ピーク情報

イチョウ　葉

pos

Peak #10900 MN MID: SE205_S01_M90

m/z: 717.42209, RT: 88.27, 強度: 270709, ログ強度: 1.89, アダクト: [M+2(CH3OH)-3(H2O)+H]+, 共有数（同様のピークを含むサンプル数）: 8

DB検索結果: (4 names) Hovenidulcioside A2;24-Demethylbafilomycin;Hyalodendroside A;24S,25-carbonyl-23R,acetoxy-3beta,15alpha,24R,25-tetrahydroxy-cyclo-lanostan-16one-3- O-beta-D-xylopyranoside

DBごとのヒット数: ALL 4 KN 2 HM 1 LM 1

FlavonoidSearch最大スコア MS2: -, MS3: 0.083

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C38H58O12	706.39283	1.769	Hovenidulcioside A2	HMDB: HMDB0041029
C38H58O12	706.39283	1.769	24-Demethylbafilomycin	KNApSAcK: C00014917
C38H58O12	706.39283	1.769	Hyalodendroside A	KNApSAcK: C00046769
C38H58O12	706.39283	1.769	24S,25-carbonyl-23R,acetoxy-3beta,15alpha,24R,25-tetrahydroxy-cyclo-lanostan-16one-3- O-beta-D-xylopyranoside	LipidMAPS: LMST01100019

MSnスペクトル情報

Level: 2, プリカーサーm/z: 717.42194

Splash: splash10-0006-0000900000-33e4381e796169e742ec

m/z	Int.	NL	Rel.Int.
491.32	3473	226	1000
467.21	770	250	221
555.47	277	162	79

Level: 3, プリカーサーm/z: 467.25018

Splash: splash10-000i-0100900000-222ea15332016b5e900a

m/z	Int.	NL	Rel.Int.
439.40	44	28	1000
185.02	5	282	113
306.59	2	161	53
202.91	2	264	52

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.036	[Isoflavone]-A(2OH, 1(C-Prenyl))-B(1OH, 2OMe, 1(C-Prenyl))	Isoflavone	Pumilaisoflavone C
0.000	[Flavanone]-A(2OH)-B(1([2,3:@@]-(5-Hydroxymethyl-6-(p-hydroxy-m-methoxyphenyl)-dihydro[1,4]dioxinyl)))	Flavanone	Silandrin
0.000	[Flavanone]-A(2OH)-B(1OH, 1([2,3:@@]-(4-Hydroxymethyl-5-(p-hydroxy-m-methoxyphenyl)furano)))	Flavanone	Silyhermin
0.000	[Flavanone]-A(2OH)-B(1OH, 1([2,3:@@]-(4-Hydroxymethyl-5-(p-hydroxy-m-methoxyphenyl)furano)))	Flavanone	Neosilyhermin A
0.000	[UBR-type derivative / 3'-Oxocyclohexa-6'-enyl-type Flavanone]-A(2OH)-B(1OH, 1(m-((4-Hydroxy-3-methoxyphenyl)-([5,4;n,o]-tetrahydrofuran-3-yl)-methyl)))	UBR-type derivative / 3'-Oxocyclohexa-6'-enyl-type Flavanone	Silymonin
0.000	[Flavone]-A(1OMe, 1([2,3:@@]-(4-(1,2-diacetoxy-2-methylpropyl)-dihydrofurano)))-B(none)	Flavone	Polystachin (flavone)
0.000	[Dihydroflavonol]-A(2OH, 1(C-Glu))-B(2OH)	Dihydroflavonol	6-C-Glucosyltaxifolin
0.000	[Isoflavone]-A(1OH, 1(C-Prenyl), 1(1(O-(2-Hydroxyethyl))-[2,3:@@]-(5-(Hydroxyisopropanyl)dihydrofurano)))-B(1OH)	Isoflavone	Eriotriochin

Level: 3, プリカーサーm/z: 491.33197

Splash: splash10-052f-0193000000-8a11c5aa644c2eb880b1

m/z	Int.	NL	Rel.Int.
243.20	10	248	1000
259.20	6	232	594
395.49	4	96	417
359.22	4	132	384
185.04	4	306	342
203.15	3	288	332
241.02	2	250	200

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.083	[Flavone]-A(1OH, 1OMe, 1(C-Glu))-B(2OMe)	Flavone	Isoorientin 7,3',4'-trimethyl ether
0.000	[Isoflavone]-A(2OH, 2(C-Prenyl))-B(2OH, 1(C-Prenyl))	Isoflavone	Euchrenone b2
0.000	[Flavone]-A(2OH, 2(C-Prenyl))-B(2OH, 1(C-Prenyl))	Flavone	Dorsilurin A
0.000	[Dihydrochalcone]-A(2OH, 1OMe, 1(1-(2-Hydroxy-5-methoxycarbonylphenyl)-3-methylbut-2-enyl))-B(none)	Dihydrochalcone	Piperaduncin A
0.000	[Flavanone]-A(2OH, 1(C-Prenyl), 1(6-Ethyl-4-hydroxy-5-methyl-2-oxo-2H-pyran-3-yl))-B(none)	Flavanone	8-Prenyllepidissipyrone
0.000	[Flavanone]-A(2OH, 2(C-Prenyl))-B(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))	Flavanone	Amorinin
0.000	[Flavanone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OH, 1(C-Prenyl))	Flavanone	Amoridin
0.000	[Flavanone]-A(2OH, 1(C-Prenyl))-B(1OH, 1([2,3:@@]-(6-Methyl-6-(4-methyl-3-pentenyl)pyrano)))	Flavanone	Tanariflavanone B
0.000	[Flavanone]-A(2OH, 2(C-Prenyl))-B(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))	Flavanone	Euchrenone a6
0.000	[Flavone]-A(2OH, 1(1(O-Acetyl)-C-Glu))-B(2OH)	Flavone	Isoorientin 2''-O-acetate
0.000	[Flavone]-A(2OH, 1(1(O-Acetyl)-C-Glu))-B(2OH)	Flavone	Isoorientin 6''-O-acetate
0.000	[Flavone]-A(2OH, 1(1(O-Acetyl)-C-Glu))-B(2OH)	Flavone	Orientin 2''-O-acetate
0.000	[Flavone]-A(2OH, 1(1(O-Acetyl)-C-Glu))-B(2OH)	Flavone	Orientin 6''-O-acetate
0.000	[3-substituted Flavone (3-C-Prenyl)]-A(2OH, 2(C-Prenyl))-B(2OH)	3-substituted Flavone	Artelasticin
0.000	[3-substituted Flavone (3-Geranyl)]-A(2OH, 1(C-Prenyl))-B(2OH)	3-substituted Flavone	Rubraflavone C
0.000	[3-substituted Flavone (3-Geranyl)]-A(2OH, 1(C-Prenyl))-B(2OH)	3-substituted Flavone	Artocommunol CD
0.000	[Flavone]-A(2OH, 1Farnesyl)-B(2OH)	Flavone	Moralbanone
0.000	[UBR-type derivative / 2'-Oxo, 4-hydroxy-(2,1'),(3,4)-butadiene-type 3-substituted Flavone ([2,3:4,3]-(6,6-Dimethyldihydropyrano))]-A(2([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH)	UBR-type derivative / 2'-Oxo, 4-hydroxy-(2,1'),(3,4)-butadiene-type 3-substituted Flavone	Dorsilurin E
0.000	[Isoflavone]-A(2OH, 1(1(O-Acetyl)-C-Glu))-B(2OH)	Isoflavone	Orobol 6-C-(6''-acetylglucoside)
0.000	[Isoflavone]-A(2OH, 1(1(O-Acetyl)-C-Glu))-B(2OH)	Isoflavone	Orobol 8-C-(6''-acetylglucoside)

関連ピーク情報

ピーク番号	保持時間 (min)	m/z	m/z差分	ログ強度	アダクト	DB検索結果	ヒット数	MSn	FS3	共有数
	88.28	752.46008	35.0380	1.20	[M+CH3OH+CH5N-H2O+H]+, [M+NH4]+, [M+C2H7N+H]+	(4 names) Hovenidulcioside A2; 24-Demethylbafilomycin; Hyalodendroside A; 24S,25-carbonyl-23R,acetoxy-3beta,15alpha,24R,25-tetrahydroxy-cyclo-lanostan-16one-3- O-beta-D-xylopyranoside	ALL 4 KN 2 HM 1 LM 1			10
	88.78	749.44910	32.0270	0.30	[M+3(CH3OH)-3(H2O)+H]+, [M+IsoProp-H2O+H]+	(4 names) Hovenidulcioside A2; 24-Demethylbafilomycin; Hyalodendroside A; 24S,25-carbonyl-23R,acetoxy-3beta,15alpha,24R,25-tetrahydroxy-cyclo-lanostan-16one-3- O-beta-D-xylopyranoside	ALL 4 KN 2 HM 1 LM 1			3
10900	88.27	717.42209	0.0000	1.89	[M+2(CH3OH)-3(H2O)+H]+	(4 names) Hovenidulcioside A2; 24-Demethylbafilomycin; Hyalodendroside A; 24S,25-carbonyl-23R,acetoxy-3beta,15alpha,24R,25-tetrahydroxy-cyclo-lanostan-16one-3- O-beta-D-xylopyranoside	ALL 4 KN 2 HM 1 LM 1	MS2 MS3 x 2	0.083	8