ピーク情報
|
ポプラ, 幼植物, 地上部
pos
|
| Peak #5795 MN MID: SE205_S08_M90 |
| m/z: 405.11840, RT: 53.94, 強度: 26251, ログ強度: 0.82, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 2 |
| DB検索結果: (34 names) 3,5-Dihydroxy-6,7,8,3',4'-pentamethoxyflavone;Agehoustin F;6,2'-Dihydroxy-3,5,7,4',5'-pentamethoxyflavone;6,5'-Dihydroxy-3,5,7,2',4'-pentamethoxyflavone;Conyzatin;5,3'-Dihydroxy-3,6,7,8,4'-pentamethox... |
| DBごとのヒット数: ALL 31 KN 27 HM 4 |
| FlavonoidSearch最大スコア MS2: 0.091, MS3: 0.045 |
DB検索結果
ppm
| 組成式 | 分子量 | 誤差(Δppm） | 候補化合物名（代表で最短名を記載） | 化合物ID |
|---|---|---|---|---|
| C20H20O9 | 404.11073 | 0.958 | 3,5-Dihydroxy-6,7,8,3',4'-pentamethoxyflavone | FlavonoidViewer: FL5FGCNS0016 KNApSAcK: C00004801 LipidMAPS: LMPK12113342 |
| C20H20O9 | 404.11073 | 0.958 | Agehoustin F | FlavonoidViewer: FL3FGLNS0003 KNApSAcK: C00003967 LipidMAPS: LMPK12111501 |
| C20H20O9 | 404.11073 | 0.958 | 6,2'-Dihydroxy-3,5,7,4',5'-pentamethoxyflavone | FlavonoidViewer: FL5FELNS0013 KNApSAcK: C00004816 LipidMAPS: LMPK12113060 |
| C20H20O9 | 404.11073 | 0.958 | 6,5'-Dihydroxy-3,5,7,2',4'-pentamethoxyflavone | FlavonoidViewer: FL5FELNS0012 KNApSAcK: C00004815 LipidMAPS: LMPK12113059 |
| C20H20O9 | 404.11073 | 0.958 | Conyzatin | FlavonoidViewer: FL5FFGNS0006 KNApSAcK: C00004846 LipidMAPS: LMPK12113277 |
| C20H20O9 | 404.11073 | 0.958 | 5,3'-Dihydroxy-3,6,7,8,4'-pentamethoxyflavone | FlavonoidViewer: FL5FGCNS0015 KNApSAcK: C00004800 LipidMAPS: LMPK12113341 |
| C20H20O9 | 404.11073 | 0.958 | Apulein | FlavonoidViewer: FL5FELNS0011 KNApSAcK: C00004814 LipidMAPS: LMPK12113058 |
| C20H20O9 | 404.11073 | 0.958 | 5,2'-Dihydroxy-3,6,7,8,4'-pentamethoxyflavone | FlavonoidViewer: FL5FGLNS0003 KNApSAcK: C00004783 LipidMAPS: LMPK12113376 |
| C20H20O9 | 404.11073 | 0.958 | 2,2'-Dihydroxy-3,4,5,6'-tetramethoxy-3',4'-methylenedioxychalcone | FlavonoidViewer: FL1CELNS0003 KNApSAcK: C00007031 LipidMAPS: LMPK12120353 |
| C20H20O9 | 404.11073 | 0.958 | 5,3'-Dihydroxy-3,6,7,4',5'-pentamethoxyflavone | FlavonoidViewer: FL5FEGNS0014 KNApSAcK: C00004834 LipidMAPS: LMPK12110622 |
| C20H20O9 | 404.11073 | 0.958 | Murrayanol | FlavonoidViewer: FL5FEGNS0013 KNApSAcK: C00004833 LipidMAPS: LMPK12110621 |
| C20H20O9 | 404.11073 | 0.958 | Gardenin C | FlavonoidViewer: FL3FGGNS0003 KNApSAcK: C00003972 LipidMAPS: LMPK12111489 |
| C20H20O9 | 404.11073 | 0.958 | Chalconaringenin 2'-xyloside | FlavonoidViewer: FL1CAAGS0003 KNApSAcK: C00007880 LipidMAPS: LMPK12120249 |
| C20H20O9 | 404.11073 | 0.958 | cis-Resveratrol 4'-O-glucuronide | HMDB: HMDB0041713, HMDB0041783 |
| C20H20O9 | 404.11073 | 0.958 | Wattersiixanthone B | KNApSAcK: C00046975 |
| C20H20O9 | 404.11073 | 0.958 | Apuleirin | FlavonoidViewer: FL5FEGNS0012 KNApSAcK: C00004832 LipidMAPS: LMPK12110620 |
| C20H20O9 | 404.11073 | 0.958 | Irisjaponin A | KNApSAcK: C00019496 |
| C20H20O9 | 404.11073 | 0.958 | cis-Resveratrol 3-O-glucuronide | HMDB: HMDB0041711, HMDB0041782 |
| C20H20O9 | 404.11073 | 0.958 | Cassiaside | HMDB: HMDB0033913 |
| C20H20O9 | 404.11073 | 0.958 | 5,5'-Dihidroxy-3,6,7,2',4'-pentamethoxyflavone | FlavonoidViewer: FL5FELNS0014 KNApSAcK: C00004817 LipidMAPS: LMPK12113061 |
| C20H20O9 | 404.11073 | 0.958 | 5,4'-Dihydroxy-6,7,8,3',5'-pentamethoxyflavone | FlavonoidViewer: FL3FGGNS0012 KNApSAcK: C00013347 LipidMAPS: LMPK12111498 |
| C20H20O9 | 404.11073 | 0.958 | Sculezonone B | KNApSAcK: C00046919 |
| C20H20O9 | 404.11073 | 0.958 | 5,4'-Dihydroxy-3,6,7,8,3'-pentamethoxyflavone | FlavonoidViewer: FL5FGCNS0014 KNApSAcK: C00004799 LipidMAPS: LMPK12113340 |
| C20H20O9 | 404.11073 | 0.958 | 5,8-Dihydroxy-3,7,2',3',4'-pentamethoxyflavone | FlavonoidViewer: FL5FFLNS0004 KNApSAcK: C00004838 LipidMAPS: LMPK12113286 |
| C20H20O9 | 404.11073 | 0.958 | Moracin M 3'-O-beta-glucopyranoside | KNApSAcK: C00019244 |
| C20H20O9 | 404.11073 | 0.958 | Psiadiarabicin | FlavonoidViewer: FL3FELNS0005 KNApSAcK: C00003978 LipidMAPS: LMPK12111285 |
| C20H20O9 | 404.11073 | 0.958 | 5,7-Dihydroxy-3,6,8,3',4'-pentamethoxyflavone | FlavonoidViewer: FL5FGCNS0027 KNApSAcK: C00013377 LipidMAPS: LMPK12113353 |
| C20H20O9 | 404.11073 | 0.958 | Distemonatin | FlavonoidViewer: FL5FELNS0016 KNApSAcK: C00004819 LipidMAPS: LMPK12113063 |
| C20H20O9 | 404.11073 | 0.958 | 5,4'-Dihydroxy-3,6,7,8,2'-pentamethoxyflavone | FlavonoidViewer: FL5FGLNS0002 KNApSAcK: C00004782 LipidMAPS: LMPK12113375 |
| C20H20O9 | 404.11073 | 0.958 | Brickellin | FlavonoidViewer: FL5FELNS0015 KNApSAcK: C00004818 LipidMAPS: LMPK12113062 |
| C21H21O5SF | 404.10937 | 4.322 | Ipragliflozin | HMDB: HMDB0253567 |
MSnスペクトル情報
| Level: 2, プリカーサーm/z: 405.11795 |
| Splash: splash10-0019-0194000000-469cfb3ccc33c17234c9 |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 387.01 | 10250 | 18 | 1000 |
| 230.99 | 9267 | 174 | 904 |
| 248.97 | 3285 | 156 | 320 |
| 223.02 | 1898 | 182 | 185 |
| 203.05 | 1629 | 202 | 158 |
| 213.02 | 1435 | 192 | 140 |
| 242.94 | 1217 | 162 | 118 |
| 120.83 | 1204 | 284 | 117 |
| 369.07 | 904 | 36 | 88 |
| 161.05 | 884 | 244 | 86 |
| 204.95 | 812 | 200 | 79 |
| 207.04 | 673 | 198 | 65 |
| 186.95 | 581 | 218 | 56 |
| 247.04 | 514 | 158 | 50 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.091 | [Flavanone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1([2,3:@@]-(6,6-Dimethylpyrano))) | Flavanone | Euchrenone a1 |
| 0.080 | [2'-Hydroxychalcone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano))) | 2'-Hydroxychalcone | Glyinflanin G |
| 0.045 | [Dihydroflavonol]-A(1([2,3:@@]-(6,6-Dimethylpyrano)))-B(none) | Dihydroflavonol | MS II |
| 0.045 | [Chalcone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH) | Chalcone | Laxichalcone |
| 0.042 | [Flavanone]-A(3OMe)-B(3OMe) | Flavanone | 5,6,7,3',4',5'-Hexamethoxyflavanone |
| 0.034 | [Flavonol]-A(1OH, 3OMe)-B(2OMe) | Flavonol | 3,5-Dihydroxy-6,7,8,3',4'-pentamethoxyflavone |
| 0.000 | [Flavone]-A(1OH, 2OMe)-B(1OH, 3OMe) | Flavone | Psiadiarabicin |
| 0.000 | [Flavone]-A(1OH, 3OMe)-B(1OH, 2OMe) | Flavone | Gardenin C |
| 0.000 | [Flavone]-A(1OH, 3OMe)-B(1OH, 2OMe) | Flavone | 5,4'-Dihydroxy-6,7,8,3',5'-pentamethoxyflavone |
| 0.000 | [Flavone]-A(1OH, 3OMe)-B(1OH, 2OMe) | Flavone | Agehoustin F |
| 0.000 | [2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(6-Methyl-6-(4-Hydroxy-4-methyl-2-pentenyl)pyrano)))-B(none) | 2'-Hydroxychalcone | Boesenbergin A |
| 0.000 | [2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(6-Methyl-6-(4-Hydroxy-4-methyl-2-pentenyl)pyrano)))-B(none) | 2'-Hydroxychalcone | Boesenbergin B |
| 0.000 | [2'-Hydroxychalcone]-A(1OH, 1OMe, 1([@@]-Methylenedioxy))-B(1OH, 3OMe) | 2'-Hydroxychalcone | 2,2'-Dihydroxy-3,4,5,6'-tetramethoxy-3',4'-methylenedioxychalcone |
| 0.000 | [beta-Hydroxy(or Oxodihydro)chalcone]-A(1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano))) | beta-Hydroxy(or Oxodihydro)chalcone | Glyinflanin D |
| 0.000 | [Dihydrochalcone]-A(2OH, 1([2,3:@@]-(4-(p-Hydroxyphenyl)-6-oxodihydropyrano)))-B(none) | Dihydrochalcone | Calomelanol C |
| 0.000 | [Dihydrochalcone]-A(2OH, 1([2,3:@@]-(4-Phenyl-4,5-dihydro-6-oxopyrano)))-B(1OH) | Dihydrochalcone | Calomelanol B |
| 0.000 | [Flavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)), 1(3-Hydroxy-3-methyl-1-butenyl))-B(none) | Flavone | Fulvinervin C |
| 0.000 | [Flavone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH) | Flavone | Laxifolin |
| 0.000 | [Flavone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH) | Flavone | Isolaxifolin |
| 0.000 | [Flavonol]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(none) | Flavonol | Sericetin |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH, 2OMe) | Flavonol | Apuleirin |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH, 2OMe) | Flavonol | Murrayanol |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH, 2OMe) | Flavonol | 5,3'-Dihydroxy-3,6,7,4',5'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(3OMe)-B(2OH, 1OMe) | Flavonol | Apulein |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH, 2OMe) | Flavonol | 6,5'-Dihydroxy-3,5,7,2',4'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH, 2OMe) | Flavonol | 6,2'-Dihydroxy-3,5,7,4',5'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH, 2OMe) | Flavonol | 5,5'-Dihidroxy-3,6,7,2',4'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH, 2OMe) | Flavonol | Brickellin |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1OMe)-B(3OMe) | Flavonol | Distemonatin |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1OMe)-B(3OMe) | Flavonol | Conyzatin |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1OMe)-B(3OMe) | Flavonol | 5,8-Dihydroxy-3,7,2',3',4'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 3OMe)-B(1OH, 1OMe) | Flavonol | 5,4'-Dihydroxy-3,6,7,8,3'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 3OMe)-B(1OH, 1OMe) | Flavonol | 5,3'-Dihydroxy-3,6,7,8,4'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 2OMe)-B(2OMe) | Flavonol | 5,7-Dihydroxy-3,6,8,3',4'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 3OMe)-B(1OH, 1OMe) | Flavonol | 5,4'-Dihydroxy-3,6,7,8,2'-pentamethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 3OMe)-B(1OH, 1OMe) | Flavonol | 5,2'-Dihydroxy-3,6,7,8,4'-pentamethoxyflavone |
| 0.000 | [4-substituted Flavan (4-(4-Hydroxystyryl))]-A(2OMe)-B(1OH) | 4-substituted Flavan | 4'-Hydroxy-4-(4-hydroxystyryl)-5,7-dimethoxyflavan |
| 0.000 | [Isoflavone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH) | Isoflavone | Osajin |
| 0.000 | [Isoflavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH, 1(C-Prenyl)) | Isoflavone | Chandalone |
| 0.000 | [Isoflavone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH) | Isoflavone | Warangalone |
| 0.000 | [Isoflavone]-A(2OH, 1(C-Prenyl))-B(1([2,3:@@]-(6,6-Dimethylpyrano))) | Isoflavone | Isochandalone |
| 0.000 | [Isoflavone]-A(2OH, 1(C-Prenyl))-B(1([2,3:@@]-(6,6-Dimethylpyrano))) | Isoflavone | Ulexone A |
| 0.000 | [Coumestan]-A(1OH, 1Geranyl)-B(1OH) | Coumestan | Puerarol |
| 0.000 | [4-phenylcoumarin]-A(1([2,3:@@]-(6,6-Dimethylpyrano)), 1([2,3:@@]-(5,6-Dimethyl-4-hydroxydihydropyrano)))-B(none) | 4-phenylcoumarin | Inophyllolide chromanol |
| 0.000 | [4-phenylcoumarin]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(5,6-Dimethyl-4-oxodihydropyrano)))-B(none) | 4-phenylcoumarin | 5-Hydroxy-10-prenyl-7,8-dihydro-7,8-trans-dimethyl-4-phenyl-2H,6H-benzo[1,2-b:5,4-b']dipyran-2,6-dione |
| 0.000 | [4-phenylcoumarin]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)), 1Isovaleryl)-B(none) | 4-phenylcoumarin | Mammeigin |
| 0.000 | [4-phenylcoumarin]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)), 1(2-Methylbutyroyl))-B(none) | 4-phenylcoumarin | 5-Hydroxy-6'',6''-dimethyl-6-(2-methylbutyryl)-4-phenylpyrano[2'',3'':7,8]coumarin |
| Level: 3, プリカーサーm/z: 387.01178 |
| Splash: splash10-001i-0091000000-8c9622bd33c469db7408 |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 231.05 | 4465 | 156 | 1000 |
| 369.14 | 1024 | 18 | 229 |
| 247.06 | 909 | 140 | 203 |
| 202.97 | 843 | 184 | 188 |
| 257.08 | 390 | 130 | 87 |
| 327.03 | 353 | 60 | 78 |
| 228.99 | 340 | 158 | 76 |
| 175.08 | 328 | 212 | 73 |
| 213.02 | 283 | 174 | 63 |
| 248.92 | 272 | 138 | 60 |
| 160.98 | 233 | 226 | 52 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.045 | [Dihydroflavonol]-A(2OH, 1(C-Prenyl))-B(1OH, 1OMe) | Dihydroflavonol | 3,5,7,4'-Tetrahydroxy-3'-methoxy-8-prenylflavanone |
| 0.040 | [Flavanone]-A(2OH, 1(C-Prenyl))-B(2OH, 1OMe) | Flavanone | Kushenol V |
| 0.040 | [Flavanone]-A(2OH, 1(C-Prenyl))-B(2OH, 1OMe) | Flavanone | Kushenol W |
| 0.040 | [Flavanone]-A(2OH, 1(C-Prenyl))-B(2OH, 1OMe) | Flavanone | Kenusanone D |
| 0.000 | [2'-Hydroxychalcone]-A(2OH, 1([2,3:@@]-(4-Phenyl-4,5-dihydro-6-oxopyrano)))-B(none) | 2'-Hydroxychalcone | 8-Cinnamoyl-3,4-dihydro-5,7-dihydroxy-4-phenylcoumarin |
| 0.000 | [Flavanone]-A(1OH, 1([2,3:@@]-(4-Phenyl-4,5-dihydro-6-oxopyrano)))-B(none) | Flavanone | Calomelanol J |
| 0.000 | [Flavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)), 1(3-Methylbutadienyl))-B(none) | Flavone | Fulvinervin B |
| 0.000 | [Flavone]-A(3OMe)-B(1OMe, 1([@@]-Methylenedioxy)) | Flavone | 5,6,7,3'-Tetramethoxy-4',5'-methylenedioxyflavone |
| 0.000 | [Flavone]-A(1OMe, 1([@@]-Methylenedioxy))-B(3OMe) | Flavone | 5,3',4',5'-Tetramethoxy-6,7-methylenedioxyflavone |
| 0.000 | [Flavone]-A(4OMe)-B(1([@@]-Methylenedioxy)) | Flavone | Linderoflavone B |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1(3-hydroxy-3-methylbutyl))-B(1OH) | Flavonol | Topazolin hydrate |
| 0.000 | [Flavonol]-A(2OH, 1(3-hydroxy-3-methylbutyl))-B(1OMe) | Flavonol | Icaritin |
| 0.000 | [Flavonol (3-OMe)]-A(3OMe)-B(1([@@]-Methylenedioxy)) | Flavonol | Melisimplexin |
| 0.000 | [Flavonol (3-OMe)]-A(3OMe)-B(1([@@]-Methylenedioxy)) | Flavonol | Meliternin |
| 0.000 | [Flavan 3,4-diol (3-OMe)]-A(1OH, 1OMe, 1(C-Prenyl))-B(1OH) | Flavan 3,4-diol | 3,5-Di-O-methyl-8-prenylafzelechin-4beta-ol |
| 0.000 | [Flavan 3,4-diol (4-OMe)]-A(1OH, 1OMe, 1(C-Prenyl))-B(1OH) | Flavan 3,4-diol | 4,5-Di-O-methyl-8-prenylafzelechin-4beta-ol |
| 0.000 | [Isoflavone]-A(1OH)-B(2OH, 1OMe, 1(3-hydroxy-3-methylbutyl)) | Isoflavone | Kwakhurin hydrate |
| 0.000 | [Isoflavone]-A(1OMe, 1([@@]-Methylenedioxy))-B(3OMe) | Isoflavone | Irisflorentin |
| 0.000 | [Isoflavone]-A(4OMe)-B(1([@@]-Methylenedioxy)) | Isoflavone | 5,6,7,8-Tetramethoxy-3',4'-methylenedioxyisoflavone |
| 0.000 | [Isoflavanone-3-ol]-A(1OH)-B(2OH, 1OMe, 1(1,1-Dimethylallyl)) | Isoflavanone-3-ol | Secundifloran |