ピーク情報
|
ポプラ, 幼植物, 地上部
pos
|
| Peak #7412 MN MID: SE205_S08_M90 |
| m/z: 405.11804, RT: 64.89, 強度: 55962, ログ強度: 1.15, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 1 |
| DB検索結果: (34 names) 3,5-Dihydroxy-6,7,8,3',4'-pentamethoxyflavone;Agehoustin F;6,2'-Dihydroxy-3,5,7,4',5'-pentamethoxyflavone;6,5'-Dihydroxy-3,5,7,2',4'-pentamethoxyflavone;Conyzatin;5,3'-Dihydroxy-3,6,7,8,4'-pentamethox... |
| DBごとのヒット数: ALL 31 KN 27 HM 4 |
| FlavonoidSearch最大スコア MS2: 0.059, MS3: 0.040 |
DB検索結果
ppm
| 組成式 | 分子量 | 誤差(Δppm） | 候補化合物名（代表で最短名を記載） | 化合物ID |
|---|---|---|---|---|
| C20H20O9 | 404.11073 | 0.074 | 3,5-Dihydroxy-6,7,8,3',4'-pentamethoxyflavone | FlavonoidViewer: FL5FGCNS0016 KNApSAcK: C00004801 LipidMAPS: LMPK12113342 |
| C20H20O9 | 404.11073 | 0.074 | Agehoustin F | FlavonoidViewer: FL3FGLNS0003 KNApSAcK: C00003967 LipidMAPS: LMPK12111501 |
| C20H20O9 | 404.11073 | 0.074 | 6,2'-Dihydroxy-3,5,7,4',5'-pentamethoxyflavone | FlavonoidViewer: FL5FELNS0013 KNApSAcK: C00004816 LipidMAPS: LMPK12113060 |
| C20H20O9 | 404.11073 | 0.074 | 6,5'-Dihydroxy-3,5,7,2',4'-pentamethoxyflavone | FlavonoidViewer: FL5FELNS0012 KNApSAcK: C00004815 LipidMAPS: LMPK12113059 |
| C20H20O9 | 404.11073 | 0.074 | Conyzatin | FlavonoidViewer: FL5FFGNS0006 KNApSAcK: C00004846 LipidMAPS: LMPK12113277 |
| C20H20O9 | 404.11073 | 0.074 | 5,3'-Dihydroxy-3,6,7,8,4'-pentamethoxyflavone | FlavonoidViewer: FL5FGCNS0015 KNApSAcK: C00004800 LipidMAPS: LMPK12113341 |
| C20H20O9 | 404.11073 | 0.074 | Apulein | FlavonoidViewer: FL5FELNS0011 KNApSAcK: C00004814 LipidMAPS: LMPK12113058 |
| C20H20O9 | 404.11073 | 0.074 | 5,2'-Dihydroxy-3,6,7,8,4'-pentamethoxyflavone | FlavonoidViewer: FL5FGLNS0003 KNApSAcK: C00004783 LipidMAPS: LMPK12113376 |
| C20H20O9 | 404.11073 | 0.074 | 2,2'-Dihydroxy-3,4,5,6'-tetramethoxy-3',4'-methylenedioxychalcone | FlavonoidViewer: FL1CELNS0003 KNApSAcK: C00007031 LipidMAPS: LMPK12120353 |
| C20H20O9 | 404.11073 | 0.074 | 5,3'-Dihydroxy-3,6,7,4',5'-pentamethoxyflavone | FlavonoidViewer: FL5FEGNS0014 KNApSAcK: C00004834 LipidMAPS: LMPK12110622 |
| C20H20O9 | 404.11073 | 0.074 | Murrayanol | FlavonoidViewer: FL5FEGNS0013 KNApSAcK: C00004833 LipidMAPS: LMPK12110621 |
| C20H20O9 | 404.11073 | 0.074 | Gardenin C | FlavonoidViewer: FL3FGGNS0003 KNApSAcK: C00003972 LipidMAPS: LMPK12111489 |
| C20H20O9 | 404.11073 | 0.074 | Chalconaringenin 2'-xyloside | FlavonoidViewer: FL1CAAGS0003 KNApSAcK: C00007880 LipidMAPS: LMPK12120249 |
| C20H20O9 | 404.11073 | 0.074 | cis-Resveratrol 4'-O-glucuronide | HMDB: HMDB0041713, HMDB0041783 |
| C20H20O9 | 404.11073 | 0.074 | Wattersiixanthone B | KNApSAcK: C00046975 |
| C20H20O9 | 404.11073 | 0.074 | Apuleirin | FlavonoidViewer: FL5FEGNS0012 KNApSAcK: C00004832 LipidMAPS: LMPK12110620 |
| C20H20O9 | 404.11073 | 0.074 | Irisjaponin A | KNApSAcK: C00019496 |
| C20H20O9 | 404.11073 | 0.074 | cis-Resveratrol 3-O-glucuronide | HMDB: HMDB0041711, HMDB0041782 |
| C20H20O9 | 404.11073 | 0.074 | Cassiaside | HMDB: HMDB0033913 |
| C20H20O9 | 404.11073 | 0.074 | 5,5'-Dihidroxy-3,6,7,2',4'-pentamethoxyflavone | FlavonoidViewer: FL5FELNS0014 KNApSAcK: C00004817 LipidMAPS: LMPK12113061 |
| C20H20O9 | 404.11073 | 0.074 | 5,4'-Dihydroxy-6,7,8,3',5'-pentamethoxyflavone | FlavonoidViewer: FL3FGGNS0012 KNApSAcK: C00013347 LipidMAPS: LMPK12111498 |
| C20H20O9 | 404.11073 | 0.074 | Sculezonone B | KNApSAcK: C00046919 |
| C20H20O9 | 404.11073 | 0.074 | 5,4'-Dihydroxy-3,6,7,8,3'-pentamethoxyflavone | FlavonoidViewer: FL5FGCNS0014 KNApSAcK: C00004799 LipidMAPS: LMPK12113340 |
| C20H20O9 | 404.11073 | 0.074 | 5,8-Dihydroxy-3,7,2',3',4'-pentamethoxyflavone | FlavonoidViewer: FL5FFLNS0004 KNApSAcK: C00004838 LipidMAPS: LMPK12113286 |
| C20H20O9 | 404.11073 | 0.074 | Moracin M 3'-O-beta-glucopyranoside | KNApSAcK: C00019244 |
| C20H20O9 | 404.11073 | 0.074 | Psiadiarabicin | FlavonoidViewer: FL3FELNS0005 KNApSAcK: C00003978 LipidMAPS: LMPK12111285 |
| C20H20O9 | 404.11073 | 0.074 | 5,7-Dihydroxy-3,6,8,3',4'-pentamethoxyflavone | FlavonoidViewer: FL5FGCNS0027 KNApSAcK: C00013377 LipidMAPS: LMPK12113353 |
| C20H20O9 | 404.11073 | 0.074 | Distemonatin | FlavonoidViewer: FL5FELNS0016 KNApSAcK: C00004819 LipidMAPS: LMPK12113063 |
| C20H20O9 | 404.11073 | 0.074 | 5,4'-Dihydroxy-3,6,7,8,2'-pentamethoxyflavone | FlavonoidViewer: FL5FGLNS0002 KNApSAcK: C00004782 LipidMAPS: LMPK12113375 |
| C20H20O9 | 404.11073 | 0.074 | Brickellin | FlavonoidViewer: FL5FELNS0015 KNApSAcK: C00004818 LipidMAPS: LMPK12113062 |
| C21H21O5SF | 404.10937 | 3.438 | Ipragliflozin | HMDB: HMDB0253567 |
MSnスペクトル情報
| Level: 2, プリカーサーm/z: 405.11795 |
| Splash: splash10-001a-0397000000-2cfaf027481d127df332 |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 386.98 | 16122 | 18 | 1000 |
| 248.98 | 9144 | 156 | 567 |
| 230.99 | 8457 | 174 | 524 |
| 120.93 | 6673 | 284 | 413 |
| 242.97 | 2423 | 162 | 150 |
| 369.10 | 2196 | 36 | 136 |
| 126.95 | 2011 | 278 | 124 |
| 225.11 | 1677 | 180 | 104 |
| 265.05 | 1615 | 140 | 100 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.059 | [Dihydroflavonol]-A(1([2,3:@@]-(6,6-Dimethylpyrano)))-B(none) | Dihydroflavonol | MS II |
| 0.059 | [Chalcone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH) | Chalcone | Laxichalcone |
| 0.056 | [Flavanone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1([2,3:@@]-(6,6-Dimethylpyrano))) | Flavanone | Euchrenone a1 |
| 0.053 | [Flavanone]-A(3OMe)-B(3OMe) | Flavanone | 5,6,7,3',4',5'-Hexamethoxyflavanone |
| 0.048 | [2'-Hydroxychalcone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano))) | 2'-Hydroxychalcone | Glyinflanin G |
| 0.000 | [Flavone]-A(1OH, 2OMe)-B(1OH, 3OMe) | Flavone | Psiadiarabicin |
| 0.000 | [Flavone]-A(1OH, 3OMe)-B(1OH, 2OMe) | Flavone | Gardenin C |
| 0.000 | [Flavone]-A(1OH, 3OMe)-B(1OH, 2OMe) | Flavone | 5,4'-Dihydroxy-6,7,8,3',5'-pentamethoxyflavone |
| 0.000 | [Flavone]-A(1OH, 3OMe)-B(1OH, 2OMe) | Flavone | Agehoustin F |
| 0.000 | [Flavonol]-A(1OH, 3OMe)-B(2OMe) | Flavonol | 3,5-Dihydroxy-6,7,8,3',4'-pentamethoxyflavone |
| 0.000 | [2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(6-Methyl-6-(4-Hydroxy-4-methyl-2-pentenyl)pyrano)))-B(none) | 2'-Hydroxychalcone | Boesenbergin A |
| 0.000 | [2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(6-Methyl-6-(4-Hydroxy-4-methyl-2-pentenyl)pyrano)))-B(none) | 2'-Hydroxychalcone | Boesenbergin B |
| 0.000 | [2'-Hydroxychalcone]-A(1OH, 1OMe, 1([@@]-Methylenedioxy))-B(1OH, 3OMe) | 2'-Hydroxychalcone | 2,2'-Dihydroxy-3,4,5,6'-tetramethoxy-3',4'-methylenedioxychalcone |
| 0.000 | [beta-Hydroxy(or Oxodihydro)chalcone]-A(1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano))) | beta-Hydroxy(or Oxodihydro)chalcone | Glyinflanin D |
| 0.000 | [Dihydrochalcone]-A(2OH, 1([2,3:@@]-(4-(p-Hydroxyphenyl)-6-oxodihydropyrano)))-B(none) | Dihydrochalcone | Calomelanol C |
| 0.000 | [Dihydrochalcone]-A(2OH, 1([2,3:@@]-(4-Phenyl-4,5-dihydro-6-oxopyrano)))-B(1OH) | Dihydrochalcone | Calomelanol B |
| 0.000 | [Flavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)), 1(3-Hydroxy-3-methyl-1-butenyl))-B(none) | Flavone | Fulvinervin C |
| 0.000 | [Flavone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH) | Flavone | Laxifolin |
| 0.000 | [Flavone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH) | Flavone | Isolaxifolin |
| 0.000 | [Flavonol]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(none) | Flavonol | Sericetin |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH, 2OMe) | Flavonol | Apuleirin |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH, 2OMe) | Flavonol | Murrayanol |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH, 2OMe) | Flavonol | 5,3'-Dihydroxy-3,6,7,4',5'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(3OMe)-B(2OH, 1OMe) | Flavonol | Apulein |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH, 2OMe) | Flavonol | 6,5'-Dihydroxy-3,5,7,2',4'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH, 2OMe) | Flavonol | 6,2'-Dihydroxy-3,5,7,4',5'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH, 2OMe) | Flavonol | 5,5'-Dihidroxy-3,6,7,2',4'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH, 2OMe) | Flavonol | Brickellin |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1OMe)-B(3OMe) | Flavonol | Distemonatin |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1OMe)-B(3OMe) | Flavonol | Conyzatin |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1OMe)-B(3OMe) | Flavonol | 5,8-Dihydroxy-3,7,2',3',4'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 3OMe)-B(1OH, 1OMe) | Flavonol | 5,4'-Dihydroxy-3,6,7,8,3'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 3OMe)-B(1OH, 1OMe) | Flavonol | 5,3'-Dihydroxy-3,6,7,8,4'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 2OMe)-B(2OMe) | Flavonol | 5,7-Dihydroxy-3,6,8,3',4'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 3OMe)-B(1OH, 1OMe) | Flavonol | 5,4'-Dihydroxy-3,6,7,8,2'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 3OMe)-B(1OH, 1OMe) | Flavonol | 5,2'-Dihydroxy-3,6,7,8,4'-pentamethoxyflavone |
| 0.000 | [4-substituted Flavan (4-(4-Hydroxystyryl))]-A(2OMe)-B(1OH) | 4-substituted Flavan | 4'-Hydroxy-4-(4-hydroxystyryl)-5,7-dimethoxyflavan |
| 0.000 | [Isoflavone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH) | Isoflavone | Osajin |
| 0.000 | [Isoflavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH, 1(C-Prenyl)) | Isoflavone | Chandalone |
| 0.000 | [Isoflavone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH) | Isoflavone | Warangalone |
| 0.000 | [Isoflavone]-A(2OH, 1(C-Prenyl))-B(1([2,3:@@]-(6,6-Dimethylpyrano))) | Isoflavone | Isochandalone |
| 0.000 | [Isoflavone]-A(2OH, 1(C-Prenyl))-B(1([2,3:@@]-(6,6-Dimethylpyrano))) | Isoflavone | Ulexone A |
| 0.000 | [Coumestan]-A(1OH, 1Geranyl)-B(1OH) | Coumestan | Puerarol |
| 0.000 | [4-phenylcoumarin]-A(1([2,3:@@]-(6,6-Dimethylpyrano)), 1([2,3:@@]-(5,6-Dimethyl-4-hydroxydihydropyrano)))-B(none) | 4-phenylcoumarin | Inophyllolide chromanol |
| 0.000 | [4-phenylcoumarin]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(5,6-Dimethyl-4-oxodihydropyrano)))-B(none) | 4-phenylcoumarin | 5-Hydroxy-10-prenyl-7,8-dihydro-7,8-trans-dimethyl-4-phenyl-2H,6H-benzo[1,2-b:5,4-b']dipyran-2,6-dione |
| 0.000 | [4-phenylcoumarin]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)), 1Isovaleryl)-B(none) | 4-phenylcoumarin | Mammeigin |
| 0.000 | [4-phenylcoumarin]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)), 1(2-Methylbutyroyl))-B(none) | 4-phenylcoumarin | 5-Hydroxy-6'',6''-dimethyl-6-(2-methylbutyryl)-4-phenylpyrano[2'',3'':7,8]coumarin |
| Level: 3, プリカーサーm/z: 248.96912 |
| Splash: splash10-0udi-0900000000-51a27caece826a397c97 |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 104.80 | 2652 | 144 | 1000 |
| 188.90 | 248 | 60 | 93 |
| 126.97 | 200 | 122 | 75 |
| 108.96 | 173 | 140 | 65 |
FlavonoidSearch結果
ヒットなし
| Level: 3, プリカーサーm/z: 386.89450 |
| Splash: splash10-00xu-0893000000-71355911f50c071dbc3d |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 120.84 | 741 | 266 | 1000 |
| 242.86 | 657 | 144 | 886 |
| 230.81 | 341 | 156 | 460 |
| 368.92 | 330 | 18 | 445 |
| 126.96 | 231 | 260 | 312 |
| 138.80 | 200 | 248 | 269 |
| 249.16 | 195 | 138 | 262 |
| 265.22 | 108 | 122 | 145 |
| 369.55 | 94 | 17 | 127 |
| 122.75 | 85 | 264 | 114 |
| 247.02 | 72 | 140 | 96 |
| 224.92 | 55 | 162 | 74 |
| 323.44 | 55 | 63 | 74 |
| 111.08 | 53 | 276 | 71 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.040 | [Dihydroflavonol]-A(2OH, 1(C-Prenyl))-B(1OH, 1OMe) | Dihydroflavonol | 3,5,7,4'-Tetrahydroxy-3'-methoxy-8-prenylflavanone |
| 0.036 | [Flavanone]-A(2OH, 1(C-Prenyl))-B(2OH, 1OMe) | Flavanone | Kushenol V |
| 0.036 | [Flavanone]-A(2OH, 1(C-Prenyl))-B(2OH, 1OMe) | Flavanone | Kushenol W |
| 0.036 | [Flavanone]-A(2OH, 1(C-Prenyl))-B(2OH, 1OMe) | Flavanone | Kenusanone D |
| 0.000 | [2'-Hydroxychalcone]-A(2OH, 1([2,3:@@]-(4-Phenyl-4,5-dihydro-6-oxopyrano)))-B(none) | 2'-Hydroxychalcone | 8-Cinnamoyl-3,4-dihydro-5,7-dihydroxy-4-phenylcoumarin |
| 0.000 | [Flavanone]-A(1OH, 1([2,3:@@]-(4-Phenyl-4,5-dihydro-6-oxopyrano)))-B(none) | Flavanone | Calomelanol J |
| 0.000 | [Flavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)), 1(3-Methylbutadienyl))-B(none) | Flavone | Fulvinervin B |
| 0.000 | [Flavone]-A(3OMe)-B(1OMe, 1([@@]-Methylenedioxy)) | Flavone | 5,6,7,3'-Tetramethoxy-4',5'-methylenedioxyflavone |
| 0.000 | [Flavone]-A(1OMe, 1([@@]-Methylenedioxy))-B(3OMe) | Flavone | 5,3',4',5'-Tetramethoxy-6,7-methylenedioxyflavone |
| 0.000 | [Flavone]-A(4OMe)-B(1([@@]-Methylenedioxy)) | Flavone | Linderoflavone B |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1(3-hydroxy-3-methylbutyl))-B(1OH) | Flavonol | Topazolin hydrate |
| 0.000 | [Flavonol]-A(2OH, 1(3-hydroxy-3-methylbutyl))-B(1OMe) | Flavonol | Icaritin |
| 0.000 | [Flavonol (3-OMe)]-A(3OMe)-B(1([@@]-Methylenedioxy)) | Flavonol | Melisimplexin |
| 0.000 | [Flavonol (3-OMe)]-A(3OMe)-B(1([@@]-Methylenedioxy)) | Flavonol | Meliternin |
| 0.000 | [Flavan 3,4-diol (3-OMe)]-A(1OH, 1OMe, 1(C-Prenyl))-B(1OH) | Flavan 3,4-diol | 3,5-Di-O-methyl-8-prenylafzelechin-4beta-ol |
| 0.000 | [Flavan 3,4-diol (4-OMe)]-A(1OH, 1OMe, 1(C-Prenyl))-B(1OH) | Flavan 3,4-diol | 4,5-Di-O-methyl-8-prenylafzelechin-4beta-ol |
| 0.000 | [Isoflavone]-A(1OH)-B(2OH, 1OMe, 1(3-hydroxy-3-methylbutyl)) | Isoflavone | Kwakhurin hydrate |
| 0.000 | [Isoflavone]-A(1OMe, 1([@@]-Methylenedioxy))-B(3OMe) | Isoflavone | Irisflorentin |
| 0.000 | [Isoflavone]-A(4OMe)-B(1([@@]-Methylenedioxy)) | Isoflavone | 5,6,7,8-Tetramethoxy-3',4'-methylenedioxyisoflavone |
| 0.000 | [Isoflavanone-3-ol]-A(1OH)-B(2OH, 1OMe, 1(1,1-Dimethylallyl)) | Isoflavanone-3-ol | Secundifloran |