flavanone]-A(2OH, 1OMe)-B(1OH) | Flavanone | 5,8,2'-Trihydroxy-7-methoxyflavanone |
| 0.077 | [Flavanone]-A(2OH, 1OMe)-B(1OH) | Flavanone | 5,7,4'-Trihydroxy-8-methoxyflavanone |
| 0.050 | [Flavonol]-A(3OH)-B(1OH) | Flavonol | 6-Hydroxykaempferol |
| 0.050 | [Flavonol]-A(3OH)-B(1OH) | Flavonol | Herbacetin |
| 0.050 | [Flavonol]-A(1OH)-B(3OH) | Flavonol | Robinetin |
| 0.050 | [Flavonol]-A(1OH)-B(3OH) | Flavonol | 3,7,2',3',4'-Pentahydroxyflavone |
| 0.000 | [Flavone]-A(3OH)-B(2OH) | Flavone | 6-Hydroxyluteolin |
| 0.000 | [Flavone]-A(3OH)-B(2OH) | Flavone | Hypolaetin |
| 0.000 | [Flavone]-A(2OH)-B(3OH) | Flavone | Tricetin |
| 0.000 | [Flavone]-A(2OH)-B(3OH) | Flavone | Isoetin |
| 0.000 | [Dihydroflavonol (3-OMe)]-A(2OH)-B(1OH) | Dihydroflavonol | Aromadendrin 3-methyl ether |
| 0.000 | [Dihydroflavonol (3-OMe)]-A(1OH)-B(2OH) | Dihydroflavonol | 3-O-Methyl-2,3-trans-fustin |
| 0.000 | [Anthocyanidin]-A(2OH)-B(3OH) | Anthocyanidin | Delphinidin |
| 0.000 | [Anthocyanidin]-A(3OH)-B(2OH) | Anthocyanidin | 6-Hydroxycyanidin |
| 0.000 | [Dihydroflavonol]-A(2OH, 1OMe)-B(none) | Dihydroflavonol | Alnustinol |
| 0.000 | [Dihydroflavonol]-A(2OH)-B(1OMe) | Dihydroflavonol | Aromadendrin 4'-methyl ether |
| 0.000 | [Dihydroflavonol]-A(2OH, 1OMe)-B(none) | Dihydroflavonol | 3,5,8-Trihydroxy-7-methoxyflavanone |
| 0.000 | [Dihydroflavonol]-A(1OH, 1OMe)-B(1OH) | Dihydroflavonol | Aromadendrin 5-methyl ether |
| 0.000 | [Dihydroflavonol]-A(1OH, 1OMe)-B(1OH) | Dihydroflavonol | Aromadendrin 7-methyl ether |
| 0.000 | [Flavanone]-A(3OH, 1OMe)-B(none) | Flavanone | Oresbiusin |
| 0.000 | [Flavanone]-A(2OH)-B(1OH, 1OMe) | Flavanone | Alysifolinone |
| 0.000 | [Flavanone]-A(2OH)-B(1OH, 1OMe) | Flavanone | Homoeriodictyol |
| 0.000 | [Flavanone]-A(2OH)-B(1OH, 1OMe) | Flavanone | Hesperetin |
| 0.000 | [Flavanone]-A(3OH)-B(1OMe) | Flavanone | 4'-O-Methylcarthamidin |
| 0.000 | [Flavanone]-A(3OH)-B(1OMe) | Flavanone | 5,7,8-Trihydroxy-4'-methoxyflavanone |
| 0.000 | [Isoflavan]-A(2OMe)-B(2OH) | Isoflavan | Lotisoflavan |
| 0.000 | [Isoflavan]-A(1OH)-B(1OH, 2OMe) | Isoflavan | Sphaerosin |
| 0.000 | [Isoflavan]-A(1OH)-B(1OH, 2OMe) | Isoflavan | 4',7-Dihydroxy-2',3'-dimethoxyisoflavan (+-) |
| 0.000 | [Isoflavan]-A(1OH)-B(1OH, 2OMe) | Isoflavan | Mucronulatol |
| 0.000 | [Isoflavan]-A(1OH)-B(1OH, 2OMe) | Isoflavan | Isomucronulatol |
| 0.000 | [Isoflavan]-A(1OH)-B(1OH, 2OMe) | Isoflavan | Methoxyvestitol |
| 0.000 | [Dihydrochalcone]-A(1OH, 2OMe)-B(1OH) | Dihydrochalcone | Dihydroflavokawain C |
| 0.000 | [Dihydrochalcone]-A(1OH)-B(1OH, 2OMe) | Dihydrochalcone | 2,4'-Dihydroxy-4,6-dimethoxydihydrochalcone |
| 0.000 | [Dihydrochalcone]-A(1OH)-B(1OH, 2OMe) | Dihydrochalcone | 4,4'-Dihydroxy-2,6-dimethoxydihydrochalcone |
| 0.000 | [Dihydrochalcone]-A(2OH, 2OMe)-B(none) | Dihydrochalcone | Dihydropashanone |
| 0.000 | [Dihydrochalcone]-A(2OH, 2OMe)-B(none) | Dihydrochalcone | 2',4'-Dihydroxy-3',6'-dimethoxydihydrochalcone |
| 0.000 | [Dihydrochalcone]-A(2OH, 2OMe)-B(none) | Dihydrochalcone | 2',3'-Dihydroxy-4',6'-dimethoxydihydrochalcone |
| 0.000 | [2'-Hydroxychalcone]-A(3OH)-B(1OH, 1OMe) | 2'-Hydroxychalcone | Okanin 4-methyl ether |
| 0.000 | [2'-Hydroxychalcone]-A(3OH)-B(1OH, 1OMe) | 2'-Hydroxychalcone | 4,2',4',6'-Tetrahydroxy-3-methoxychalcone |
| 0.000 | [Isoflavone]-A(3OH)-B(2OH) | Isoflavone | 5,7,8,2',4'-Pentahydroxyisoflavone |
| 0.000 | [Flavonol]-A(2OH)-B(2OH) | Flavonol | Rhynchosin |
| 0.000 | [Flavonol]-A(2OH)-B(2OH) | Flavonol | Melanoxetin |
| 0.000 | [Flavonol]-A(2OH)-B(2OH) | Flavonol | Quercetin |
| 0.000 | [Flavonol]-A(2OH)-B(2OH) | Flavonol | Morin |
| 0.000 | [Flavonol]-A(2OH)-B(2OH) | Flavonol | 3,5,7,2',5'-Pentahydroxyflavone |
| 0.000 | [Flavonol]-A(2OH)-B(2OH) | Flavonol | Viscidulin I |
| 0.000 | [Isoflavanone]-A(2OH)-B(1OH, 1OMe) | Isoflavanone | Ferreirin |
| 0.000 | [Isoflavanone]-A(2OH)-B(1OH, 1OMe) | Isoflavanone | Isoferreirin |
| 0.000 | [Aurone]-A(2OH)-B(3OH) | Aurone | Bracteatin |
| 0.000 | [Auronol]-A(1OH)-B(1OH, 1OMe) | Auronol | 2,6,3'-Trihydroxy-4'-methoxy-2-benzylcoumaranone |
| 0.000 | [Auronol]-A(1OH, 1OMe)-B(1OH) | Auronol | Carpusin |
| 0.000 | [Dihydrochalcone]-A(2OH, 1OMe, 1Methyl)-B(1OH) | Dihydrochalcone | 4,2',6'-Trihydroxy-4'-methoxy-3'-methyldihydrochalcone |
| 0.000 | [Dihydrochalcone alpha-ol]-A(1OH, 1OMe)-B(1OMe) | Dihydrochalcone alpha-ol | Odoratol |
| 0.000 | [UBR-type derivative / 2'-Oxocyclohexa-4',6'-dienyl-type Dihydrochalcone]-A(3OH, 2Methyl)-B(none) | UBR-type derivative / 2'-Oxocyclohexa-4',6'-dienyl-type Dihydrochalcone | Ceratiolin |
| 0.000 | [Flavanone]-A(2OH, 1Methyl)-B(2OH) | Flavanone | 5,7,3',5'-Tetrahydroxy-6-methylflavanone |
| 0.000 | [Flavanone]-A(2OH, 1Methyl)-B(2OH) | Flavanone | 6-C-Methyleriodictylol |
| 0.000 | [Flavanone]-A(2OH)-B(2OH, 1Methyl) | Flavanone | 5'-C-Methyleriodictylol |
| 0.000 | [Dihydroflavonol]-A(2OH, 1Methyl)-B(1OH) | Dihydroflavonol | 6-Methylaromadendrin |
| 0.000 | [Flavan 4-ol]-A(2OH, 1Hydroxymethyl, 1Methyl)-B(none) | Flavan 4-ol | 4,5,7-Trihydroxy-6-hydroxymethyl-8-methylflavan |
| 0.000 | [CCS-type derivative / [3,2']-Epoxymethanoflavan 4-ol]-A(1OH)-B(2OH) | CCS-type derivative / [3,2']-Epoxymethanoflavan 4-ol | Peltogynan-4-alpha-ol |
| 0.000 | [CCS-type derivative / [3,2']-Epoxymethanoflavan 4-ol]-A(1OH)-B(2OH) | CCS-type derivative / [3,2']-Epoxymethanoflavan 4-ol | Mopanan-4-alpha-ol |
| 0.000 | [Flavan]-A(2OH)-B(2OMe) | Flavan | Diffutidin |
| 0.000 | [Flavan]-A(2OMe)-B(2OH) | Flavan | 3',4'-Dihydroxy-5,7-dimethoxyflavan |
| 0.000 | [Pterocarpan-6a-ol]-A(1OH)-B(1OH, 1OMe) | Pterocarpan-6a-ol | 6a,7-Dihydroxymedicarpin |
| 0.000 | [[3,2']-Methano-4-phenylchroman (3-OH)]-A(2OH)-B(2OH) | [3,2']-Methano-4-phenylchroman | Haematoxylin |
| Level: 3, プリカーサーm/z: 140.93304 |
| Splash: splash10-0bt9-1900000000-2620832da82bd2dbaaa5 |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 108.97 | 992 | 32 | 1000 |
| 125.85 | 433 | 15 | 436 |
| 122.93 | 373 | 18 | 375 |
| 112.82 | 326 | 28 | 328 |
| 66.83 | 212 | 74 | 214 |
| 140.96 | 212 | -0 | 213 |
| 110.90 | 186 | 30 | 187 |
| 98.76 | 115 | 42 | 115 |
| 80.84 | 63 | 60 | 63 |
FlavonoidSearch結果
ヒットなし