ピーク情報

ヒメツリガネゴケ　原糸体（プロトネマ）

pos

Peak #1842 MN MID: SE205_S03_M90

m/z: 376.22318, RT: 45.34, 強度: 15580, ログ強度: 0.83, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 1

DB検索結果: Phe-Pro-Ile

DBごとのヒット数: ALL 1 HM 1

FlavonoidSearch最大スコア MS2: -, MS3: -

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C20H29O4N3	375.21581	0.266	Phe-Pro-Ile	HMDB: HMDB0304808

MSnスペクトル情報

Level: 2, プリカーサーm/z: 376.22223

Splash: splash10-014i-0119000000-eb50e201dc6f0efc5154

m/z	Int.	NL	Rel.Int.
317.18	25450	59	1000
175.09	3816	201	149
221.04	2272	155	89
203.16	1906	173	74
156.97	1290	219	50

Level: 3, プリカーサーm/z: 317.18057

Splash: splash10-0uk9-0690000000-ba081d38990e6533cba5

m/z	Int.	NL	Rel.Int.
203.13	7989	114	1000
221.15	3813	96	477
175.00	3028	142	379
159.05	1799	158	225
156.98	1446	160	180
185.07	974	132	121
97.02	872	220	109
157.96	654	159	81
130.01	544	187	68
255.17	449	62	56

FlavonoidSearch結果

Symbolized Name	MSMS-Category	MSMS-Aglycone
[Flavone]-A(2OH)-B(2OH, 1OMe)	Flavone	Tricetin 3'-methyl ether
[Flavone]-A(2OH)-B(2OH, 1OMe)	Flavone	Tricetin 4'-methyl ether
[Flavone]-A(1OH, 1OMe)-B(3OH)	Flavone	Tricetin 7-methyl ether
[Flavone]-A(3OH)-B(1OH, 1OMe)	Flavone	Nodifloretin
[Flavone]-A(3OH)-B(1OH, 1OMe)	Flavone	6-Hydroxyluteolin 4'-methyl ether
[Flavone]-A(2OH, 1OMe)-B(2OH)	Flavone	Carajuflavone
[Flavone]-A(2OH, 1OMe)-B(2OH)	Flavone	Nepetin
[Flavone]-A(2OH, 1OMe)-B(2OH)	Flavone	Pedalitin
[Flavone]-A(3OH)-B(1OH, 1OMe)	Flavone	Hypolaetin 3'-methyl ether
[Flavone]-A(3OH)-B(1OH, 1OMe)	Flavone	Hypolaetin 4'-methyl ether
[Flavone]-A(2OH, 1OMe)-B(2OH)	Flavone	Onopordin
[Anthocyanidin]-A(2OH)-B(2OH, 1OMe)	Anthocyanidin	Petunidin
[Anthocyanidin]-A(1OH, 1OMe)-B(3OH)	Anthocyanidin	Pulchellidin
[Dihydroflavonol (3-OMe)]-A(1OMe)-B(2OH)	Dihydroflavonol	Fustin 3,7-dimethyl ether
[Isoflavone]-A(2OH)-B(2OH, 1OMe)	Isoflavone	Junipegenin A
[Isoflavone]-A(3OH, 1OMe)-B(1OH)	Isoflavone	5,6,7,4'-Tetrahydroxy-8-methoxyisoflavone
[Isoflavone]-A(3OH)-B(1OH, 1OMe)	Isoflavone	5,6,7,4'-Tetrahydroxy-3'-methoxyisoflavone
[Dihydroflavonol]-A(1OH, 1OMe)-B(1OMe)	Dihydroflavonol	Aromadendrin 7,4'-dimethyl ether
[Dihydroflavonol]-A(2OMe)-B(1OH)	Dihydroflavonol	Aromadendrin 5,7-dimethyl ether
[Flavanone]-A(2OH)-B(2OMe)	Flavanone	Eriodictyol 3',4'-dimethyl ether
[Flavanone]-A(1OH, 2OMe)-B(1OH)	Flavanone	5,4'-Dihydroxy-6,7-dimethoxyflavanone
[Flavanone]-A(1OH, 2OMe)-B(1OH)	Flavanone	Dihydroskullcap flavone I
[Flavanone]-A(1OH, 2OMe)-B(1OH)	Flavanone	5,4'-Dihydroxy-7,8-dimethoxyflavanone
[Flavanone]-A(2OH, 2OMe)-B(none)	Flavanone	Didymocarpin A
[Flavanone]-A(2OH, 1OMe)-B(1OMe)	Flavanone	7,8-Dihydroxy-6,4'-dimethoxyflavanone
[Flavanone]-A(2OH, 1OMe)-B(1OMe)	Flavanone	5,7-Dihydroxy-8,2'-dimethoxyflavanone
[Flavanone]-A(2OH, 1OMe)-B(1OMe)	Flavanone	5,7-Dihydroxy-8,4'-dimethoxyflavanone
[Flavanone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavanone	7,4'-Dihydroxy-8,3'-dimethoxyflavanone
[Flavanone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavanone	5,2'-Dihydroxy-7,5'-dimethoxyflavanone
[Flavanone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavanone	5,3'-Dihydroxy-7,2'-dimethoxyflavanone
[Flavanone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavanone	Eriodictyol 5,4'-dimethyl ether
[Flavanone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavanone	Eriodictyol 7,3'-dimethyl ether
[Flavanone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavanone	Persicogenin
[Flavanone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavanone	5,2'-Dihydroxy-7,4'-dimethoxyflavanone
[Dihydrochalcone]-A(1OH, 2OMe)-B(1OMe)	Dihydrochalcone	Flavokawin A
[Dihydrochalcone]-A(none)-B(1OH, 3OMe)	Dihydrochalcone	2-Hydroxy-3,4,6-trimethoxydihydrochalcone
[Dihydrochalcone]-A(none)-B(1OH, 3OMe)	Dihydrochalcone	2-Hydroxy-4,5,6-trimethoxydihydrochalcone
[Dihydrochalcone]-A(3OMe)-B(1OH)	Dihydrochalcone	4-Hydroxy-2',4',6'-trimethoxydihydrochalcone
[Dihydrochalcone]-A(1OH)-B(3OMe)	Dihydrochalcone	Loureirin B
[Dihydrochalcone]-A(1OH, 3OMe)-B(none)	Dihydrochalcone	2'-Hydroxy-3',4',6'-trimethoxydihydrochalcone
[2'-Hydroxychalcone]-A(3OH, 2OMe)-B(none)	2'-Hydroxychalcone	3',4',6'-Trihydroxy-2',5'-dimethoxychalcone
[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OH, 1OMe)	2'-Hydroxychalcone	2',4',4-Trihydroxy-3',3-methoxychalcone
[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OH, 1OMe)	2'-Hydroxychalcone	3,4',6'-Trihydroxy-4,2'-dimethoxychalcone
[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OH, 1OMe)	2'-Hydroxychalcone	4,2',6'-Trihydroxy-3,4'-dimethoxychalcone
[2'-Hydroxychalcone]-A(3OH)-B(2OMe)	2'-Hydroxychalcone	Okanin 3,4-dimethyl ether
[Flavonol]-A(1OH, 1OMe)-B(2OH)	Flavonol	7-Methoxy-3,6,3',4'-tetrahydroxyflavone
[Flavonol]-A(1OH, 1OMe)-B(2OH)	Flavonol	3,7,3',4'-Tetrahydroxy-8-methoxyflavone
[Flavonol]-A(1OH, 1OMe)-B(2OH)	Flavonol	Azaleatin
[Flavonol]-A(1OH, 1OMe)-B(2OH)	Flavonol	Rhamnetin
[Flavonol]-A(2OH, 1OMe)-B(1OH)	Flavonol	Vogeletin
[Flavonol]-A(2OH, 1OMe)-B(1OH)	Flavonol	6-Methoxykaempferol
[Flavonol]-A(2OH, 1OMe)-B(1OH)	Flavonol	3,5,6,4'-Tetrahydroxy-7-methoxyflavone
[Flavonol]-A(2OH, 1OMe)-B(1OH)	Flavonol	3,5,8,2'-Tetrahydroxy-7-methoxyflavone
[Flavonol]-A(2OH, 1OMe)-B(1OH)	Flavonol	Pollenitin
[Flavonol]-A(2OH, 1OMe)-B(1OH)	Flavonol	Sexangularetin
[Flavonol]-A(3OH)-B(1OMe)	Flavonol	3,5,6,7-Tetrahydroxy-4'-methoxyflavone
[Flavonol]-A(3OH)-B(1OMe)	Flavonol	Herbacetin 4'-methyl ether
[Flavonol]-A(2OH)-B(1OH, 1OMe)	Flavonol	3'-O-Methylmelanoxetin
[Flavonol]-A(2OH)-B(1OH, 1OMe)	Flavonol	Isorhamnetin
[Flavonol]-A(2OH)-B(1OH, 1OMe)	Flavonol	Tamarixetin
[Flavonol]-A(2OH)-B(1OH, 1OMe)	Flavonol	Milimorin
[Pterocarpan]-A(1OH)-B(1OH, 2OMe)	Pterocarpan	Philenopteran
[Pterocarpan]-A(1OH, 1OMe)-B(1OH, 1OMe)	Pterocarpan	2,8-Dihydroxy-3,9-dimethoxypterocarpan
[Pterocarpan]-A(1OH, 1OMe)-B(1OH, 1OMe)	Pterocarpan	Mucronucarpan
[Pterocarpan]-A(1OH, 1OMe)-B(1OH, 1OMe)	Pterocarpan	Nissolicarpin
[Pterocarpan]-A(1OH, 1OMe)-B(1OH, 1OMe)	Pterocarpan	Melilotocarpan D
[Pterocarpan]-A(1OH, 1OMe)-B(1OH, 1OMe)	Pterocarpan	Melilotocarpan E
[Isoflavanone]-A(1OH)-B(1OH, 2OMe)	Isoflavanone	7,4'-Dihydroxy-3',5'-dimethoxyisoflavanone
[Isoflavanone]-A(1OH)-B(1OH, 2OMe)	Isoflavanone	Violanone
[Isoflavanone]-A(1OH)-B(1OH, 2OMe)	Isoflavanone	Lespedeol C
[Isoflavanone]-A(2OH)-B(2OMe)	Isoflavanone	Homoferreirin
[Isoflavanone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Isoflavanone	Cajanol
[Isoflavanone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Isoflavanone	7,4'-Dihydroxy-5,2'-dimethoxyisoflavanone
[Aurone]-A(1OH, 1OMe)-B(3OH)	Aurone	Bracteatin 4-Methyl ether
[Dihydrochalcone]-A(2OH, 1OMe, 2Methyl)-B(1OH)	Dihydrochalcone	4,2',6'-Trihydroxy-4'-methoxy-3',5'-dimethyldihydrochalcone
[Dihydrochalcone]-A(2OH, 1OMe)-B(1([@@]-Methylenedioxy))	Dihydrochalcone	2',4'-Dihydroxy-6'-methoxy-3,4-methylenedioxydihydrochalcone
[Dihydrochalcone alpha-ol]-A(2OMe)-B(1OMe)	Dihydrochalcone alpha-ol	O-Methylodoratol
[Flavanone]-A(1OH, 1OMe, 1Methyl)-B(2OH)	Flavanone	7,3',4'-Trihydroxy-5-methoxy-6-C-methylflavanone
[Flavanone]-A(2OH, 2Methyl)-B(2OH)	Flavanone	Cyrtominetin
[Flavanone]-A(1OH, 1([@@]-Methylenedioxy))-B(2OH)	Flavanone	5,2',3'-Trihydroxy-6,7-methylenedioxyflavanone
[2-Hydroxyflavanone]-A(1OH, 2OMe, 1Methyl)-B(none)	2-Hydroxyflavanone	Mosloflavanone
[Dihydroflavonol]-A(2OH, 1Methyl)-B(1OMe)	Dihydroflavonol	3,5,7-Trihydroxy-4'-methoxy-6-methylflavanone
[Dihydroflavonol]-A(1OH, 1OMe, 1Methyl)-B(1OH)	Dihydroflavonol	3,7,4'-Trihydroxy-5-methoxy-6-methylflavanone
[CCS-type derivative / [3,2']-Epoxymethanodihydroflavanone]-A(2OH)-B(2OH)	CCS-type derivative / [3,2']-Epoxymethanodihydroflavanone	Crombeone
[Flavonol (3-OMe)]-A(2OH)-B(2OH)	Flavonol	3-Methoxy-6,7,3',4'-tetrahydroxyflavone
[Flavonol (3-OMe)]-A(2OH)-B(2OH)	Flavonol	Transilitin
[Flavonol (3-OMe)]-A(2OH)-B(2OH)	Flavonol	Quercetin 3-methyl ether
[Flavonol]-A(2OH, 1Methyl)-B(2OH)	Flavonol	Pinoquercetin
[Flavonol]-A(2OH, 1Methyl)-B(2OH)	Flavonol	8-C-Methylquercetin
[Flavonol (3-OMe)]-A(3OH)-B(1OH)	Flavonol	5,6,7,4'-Tetrahydroxy-3-methoxyflavone
[Flavonol (3-OMe)]-A(3OH)-B(1OH)	Flavonol	3-Methylherbacetin
[Flavan 4-ol]-A(2OMe)-B(1OMe)	Flavan 4-ol	4-Hydroxy-5,7,4'-trimethoxyflavan
[Flavan 4-ol]-A(2OH, 2Methyl)-B(1OMe)	Flavan 4-ol	4,5,7-Trihydroxy-4'-methoxy-6,8-dimethylflavan
[CCS-type derivative / [3,2']-Epoxymethanoflavan 4-ol]-A(1OMe)-B(2OH)	CCS-type derivative / [3,2']-Epoxymethanoflavan 4-ol	7-O-Methylpeltogynol
[Flavan]-A(1OH, 1OMe)-B(2OMe)	Flavan	2-(3,5-Dimethoxyphenyl)-3,4-dihydro-7-methoxy-2H-1-benzopyran-5-ol
[Flavan]-A(1OH, 1OMe)-B(2OMe)	Flavan	5-Hydroxy-7,3',4'-trimethoxyflavan
[Flavan]-A(2OMe)-B(1OH, 1OMe)	Flavan	4'-Hydroxy-5,7,3'-trimethoxyflavan
[Isoflavanone]-A(1OH, 1OMe, 1Methyl)-B(2OH)	Isoflavanone	Ougenin
[UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavan]-A(1OH)-B(2OMe)	UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavan	Pendulone
[UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavan]-A(1OH, 1OMe)-B(1OMe)	UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavan	Mucroquinone
[isoflavan-4-ol]-A(1OH, 1OMe, 1([@@]-Methylenedioxy))-B(none)	isoflavan-4-ol	Lapathinol
[isoflavene]-A(2OH)-B(1OH, 2OMe)	isoflavene	6,7,3'-Trihydroxy-2',4'-dimethoxyisoflavene
[Pterocarpan-6a-ol]-A(1OH)-B(1OH, 1([@@]-Methylenedioxy))	Pterocarpan-6a-ol	6a,7-Dihydroxymaackiain
[12a-Hydroxyrotenone]-A(2OH)-B(1OH)	12a-Hydroxyrotenone	4,9,11,12a-Tetrahydroxyrotenoid
[4-phenylcoumarin]-A(1OH, 1OMe)-B(3OH)	4-phenylcoumarin	5,2',4',5'-Tetrahydroxy-7-methoxy-4-phenylcoumarin
[Dalbergiquinol]-A(1OH, 3OMe)-B(1OH)	Dalbergiquinol	Kuhlmanniquinol

Level: 3, プリカーサーm/z: 175.09024

Splash: splash10-0a59-0900000000-43a9ed93c3a2dbc18957

m/z	Int.	NL	Rel.Int.
157.98	2094	17	1000
130.02	1579	45	754
156.93	350	18	167