ピーク情報
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ミヤコグサ
pos
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| Peak #5015 MN MID: SE205_S07_M90 |
| m/z: 465.17580, RT: 53.59, 強度: 24073, ログ強度: 0.88, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 2 |
| DB検索結果: (24 names) Longipin;Glaucolide A;1-(2-Hydroxy-3,4,5,6-tetramethoxyphenyl)-3-(2,3,4,6-tetramethoxyphenyl)-2-propen-1-one;4,7-Dihydroxy-2,3,6-trimethoxy-9.10-dihydrophenanthrene 4-O-glucoside;Icariside A3;Diffutin... |
| DBごとのヒット数: ALL 18 KG 4 KN 14 |
| FlavonoidSearch最大スコア MS2: -, MS3: 0.600 |
DB検索結果
ppm
| 組成式 | 分子量 | 誤差(Δppm） | 候補化合物名（代表で最短名を記載） | 化合物ID |
|---|---|---|---|---|
| C23H28O10 | 464.16825 | 0.606 | Longipin | KNApSAcK: C00012294 |
| C23H28O10 | 464.16825 | 0.606 | Glaucolide A | KEGG: C09463 KNApSAcK: C00003290 |
| C23H28O10 | 464.16825 | 0.606 | 1-(2-Hydroxy-3,4,5,6-tetramethoxyphenyl)-3-(2,3,4,6-tetramethoxyphenyl)-2-propen-1-one | KEGG: C14895 |
| C23H28O10 | 464.16825 | 0.606 | 4,7-Dihydroxy-2,3,6-trimethoxy-9.10-dihydrophenanthrene 4-O-glucoside | KNApSAcK: C00015541 |
| C23H28O10 | 464.16825 | 0.606 | Diffutin | FlavonoidViewer: FL6FAFGS0001 KEGG: C09636 KNApSAcK: C00008768 LipidMAPS: LMPK12020267 |
| C23H28O10 | 464.16825 | 0.606 | Salvidivin B | KNApSAcK: C00041821 |
| C23H28O10 | 464.16825 | 0.606 | Enhydrin | HMDB: HMDB0034608, HMDB0251809 KEGG: C09405 KNApSAcK: C00003255 |
| C23H28O10 | 464.16825 | 0.606 | Isomucronulator 7-O-glucoside | FlavonoidViewer: FLIC1LGS0001 KNApSAcK: C00010190 LipidMAPS: LMPK12080004 |
| C23H28O10 | 464.16825 | 0.606 | Leucanthinin | KNApSAcK: C00012280 |
| C23H28O10 | 464.16825 | 0.606 | Icariside A5 | KNApSAcK: C00015207 |
| C23H28O10 | 464.16825 | 0.606 | Melcanthin B | KNApSAcK: C00012236 |
| C23H28O10 | 464.16825 | 0.606 | Salvidivin C | KNApSAcK: C00041822 |
| C23H28O10 | 464.16825 | 0.606 | Glaucolide D | KNApSAcK: C00012148 |
| C23H28O10 | 464.16825 | 0.606 | Scorzodihydrostilbene A | KNApSAcK: C00047560 |
| C23H28O10 | 464.16825 | 0.606 | Salvidivin A | KNApSAcK: C00041820 |
| C23H28O10 | 464.16825 | 0.606 | Icariside A7 | KNApSAcK: C00050806 |
| C23H28O10 | 464.16825 | 0.606 | Polymatin C | KNApSAcK: C00011878 |
| C23H28O10 | 464.16825 | 0.606 | Salvidivin D | KNApSAcK: C00047343 |
MSnスペクトル情報
| Level: 2, プリカーサーm/z: 465.17538 |
| Splash: splash10-0udi-0009000000-57f5053e664f3cf60045 |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 303.11 | 22073 | 162 | 1000 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.000 | [Flavone]-A(2OH, 1(C-Glu))-B(3OH) | Flavone | Isoaffinetin |
| 0.000 | [Flavone]-A(2OH, 1(C-Glu))-B(3OH) | Flavone | Tricetin 8-C-glucopyranoside |
| 0.000 | [Flavone]-A(2OH, 1(C-Glu))-B(3OH) | Flavone | 6-C-beta-D-Glucopyranosylisoetin |
| 0.000 | [Flavonol]-A(2OH, 1(C-Glu))-B(2OH) | Flavonol | 6-C-Glucosylquercetin |
| 0.000 | [Flavanone]-A(2OH, 1(C-Glu))-B(1OH, 1OMe) | Flavanone | Dihydroscoparin |
| 0.000 | [Dihydroflavonol]-A(1OH, 1OMe, 1(C-Glu))-B(1OH) | Dihydroflavonol | Keyakinol |
| 0.000 | [Flavonol]-A(2OH, 1(C-Glu))-B(2OH) | Flavonol | 8-C-Glucosylquercetin |
| 0.000 | [Isoflavone]-A(2OH, 2(C-Prenyl))-B(1OMe, 1([@@]-Methylenedioxy)) | Isoflavone | Euchrenone b4 |
| Level: 3, プリカーサーm/z: 303.10846 |
| Splash: splash10-0udr-0900000000-8113454916dc9f52a0a9 |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 152.93 | 13587 | 150 | 1000 |
| 136.94 | 8385 | 166 | 617 |
| 162.98 | 729 | 140 | 53 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.600 | [Isoflavan]-A(1OH, 1OMe)-B(1OH, 1OMe) | Isoflavan | 5-Methoxyvestitol |
| 0.333 | [Flavan 3-ol]-A(1OH, 1OMe)-B(1OMe) | Flavan 3-ol | Afzelechin 5,4'-dimethyl ether |
| 0.333 | [Isoflavanone]-A(1OH)-B(2OH, 1OMe) | Isoflavanone | 7,2',3'-Trihydroxy-4'-methoxyisoflavanone |
| 0.333 | [Isoflavanone]-A(2OH)-B(1OH, 1OMe) | Isoflavanone | Ferreirin |
| 0.333 | [Isoflavanone]-A(2OH)-B(1OH, 1OMe) | Isoflavanone | Isoferreirin |
| 0.200 | [Dihydrochalcone]-A(2OH, 1OMe)-B(1OMe) | Dihydrochalcone | Lusianin |
| 0.200 | [Dihydrochalcone]-A(2OH, 1OMe)-B(1OMe) | Dihydrochalcone | Calomelanone |
| 0.200 | [Dihydrochalcone]-A(2OH, 1OMe)-B(1OMe) | Dihydrochalcone | 2',4'-Dihydroxy-4,6'-dimethoxydihydrochalcone |
| 0.200 | [Dihydroflavonol (3-OMe)]-A(1OH)-B(2OH) | Dihydroflavonol | 3-O-Methyl-2,3-trans-fustin |
| 0.176 | [Flavonol]-A(2OH)-B(2OH) | Flavonol | 3,5,7,2',5'-Pentahydroxyflavone |
| 0.176 | [Flavonol]-A(2OH)-B(2OH) | Flavonol | Viscidulin I |
| 0.167 | [Chalcone]-A(2OH)-B(2OH, 1OMe) | Chalcone | 3,4,3',4'-Tetrahydroxy-2-methoxychalcone |
| 0.167 | [Flavone]-A(2OH)-B(3OH) | Flavone | Tricetin |
| 0.167 | [Flavone]-A(2OH)-B(3OH) | Flavone | Isoetin |
| 0.167 | [Flavanone]-A(1OH, 1OMe)-B(2OH) | Flavanone | 8-Methoxybutin |
| 0.167 | [Flavanone]-A(1OH, 1OMe)-B(2OH) | Flavanone | 7,2',6'-Trihydroxy-5-methoxyflavanone |
| 0.167 | [Flavanone]-A(1OH, 1OMe)-B(2OH) | Flavanone | Scutamoenin |
| 0.167 | [Flavanone]-A(1OH, 1OMe)-B(2OH) | Flavanone | 5,2',3'-Trihydroxy-7-methoxyflavanone |
| 0.167 | [Flavanone]-A(1OH, 1OMe)-B(2OH) | Flavanone | Eriodictyol 5-methyl ether |
| 0.167 | [Flavanone]-A(1OH, 1OMe)-B(2OH) | Flavanone | Sternbin |
| 0.167 | [Flavanone]-A(1OH, 1OMe)-B(2OH) | Flavanone | Artocarpanone |
| 0.167 | [Flavonol]-A(2OH)-B(2OH) | Flavonol | Rhynchosin |
| 0.167 | [Flavonol]-A(2OH)-B(2OH) | Flavonol | Melanoxetin |
| 0.167 | [Flavonol]-A(2OH)-B(2OH) | Flavonol | Quercetin |
| 0.167 | [Flavonol]-A(2OH)-B(2OH) | Flavonol | Morin |
| 0.143 | [Isoflavan]-A(2OMe)-B(2OH) | Isoflavan | Lotisoflavan |
| 0.143 | [Isoflavan]-A(1OH)-B(1OH, 2OMe) | Isoflavan | Sphaerosin |
| 0.143 | [Isoflavan]-A(1OH)-B(1OH, 2OMe) | Isoflavan | 4',7-Dihydroxy-2',3'-dimethoxyisoflavan (+-) |
| 0.143 | [Isoflavan]-A(1OH)-B(1OH, 2OMe) | Isoflavan | Mucronulatol |
| 0.143 | [Isoflavan]-A(1OH)-B(1OH, 2OMe) | Isoflavan | Isomucronulatol |
| 0.143 | [Isoflavan]-A(1OH)-B(1OH, 2OMe) | Isoflavan | Methoxyvestitol |
| 0.125 | [Dihydroflavonol (3-OMe)]-A(2OH)-B(1OH) | Dihydroflavonol | Aromadendrin 3-methyl ether |
| 0.111 | [Dihydroflavonol]-A(2OH)-B(1OMe) | Dihydroflavonol | Aromadendrin 4'-methyl ether |
| 0.105 | [Flavonol]-A(1OH)-B(3OH) | Flavonol | Robinetin |
| 0.105 | [Flavonol]-A(1OH)-B(3OH) | Flavonol | 3,7,2',3',4'-Pentahydroxyflavone |
| 0.091 | [2'-Hydroxychalcone]-A(2OH, 1OMe)-B(2OH) | 2'-Hydroxychalcone | Lanceoletin |
| 0.091 | [2'-Hydroxychalcone]-A(3OH)-B(1OH, 1OMe) | 2'-Hydroxychalcone | Okanin 4-methyl ether |
| 0.091 | [2'-Hydroxychalcone]-A(3OH)-B(1OH, 1OMe) | 2'-Hydroxychalcone | 4,2',4',6'-Tetrahydroxy-3-methoxychalcone |
| 0.077 | [Flavone]-A(3OH)-B(2OH) | Flavone | 6-Hydroxyluteolin |
| 0.077 | [Flavone]-A(3OH)-B(2OH) | Flavone | Hypolaetin |
| 0.077 | [Flavanone]-A(2OH)-B(1OH, 1OMe) | Flavanone | Alysifolinone |
| 0.077 | [Flavanone]-A(2OH)-B(1OH, 1OMe) | Flavanone | Homoeriodictyol |
| 0.077 | [Flavanone]-A(2OH)-B(1OH, 1OMe) | Flavanone | Hesperetin |
| 0.050 | [Flavonol]-A(3OH)-B(1OH) | Flavonol | 6-Hydroxykaempferol |
| 0.050 | [Flavonol]-A(3OH)-B(1OH) | Flavonol | Herbacetin |
| 0.000 | [Anthocyanidin]-A(2OH)-B(3OH) | Anthocyanidin | Delphinidin |
| 0.000 | [Anthocyanidin]-A(3OH)-B(2OH) | Anthocyanidin | 6-Hydroxycyanidin |
| 0.000 | [Dihydroflavonol]-A(2OH, 1OMe)-B(none) | Dihydroflavonol | Alnustinol |
| 0.000 | [Dihydroflavonol]-A(2OH, 1OMe)-B(none) | Dihydroflavonol | 3,5,8-Trihydroxy-7-methoxyflavanone |
| 0.000 | [Dihydroflavonol]-A(1OH, 1OMe)-B(1OH) | Dihydroflavonol | Aromadendrin 5-methyl ether |
| 0.000 | [Dihydroflavonol]-A(1OH, 1OMe)-B(1OH) | Dihydroflavonol | Aromadendrin 7-methyl ether |
| 0.000 | [Flavanone]-A(3OH, 1OMe)-B(none) | Flavanone | Oresbiusin |
| 0.000 | [Flavanone]-A(2OH, 1OMe)-B(1OH) | Flavanone | 5,7,4'-Trihydroxy-6-methoxyflavanone |
| 0.000 | [Flavanone]-A(2OH, 1OMe)-B(1OH) | Flavanone | 5,8,2'-Trihydroxy-7-methoxyflavanone |
| 0.000 | [Flavanone]-A(2OH, 1OMe)-B(1OH) | Flavanone | 5,7,4'-Trihydroxy-8-methoxyflavanone |
| 0.000 | [Flavanone]-A(3OH)-B(1OMe) | Flavanone | 4'-O-Methylcarthamidin |
| 0.000 | [Flavanone]-A(3OH)-B(1OMe) | Flavanone | 5,7,8-Trihydroxy-4'-methoxyflavanone |
| 0.000 | [Dihydrochalcone]-A(1OH, 2OMe)-B(1OH) | Dihydrochalcone | Dihydroflavokawain C |
| 0.000 | [Dihydrochalcone]-A(1OH)-B(1OH, 2OMe) | Dihydrochalcone | 2,4'-Dihydroxy-4,6-dimethoxydihydrochalcone |
| 0.000 | [Dihydrochalcone]-A(1OH)-B(1OH, 2OMe) | Dihydrochalcone | 4,4'-Dihydroxy-2,6-dimethoxydihydrochalcone |
| 0.000 | [Dihydrochalcone]-A(2OH, 2OMe)-B(none) | Dihydrochalcone | Dihydropashanone |
| 0.000 | [Dihydrochalcone]-A(2OH, 2OMe)-B(none) | Dihydrochalcone | 2',4'-Dihydroxy-3',6'-dimethoxydihydrochalcone |
| 0.000 | [Dihydrochalcone]-A(2OH, 2OMe)-B(none) | Dihydrochalcone | 2',3'-Dihydroxy-4',6'-dimethoxydihydrochalcone |
| 0.000 | [Isoflavone]-A(3OH)-B(2OH) | Isoflavone | 5,7,8,2',4'-Pentahydroxyisoflavone |
| 0.000 | [Aurone]-A(2OH)-B(3OH) | Aurone | Bracteatin |
| 0.000 | [Auronol]-A(1OH)-B(1OH, 1OMe) | Auronol | 2,6,3'-Trihydroxy-4'-methoxy-2-benzylcoumaranone |
| 0.000 | [Auronol]-A(1OH, 1OMe)-B(1OH) | Auronol | Carpusin |
| 0.000 | [Dihydrochalcone]-A(2OH, 1OMe, 1Methyl)-B(1OH) | Dihydrochalcone | 4,2',6'-Trihydroxy-4'-methoxy-3'-methyldihydrochalcone |
| 0.000 | [Dihydrochalcone alpha-ol]-A(1OH, 1OMe)-B(1OMe) | Dihydrochalcone alpha-ol | Odoratol |
| 0.000 | [UBR-type derivative / 2'-Oxocyclohexa-4',6'-dienyl-type Dihydrochalcone]-A(3OH, 2Methyl)-B(none) | UBR-type derivative / 2'-Oxocyclohexa-4',6'-dienyl-type Dihydrochalcone | Ceratiolin |
| 0.000 | [Flavanone]-A(2OH, 1Methyl)-B(2OH) | Flavanone | 5,7,3',5'-Tetrahydroxy-6-methylflavanone |
| 0.000 | [Flavanone]-A(2OH, 1Methyl)-B(2OH) | Flavanone | 6-C-Methyleriodictylol |
| 0.000 | [Flavanone]-A(2OH)-B(2OH, 1Methyl) | Flavanone | 5'-C-Methyleriodictylol |
| 0.000 | [Dihydroflavonol]-A(2OH, 1Methyl)-B(1OH) | Dihydroflavonol | 6-Methylaromadendrin |
| 0.000 | [Flavan 4-ol]-A(2OH, 1Hydroxymethyl, 1Methyl)-B(none) | Flavan 4-ol | 4,5,7-Trihydroxy-6-hydroxymethyl-8-methylflavan |
| 0.000 | [CCS-type derivative / [3,2']-Epoxymethanoflavan 4-ol]-A(1OH)-B(2OH) | CCS-type derivative / [3,2']-Epoxymethanoflavan 4-ol | Peltogynan-4-alpha-ol |
| 0.000 | [CCS-type derivative / [3,2']-Epoxymethanoflavan 4-ol]-A(1OH)-B(2OH) | CCS-type derivative / [3,2']-Epoxymethanoflavan 4-ol | Mopanan-4-alpha-ol |
| 0.000 | [Flavan]-A(2OH)-B(2OMe) | Flavan | Diffutidin |
| 0.000 | [Flavan]-A(2OMe)-B(2OH) | Flavan | 3',4'-Dihydroxy-5,7-dimethoxyflavan |
| 0.000 | [Pterocarpan-6a-ol]-A(1OH)-B(1OH, 1OMe) | Pterocarpan-6a-ol | 6a,7-Dihydroxymedicarpin |
| 0.000 | [[3,2']-Methano-4-phenylchroman (3-OH)]-A(2OH)-B(2OH) | [3,2']-Methano-4-phenylchroman | Haematoxylin |