ピーク情報

ヒメツリガネゴケ　茎葉体（ガメトフォア）

pos

Peak #3803 MN MID: SE205_S04_M90

m/z: 271.24201, RT: 59.74, 強度: 8851, ログ強度: 0.53, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 2

DB検索結果: (6 names) Erogorgiaene;(+)-Erogorgiaene;2-[(1E,3E,5E)-3,7-Dimethylnona-1,3,5,8-tetraenyl]-1,3,3-trimethylcyclohexene;ar-Artemisene;ar-Artemisene;Dehydroabietane

DBごとのヒット数: ALL 6 KG 1 KN 2 HM 2 LM 1

FlavonoidSearch最大スコア MS2: 0.162, MS3: -

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C20H30	270.23475	-0.076		LipidMAPS: LMPR0104020002
C20H30	270.23475	-0.076	2-[(1E,3E,5E)-3,7-Dimethylnona-1,3,5,8-tetraenyl]-1,3,3-trimethylcyclohexene	HMDB: HMDB0247831
C20H30	270.23475	-0.076	Erogorgiaene	KNApSAcK: C00035097, C00045926 LipidMAPS: LMPR0104480001
C20H30	270.23475	-0.076	ar-Artemisene	KNApSAcK: C00055291
C20H30	270.23475	-0.076	ar-Artemisene	HMDB: HMDB0039155
C20H30	270.23475	-0.076	Abieta-8,11,13-triene	HMDB: HMDB0302739 KEGG: C21425 KNApSAcK: C00035987

MSnスペクトル情報

Level: 2, プリカーサーm/z: 271.24158

Splash: splash10-00or-0970000000-cc48614d83ccd0fc80c8

m/z	Int.	NL	Rel.Int.
215.13	11584	56	1000
229.11	8748	42	755
175.14	4980	96	429
161.09	3726	110	321
201.12	2856	70	246
134.99	2303	136	198
109.01	2232	162	192
148.97	2023	122	174
119.04	1953	152	168
187.15	1920	84	165
120.97	1894	150	163
133.06	1532	138	132
163.06	1481	108	127
189.12	1449	82	125
147.05	1418	124	122
253.14	1154	18	99
243.30	1145	28	98
94.99	1144	176	98
177.16	1144	94	98
105.00	1057	166	91

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.357	[Flavonol]-A(1OH)-B(1OH)	Flavonol	Resokaempferol
0.194	[Flavonol]-A(2OH)-B(none)	Flavonol	Galangin
0.192	[Flavanone]-A(1OH)-B(1OMe)	Flavanone	4'-Methylliquiritigenin
0.148	[Flavone]-A(2OH)-B(1OH)	Flavone	5,8,2'-Trihydroxyflavone
0.148	[Flavone]-A(2OH)-B(1OH)	Flavone	5,7,2'-Trihydroxyflavone
0.148	[Flavone]-A(2OH)-B(1OH)	Flavone	Apigenin
0.148	[Flavanone]-A(1OMe)-B(1OH)	Flavanone	Methyl-liquiritigenin
0.143	[Isoflavone]-A(1OH)-B(2OH)	Isoflavone	3'-Hydroxydaidzein
0.143	[Isoflavone]-A(1OH)-B(2OH)	Isoflavone	2'-Hydroxydaidzein
0.115	[2'-Hydroxychalcone]-A(2OH)-B(1OMe)	2'-Hydroxychalcone	Isoliquiritigenin 4-methyl ether
0.115	[2'-Hydroxychalcone]-A(2OH)-B(1OMe)	2'-Hydroxychalcone	2',5'-Dihydroxy-4-methoxychalcone
0.107	[Flavone]-A(3OH)-B(none)	Flavone	Baicalein
0.107	[Flavone]-A(3OH)-B(none)	Flavone	Norwogonin
0.107	[Flavone]-A(1OH)-B(2OH)	Flavone	7,3',4'-Trihydroxyflavone
0.107	[Flavone]-A(1OH)-B(2OH)	Flavone	5,2',5'-Trihydroxyflavone
0.107	[Anthocyanidin]-A(2OH)-B(1OH)	Anthocyanidin	Pelargonidin
0.103	[Isoflavone]-A(2OH)-B(1OH)	Isoflavone	Demethyltexasin
0.103	[Isoflavone]-A(2OH)-B(1OH)	Isoflavone	8-Hydroxydaidzein
0.103	[Isoflavone]-A(2OH)-B(1OH)	Isoflavone	5,7,2'-Trihydroxyisoflavone
0.103	[Isoflavone]-A(2OH)-B(1OH)	Isoflavone	5,7,3'-Trihydroxyisoflavone
0.103	[Isoflavone]-A(2OH)-B(1OH)	Isoflavone	Genistein
0.083	[Pterocarpan]-A(1OMe)-B(1OH)	Pterocarpan	Isomedicarpin
0.074	[2'-Hydroxychalcone]-A(1OH, 1OMe)-B(1OH)	2'-Hydroxychalcone	Isoliquiritigenin 4'-methyl ether
0.074	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(none)	2'-Hydroxychalcone	Flemichapparin
0.074	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(none)	2'-Hydroxychalcone	Larrein
0.074	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(none)	2'-Hydroxychalcone	Cardamonin
0.074	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(none)	2'-Hydroxychalcone	2',6'-Dihydroxy-4'-methoxychalcone
0.074	[Isoflavanone]-A(1OH)-B(1OMe)	Isoflavanone	Dihydroformononetin
0.069	[Chalcone]-A(1OH)-B(1OH, 1OMe)	Chalcone	Echinatin
0.069	[Flavanone]-A(1OH, 1OMe)-B(none)	Flavanone	7-Hydroxy-8-methoxyflavanone
0.069	[Flavanone]-A(1OH, 1OMe)-B(none)	Flavanone	Alpinetin
0.069	[Flavanone]-A(1OH, 1OMe)-B(none)	Flavanone	Pinostrobin
0.040	[Pterocarpan]-A(1OH)-B(1OMe)	Pterocarpan	Medicarpin
0.033	[Chalcone]-A(1OH, 1OMe)-B(1OH)	Chalcone	Isoliquiritigenin 2'-methy ether
0.000	[Aurone]-A(1OH)-B(2OH)	Aurone	Sulfuretin
0.000	[Aurone]-A(2OH)-B(1OH)	Aurone	4,6,4'-Trihydroxyaurone
0.000	[UBR-type derivative / 2',5'-Dioxo-3'-cyclopentenyl-type Calcone (alpha-OMe)]-A(1OMe)-B(none)	UBR-type derivative / 2',5'-Dioxo-3'-cyclopentenyl-type Calcone	Methyllucidone
0.000	[UBR-type derivative / 3',5'-Dioxo-1'-cyclopentenyl-type Dihydrocalcone]-A(3Methyl)-B(none)	UBR-type derivative / 3',5'-Dioxo-1'-cyclopentenyl-type Dihydrocalcone	4-Hydrocinnamoyl-2,2,5-trimethyl-4-cyclopentene-1,3-dione
0.000	[Flavanone]-A(2OH, 1Methyl)-B(none)	Flavanone	Strobopinin
0.000	[Flavanone]-A(2OH, 1Methyl)-B(none)	Flavanone	Cryptostrobin
0.000	[Flavan]-A(1OMe, 1Methyl)-B(1OH)	Flavan	4'-Hydroxy-7-methoxy-8-methylflavan
0.000	[Flavan]-A(1OH)-B(1([@@]-Methylenedioxy))	Flavan	7-Hydroxy-3',4'-methylenedioxyflavan
0.000	[Flavan]-A(2OMe)-B(none)	Flavan	Tephrowatsin E
0.000	[Flavan]-A(1OH, 1OMe, 1Methyl)-B(none)	Flavan	7-Hydroxy-5-methoxy-6-methylflavan
0.000	[3-DehydroxyAnthocyanidin]-A(2OH)-B(2OH)	3-DehydroxyAnthocyanidin	Luteolinidin
0.000	[isoflavene]-A(1OH)-B(1OH, 1OMe)	isoflavene	Haginin B
0.000	[2-Phenylbenzofuran]-A(1OMe)-B(1OH, 1OMe)	2-Phenylbenzofuran	Vignafuran
0.000	[2-Phenylbenzofuran]-A(1([@@]-Methylenedioxy))-B(2OH)	2-Phenylbenzofuran	2',4'-Dihydroxy-5,6-methylenedioxy-2-phenylbenzofuran
0.000	[Dalbergiquinol]-A(1OH, 2OMe)-B(none)	Dalbergiquinol	5-Hydroxy-2,4-dimethoxydalbergiquinol
0.000	[UBR-type derivative / [2,5]-Benzoquinonyl-type Dalbergiquinol]-A(1OMe)-B(1OH)	UBR-type derivative / [2,5]-Benzoquinonyl-type Dalbergiquinol	4'-Hydroxy-4-methoxydalbergione

Level: 3, プリカーサーm/z: 215.13368

Splash: splash10-0ab9-0900000000-a2132b234a6ea7471187

m/z	Int.	NL	Rel.Int.
159.02	1597	56	1000
145.10	952	70	596
173.02	856	42	535
187.05	653	28	409
133.05	484	82	303
120.95	408	94	255
131.05	388	84	242
105.00	350	110	219
119.03	339	96	212
106.99	288	108	180
80.96	204	134	127
135.01	192	80	120
94.99	177	120	110
147.15	154	68	96
108.97	136	106	85

Level: 3, プリカーサーm/z: 229.11162

Splash: splash10-00e9-0900000000-4d0f562d1357ec167714

m/z	Int.	NL	Rel.Int.
173.11	1481	56	1000
132.97	632	96	426
134.97	529	94	357
201.19	455	28	307
147.08	370	82	249
159.10	322	70	217
187.09	266	42	179
145.05	226	84	152
119.03	150	110	101
80.97	148	148	100
148.99	141	80	95
130.91	126	98	84
105.01	121	124	81
106.95	93	122	62
94.97	79	134	53