ピーク情報
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イヌカタヒバ
pos
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| Peak #3803 MN MID: SE205_S02_M90 |
| m/z: 475.12354, RT: 40.77, 強度: 60955, ログ強度: 1.26, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 2 |
| DB検索結果: (25 names) Vitexin 3''-O-acetate;Apigenin 7-(2''-acetylglucoside);3-Hydroxy-5,4'-dimethoxy-6,7-methylenedioxyflavone 3-xyloside;Apigenin 7-(6''-acetylglucoside);Vitexin 6''-O-acetate;Psilosin;Betavulgarin glucos... |
| DBごとのヒット数: ALL 22 KN 22 |
| FlavonoidSearch最大スコア MS2: -, MS3: 0.050 |
DB検索結果
ppm
| 組成式 | 分子量 | 誤差(Δppm） | 候補化合物名（代表で最短名を記載） | 化合物ID |
|---|---|---|---|---|
| C23H22O11 | 474.11621 | 0.112 | Vitexin 3''-O-acetate | FlavonoidViewer: FL3FAACS0088 KNApSAcK: C00014089 LipidMAPS: LMPK12110278 |
| C23H22O11 | 474.11621 | 0.112 | Apigenin 7-(2''-acetylglucoside) | FlavonoidViewer: FL3FAAGS0040 HMDB: HMDB0037341 KNApSAcK: C00004176 LipidMAPS: LMPK12110374 |
| C23H22O11 | 474.11621 | 0.112 | Viviparum A | FlavonoidViewer: FL5FEAGS0026 KNApSAcK: C00013999 LipidMAPS: LMPK12112851 |
| C23H22O11 | 474.11621 | 0.112 | Apigenin 7-(6''-acetylglucoside) | FlavonoidViewer: FL3FAAGS0041 HMDB: HMDB0037342, HMDB0302734 KNApSAcK: C00004177 LipidMAPS: LMPK12110375 |
| C23H22O11 | 474.11621 | 0.112 | Vitexin 6''-O-acetate | FlavonoidViewer: FL3FAACS0010, FL3FAACS0089 KNApSAcK: C00006156, C00014090 LipidMAPS: LMPK12110203, LMPK12110279 |
| C23H22O11 | 474.11621 | 0.112 | Betavulgarin glucoside | HMDB: HMDB0041215 KNApSAcK: C00054341 |
| C23H22O11 | 474.11621 | 0.112 | Pongamoside D | FlavonoidViewer: FL5F1CGS0005 KNApSAcK: C00011170 LipidMAPS: LMPK12111561 |
| C23H22O11 | 474.11621 | 0.112 | Acacetin 7-(6''-methylglucuronide) | FlavonoidViewer: FL3FABGS0004 KNApSAcK: C00004204 LipidMAPS: LMPK12110448 |
| C23H22O11 | 474.11621 | 0.112 | Aristofolin A | KNApSAcK: C00040878 |
| C23H22O11 | 474.11621 | 0.112 | Genistin 6''-O-acetate | FlavonoidViewer: FLIAAAGS0002 HMDB: HMDB0029528 KNApSAcK: C00010104 LipidMAPS: LMPK12050167 |
| C23H22O11 | 474.11621 | 0.112 | Isovitexin 6''-O-acetyl | FlavonoidViewer: FL3FAACS0084 KNApSAcK: C00014085 LipidMAPS: LMPK12110274 |
| C23H22O11 | 474.11621 | 0.112 | 7-Hydroxy-5,8-dimethoxyflavone 7-glucuronide | FlavonoidViewer: FL3FF9GS0008 KNApSAcK: C00004485 LipidMAPS: LMPK12111326 |
| C23H22O11 | 474.11621 | 0.112 | Apigenin 7-(6''-ethylglucuronide) | FlavonoidViewer: FL3FAAGS0013 KNApSAcK: C00004148 LipidMAPS: LMPK12110348 |
| C23H22O11 | 474.11621 | 0.112 | Vitexin 2''-acetate | FlavonoidViewer: FL3FAACS0044 KNApSAcK: C00006369 LipidMAPS: LMPK12110237 |
| C23H22O11 | 474.11621 | 0.112 | Fujikinetin 7-O-glucoside | FlavonoidViewer: FLIA2CGS0001 KNApSAcK: C00010097 LipidMAPS: LMPK12050106 |
| C23H22O11 | 474.11621 | 0.112 | 8-C-beta-D-Glucofuranosylapigenin 2''-O-acetate | FlavonoidViewer: FL3FAACS0092 KNApSAcK: C00014093 LipidMAPS: LMPK12110282 |
| C23H22O11 | 474.11621 | 0.112 | 6,7-Dihydroxy-3'-methyoxy-4',5'-methylenedioxyisoflavone 6-O-rhamnoside | KNApSAcK: C00019744 |
| C23H22O11 | 474.11621 | 0.112 | Kaempferol 3-(4''-acetylrhamnoside) | FlavonoidViewer: FL5FAAGS0049 HMDB: HMDB0039746 KNApSAcK: C00005862 LipidMAPS: LMPK12111885 |
| C23H22O11 | 474.11621 | 0.112 | Germanaism B | KNApSAcK: C00019117 |
| C23H22O11 | 474.11621 | 0.112 | Pelargonidin 3-(6''-acetylglucoside) | FlavonoidViewer: [1]FL7AAAGL0015 KNApSAcK: [1]C00006754 LipidMAPS: [1]LMPK12010029 |
| C23H22O11 | 474.11621 | 0.112 | Kaempferol 3-(3''-acetylrhamnoside) | FlavonoidViewer: FL5FAAGS0048 HMDB: HMDB0039747 KNApSAcK: C00005861 LipidMAPS: LMPK12111884 |
| C23H22O11 | 474.11621 | 0.112 | Kaempferol 3-(2''-acetylrhamnoside) | FlavonoidViewer: FL5FAAGS0047 HMDB: HMDB0039748 KNApSAcK: C00005860 LipidMAPS: LMPK12111883 |
MSnスペクトル情報
| Level: 2, プリカーサーm/z: 475.12357 |
| Splash: splash10-03di-0039000000-9146a771c43676568c54 |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 313.07 | 117927 | 162 | 1000 |
| 295.11 | 42814 | 180 | 363 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.000 | [Isoflavone]-A(2OH, 2(C-Prenyl))-B(1OH, 1(C-Prenyl)) | Isoflavone | Euchrenone b1 |
| 0.000 | [Isoflavone]-A(2OH, 1(C-Prenyl))-B(1OH, 2(C-Prenyl)) | Isoflavone | Flemiphyllin |
| 0.000 | [2'-Hydroxychalcone]-A(2OH, 1(C-Prenyl))-B(1OH, 1([2,3:@@]-(6-Methyl-6-(4-methyl-3-pentenyl)pyrano))) | 2'-Hydroxychalcone | Poinsettifolin B |
| 0.000 | [Flavanone]-A(2OH, 2(C-Prenyl))-B(1([2,3:@@]-(6,6-Dimethylpyrano))) | Flavanone | Euchrenone a4 |
| 0.000 | [3-substituted Flavone (3-Geranyl)]-A(1OH, 1(C-Prenyl))-B(2OH) | 3-substituted Flavone | Rubraflavone B |
| 0.000 | [Flavone]-A(2OH, 1(1(O-Acetyl)-C-Glu))-B(1OH) | Flavone | Vitexin 2''-O-acetate |
| 0.000 | [Flavone]-A(2OH, 1(1(O-Acetyl)-C-Glu))-B(1OH) | Flavone | Vitexin 3''-O-acetate |
| 0.000 | [Flavone]-A(2OH, 1(1(O-Acetyl)-C-Glu))-B(1OH) | Flavone | Vitexin 6''-O-acetate |
| 0.000 | [Flavone]-A(2OH, 1(1(O-Acetyl)-C-Glu))-B(1OH) | Flavone | Isovitexin 6''-O-acetate |
| 0.000 | [Flavone]-A(2OH, 1(1(O-Acetyl)-Galactosyl))-B(1OH) | Flavone | Apigenin 8-C-(6''-acetylgalactoside) |
| 0.000 | [Flavone]-A(2OH, 1(1(O-Acetyl)-Glucofuranosyl))-B(1OH) | Flavone | 8-C-beta-D-Glucofuranosylapigenin 2''-O-acetate |
| Level: 3, プリカーサーm/z: 313.06870 |
| Splash: splash10-0002-0090000000-f57013e01d9b469bb85d |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 295.05 | 94725 | 18 | 1000 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.050 | [Isoflavone]-A(1OMe)-B(2OMe) | Isoflavone | Cabreuvin |
| 0.000 | [Flavone]-A(1OMe)-B(2OMe) | Flavone | 7,3',4'-Trimethoxyflavone |
| 0.000 | [Flavone]-A(1OMe)-B(2OMe) | Flavone | 7,2',4'-Trimethoxyflavone |
| 0.000 | [Flavone]-A(2OMe)-B(1OMe) | Flavone | 5,6,2'-Trimethoxyflavone |
| 0.000 | [Flavone]-A(1OMe)-B(2OMe) | Flavone | 6,2',3'-Trimethoxyflavone |
| 0.000 | [Flavone]-A(2OMe)-B(1OMe) | Flavone | 5,6,3'-Trimethoxyflavone |
| 0.000 | [Flavone]-A(none)-B(3OMe) | Flavone | 3',4',5'-Trimethoxyflavone |
| 0.000 | [Flavone]-A(2OMe)-B(1OMe) | Flavone | 5,7,2'-Trimethoxyflavone |
| 0.000 | [Flavone]-A(2OMe)-B(1OMe) | Flavone | Apigenin 5,7,4'-trimethyl ether |
| 0.000 | [Flavone]-A(3OMe)-B(none) | Flavone | Baicalein 5,6,7-trimethyl ether |
| 0.000 | [Flavone]-A(3OMe)-B(none) | Flavone | Norwogonin 5,7,8-trimethyl ether |
| 0.000 | [Coumestan]-A(1OH)-B(2OMe) | Coumestan | 3-Hydroxy-8,9-dimethoxycoumestan |
| 0.000 | [Coumestan]-A(1OH)-B(2OMe) | Coumestan | Wairol |
| 0.000 | [Chalcone]-A(none)-B(2OH, 1OMe, 1Formyl, 1Methyl) | Chalcone | 3-Formyl-4,6-dihydroxy-2-methoxy-5-methylchalcone |
| 0.000 | [Chalcone]-A(2OMe)-B(1([@@]-Methylenedioxy)) | Chalcone | 3,4-Methylenedioxy-2',4'-dimethoxychalcone |
| 0.000 | [2'-Hydroxychalcone]-A(2OH, 1OMe, 1Formyl, 1Methyl)-B(none) | 2'-Hydroxychalcone | Leridal chalcone |
| 0.000 | [Chalcone]-A(2OMe, 1([@@]-Methylenedioxy))-B(none) | Chalcone | Helilandin A |
| 0.000 | [beta-Hydroxy(or Oxodihydro)chalcone]-A(1([@@]-Methylenedioxy))-B(1([@@]-Methylenedioxy)) | beta-Hydroxy(or Oxodihydro)chalcone | Galiposin |
| 0.000 | [UBR-type derivative / 2',6'-Dioxo-3'-enyl-0-hydroxy-type Chalcone]-A(1OMe, 3Methyl)-B(none) | UBR-type derivative / 2',6'-Dioxo-3'-enyl-0-hydroxy-type Chalcone | Desmosdumotin C |
| 0.000 | [Flavanone]-A(1OH, 1OMe, 1Formyl, 1Methyl)-B(none) | Flavanone | Leridal |
| 0.000 | [Flavanone]-A(1OH, 1OMe, 1Formyl, 1Methyl)-B(none) | Flavanone | Desmosflavanone II |
| 0.000 | [Flavone]-A(1OH, 1OMe)-B(1([@@]-Methylenedioxy)) | Flavone | Prosogerin A |
| 0.000 | [Flavone]-A(1OH, 1OMe)-B(1([@@]-Methylenedioxy)) | Flavone | 6-Hydroxy-7-methoxy-3',4'-methylenedioxyflavone |
| 0.000 | [Flavone]-A(1OH, 1OMe, 2Methyl)-B(1OH) | Flavone | 5,2'-Dihydroxy-7-methoxy- 6,8-dimethylflavone |
| 0.000 | [Flavone]-A(1OH, 1OMe, 1Methyl)-B(1OMe) | Flavone | 8-Demethyleucalyptin |
| 0.000 | [Flavone]-A(1OH, 1OMe, 2Methyl)-B(1OH) | Flavone | Sideroxylin |
| 0.000 | [Flavone]-A(1OH, 1OMe)-B(1([@@]-Methylenedioxy)) | Flavone | 5-Hydroxy-7-methoxy-3',4'-methylenedioxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH)-B(1([@@]-Methylenedioxy)) | Flavonol | 3-Hydroxy-7-methoxy-3',4'-methylenedioxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(2OMe)-B(none) | Flavonol | Galangin 3,5,7-trimethyl ether |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 2Methyl)-B(none) | Flavonol | 5,7-Dihydroxy-3-methoxy-6,8-dimethylflavone |
| 0.000 | [Flavonol]-A(1OH, 1OMe, 2Methyl)-B(none) | Flavonol | 3,5-Dihydroxy-7-methoxy-6,8-dimethylflavone |
| 0.000 | [Isoflavone]-A(1OH)-B(1OMe, 1([@@]-Methylenedioxy)) | Isoflavone | Cuneatin |
| 0.000 | [Isoflavone]-A(1OH, 1OMe)-B(1([@@]-Methylenedioxy)) | Isoflavone | Fujikinetin |
| 0.000 | [Isoflavone]-A(1OH, 1OMe)-B(1([@@]-Methylenedioxy)) | Isoflavone | Maximaisoflavone E |
| 0.000 | [Isoflavone]-A(1OH, 1OMe, 1Methyl)-B(1OMe) | Isoflavone | 7-Hydroxy-5,4'-dimethoxy-8-methylisoflavone |
| 0.000 | [Isoflavone]-A(1OMe, 1([@@]-Methylenedioxy))-B(1OH) | Isoflavone | Betavulgarin |
| 0.000 | [Isoflavone]-A(1OH, 1([@@]-Methylenedioxy))-B(1OMe) | Isoflavone | Irisone A |
| 0.000 | [Isoflavone]-A(1OMe, 1([@@]-Methylenedioxy))-B(1OH) | Isoflavone | Irisolone |
| 0.000 | [UBR-type derivative / [9,10]-Benzoquinonyl-type Pterocarpene]-A(1OMe)-B(1OMe) | UBR-type derivative / [9,10]-Benzoquinonyl-type Pterocarpene | 4-Deoxybryaquinone |
| 0.000 | [Pterocarpene]-A(1OH, 1OMe)-B(1([@@]-Methylenedioxy)) | Pterocarpene | 3-Hydroxy-4-methoxy-8,9-methylenedioxypterocarpene |
| 0.000 | [Pterocarpene]-A(1OMe)-B(2OMe) | Pterocarpene | Bryacarpene 5 |
| 0.000 | [6-Hydroxydehydrorotenone]-A(2OH, 1Methyl)-B(none) | 6-Hydroxydehydrorotenone | Boeravinone B |
| 0.000 | [4-phenylcoumarin]-A(2OMe)-B(1OMe) | 4-phenylcoumarin | 5,7,4'-Trimethoxy-4-phenylcoumarin |
| 0.000 | [CCS-type derivative / [5,2']-Epoxy-4-phenylcoumarin]-A(1OMe)-B(1OH, 1OMe) | CCS-type derivative / [5,2']-Epoxy-4-phenylcoumarin | 5'-Hydroxy-7,4'-dimethoxy-5,2'-oxido-4-phenylcoumarin |
| Level: 3, プリカーサーm/z: 295.10614 |
| Splash: splash10-014i-0090000000-75d6074280111cfacf9e |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 267.08 | 31455 | 28 | 1000 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.000 | [Auronol (2-OMe)]-A(1([2,3:@@]-Furano))-B(none) | Auronol | Castillene A |
| 0.000 | [beta-Hydroxy(or Oxodihydro)chalcone]-A(1OMe, 1Oxo, 1([2,3:@@]-Furano))-B(none) | beta-Hydroxy(or Oxodihydro)chalcone | Pongamol |
| 0.000 | [Flavanone]-A(1OMe, 1([2,3:@@]-Furano))-B(none) | Flavanone | 6-Methoxy-[2'',3'':7,8]furanoflavanone |
| 0.000 | [Dihydroflavonol (3-OMe)]-A(1([2,3:@@]-Furano))-B(none) | Dihydroflavonol | 3-Methoxy-[2'',3'':7,8]furanoflavanone |
| 0.000 | [2-substituted Isoflavone (2-Methyl)]-A(1OH, 1Acetyl)-B(none) | 2-substituted Isoflavone | Glyzarin |
| 0.000 | [Pterocarpan]-A(1([2,3:@@]-Furano))-B(1OMe) | Pterocarpan | 9-O-Methylneodunol |