ピーク情報

イヌカタヒバ

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Peak #6627 MN MID: SE205_S02_M90

m/z: 565.26472, RT: 54.86, 強度: 24979, ログ強度: 0.87, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 3

DB検索結果: (9 names) Hellebortin A;Taxuyunnanine K;(-)-Taxuyunnanine K;Taxuyunnanine L;(-)-Taxuyunnanine L;Frajunolide J;(-)-Frajunolide J;Hellebortin C;14-chlorotetracosane-1,15-disulfate

DBごとのヒット数: ALL 6 KN 5 LM 1

FlavonoidSearch最大スコア MS2: -, MS3: 0.057

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C29H40O11	564.25706	0.667	Hellebortin A	KNApSAcK: C00037257
C29H40O11	564.25706	0.667	Taxuyunnanine L	KNApSAcK: C00046947
C29H40O11	564.25706	0.667	Taxuyunnanine K	KNApSAcK: C00046946
C29H40O11	564.25706	0.667	Hellebortin C	KNApSAcK: C00037259
C29H40O11	564.25706	0.667	Frajunolide J	KNApSAcK: C00039226
C24H49O8S2Cl	564.25574	3.013	14-chlorotetracosane-1,15-disulfate	LipidMAPS: LMFA00000023

MSnスペクトル情報

Level: 2, プリカーサーm/z: 565.26434

Splash: splash10-0002-0040190000-075c3a9120bd57d6b7b9

m/z	Int.	NL	Rel.Int.
547.18	3130	18	1000
299.24	1112	266	355
529.13	901	36	287
281.26	411	284	131
283.30	403	282	128
511.28	386	54	123
499.25	321	66	102
427.24	268	138	85
317.28	244	248	77
265.28	188	300	60
445.10	169	120	53

Symbolized Name	MSMS-Category	MSMS-Aglycone
[Flavone]-A(2OH, 1(C-Glu), 1(C-Xylosyl))-B(1OH)	Flavone	Vicenin 1
[Flavone]-A(2OH, 1(C-Glu), 1(C-Arabinosyl))-B(1OH)	Flavone	Schaftoside
[Flavone]-A(2OH, 1(C-Galactosyl), 1(C-Xylosyl))-B(1OH)	Flavone	Isocorymboside
[Flavone]-A(2OH, 1(C-Arabinosyl), 1(C-Galactosyl))-B(1OH)	Flavone	Neocorymboside
[Flavone]-A(2OH, 1(C-Galactosyl), 1(C-Xylosyl))-B(1OH)	Flavone	6-C-Xylopyranosyl-8-C-galactopyranosylapigenin
[Flavone]-A(2OH, 1(C-Galactosyl), 1(C-Xylosyl))-B(1OH)	Flavone	6-C-Galactopyranosyl-8-C-xylopyranosylapigenin
[Flavone]-A(2OH, 1(C-Glu), 1(C-Xylosyl))-B(1OH)	Flavone	Vicenin 3
[Flavone]-A(2OH, 1(C-Glu), 1(C-Arabinosyl))-B(1OH)	Flavone	Isoschaftoside
[Flavone]-A(2OH, 1(C-Glu), 1(C-Arabinosyl))-B(1OH)	Flavone	Neoschaftoside
[Flavone]-A(2OH, 1(C-Glu), 1(C-Arabinosyl))-B(1OH)	Flavone	Neoisoschaftoside
[Flavone]-A(2OH, 1(C-Glu), 1(C-Apiofuranosyl))-B(1OH)	Flavone	6-C-beta-D-Glucopyranosyl-8-C-beta-D-apiofuranosylapigenin
[Flavone]-A(2OH, 1(C-Arabinosyl), 1(C-Galactosyl))-B(1OH)	Flavone	Corymboside

Level: 3, プリカーサーm/z: 547.17523

Splash: splash10-004i-0000980000-4aae04fb604b0310d689

m/z	Int.	NL	Rel.Int.
529.16	710	18	1000
511.13	262	36	369
499.21	240	48	338
457.20	206	90	290
427.17	189	120	267
481.20	163	66	229
469.27	135	78	190
451.12	69	96	97
281.29	61	266	85
493.07	57	54	80
409.11	54	138	75
299.28	49	248	68
503.45	42	44	59

Level: 3, プリカーサーm/z: 299.23587

Splash: splash10-001i-0290000000-b7b80081521c5d608f50

m/z	Int.	NL	Rel.Int.
281.27	161	18	1000
243.21	70	56	431
253.04	70	46	430
271.12	41	28	252
217.14	37	82	228
187.13	34	112	208
263.16	32	36	201
225.21	30	74	184
255.33	27	44	166
257.25	26	42	162
215.17	26	84	161
227.33	26	72	158
237.22	24	62	148
199.16	20	100	121
191.13	19	108	120
157.05	18	142	114
213.15	17	86	107
183.17	17	116	105
189.11	17	110	103
177.07	16	122	98

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.290	[Isoflavone]-A(1OMe)-B(1OH, 1OMe)	Isoflavone	Sayanedine
0.276	[Isoflavone]-A(1OH, 1OMe)-B(1OH)	Isoflavone	8-O-Methylretusin
0.250	[Isoflavone]-A(1OH)-B(2OMe)	Isoflavone	Cladrin
0.250	[Isoflavone]-A(1OH, 1OMe)-B(1OMe)	Isoflavone	Afrormosin
0.250	[Isoflavone]-A(1OH, 1OMe)-B(1OMe)	Isoflavone	Alfalone
0.250	[Isoflavone]-A(1OH, 1OMe)-B(1OMe)	Isoflavone	5-O-Methylbiochanin A
0.091	[Flavonol]-A(2OMe)-B(none)	Flavonol	Galangin 5,7-dimethyl ether
0.087	[Coumestan]-A(1OH)-B(1OH, 1OMe)	Coumestan	8-Methoxycoumestrol
0.087	[Coumestan]-A(1OH)-B(1OH, 1OMe)	Coumestan	Trifoliol
0.087	[Coumestan]-A(1OH, 1OMe)-B(1OH)	Coumestan	Sativol
0.000	[Flavone]-A(1OH)-B(2OMe)	Flavone	7-Hydroxy-3',4'-dimethoxyflavone
0.000	[Flavone]-A(1OMe)-B(1OH, 1OMe)	Flavone	Tithonine
0.000	[Flavone]-A(1OH, 1OMe)-B(1OMe)	Flavone	5-Hydroxy-6,2'-dimethoxyflavone
0.000	[Flavone]-A(1OH, 1OMe)-B(1OMe)	Flavone	5-Hydroxy-7,2'-dimethoxyflavone
0.000	[Flavone]-A(1OH, 1OMe)-B(1OMe)	Flavone	Apigenin 5,4'-dimethyl ether
0.000	[Flavone]-A(2OMe)-B(1OH)	Flavone	Apigenin 5,7-dimethyl ether
0.000	[Flavone]-A(1OH, 1OMe)-B(1OMe)	Flavone	Apigenin 7,4'-dimethyl ether
0.000	[Flavone]-A(1OH, 2OMe)-B(none)	Flavone	Baicalein 5,6-dimethyl ether
0.000	[Flavone]-A(1OH, 2OMe)-B(none)	Flavone	Mosloflavone
0.000	[Flavone]-A(1OH, 2OMe)-B(none)	Flavone	Norwogonin 5,8-dimethyl ether
0.000	[Flavone]-A(1OH, 2OMe)-B(none)	Flavone	Moslosooflavone
0.000	[Chalcone]-A(1OH, 1OMe, 1Formyl)-B(1OH)	Chalcone	Isoneobavachalcone
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1Formyl)-B(1OH)	2'-Hydroxychalcone	Neobavachalcone
0.000	[2'-Hydroxychalcone]-A(1OH, 2OMe, 1Methyl)-B(none)	2'-Hydroxychalcone	Aurentiacin
0.000	[2'-Hydroxychalcone]-A(2OH, 1OMe, 2Methyl)-B(none)	2'-Hydroxychalcone	2',4'-Dihydroxy-6'-methoxy-3',5'-dimethylchalcone
0.000	[UBR-type derivative / 2'-Oxocyclohexa-3',6'-dienyl-type Chalcone]-A(1OH, 1OMe, 2Methyl)-B(none)	UBR-type derivative / 2'-Oxocyclohexa-3',6'-dienyl-type Chalcone	Ceroptene
0.000	[UBR-type derivative / 2'-Oxo-3'-enyl-0-hydroxy-type Chalcone]-A(1Methoxycarbonylmethyl)-B(none)	UBR-type derivative / 2'-Oxo-3'-enyl-0-hydroxy-type Chalcone	Infectocaryone
0.000	[Flavanone]-A(1OMe, 1Methyl)-B(1OMe)	Flavanone	7,4'-Dimethoxy-6-C-methylflavanone
0.000	[Flavanone]-A(2OMe, 1Methyl)-B(none)	Flavanone	5,7-Dimethoxy-6-C-methylflavanone
0.000	[Flavanone]-A(1OH, 1OMe, 2Methyl)-B(none)	Flavanone	5-Hydroxy-7-methoxy-6,8-di-C-methylflavanone
0.000	[Flavanone]-A(1OH, 1OMe, 2Methyl)-B(none)	Flavanone	6,8-Di-C-methylpinocembrin 5-methyl ether
0.000	[Flavanone]-A(2OH, 1Formyl, 1Methyl)-B(none)	Flavanone	Lawinal
0.000	[Flavone]-A(1OH, 1OMe, 1Methyl)-B(1OH)	Flavone	8-Demethylsideroxylin
0.000	[Flavone]-A(2OH, 2Methyl)-B(1OH)	Flavone	Syzalterin
0.000	[Flavone]-A(1OH, 1([@@]-Methylenedioxy))-B(1OH)	Flavone	Kanzakiflavone 2
0.000	[Flavonol (3-OMe)]-A(1OH, 1OMe)-B(none)	Flavonol	Galangin 3,7-dimethyl ether
0.000	[Flavonol (3-OMe)]-A(2OH, 1Methyl)-B(none)	Flavonol	5,7-Dihydroxy-3-methoxy-8-methylflavone
0.000	[Flavonol]-A(1OH, 1OMe, 1Methyl)-B(none)	Flavonol	3,5-Dihydroxy-7-methoxy-8-methylflavone
0.000	[Flavonol]-A(2OH, 2Methyl)-B(none)	Flavonol	6,8-Dimethylgalangin
0.000	[CCS-type derivative / [3,2']-Epoxymethanoflavone]-A(1OH)-B(2OH)	CCS-type derivative / [3,2']-Epoxymethanoflavone	Peltogynin
0.000	[CCS-type derivative / [3,2']-Epoxymethanoflavone]-A(1OH)-B(2OH)	CCS-type derivative / [3,2']-Epoxymethanoflavone	Mopanin
0.000	[3-DehydroxyAnthocyanidin]-A(2OH, 1OMe)-B(1OMe)	3-DehydroxyAnthocyanidin	Carajurin
0.000	[Isoflavone]-A(1OH)-B(1OH, 1([@@]-Methylenedioxy))	Isoflavone	2-Hydroxypseudobaptigenin
0.000	[Isoflavone]-A(1OH)-B(1OH, 1([@@]-Methylenedioxy))	Isoflavone	Glyzaglabrin
0.000	[Isoflavone]-A(2OH)-B(1([@@]-Methylenedioxy))	Isoflavone	5-Hydroxypseudobaptigenin
0.000	[Isoflavone]-A(1OH, 1([@@]-Methylenedioxy))-B(1OH)	Isoflavone	Irisone B
0.000	[Isoflavone]-A(1OH, 1([@@]-Methylenedioxy))-B(1OH)	Isoflavone	Irilone
0.000	[UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavone]-A(1OH)-B(1OMe)	UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavone	Bowdichione
0.000	[Pterocarpan]-A(1OMe)-B(1([@@]-Methylenedioxy))	Pterocarpan	Pterocarpin
0.000	[3-Phenylcoumarin]-A(1OH)-B(1OH, 1([@@]-Methylenedioxy))	3-Phenylcoumarin	7,2'-Dihydroxy-4',5'-methylenedioxy-3-phenylcoumarin
0.000	[4-phenylcoumarin]-A(1OH, 2OMe)-B(none)	4-phenylcoumarin	Kuhlmannin
0.000	[4-phenylcoumarin]-A(2OMe)-B(1OH)	4-phenylcoumarin	4'-Hydroxy-5,7-dimethoxy-4-phenylcoumarin
0.000	[4-phenylcoumarin]-A(1OH, 1OMe)-B(1OMe)	4-phenylcoumarin	5-Hydroxy-7,4'-dimethoxy-4-phenylcoumarin
0.000	[CCS-type derivative / [5,2']-Epoxy-4-phenylcoumarin]-A(1OMe)-B(2OH)	CCS-type derivative / [5,2']-Epoxy-4-phenylcoumarin	4',5'-Dihydroxy-7-methoxy-5,2'-oxido-4-phenylcoumarin