ピーク情報

イチョウ　葉

pos

Peak #1245 MN MID: SE205_S01_M90

m/z: 346.14935, RT: 13.49, 強度: 288746, ログ強度: 1.91, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 1

DB検索結果: (2 names) Leptoclinidamine A;(+)-Leptoclinidamine A

DBごとのヒット数: ALL 1 KN 1

FlavonoidSearch最大スコア MS2: -, MS3: 0.111

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C16H19O4N5	345.14370	-4.723	Leptoclinidamine A	KNApSAcK: C00047489

MSnスペクトル情報

Level: 2, プリカーサーm/z: 346.14920

Splash: splash10-014i-0109000000-96d2b245fd692d88e5be

m/z	Int.	NL	Rel.Int.
315.09	493990	31	1000
185.10	51421	161	104
183.97	30481	162	61

Level: 3, プリカーサーm/z: 315.16861

Splash: splash10-0zg0-0900000000-8872a7230f40760f0897

m/z	Int.	NL	Rel.Int.
152.97	16682	162	1000
107.93	12846	207	770
152.00	12674	163	759
137.03	12264	178	735
108.98	11688	206	700
136.01	11254	179	674
134.11	2211	181	132
135.00	1912	180	114
297.15	1383	18	82

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.111	[Flavanone]-A(2OMe)-B(1OMe)	Flavanone	Naringenin trimethyl ether
0.087	[Flavonol]-A(1OH, 1OMe)-B(1OMe)	Flavonol	3,7-Dihydroxy-5,4'-dimethoxyflavone
0.087	[Flavonol]-A(1OH, 1OMe)-B(1OMe)	Flavonol	Kaempferol 7,4'-dimethyl ether
0.074	[Isoflavone]-A(2OH)-B(2OMe)	Isoflavone	Pratensein 3'-O-methyl ether
0.074	[Isoflavone]-A(2OH)-B(2OMe)	Isoflavone	2'-Methoxybiochanin A
0.074	[Isoflavone]-A(2OMe)-B(2OH)	Isoflavone	5,7-Dimethixyorobol
0.074	[Isoflavone]-A(2OMe)-B(2OH)	Isoflavone	2',4'-Dihydroxy-5,7-dimethoxyisoflavone
0.074	[Isoflavone]-A(1OH)-B(1OH, 2OMe)	Isoflavone	7,2'-Dihydroxy-3',4'-dimethoxyisoflavone
0.071	[Pterocarpan]-A(2OMe)-B(1OMe)	Pterocarpan	2-Methoxyhomopterocarpin
0.071	[Pterocarpan]-A(2OMe)-B(1OMe)	Pterocarpan	4-Methoxyhomopterocarpin
0.059	[2'-Hydroxychalcone]-A(1OH)-B(3OMe)	2'-Hydroxychalcone	Crotaoprostrin
0.059	[2'-Hydroxychalcone]-A(1OH, 2OMe)-B(1OMe)	2'-Hydroxychalcone	2'-Hydroxy-2,4',6'-trimethoxychalcone
0.059	[2'-Hydroxychalcone]-A(1OH, 2OMe)-B(1OMe)	2'-Hydroxychalcone	Flavokawin A
0.059	[2'-Hydroxychalcone]-A(1OH, 3OMe)-B(none)	2'-Hydroxychalcone	Helilandin B
0.059	[2'-Hydroxychalcone]-A(1OH, 3OMe)-B(none)	2'-Hydroxychalcone	2'-Hydroxy-3',4',6'-trimethoxychalcone
0.053	[Chalcone]-A(1OH, 2OMe)-B(1OMe)	Chalcone	4'-Hydroxy-2',4,6'-trimethoxychalcone
0.053	[Chalcone]-A(none)-B(1OH, 3OMe)	Chalcone	Tepanone
0.053	[Flavanone]-A(1OMe)-B(2OMe)	Flavanone	6,3',4'-Trimethoxyflavanone
0.053	[Flavanone]-A(3OMe)-B(none)	Flavanone	5,7,8-Trimethoxyflavanone
0.036	[Isoflavone]-A(2OH, 1OMe)-B(1OMe)	Isoflavone	Dipteryxin
0.036	[Isoflavone]-A(2OH, 1OMe)-B(1OMe)	Isoflavone	5,7-Dihydroxy-6,2'-dimethoxyisoflavone
0.036	[Isoflavone]-A(2OH, 1OMe)-B(1OMe)	Isoflavone	Irisolidone
0.036	[Isoflavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Isoflavone	Odoratin
0.036	[Isoflavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Isoflavone	7,2'-Dihydroxy-6,4'-dimethoxyisoflavone
0.036	[Isoflavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Isoflavone	3'-Hydroxy-8-O-methylretusin
0.036	[Isoflavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Isoflavone	7,3'-Dimethixyorobol
0.036	[Isoflavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Isoflavone	5,3'-Dihydroxy-7,4'-dimethoxyisoflavone
0.036	[Isoflavone]-A(1OH, 2OMe)-B(1OH)	Isoflavone	Muningin
0.036	[Isoflavone]-A(1OH, 2OMe)-B(1OH)	Isoflavone	7-O-Methyltectorigenin
0.036	[Isoflavone]-A(1OH, 2OMe)-B(1OH)	Isoflavone	5,2'-Dihydroxy-7,8-dimethoxyisoflavone
0.000	[Flavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavone	Abrectorin
0.000	[Flavone]-A(2OH, 1OMe)-B(1OMe)	Flavone	6,8-Dihydroxy-7,4'-dimethoxyflavone
0.000	[Flavone]-A(2OH)-B(2OMe)	Flavone	Luteolin 3',4'-dimethyl ether
0.000	[Flavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavone	Luteolin 5,3'-dimethyl ether
0.000	[Flavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavone	7,3'-Dihydroxy-5,4'-dimethoxyflavone
0.000	[Flavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavone	Velutin
0.000	[Flavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavone	Pilloin
0.000	[Flavone]-A(2OH, 1OMe)-B(1OMe)	Flavone	Scutellarein 5,4'-dimethyl ether
0.000	[Flavone]-A(2OH, 1OMe)-B(1OMe)	Flavone	Pectolinarigenin
0.000	[Flavone]-A(1OH, 2OMe)-B(1OH)	Flavone	Cirsimaritin
0.000	[Flavone]-A(2OH, 1OMe)-B(1OMe)	Flavone	Ladanein
0.000	[Flavone]-A(1OH, 2OMe)-B(1OH)	Flavone	Skullcapflavone I
0.000	[Flavone]-A(2OH, 1OMe)-B(1OMe)	Flavone	5,7-Dihydroxy-8,2'-dimethoxyflavone
0.000	[Flavone]-A(2OH, 1OMe)-B(1OMe)	Flavone	5,8-dihydroxy-7,4'-dimethoxyflavone
0.000	[Flavone]-A(1OH, 2OMe)-B(1OH)	Flavone	Isoscutellarein 7,8-dimethyl ether
0.000	[Flavone]-A(2OH, 1OMe)-B(1OMe)	Flavone	Bucegin
0.000	[Flavone]-A(2OH, 2OMe)-B(none)	Flavone	5,8-Dihydroxy-6,7-dimethoxyflavone
0.000	[Flavone]-A(2OH, 2OMe)-B(none)	Flavone	5,7-Dihydroxy-6,8-dimethoxyflavone
0.000	[Anthocyanidin]-A(1OH, 1OMe)-B(1OH, 1OMe)	Anthocyanidin	Rosinidin
0.000	[Coumestan]-A(1OH, 1OMe)-B(2OH)	Coumestan	Wedelolactone
0.000	[Flavonol]-A(1OH, 2OMe)-B(none)	Flavonol	3,7-Dihydroxy-5,6-dimethoxyflavone
0.000	[Flavonol]-A(1OH, 2OMe)-B(none)	Flavonol	3,6-Dihydroxy-5,7-dimethoxyflavone
0.000	[Flavonol]-A(1OH, 2OMe)-B(none)	Flavonol	3,5-Dihydroxy-6,7-dimethoxyflavone
0.000	[Flavonol]-A(1OH, 2OMe)-B(none)	Flavonol	3,5-Dihydroxy-7,8-dimethoxyflavone
0.000	[Flavonol]-A(2OMe)-B(1OH)	Flavonol	3,4'-Dihydroxy-7,8-dimethoxyflavone
0.000	[Aurone]-A(1OH, 1OMe, 1Methyl)-B(2OH)	Aurone	6,3',4'-Trihydroxy-4-methoxy-5-methylaurone
0.000	[Aurone]-A(1OH, 1OMe, 1Methyl)-B(2OH)	Aurone	6,3',4'-Trihydroxy-4-methoxy-7-methylaurone
0.000	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1([@@]-Methylenedioxy))	2'-Hydroxychalcone	Prosogerin B
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1([@@]-Methylenedioxy))-B(1OH)	2'-Hydroxychalcone	4,2'-Dihydroxy-6'-methoxy-3',4'-methylenedioxychalcone
0.000	[beta-Hydroxy(or Oxodihydro)chalcone]-A(3OH, 1Formyl, 1Methyl)-B(none)	beta-Hydroxy(or Oxodihydro)chalcone	3'-Formyl-2',4',6',beta-tetrahydroxy-5'-methylchalcone
0.000	[UBR-type derivative / [2',5']-Benzoquinonyl-type chalcone]-A(1OH, 2OMe)-B(none)	UBR-type derivative / [2',5']-Benzoquinonyl-type chalcone	Methylpedicinin
0.000	[UBR-type derivative / 2'-Oxocyclohexa-4',6'-dienyl-type beta-Hydroxychalcone]-A(1OH, 1OMe, 2Methyl)-B(none)	UBR-type derivative / 2'-Oxocyclohexa-4',6'-dienyl-type beta-Hydroxychalcone	Syzygiol
0.000	[Dihydrochalcone]-A(2OMe)-B(1([@@]-Methylenedioxy))	Dihydrochalcone	Ponganone VII
0.000	[Dihydrochalcone]-A(2OMe, 1([@@]-Methylenedioxy))-B(none)	Dihydrochalcone	2',6'-Dimethoxy-3',4'-methylenedioxydihydrochalcone
0.000	[UBR-type derivative / 2',4'-Dioxo-6'-cyclohexenyl-type Dihydrochalcone]-A(1OH, 4Methyl)-B(none)	UBR-type derivative / 2',4'-Dioxo-6'-cyclohexenyl-type Dihydrochalcone	Grandiflorone
0.000	[Flavanone]-A(1OH, 1OMe)-B(1([@@]-Methylenedioxy))	Flavanone	6-Hydroxy-7-methoxy-3',4'-methylenedioxyflavanone
0.000	[Flavanone]-A(1OH, 1OMe, 1Hydroxymethyl, 1Methyl)-B(none)	Flavanone	Leridol
0.000	[Flavanone]-A(2OH, 2Methyl)-B(1OMe)	Flavanone	Isomatteucinol
0.000	[Flavanone]-A(2OH, 2Methyl)-B(1OMe)	Flavanone	Matteucinol
0.000	[Flavanone]-A(1OH, 1OMe, 2Methyl)-B(1OH)	Flavanone	Angophorol
0.000	[Flavone]-A(1OH, 1OMe, 1Methyl)-B(2OH)	Flavone	5,3',4'-Trihydroxy-7-methoxy-6-methylflavone
0.000	[Dihydroflavonol]-A(2OH)-B(none)-C(1(O-Acetyl))	Dihydroflavonol	Pinobanksin 3-O-acetate
0.000	[Dihydroflavonol]-A(1OMe, 1([@@]-Methylenedioxy))-B(none)	Dihydroflavonol	3-Hydroxy-5-methoxy-6,7-methylenedioxyflavanone
0.000	[Flavonol (3-OMe)]-A(1OH, 1OMe)-B(1OH)	Flavonol	7,4'-Dihydroxy-3,6-dimethoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH, 1Methyl)-B(1OH)	Flavonol	Sylpin
0.000	[Flavonol (3-OMe)]-A(2OH)-B(1OMe)	Flavonol	Ermanin
0.000	[Flavonol (3-OMe)]-A(1OH, 1OMe)-B(1OH)	Flavonol	Kaempferol 3,5-dimethyl ether
0.000	[Flavonol (3-OMe)]-A(1OH, 1OMe)-B(1OH)	Flavonol	Kumatakenin
0.000	[Flavonol (3-OMe)]-A(2OH, 1Methyl)-B(1OH)	Flavonol	5,7,4'-Trihydroxy-3-methoxy-6-methylflavone
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(none)	Flavonol	Alnusin 3-methyl ether
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(none)	Flavonol	5,6-Dihydroxy-3,7-dimethoxyflavone
0.000	[Flavonol]-A(1OH, 1([@@]-Methylenedioxy))-B(1OH)	Flavonol	Gomphrenol
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(none)	Flavonol	5,8-Dihydroxy-3,7-dimethoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(none)	Flavonol	Gnaphaliin
0.000	[Flavonol (3-OMe)]-A(3OH, 1Methyl)-B(none)	Flavonol	Platanin 3-methyl ether
0.000	[Flavonol]-A(2OH, 1OMe, 1Methyl)-B(none)	Flavonol	3,5,8-Trihydroxy-7-methoxy-6-methylflavone
0.000	[Flavonol]-A(2OH, 1OMe, 1Methyl)-B(none)	Flavonol	Pityrogrammin
0.000	[CCS-type derivative / [3,2']-Epoxymethanoflavone]-A(2OH)-B(2OH)	CCS-type derivative / [3,2']-Epoxymethanoflavone	2,3,8,10-Tetrahydroxy[2]benzopyrano[4,3-b][1]benzopyran-7(5H)-one
0.000	[CCS-type derivative / [3,2']-Epoxyhydroxymethanoflavone]-A(1OH)-B(2OH)	CCS-type derivative / [3,2']-Epoxyhydroxymethanoflavone	Fasciculiferin
0.000	[Flavan]-A(1OH, 2Methyl)-B(1OH, 1([@@]-Methylenedioxy))	Flavan	7,2'-Dihydroxy-6,8-dimethyl-4',5'-methylenedioxyflavan
0.000	[Flavan]-A(1OH, 2Methyl)-B(1OH, 1([@@]-Methylenedioxy))	Flavan	7,2'-Dihydroxy-5,8-dimethyl-4',5'-methylenedioxyflavan
0.000	[3-DehydroxyAnthocyanidin]-A(2OH, 1OMe)-B(1OH, 1OMe)	3-DehydroxyAnthocyanidin	5,4'-Dimethyl-6-hydroxyluteolinidin
0.000	[UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavone]-A(2OH)-B(1OMe)	UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavone	5-Hydroxybowdichione
0.000	[Isoflavanone]-A(1OH)-B(1OMe, 1([@@]-Methylenedioxy))	Isoflavanone	Onogenin
0.000	[Pterocarpan]-A(1OH, 1OMe)-B(1([@@]-Methylenedioxy))	Pterocarpan	2-Hydroxyhomopterocarpin
0.000	[Pterocarpan]-A(1OH, 1OMe)-B(1([@@]-Methylenedioxy))	Pterocarpan	4-Methoxymaackiain
0.000	[Pterocarpan]-A(1OH, 1OMe)-B(1([@@]-Methylenedioxy))	Pterocarpan	4-Hydroxypterocarpin
0.000	[Pterocarpan-6a-ol]-A(1OMe)-B(1([@@]-Methylenedioxy))	Pterocarpan-6a-ol	Pisatin
0.000	[Pterocarpan-6-ol (6-OMe)]-A(1OH)-B(1([@@]-Methylenedioxy))	Pterocarpan-6-ol	Sophoracarpan B
0.000	[Pterocarpan-6-ol (3-OMe)]-A(1OMe)-B(1OMe)	Pterocarpan-6-ol	6-Methoxyhomopterocarpin
0.000	[4-phenylcoumarin]-A(1OH, 1OMe)-B(1OH, 1OMe)	4-phenylcoumarin	Melannein
0.000	[4-phenylcoumarin]-A(1OH, 1OMe)-B(1OH, 1OMe)	4-phenylcoumarin	7,3'-Dihydroxy-5,4'-dimethoxy-4-phenylcoumarin
0.000	[4-phenylcoumarin]-A(1OH, 1OMe)-B(1OH, 1OMe)	4-phenylcoumarin	5,3'-Dihydroxy-7,4'-dimethoxy-4-phenylcoumarin
0.000	[4-phenylcoumarin]-A(2OMe)-B(2OH)	4-phenylcoumarin	3',4'-Dihydroxy-5,7-dimethoxy-4-phenylcoumarin

Level: 3, プリカーサーm/z: 185.00284

Splash: splash10-0udi-0900000000-fd928dafaab7b7bec354

m/z	Int.	NL	Rel.Int.
152.98	12018	32	1000
152.02	2200	33	183