ピーク情報
|
ポプラ, 幼植物, 地上部
pos
|
| Peak #2318 MN MID: SE205_S08_M90 |
| m/z: 597.14537, RT: 35.16, 強度: 138670, ログ強度: 1.54, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 2 |
| DB検索結果: (24 names) Quercetin 3-lathyroside;Tricetin 6-C-arabinoside-8-C-glucoside;Delphinidin 3-lathyroside;Phlomisflavoside A;(-)-Phlomisflavoside A;Quercetin 3-apiosyl-(1->2)-glucoside;Quercetin 3-vicianoside;Querceti... |
| DBごとのヒット数: ALL 21 KG 2 KN 15 HM 4 |
| FlavonoidSearch最大スコア MS2: -, MS3: 0.583 |
DB検索結果
ppm
| 組成式 | 分子量 | 誤差(Δppm） | 候補化合物名（代表で最短名を記載） | 化合物ID |
|---|---|---|---|---|
| C26H28O16 | 596.13773 | 0.594 | Quercetin 3-lathyroside | FlavonoidViewer: FL5FACGA0004, FL5FACGL0003, FL5FACGL0005 HMDB: HMDB0037536 KEGG: C12637 KNApSAcK: C00005395, C00005403, C00005405 LipidMAPS: LMPK12112044, LMPK12112088, LMPK12112090 |
| C26H28O16 | 596.13773 | 0.594 | Tricetin 6-C-arabinoside-8-C-glucoside | FlavonoidViewer: FL3FAGCS0004 KNApSAcK: C00006190 LipidMAPS: LMPK12110835 |
| C26H28O16 | 596.13773 | 0.594 | Delphinidin 3-lathyroside | FlavonoidViewer: [1]FL7AAGGA0002, [1]FL7AAGGL0003 HMDB: [1]HMDB0038003 KEGG: [1]C20491 KNApSAcK: [1]C00006702, [1]C00006704 LipidMAPS: [1]LMPK12010261, [1]LMPK12010279 |
| C26H28O16 | 596.13773 | 0.594 | Phlomisflavoside A | KNApSAcK: C00033293 |
| C26H28O16 | 596.13773 | 0.594 | Quercetin 3-apiosyl-(1->2)-glucoside | FlavonoidViewer: FL5FACGA0002, FL5FACGL0002 KNApSAcK: C00005393, C00005402 LipidMAPS: LMPK12112042, LMPK12112087 |
| C26H28O16 | 596.13773 | 0.594 | Quercetin 3-vicianoside | FlavonoidViewer: FL5FACGA0003, FL5FACGL0004, FL5FACGL0006 HMDB: HMDB0040488 KNApSAcK: C00005394, C00005404, C00005406 LipidMAPS: LMPK12112043, LMPK12112089, LMPK12112091 |
| C26H28O16 | 596.13773 | 0.594 | Quercetin 3-galactoside-7-xyloside | FlavonoidViewer: FL5FACGA0012, FL5FACGL0014 HMDB: HMDB0037364 KNApSAcK: C00005423, C00005426 LipidMAPS: LMPK12112052, LMPK12112099 |
| C26H28O16 | 596.13773 | 0.594 | Myricetin 3-xylosyl-(1->3)-rhamnoside | FlavonoidViewer: FL5FAGGS0021 KNApSAcK: C00013963 LipidMAPS: LMPK12112453 |
| C26H28O16 | 596.13773 | 0.594 | 6-Hydroxyluteolin 7-sambubioside | FlavonoidViewer: FL3FECGS0034 KNApSAcK: C00004509 LipidMAPS: LMPK12111207 |
| C26H28O16 | 596.13773 | 0.594 | Myricetin 3-xylosyl-(1->2)-rhamnoside | FlavonoidViewer: FL5FAGGS0009 KNApSAcK: C00005738 LipidMAPS: LMPK12112441 |
| C26H28O16 | 596.13773 | 0.594 | Quercetin 3-O-(2-O-beta-D-xylopyranosyl-beta-D-galactopyranoside) | HMDB: HMDB0302323 |
| C26H28O16 | 596.13773 | 0.594 | Isoetin 7-glucoside-2'-xyloside | FlavonoidViewer: FL3FALGS0004 KNApSAcK: C00004474 LipidMAPS: LMPK12110885 |
| C26H28O16 | 596.13773 | 0.594 | Quercetin 3-xyloside-7-glucoside | FlavonoidViewer: FL5FACGS0030, FL5FACGS0031 HMDB: HMDB0037355 KNApSAcK: C00005420, C00005421 LipidMAPS: LMPK12112195, LMPK12112196 |
| C26H28O16 | 596.13773 | 0.594 | 6-Hydroxyluteolin 7-xylosyl-(1->6)-glucoside | FlavonoidViewer: FL3FECGS0044 KNApSAcK: C00013689 LipidMAPS: LMPK12111217 |
| C26H28O16 | 596.13773 | 0.594 | Quercetin 3-gluco-xyloside | HMDB: HMDB0302919 |
| C26H28O16 | 596.13773 | 0.594 | Quercetin 3-O-glucosyl-xyloside | HMDB: HMDB0301687 |
| C26H28O16 | 596.13773 | 0.594 | Quercetin 3-alpha-L-arabinofuranosyl-(1->2)-glucoside | FlavonoidViewer: FL5FACGS0066 KNApSAcK: C00013838 LipidMAPS: LMPK12112231 |
| C26H28O16 | 596.13773 | 0.594 | Quercetin 3-glucosyl-(1->2)-xyloside | FlavonoidViewer: FL5FACGS0024 KNApSAcK: C00005392 LipidMAPS: LMPK12112189 |
| C26H28O16 | 596.13773 | 0.594 | Tricetin 6-C-glucoside-8-C-arabinoside | FlavonoidViewer: FL3FAGCS0003 KNApSAcK: C00006189 LipidMAPS: LMPK12110834 |
| C26H28O16 | 596.13773 | 0.594 | formononetin methylated | HMDB: HMDB0304567 |
| C26H28O16 | 596.13773 | 0.594 | Rhodalidin | FlavonoidViewer: FL5FFAGL0002 KNApSAcK: C00005345 LipidMAPS: LMPK12113105 |
MSnスペクトル情報
| Level: 2, プリカーサーm/z: 597.14447 |
| Splash: splash10-014i-0002900000-65bdb03544353318296a |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 465.05 | 42752 | 132 | 1000 |
| 303.04 | 17040 | 294 | 398 |
| 434.97 | 9356 | 162 | 218 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.000 | [Flavanone]-A(2OH, 2(C-Glu))-B(1OH) | Flavanone | 6,8-Di-C-glucopyranosylnaringenin |
| 0.000 | [Flavone]-A(2OH, 1(C-Glu), 1(C-Arabinosyl))-B(3OH) | Flavone | Tricetin 6-C-glucoside-8-C-arabinoside |
| 0.000 | [Flavone]-A(2OH, 1(C-Glu), 1(C-Arabinosyl))-B(3OH) | Flavone | Tricetin 6-C-arabinoside-8-C-glucoside |
| Level: 3, プリカーサーm/z: 465.04620 |
| Splash: splash10-0udi-0009000000-5fd25f7dc9436a8f54f7 |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 303.03 | 84074 | 162 | 1000 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.000 | [Flavone]-A(2OH, 1(C-Glu))-B(3OH) | Flavone | Isoaffinetin |
| 0.000 | [Flavone]-A(2OH, 1(C-Glu))-B(3OH) | Flavone | Tricetin 8-C-glucopyranoside |
| 0.000 | [Flavone]-A(2OH, 1(C-Glu))-B(3OH) | Flavone | 6-C-beta-D-Glucopyranosylisoetin |
| 0.000 | [Flavonol]-A(2OH, 1(C-Glu))-B(2OH) | Flavonol | 6-C-Glucosylquercetin |
| 0.000 | [Flavanone]-A(2OH, 1(C-Glu))-B(1OH, 1OMe) | Flavanone | Dihydroscoparin |
| 0.000 | [Dihydroflavonol]-A(1OH, 1OMe, 1(C-Glu))-B(1OH) | Dihydroflavonol | Keyakinol |
| 0.000 | [Flavonol]-A(2OH, 1(C-Glu))-B(2OH) | Flavonol | 8-C-Glucosylquercetin |
| 0.000 | [Isoflavone]-A(2OH, 2(C-Prenyl))-B(1OMe, 1([@@]-Methylenedioxy)) | Isoflavone | Euchrenone b4 |
| Level: 3, プリカーサーm/z: 303.04089 |
| Splash: splash10-0a70-0390000000-856bc0b042d220a3d5bf |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 256.98 | 2547 | 46 | 1000 |
| 229.02 | 1831 | 74 | 718 |
| 285.04 | 1302 | 18 | 511 |
| 164.91 | 1138 | 138 | 446 |
| 247.09 | 866 | 56 | 339 |
| 303.08 | 692 | -0 | 271 |
| 152.94 | 534 | 150 | 209 |
| 136.93 | 516 | 166 | 202 |
| 275.03 | 336 | 28 | 132 |
| 161.10 | 205 | 142 | 80 |
| 148.97 | 204 | 154 | 79 |
| 219.20 | 177 | 84 | 69 |
| 201.05 | 175 | 102 | 68 |
| 162.92 | 174 | 140 | 68 |
| 274.01 | 173 | 29 | 68 |
| 194.97 | 163 | 108 | 64 |
| 120.93 | 157 | 182 | 61 |
| 233.06 | 154 | 70 | 60 |
| 213.15 | 142 | 90 | 55 |
| 165.88 | 139 | 137 | 54 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.682 | [Flavonol]-A(2OH)-B(2OH) | Flavonol | Rhynchosin |
| 0.682 | [Flavonol]-A(2OH)-B(2OH) | Flavonol | Melanoxetin |
| 0.682 | [Flavonol]-A(2OH)-B(2OH) | Flavonol | Quercetin |
| 0.682 | [Flavonol]-A(2OH)-B(2OH) | Flavonol | Morin |
| 0.682 | [Flavonol]-A(1OH)-B(3OH) | Flavonol | Robinetin |
| 0.682 | [Flavonol]-A(1OH)-B(3OH) | Flavonol | 3,7,2',3',4'-Pentahydroxyflavone |
| 0.636 | [Flavonol]-A(2OH)-B(2OH) | Flavonol | 3,5,7,2',5'-Pentahydroxyflavone |
| 0.636 | [Flavonol]-A(2OH)-B(2OH) | Flavonol | Viscidulin I |
| 0.480 | [Flavonol]-A(3OH)-B(1OH) | Flavonol | 6-Hydroxykaempferol |
| 0.480 | [Flavonol]-A(3OH)-B(1OH) | Flavonol | Herbacetin |
| 0.364 | [Flavone]-A(2OH)-B(3OH) | Flavone | Tricetin |
| 0.364 | [Flavone]-A(2OH)-B(3OH) | Flavone | Isoetin |
| 0.348 | [Isoflavone]-A(3OH)-B(2OH) | Isoflavone | 5,7,8,2',4'-Pentahydroxyisoflavone |
| 0.304 | [Flavone]-A(3OH)-B(2OH) | Flavone | 6-Hydroxyluteolin |
| 0.304 | [Flavone]-A(3OH)-B(2OH) | Flavone | Hypolaetin |
| 0.304 | [Anthocyanidin]-A(2OH)-B(3OH) | Anthocyanidin | Delphinidin |
| 0.304 | [Anthocyanidin]-A(3OH)-B(2OH) | Anthocyanidin | 6-Hydroxycyanidin |
| 0.273 | [Isoflavanone]-A(2OH)-B(1OH, 1OMe) | Isoflavanone | Ferreirin |
| 0.273 | [Isoflavanone]-A(2OH)-B(1OH, 1OMe) | Isoflavanone | Isoferreirin |
| 0.217 | [Isoflavanone]-A(1OH)-B(2OH, 1OMe) | Isoflavanone | 7,2',3'-Trihydroxy-4'-methoxyisoflavanone |
| 0.200 | [Chalcone]-A(2OH)-B(2OH, 1OMe) | Chalcone | 3,4,3',4'-Tetrahydroxy-2-methoxychalcone |
| 0.200 | [Flavanone]-A(2OH)-B(1OH, 1OMe) | Flavanone | Alysifolinone |
| 0.200 | [Flavanone]-A(2OH)-B(1OH, 1OMe) | Flavanone | Homoeriodictyol |
| 0.200 | [Flavanone]-A(2OH)-B(1OH, 1OMe) | Flavanone | Hesperetin |
| 0.154 | [Flavanone]-A(3OH)-B(1OMe) | Flavanone | 4'-O-Methylcarthamidin |
| 0.154 | [Flavanone]-A(3OH)-B(1OMe) | Flavanone | 5,7,8-Trihydroxy-4'-methoxyflavanone |
| 0.154 | [Flavanone]-A(1OH, 1OMe)-B(2OH) | Flavanone | 8-Methoxybutin |
| 0.154 | [Flavanone]-A(1OH, 1OMe)-B(2OH) | Flavanone | 7,2',6'-Trihydroxy-5-methoxyflavanone |
| 0.154 | [Flavanone]-A(1OH, 1OMe)-B(2OH) | Flavanone | Scutamoenin |
| 0.154 | [Flavanone]-A(1OH, 1OMe)-B(2OH) | Flavanone | 5,2',3'-Trihydroxy-7-methoxyflavanone |
| 0.154 | [Flavanone]-A(1OH, 1OMe)-B(2OH) | Flavanone | Eriodictyol 5-methyl ether |
| 0.154 | [Flavanone]-A(1OH, 1OMe)-B(2OH) | Flavanone | Sternbin |
| 0.154 | [Flavanone]-A(1OH, 1OMe)-B(2OH) | Flavanone | Artocarpanone |
| 0.143 | [Flavan 3-ol]-A(1OH, 1OMe)-B(1OMe) | Flavan 3-ol | Afzelechin 5,4'-dimethyl ether |
| 0.130 | [Dihydroflavonol]-A(2OH)-B(1OMe) | Dihydroflavonol | Aromadendrin 4'-methyl ether |
| 0.111 | [Flavanone]-A(3OH, 1OMe)-B(none) | Flavanone | Oresbiusin |
| 0.111 | [Flavanone]-A(2OH, 1OMe)-B(1OH) | Flavanone | 5,7,4'-Trihydroxy-6-methoxyflavanone |
| 0.111 | [Flavanone]-A(2OH, 1OMe)-B(1OH) | Flavanone | 5,8,2'-Trihydroxy-7-methoxyflavanone |
| 0.111 | [Flavanone]-A(2OH, 1OMe)-B(1OH) | Flavanone | 5,7,4'-Trihydroxy-8-methoxyflavanone |
| 0.095 | [Dihydroflavonol]-A(2OH, 1OMe)-B(none) | Dihydroflavonol | 3,5,8-Trihydroxy-7-methoxyflavanone |
| 0.095 | [Dihydroflavonol]-A(1OH, 1OMe)-B(1OH) | Dihydroflavonol | Aromadendrin 5-methyl ether |
| 0.095 | [Dihydroflavonol]-A(1OH, 1OMe)-B(1OH) | Dihydroflavonol | Aromadendrin 7-methyl ether |
| 0.087 | [Dihydroflavonol (3-OMe)]-A(2OH)-B(1OH) | Dihydroflavonol | Aromadendrin 3-methyl ether |
| 0.083 | [Dihydroflavonol]-A(2OH, 1OMe)-B(none) | Dihydroflavonol | Alnustinol |
| 0.077 | [2'-Hydroxychalcone]-A(3OH)-B(1OH, 1OMe) | 2'-Hydroxychalcone | Okanin 4-methyl ether |
| 0.077 | [2'-Hydroxychalcone]-A(3OH)-B(1OH, 1OMe) | 2'-Hydroxychalcone | 4,2',4',6'-Tetrahydroxy-3-methoxychalcone |
| 0.048 | [Dihydroflavonol (3-OMe)]-A(1OH)-B(2OH) | Dihydroflavonol | 3-O-Methyl-2,3-trans-fustin |
| 0.043 | [Isoflavan]-A(1OH, 1OMe)-B(1OH, 1OMe) | Isoflavan | 5-Methoxyvestitol |
| 0.037 | [2'-Hydroxychalcone]-A(2OH, 1OMe)-B(2OH) | 2'-Hydroxychalcone | Lanceoletin |
| 0.000 | [Isoflavan]-A(2OMe)-B(2OH) | Isoflavan | Lotisoflavan |
| 0.000 | [Isoflavan]-A(1OH)-B(1OH, 2OMe) | Isoflavan | Sphaerosin |
| 0.000 | [Isoflavan]-A(1OH)-B(1OH, 2OMe) | Isoflavan | 4',7-Dihydroxy-2',3'-dimethoxyisoflavan (+-) |
| 0.000 | [Isoflavan]-A(1OH)-B(1OH, 2OMe) | Isoflavan | Mucronulatol |
| 0.000 | [Isoflavan]-A(1OH)-B(1OH, 2OMe) | Isoflavan | Isomucronulatol |
| 0.000 | [Isoflavan]-A(1OH)-B(1OH, 2OMe) | Isoflavan | Methoxyvestitol |
| 0.000 | [Dihydrochalcone]-A(1OH, 2OMe)-B(1OH) | Dihydrochalcone | Dihydroflavokawain C |
| 0.000 | [Dihydrochalcone]-A(1OH)-B(1OH, 2OMe) | Dihydrochalcone | 2,4'-Dihydroxy-4,6-dimethoxydihydrochalcone |
| 0.000 | [Dihydrochalcone]-A(1OH)-B(1OH, 2OMe) | Dihydrochalcone | 4,4'-Dihydroxy-2,6-dimethoxydihydrochalcone |
| 0.000 | [Dihydrochalcone]-A(2OH, 1OMe)-B(1OMe) | Dihydrochalcone | Lusianin |
| 0.000 | [Dihydrochalcone]-A(2OH, 1OMe)-B(1OMe) | Dihydrochalcone | Calomelanone |
| 0.000 | [Dihydrochalcone]-A(2OH, 1OMe)-B(1OMe) | Dihydrochalcone | 2',4'-Dihydroxy-4,6'-dimethoxydihydrochalcone |
| 0.000 | [Dihydrochalcone]-A(2OH, 2OMe)-B(none) | Dihydrochalcone | Dihydropashanone |
| 0.000 | [Dihydrochalcone]-A(2OH, 2OMe)-B(none) | Dihydrochalcone | 2',4'-Dihydroxy-3',6'-dimethoxydihydrochalcone |
| 0.000 | [Dihydrochalcone]-A(2OH, 2OMe)-B(none) | Dihydrochalcone | 2',3'-Dihydroxy-4',6'-dimethoxydihydrochalcone |
| 0.000 | [Aurone]-A(2OH)-B(3OH) | Aurone | Bracteatin |
| 0.000 | [Auronol]-A(1OH)-B(1OH, 1OMe) | Auronol | 2,6,3'-Trihydroxy-4'-methoxy-2-benzylcoumaranone |
| 0.000 | [Auronol]-A(1OH, 1OMe)-B(1OH) | Auronol | Carpusin |
| 0.000 | [Dihydrochalcone]-A(2OH, 1OMe, 1Methyl)-B(1OH) | Dihydrochalcone | 4,2',6'-Trihydroxy-4'-methoxy-3'-methyldihydrochalcone |
| 0.000 | [Dihydrochalcone alpha-ol]-A(1OH, 1OMe)-B(1OMe) | Dihydrochalcone alpha-ol | Odoratol |
| 0.000 | [UBR-type derivative / 2'-Oxocyclohexa-4',6'-dienyl-type Dihydrochalcone]-A(3OH, 2Methyl)-B(none) | UBR-type derivative / 2'-Oxocyclohexa-4',6'-dienyl-type Dihydrochalcone | Ceratiolin |
| 0.000 | [Flavanone]-A(2OH, 1Methyl)-B(2OH) | Flavanone | 5,7,3',5'-Tetrahydroxy-6-methylflavanone |
| 0.000 | [Flavanone]-A(2OH, 1Methyl)-B(2OH) | Flavanone | 6-C-Methyleriodictylol |
| 0.000 | [Flavanone]-A(2OH)-B(2OH, 1Methyl) | Flavanone | 5'-C-Methyleriodictylol |
| 0.000 | [Dihydroflavonol]-A(2OH, 1Methyl)-B(1OH) | Dihydroflavonol | 6-Methylaromadendrin |
| 0.000 | [Flavan 4-ol]-A(2OH, 1Hydroxymethyl, 1Methyl)-B(none) | Flavan 4-ol | 4,5,7-Trihydroxy-6-hydroxymethyl-8-methylflavan |
| 0.000 | [CCS-type derivative / [3,2']-Epoxymethanoflavan 4-ol]-A(1OH)-B(2OH) | CCS-type derivative / [3,2']-Epoxymethanoflavan 4-ol | Peltogynan-4-alpha-ol |
| 0.000 | [CCS-type derivative / [3,2']-Epoxymethanoflavan 4-ol]-A(1OH)-B(2OH) | CCS-type derivative / [3,2']-Epoxymethanoflavan 4-ol | Mopanan-4-alpha-ol |
| 0.000 | [Flavan]-A(2OH)-B(2OMe) | Flavan | Diffutidin |
| 0.000 | [Flavan]-A(2OMe)-B(2OH) | Flavan | 3',4'-Dihydroxy-5,7-dimethoxyflavan |
| 0.000 | [Pterocarpan-6a-ol]-A(1OH)-B(1OH, 1OMe) | Pterocarpan-6a-ol | 6a,7-Dihydroxymedicarpin |
| 0.000 | [[3,2']-Methano-4-phenylchroman (3-OH)]-A(2OH)-B(2OH) | [3,2']-Methano-4-phenylchroman | Haematoxylin |