ピーク情報

ゼニゴケ　Takaragaike-1

pos

Peak #2620 MN MID: SE205_S05_M90

m/z: 425.17462, RT: 77.50, 強度: 5958, ログ強度: 0.37, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 1

DB検索結果: (17 names) Marchantin C;Eiccardin C;11-O-Demethyl marchantin I;Neomarchantin A;Isoriccardin C;Isomarchantin C;Plagiochin E;Dihydroptychantol A;Calix[4]arene;Isoplagiochin D;Riccardin B;SPIRADOLINE;Lacdinac;Forsm...

DBごとのヒット数: ALL 17 KG 1 KN 11 HM 5

FlavonoidSearch最大スコア MS2: 0.040, MS3: 0.250

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C28H24O4	424.16746	-0.267	Marchantin C	KNApSAcK: C00015810
C28H24O4	424.16746	-0.267	Eiccardin C	KNApSAcK: C00015765
C28H24O4	424.16746	-0.267	11-O-Demethyl marchantin I	KNApSAcK: C00034366
C28H24O4	424.16746	-0.267	Neomarchantin A	KNApSAcK: C00015826
C28H24O4	424.16746	-0.267	Isoriccardin C	KNApSAcK: C00015798
C28H24O4	424.16746	-0.267	Isomarchantin C	KNApSAcK: C00015794
C28H24O4	424.16746	-0.267	Plagiochin E	KNApSAcK: C00034640
C28H24O4	424.16746	-0.267	Dihydroptychantol A	KNApSAcK: C00034481
C28H24O4	424.16746	-0.267	Calix[4]arene	HMDB: HMDB0249557
C28H24O4	424.16746	-0.267	Isoplagiochin D	KNApSAcK: C00037340
C28H24O4	424.16746	-0.267	Riccardin B	KNApSAcK: C00015866
C22H30O2N2Cl2	424.16843	-2.566	SPIRADOLINE	HMDB: HMDB0258424
C16H28O11N2	424.16931	-4.629	Chitobiose	HMDB: HMDB0062702, HMDB0253938 KEGG: C01674
C16H28O11N2	424.16931	-4.629	Forsmann antigen	HMDB: HMDB0252458
C16H28O11N2	424.16931	-4.629	Galnac-1-4-glcnac	HMDB: HMDB0252600
C22H29O6Cl	424.16527	4.902	D-Cloprostenol	HMDB: HMDB0243529
C22H29O6Cl	424.16527	4.902	Chaetomugilin Q	KNApSAcK: C00052956

MSnスペクトル情報

Level: 2, プリカーサーm/z: 425.17258

Splash: splash10-03di-0092000000-58105aa9e0710be42aa1

m/z	Int.	NL	Rel.Int.
213.08	5076	212	1000
239.04	2882	186	567
331.17	1760	94	346
211.05	1381	214	272
212.08	1155	213	227
407.28	984	18	193
225.10	741	200	146
319.18	712	106	140
214.07	593	211	116
195.11	524	230	103
317.26	401	108	78
347.16	386	78	76
316.57	348	109	68
226.12	315	199	62

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.083	[Dihydroflavonol]-A(2OH, 2(C-Prenyl))-B(1OH)	Dihydroflavonol	6,8-diprenylaromadendrin
0.040	[Dihydroflavonol]-A(2OH, 1(C-Prenyl))-B(1OH, 1(C-Prenyl))	Dihydroflavonol	Lespedezaflavanone C
0.037	[Flavanone]-A(2OH, 2(C-Prenyl))-B(2OH)	Flavanone	Monotesone B
0.037	[Flavanone]-A(2OH, 2(C-Prenyl))-B(2OH)	Flavanone	6,8-Diprenyleriodictyol
0.037	[Flavanone]-A(2OH, 2(C-Prenyl))-B(2OH)	Flavanone	Kushenol E
0.037	[Flavanone]-A(2OH)-B(2OH, 2(C-Prenyl))	Flavanone	Sigmoidin A
0.037	[Flavanone]-A(2OH)-B(2OH, 2(C-Prenyl))	Flavanone	Abyssinin III
0.037	[Isoflavanone]-A(2OH, 1(C-Prenyl))-B(2OH, 1(C-Prenyl))	Isoflavanone	3'-Dimethylallylkievitone
0.037	[Flavanone]-A(2OH, 1(C-Prenyl))-B(2OH, 1(C-Prenyl))	Flavanone	Gancaonin E
0.037	[Flavanone]-A(2OH, 1(C-Prenyl))-B(2OH, 1(C-Prenyl))	Flavanone	5,7,3',4'-Tetrahydroxy-6,5'-di-C-prenylflavanone
0.037	[Flavanone]-A(2OH, 1(C-Prenyl))-B(2OH, 1(C-Prenyl))	Flavanone	Lespedezaflavanone D
0.000	[Flavone]-A(2OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OMe)	Flavone	7,8,3',4'-Tetramethoxy-6'',6''-dimethylpyrano[2'',3'':5,6]flavone
0.000	[2'-Hydroxychalcone]-A(2OH, 1(2-hydroxy-3-methyl-3-butenyl))-B(1OH, 1(2-hydroxy-3-methyl-3-butenyl))	2'-Hydroxychalcone	Angusticornin B
0.000	[2'-Hydroxychalcone]-A(2OH, 1(C-Prenyl))-B(1([2,3:@@]-(4-Hydroxy-5-(hydroxyisopropanyl)dihydrofurano)))	2'-Hydroxychalcone	Paratocarpin G
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(5,5-Dimethyl-4-acetoxy-4,5,3a,6a-tetrahydro-furo[2,3-b]furano)))-B(none)	2'-Hydroxychalcone	Tephropurpurin
0.000	[beta-Hydroxy(or Oxodihydro)chalcone]-A(2OH, 1(C-Prenyl))-B(1OH, 1(2-hydroxy-3-methyl-3-butenyl))	beta-Hydroxy(or Oxodihydro)chalcone	Glyinflanin E
0.000	[beta-Hydroxy(or Oxodihydro)chalcone]-A(1OH, 1([2,3:@@]-(5-(hydroxyisopropanyl)dihydrofurano)))-B(1OH, 1(C-Prenyl))	beta-Hydroxy(or Oxodihydro)chalcone	Glyinflanin F
0.000	[Dihydrochalcone]-A(1OH, 1OMe, 1([2,3:@@]-(4-Ispropyl-7-methyl-7-hydroxy-3a,4,5,6,7,7a-hexahydrobenzofurano)))-B(none)	Dihydrochalcone	Adunctin E
0.000	[UBR-type derivative / 2'-Oxocyclohexa-4',6'-dienyl-type Dihydrochalcone]-A(2OH, 1OMe, 2(C-Prenyl))-B(none)	UBR-type derivative / 2'-Oxocyclohexa-4',6'-dienyl-type Dihydrochalcone	Helihumulone
0.000	[Flavanone]-A(2OH, 1Lavandulyl)-B(2OH)	Flavanone	Exiguaflavanone A
0.000	[Flavanone]-A(1OH, 1([2,3:@@]-(6,6-Dimethyl-5-prenyl-4,5-dihydropyrano)))-B(2OH)	Flavanone	Exiguaflavanone L
0.000	[Flavanone]-A(2OH, 1(C-Prenyl), 1(2-hydroxy-3-methyl-3-butenyl))-B(1OH)	Flavanone	Lupiniol A1
0.000	[Flavanone]-A(2OH, 1(C-Prenyl))-B(1OH, 1(2-hydroxy-3-methyl-3-butenyl))	Flavanone	Lupiniol B
0.000	[Flavanone]-A(2OH, 1(C-Prenyl))-B(1OH, 1(3-Methyl-2,3-epoxybutyl))	Flavanone	Flemiflavanone D
0.000	[Flavanone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(5-(hydroxyisopropanyl)dihydrofurano)))-B(1OH)	Flavanone	Lonchocarpol C
0.000	[Flavanone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(5-(hydroxyisopropanyl)dihydrofurano)))-B(1OH)	Flavanone	Lonchocarpol D
0.000	[Flavanone]-A(2OH, 1Geranyl)-B(2OH)	Flavanone	Diplacone
0.000	[Flavanone]-A(2OH)-B(2OH, 1Geranyl)	Flavanone	Propolin D
0.000	[Flavanone]-A(2OH)-B(2OH, 1Geranyl)	Flavanone	Isonymphaeol B
0.000	[Flavanone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethyldihydropyrano)))-B(2OH)	Flavanone	Dorsmanin J
0.000	[Flavanone]-A(2([2,3:@@]-(6,6-Dimethyldihydropyrano)))-B(2OH)	Flavanone	Dorsmanin E
0.000	[Flavanone]-A(2OH, 1(C-Prenyl))-B(2OH, 1(1,1-Dimethylallyl))	Flavanone	2',4'-Dihydroxy-5'-(1'',1''-dimethylallyl)-6-C-prenylpinocembrin
0.000	[Flavanone]-A(2OH, 1(C-Prenyl))-B(2OH, 1(1,1-Dimethylallyl))	Flavanone	5,7,2',4'-Tetrahydroxy-8-prenyl-5'-(1,1-dimethylallyl)flavanone
0.000	[Flavanone]-A(2OH)-B(2OH, 1Geranyl)	Flavanone	Sanggenol A
0.000	[Flavanone]-A(2OH)-B(2OH, 1Geranyl)	Flavanone	5'-Geranylsteppogenin
0.000	[Flavanone]-A(2OH, 1Geranyl)-B(2OH)	Flavanone	Sophoraflavanone C
0.000	[Flavanone]-A(2OH, 1Lavandulyl)-B(2OH)	Flavanone	Kushenol F
0.000	[Flavanone]-A(2OH, 1Lavandulyl)-B(2OH)	Flavanone	Sophoraflavanone G
0.000	[Flavanone]-A(2OH, 1(2-Isopropenyl-5-methyl-5-hexenyl))-B(2OH)	Flavanone	Remangiflavanone B
0.000	[Flavanone]-A(1OH, 1([2,3:@@]-(6,6-Dimethyl-5-prenyl-4,5-dihydropyrano)))-B(2OH)	Flavanone	Leachianone F
0.000	[Dihydroflavonol]-A(2OH, 1Geranyl)-B(1OH)	Dihydroflavonol	Bonanniol A
0.000	[Dihydroflavonol]-A(2OH)-B(1OH, 1(5-Carboxy-2-hydroxyphenyl))	Dihydroflavonol	Hypnum acid
0.000	[Flavonol (3-OMe)]-A(1OMe, 1Methyl, 1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(1OH, 1OMe)	Flavonol	8-C-Methylvelloquercetin 3,5,3'-trimethyl ether
0.000	[Flavan 3-ol]-A(1OH)-B(2OH)	Flavan 3-ol	6-(3,4-Dihydroxyphenyl)-6a,12b-dihydro-3,10,11,12-tetrahydroxy-[2]benzopyrano[3,4-c]benzopyran-8(6H)-one
0.000	[Isoflavanone]-A(2OH, 1Geranyl)-B(2OH)	Isoflavanone	6-Geranyldalbergioidin
0.000	[Isoflavan]-A(1OH, 1OMe, 1(C-Prenyl))-B(2OH, 1(C-Prenyl))	Isoflavan	Licoricidin
0.000	[Rotenone]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OMe)	Rotenone	Erythynone
0.000	[12a-Hydroxyrotenone (3-OMe)]-A(1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(2OMe)	12a-Hydroxyrotenone	12a-Methoxyrotenone
0.000	[6-Hydroxydehydrorotenone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OMe)	6-Hydroxydehydrorotenone	6-Hydroxy-6a,12a-dehydro-alpha-toxicarol

Level: 3, プリカーサーm/z: 213.07674

Splash: splash10-0006-0900000000-c85f513989e9ab615bba

m/z	Int.	NL	Rel.Int.
195.00	1031	18	1000
185.03	439	28	425
118.97	241	94	234
167.04	188	46	182
198.13	129	15	125
106.95	94	106	90
157.07	86	56	83
108.95	81	104	78
169.98	74	43	71
90.95	72	122	69
186.13	63	27	61
183.04	62	30	60
212.90	59	0	57

Level: 3, プリカーサーm/z: 239.03760

Splash: splash10-0229-0290000000-0b92bbdc39076fd31a2e

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.250	[Flavone]-A(none)-B(1OH)	Flavone	2'-Hydroxyflavone
0.250	[Flavone]-A(1OH)-B(none)	Flavone	Primuletin
0.190	[Chalcone]-A(1OMe)-B(none)	Chalcone	4'-Methoxychalcone
0.000	[Aurone]-A(none)-B(1OH)	Aurone	2'-Hydroxyaurone

m/z	Int.	NL	Rel.Int.
221.05	388	18	1000
211.16	304	28	782
193.11	130	46	335
210.26	121	29	310
209.15	108	30	278
219.06	105	20	269
197.16	99	42	253
203.06	97	36	250
224.15	89	15	229
196.55	53	42	137
237.11	46	2	118
183.12	28	56	72
206.22	28	33	71
221.97	21	17	53
194.63	21	44	52