ピーク情報

イチョウ　葉

pos

Peak #3186 MN MID: SE205_S01_M90

m/z: 371.20633, RT: 37.41, 強度: 20217, ログ強度: 0.76, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 5

DB検索結果: (3 names) 5-Megastigmen-7-yne-3,9-diol 3-glucoside;Dearabinosyl pneumonanthoside;5-Megastigmen-7-yne-3,9-diol 9-glucoside

DBごとのヒット数: ALL 3 KN 1 HM 2

FlavonoidSearch最大スコア MS2: 0.182, MS3: -

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C19H30O7	370.19915	-0.280	(2E,6E,10R)-11-(2',4'-dihydroxy-3'-methylenebutoxy)-10-hydroxy-3,7,11-trimethyldodeca-2,6-dienoic acid methyl ester	LipidMAPS: LMPR0103010032
C19H30O7	370.19915	-0.280	5-Megastigmen-7-yne-3,9-diol 3-glucoside	HMDB: HMDB0032842
C19H30O7	370.19915	-0.280	Dearabinosyl pneumonanthoside	HMDB: HMDB0036822 KNApSAcK: C00040935, C00045497, C00048245, C00048246
C19H30O7	370.19915	-0.280	(2E,6E,10R)-11-(3â²,4â²-dihydroxy-2â²-methylenebutoxy)-10-hydroxy-3,7,11-trimethyldodeca -2.6-dienoic acid methyl ester	LipidMAPS: LMPR0103010031
C19H30O7	370.19915	-0.280	5-Megastigmen-7-yne-3,9-diol 9-glucoside	HMDB: HMDB0032841

MSnスペクトル情報

Level: 2, プリカーサーm/z: 371.20584

Splash: splash10-052f-0930000000-09b9610494d8b3e87724

m/z	Int.	NL	Rel.Int.
191.06	10644	180	1000
209.01	7051	162	662
173.04	1583	198	148
151.03	1440	220	135
163.01	1419	208	133
121.01	1369	250	128
148.94	1244	222	116
137.04	1187	234	111
133.10	1007	238	94
353.17	784	18	73
135.07	635	236	59

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.182	[Flavanone]-A(1OH, 1OMe, 1(C-Prenyl))-B(2OH)	Flavanone	5,3',4'-Trihydroxy-7-methoxy-8-C-prenylflavanone
0.182	[Flavanone]-A(1OH, 1OMe, 1(C-Prenyl))-B(2OH)	Flavanone	Kenusanone I
0.130	[Flavanone]-A(2OH, 1(C-Prenyl))-B(1OH, 1OMe)	Flavanone	Exiguaflavanone K
0.097	[Flavonol]-A(2OH, 1(C-Prenyl))-B(2OH)	Flavonol	Gancaonin P
0.087	[Isoflavanone]-A(2OH)-B(1OH, 1OMe, 1(C-Prenyl))	Isoflavanone	3S-5,7,3'-Trihydroxy-4'-methoxy-5'-prenylisoflavanone
0.087	[Isoflavanone]-A(2OH)-B(1OH, 1OMe, 1(C-Prenyl))	Isoflavanone	Sophoraisoflavanone A
0.087	[Isoflavanone]-A(2OH, 1(C-Prenyl))-B(1OH, 1OMe)	Isoflavanone	4'-O-Methylkievitone
0.087	[Isoflavanone]-A(2OH, 1(C-Prenyl))-B(1OH, 1OMe)	Isoflavanone	Diphysolidone
0.083	[Flavanone]-A(2OH, 1OMe, 1(C-Prenyl))-B(1OH)	Flavanone	Dioflorin
0.063	[Flavonol]-A(2OH)-B(2OH, 1(C-Prenyl))	Flavonol	2'-Prenylrhynchosin
0.063	[Flavonol]-A(2OH)-B(2OH, 1(C-Prenyl))	Flavonol	Uralenol
0.053	[Dihydroflavonol]-A(2OH, 1OMe, 1(C-Prenyl))-B(none)	Dihydroflavonol	Dioclenol
0.040	[Flavanone]-A(2OH)-B(1OH, 1OMe, 1(C-Prenyl))	Flavanone	5'-Prenylhomoeriodictyol
0.040	[Flavanone]-A(2OH)-B(1OH, 1OMe, 1(C-Prenyl))	Flavanone	4'-Methylsigmoidin B
0.000	[Flavone]-A(2OH, 1(C-Prenyl))-B(1OH, 1OMe)	Flavone	Torosaflavone D
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1(2-Hydroperoxy-3-methyl-3-butenyl))-B(1OH)	2'-Hydroxychalcone	Xanthoangelol E
0.000	[2'-Hydroxychalcone]-A(2OH, 1OMe, 1(2-hydroxy-3-methyl-3-butenyl))-B(1OH)	2'-Hydroxychalcone	Xanthohumol D
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(6,6-Dimethyl-5-hydroxydihydropyrano)))-B(1OH)	2'-Hydroxychalcone	Dehydrocycloxanthohumol hydratechalcone
0.000	[Dihydrochalcone]-A(1OH, 2OMe, 1([2,3:@@]-Furano))-B(1([@@]-Methylenedioxy))	Dihydrochalcone	2'-Hydroxy-5',6'-dimethoxy-3,4-methylenedioxyfurano[2'',3'':4',3'] dihydrochalcon
0.000	[Flavanone]-A(2OH, 1(2-hydroxy-3-methyl-3-butenyl))-B(1OMe)	Flavanone	5,7-Dihydroxy-4'-methoxy-8-C-(2-hydroxy-3-methyl-3-butenyl)flavanone
0.000	[Flavanone]-A(2OH, 1(1,1-Dimethylallyl))-B(1OH, 1OMe)	Flavanone	5,7,4'-Trihydroxy-3'-methoxy-6-(1,1-dimethylallyl)flavanone
0.000	[Flavone]-A(2OH, 1(3-Hydroxy-3-methyl-1-butenyl))-B(2OH)	Flavone	Oxidihydroartocarpesin
0.000	[Dihydroflavonol]-A(1OH, 1OMe, 1Methyl)-B(1OH)	Dihydroflavonol	5,7,4'-Trihydroxy-5-methoxy-8-prenylflavanone
0.000	[Dihydroflavonol]-A(1OH, 1([2,3:@@]-(6-Methyl-4,7-dihydrooxepino)))-B(2OH)	Dihydroflavonol	7,8-Dihydrooxepinodihydroquercetin
0.000	[Dihydroflavonol]-A(1OH, 1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(2OH)	Dihydroflavonol	Shuterone A
0.000	[Flavonol]-A(2OH)-B(1([2,3:@@]-(6,6-Dimethyl-5-hydroxydihydropyrano)))	Flavonol	Glycyrrhiza flavonol A
0.000	[Flavonol (3-OMe)]-A(1OMe, 1([@@]-Methylenedioxy))-B(1([@@]-Methylenedioxy))	Flavonol	Meliternatin
0.000	[CCS-type derivative / [3,2']-Epoxymethanoflavone]-A(1OH, 2OMe)-B(1([@@]-Methylenedioxy))	CCS-type derivative / [3,2']-Epoxymethanoflavone	6-Methoxypulcherrimin
0.000	[Flavan 3,4-diol]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH)	Flavan 3,4-diol	4beta-Hydroxyobovatachromene
0.000	[Flavan 3,4-diol]-A(2OMe, 1([2,3:@@]-Furano))-B(none)	Flavan 3,4-diol	3,4,5,6-Tetramethoxyfurano[2,3-h]flavan
0.000	[Flavan 3,4-diol]-A(2OMe, 1([2,3:@@]-Furano))-B(none)	Flavan 3,4-diol	Diplotropin
0.000	[Isoflavone]-A(2OH, 1((Z)-4-hydroxyprenyl))-B(2OH)	Isoflavone	2,3-Dehydrokievitol
0.000	[Isoflavone]-A(1OH, 1([2,3:@@]-(5-(Hydroxyisopropanyl)dihydrofurano)))-B(2OH)	Isoflavone	Lunatone
0.000	[Isoflavone]-A(1OH, 1([2,3:@@]-(5-(Hydroxyisopropanyl)dihydrofurano)))-B(2OH)	Isoflavone	Lupinisoflavone B
0.000	[Isoflavone]-A(2OH)-B(1OH, 1([2,3:@@]-(5-(Hydroxyisopropanyl)dihydrofurano)))	Isoflavone	Lupinisoflavone D
0.000	[Isoflavan]-A(1OH)-B(1OH, 2OMe, 1(1,1-Dimethylallyl))	Isoflavan	Unanisoflavan
0.000	[Pterocarpan-6a-ol]-A(1OH)-B(1OH, 1OMe, 1(C-Prenyl))	Pterocarpan-6a-ol	Sphenostylin B
0.000	[6-Oxodehydrorotenone]-A(1OH, 1OMe)-B(2OMe)	6-Oxodehydrorotenone	Stemonone

Level: 3, プリカーサーm/z: 191.05746

Splash: splash10-00dj-0900000000-0cad19e0c6149ef0ebcf

m/z	Int.	NL	Rel.Int.
173.04	1960	18	1000
149.00	1604	42	818
135.03	1239	56	632
163.13	1081	28	551
147.03	612	44	312
120.98	554	70	282
118.94	488	72	249
133.08	431	58	219
106.94	231	84	117
131.05	186	60	94
96.96	108	94	54
122.88	99	68	50

Level: 3, プリカーサーm/z: 209.01457

Splash: splash10-0fdo-0900000000-4de4cac2ba307fea56aa

m/z	Int.	NL	Rel.Int.
191.00	1020	18	1000
173.08	438	36	429
162.98	409	46	400
133.01	354	76	347
108.98	305	100	299
149.13	291	60	285
150.92	271	58	265
100.95	252	108	247
166.93	190	42	186
121.02	149	88	146
139.00	137	70	134
137.01	135	72	132
99.02	118	110	115
122.88	109	86	107
95.04	87	114	85
181.12	62	28	60
92.89	58	116	56
106.92	57	102	55
125.13	54	84	52