ピーク情報

トマト Micro-Tom 成熟果実の果皮

pos

Peak #8574 MN MID: SE203_S11_M90

m/z: 597.16035, RT: 54.21, 強度: 530958, ログ強度: 2.16, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 2

DB検索結果: (5 names) Okanin 4'-(6''-p-coumarylglucoside);7',8'-Dihydro-7'-hydroxy-4-O-8':5':5''-triferulic acid;Bulbineloneside A;Eriodictyol 7-(6-trans-p-coumaroylglucoside);(2S)-5,7,3',4'-Tetrahydroxyflavanone 3'-(6-p-c...

DBごとのヒット数: ALL 5 KN 5

FlavonoidSearch最大スコア MS2: -, MS3: -

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C30H28O13	596.15299	0.136	Okanin 4'-(6''-p-coumarylglucoside)	FlavonoidViewer: FL1C3CGS0004 KNApSAcK: C00007895 LipidMAPS: LMPK12120158
C30H28O13	596.15299	0.136	7',8'-Dihydro-7'-hydroxy-4-O-8':5':5''-triferulic acid	KNApSAcK: C00055174
C30H28O13	596.15299	0.136	Bulbineloneside A	KNApSAcK: C00044598
C30H28O13	596.15299	0.136	(2S)-5,7,3',4'-Tetrahydroxyflavanone 7-(6-p-coumaroylglucoside)	FlavonoidViewer: FL2FACGS0017 HMDB: HMDB0039922 KNApSAcK: C00014338 LipidMAPS: LMPK12140375
C30H28O13	596.15299	0.136	(2S)-5,7,3',4'-Tetrahydroxyflavanone 3'-(6-p-coumaroylglucoside)	FlavonoidViewer: FL2FACGS0018 KNApSAcK: C00014339 LipidMAPS: LMPK12140376

MSnスペクトル情報

Level: 2, プリカーサーm/z: 597.15918

Splash: splash10-004i-0127190000-9fad214829d349b6b0f4

m/z	Int.	NL	Rel.Int.
579.07	2823	18	1000
315.05	952	282	337
273.17	780	324	276
325.08	766	272	271
381.23	482	216	170
399.24	375	198	132
417.19	285	180	101
561.23	252	36	89
195.01	229	402	81
307.15	227	290	80
435.21	215	162	76
181.13	208	416	73
553.40	186	44	65
477.09	151	120	53

Symbolized Name	MSMS-Category	MSMS-Aglycone
[Flavanone]-A(2OH, 2(C-Glu))-B(1OH)	Flavanone	6,8-Di-C-glucopyranosylnaringenin
[Flavone]-A(2OH, 1(C-Glu), 1(C-Arabinosyl))-B(3OH)	Flavone	Tricetin 6-C-glucoside-8-C-arabinoside
[Flavone]-A(2OH, 1(C-Glu), 1(C-Arabinosyl))-B(3OH)	Flavone	Tricetin 6-C-arabinoside-8-C-glucoside

Level: 3, プリカーサーm/z: 315.15314

Splash: splash10-0002-0900000000-98702622c2cae1a2261d

m/z	Int.	NL	Rel.Int.
195.06	578	120	1000

FlavonoidSearch結果

Symbolized Name	MSMS-Category	MSMS-Aglycone
[Flavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavone	Abrectorin
[Flavone]-A(2OH, 1OMe)-B(1OMe)	Flavone	6,8-Dihydroxy-7,4'-dimethoxyflavone
[Flavone]-A(2OH)-B(2OMe)	Flavone	Luteolin 3',4'-dimethyl ether
[Flavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavone	Luteolin 5,3'-dimethyl ether
[Flavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavone	7,3'-Dihydroxy-5,4'-dimethoxyflavone
[Flavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavone	Velutin
[Flavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavone	Pilloin
[Flavone]-A(2OH, 1OMe)-B(1OMe)	Flavone	Scutellarein 5,4'-dimethyl ether
[Flavone]-A(2OH, 1OMe)-B(1OMe)	Flavone	Pectolinarigenin
[Flavone]-A(1OH, 2OMe)-B(1OH)	Flavone	Cirsimaritin
[Flavone]-A(2OH, 1OMe)-B(1OMe)	Flavone	Ladanein
[Flavone]-A(1OH, 2OMe)-B(1OH)	Flavone	Skullcapflavone I
[Flavone]-A(2OH, 1OMe)-B(1OMe)	Flavone	5,7-Dihydroxy-8,2'-dimethoxyflavone
[Flavone]-A(2OH, 1OMe)-B(1OMe)	Flavone	5,8-dihydroxy-7,4'-dimethoxyflavone
[Flavone]-A(1OH, 2OMe)-B(1OH)	Flavone	Isoscutellarein 7,8-dimethyl ether
[Flavone]-A(2OH, 1OMe)-B(1OMe)	Flavone	Bucegin
[Flavone]-A(2OH, 2OMe)-B(none)	Flavone	5,8-Dihydroxy-6,7-dimethoxyflavone
[Flavone]-A(2OH, 2OMe)-B(none)	Flavone	5,7-Dihydroxy-6,8-dimethoxyflavone
[Anthocyanidin]-A(1OH, 1OMe)-B(1OH, 1OMe)	Anthocyanidin	Rosinidin
[Chalcone]-A(1OH, 2OMe)-B(1OMe)	Chalcone	4'-Hydroxy-2',4,6'-trimethoxychalcone
[Chalcone]-A(none)-B(1OH, 3OMe)	Chalcone	Tepanone
[Isoflavone]-A(2OH, 1OMe)-B(1OMe)	Isoflavone	Dipteryxin
[Isoflavone]-A(2OH, 1OMe)-B(1OMe)	Isoflavone	5,7-Dihydroxy-6,2'-dimethoxyisoflavone
[Isoflavone]-A(2OH, 1OMe)-B(1OMe)	Isoflavone	Irisolidone
[Isoflavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Isoflavone	Odoratin
[Isoflavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Isoflavone	7,2'-Dihydroxy-6,4'-dimethoxyisoflavone
[Isoflavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Isoflavone	3'-Hydroxy-8-O-methylretusin
[Isoflavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Isoflavone	7,3'-Dimethixyorobol
[Isoflavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Isoflavone	5,3'-Dihydroxy-7,4'-dimethoxyisoflavone
[Isoflavone]-A(1OH, 2OMe)-B(1OH)	Isoflavone	Muningin
[Isoflavone]-A(1OH, 2OMe)-B(1OH)	Isoflavone	7-O-Methyltectorigenin
[Isoflavone]-A(1OH, 2OMe)-B(1OH)	Isoflavone	5,2'-Dihydroxy-7,8-dimethoxyisoflavone
[Isoflavone]-A(2OH)-B(2OMe)	Isoflavone	Pratensein 3'-O-methyl ether
[Isoflavone]-A(2OH)-B(2OMe)	Isoflavone	2'-Methoxybiochanin A
[Isoflavone]-A(2OMe)-B(2OH)	Isoflavone	5,7-Dimethixyorobol
[Isoflavone]-A(2OMe)-B(2OH)	Isoflavone	2',4'-Dihydroxy-5,7-dimethoxyisoflavone
[Isoflavone]-A(1OH)-B(1OH, 2OMe)	Isoflavone	7,2'-Dihydroxy-3',4'-dimethoxyisoflavone
[Flavanone]-A(1OMe)-B(2OMe)	Flavanone	6,3',4'-Trimethoxyflavanone
[Flavanone]-A(2OMe)-B(1OMe)	Flavanone	Naringenin trimethyl ether
[Flavanone]-A(3OMe)-B(none)	Flavanone	5,7,8-Trimethoxyflavanone
[2'-Hydroxychalcone]-A(1OH)-B(3OMe)	2'-Hydroxychalcone	Crotaoprostrin
[2'-Hydroxychalcone]-A(1OH, 2OMe)-B(1OMe)	2'-Hydroxychalcone	2'-Hydroxy-2,4',6'-trimethoxychalcone
[2'-Hydroxychalcone]-A(1OH, 2OMe)-B(1OMe)	2'-Hydroxychalcone	Flavokawin A
[2'-Hydroxychalcone]-A(1OH, 3OMe)-B(none)	2'-Hydroxychalcone	Helilandin B
[2'-Hydroxychalcone]-A(1OH, 3OMe)-B(none)	2'-Hydroxychalcone	2'-Hydroxy-3',4',6'-trimethoxychalcone
[Coumestan]-A(1OH, 1OMe)-B(2OH)	Coumestan	Wedelolactone
[Flavonol]-A(1OH, 1OMe)-B(1OMe)	Flavonol	3,7-Dihydroxy-5,4'-dimethoxyflavone
[Flavonol]-A(1OH, 1OMe)-B(1OMe)	Flavonol	Kaempferol 7,4'-dimethyl ether
[Flavonol]-A(1OH, 2OMe)-B(none)	Flavonol	3,7-Dihydroxy-5,6-dimethoxyflavone
[Flavonol]-A(1OH, 2OMe)-B(none)	Flavonol	3,6-Dihydroxy-5,7-dimethoxyflavone
[Flavonol]-A(1OH, 2OMe)-B(none)	Flavonol	3,5-Dihydroxy-6,7-dimethoxyflavone
[Flavonol]-A(1OH, 2OMe)-B(none)	Flavonol	3,5-Dihydroxy-7,8-dimethoxyflavone
[Flavonol]-A(2OMe)-B(1OH)	Flavonol	3,4'-Dihydroxy-7,8-dimethoxyflavone
[Pterocarpan]-A(2OMe)-B(1OMe)	Pterocarpan	2-Methoxyhomopterocarpin
[Pterocarpan]-A(2OMe)-B(1OMe)	Pterocarpan	4-Methoxyhomopterocarpin
[Aurone]-A(1OH, 1OMe, 1Methyl)-B(2OH)	Aurone	6,3',4'-Trihydroxy-4-methoxy-5-methylaurone
[Aurone]-A(1OH, 1OMe, 1Methyl)-B(2OH)	Aurone	6,3',4'-Trihydroxy-4-methoxy-7-methylaurone
[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1([@@]-Methylenedioxy))	2'-Hydroxychalcone	Prosogerin B
[2'-Hydroxychalcone]-A(1OH, 1OMe, 1([@@]-Methylenedioxy))-B(1OH)	2'-Hydroxychalcone	4,2'-Dihydroxy-6'-methoxy-3',4'-methylenedioxychalcone
[beta-Hydroxy(or Oxodihydro)chalcone]-A(3OH, 1Formyl, 1Methyl)-B(none)	beta-Hydroxy(or Oxodihydro)chalcone	3'-Formyl-2',4',6',beta-tetrahydroxy-5'-methylchalcone
[UBR-type derivative / [2',5']-Benzoquinonyl-type chalcone]-A(1OH, 2OMe)-B(none)	UBR-type derivative / [2',5']-Benzoquinonyl-type chalcone	Methylpedicinin
[UBR-type derivative / 2'-Oxocyclohexa-4',6'-dienyl-type beta-Hydroxychalcone]-A(1OH, 1OMe, 2Methyl)-B(none)	UBR-type derivative / 2'-Oxocyclohexa-4',6'-dienyl-type beta-Hydroxychalcone	Syzygiol
[Dihydrochalcone]-A(2OMe)-B(1([@@]-Methylenedioxy))	Dihydrochalcone	Ponganone VII
[Dihydrochalcone]-A(2OMe, 1([@@]-Methylenedioxy))-B(none)	Dihydrochalcone	2',6'-Dimethoxy-3',4'-methylenedioxydihydrochalcone
[UBR-type derivative / 2',4'-Dioxo-6'-cyclohexenyl-type Dihydrochalcone]-A(1OH, 4Methyl)-B(none)	UBR-type derivative / 2',4'-Dioxo-6'-cyclohexenyl-type Dihydrochalcone	Grandiflorone
[Flavanone]-A(1OH, 1OMe)-B(1([@@]-Methylenedioxy))	Flavanone	6-Hydroxy-7-methoxy-3',4'-methylenedioxyflavanone
[Flavanone]-A(1OH, 1OMe, 1Hydroxymethyl, 1Methyl)-B(none)	Flavanone	Leridol
[Flavanone]-A(2OH, 2Methyl)-B(1OMe)	Flavanone	Isomatteucinol
[Flavanone]-A(2OH, 2Methyl)-B(1OMe)	Flavanone	Matteucinol
[Flavanone]-A(1OH, 1OMe, 2Methyl)-B(1OH)	Flavanone	Angophorol
[Flavone]-A(1OH, 1OMe, 1Methyl)-B(2OH)	Flavone	5,3',4'-Trihydroxy-7-methoxy-6-methylflavone
[Dihydroflavonol]-A(2OH)-B(none)-C(1(O-Acetyl))	Dihydroflavonol	Pinobanksin 3-O-acetate
[Dihydroflavonol]-A(1OMe, 1([@@]-Methylenedioxy))-B(none)	Dihydroflavonol	3-Hydroxy-5-methoxy-6,7-methylenedioxyflavanone
[Flavonol (3-OMe)]-A(1OH, 1OMe)-B(1OH)	Flavonol	7,4'-Dihydroxy-3,6-dimethoxyflavone
[Flavonol (3-OMe)]-A(2OH, 1Methyl)-B(1OH)	Flavonol	Sylpin
[Flavonol (3-OMe)]-A(2OH)-B(1OMe)	Flavonol	Ermanin
[Flavonol (3-OMe)]-A(1OH, 1OMe)-B(1OH)	Flavonol	Kaempferol 3,5-dimethyl ether
[Flavonol (3-OMe)]-A(1OH, 1OMe)-B(1OH)	Flavonol	Kumatakenin
[Flavonol (3-OMe)]-A(2OH, 1Methyl)-B(1OH)	Flavonol	5,7,4'-Trihydroxy-3-methoxy-6-methylflavone
[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(none)	Flavonol	Alnusin 3-methyl ether
[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(none)	Flavonol	5,6-Dihydroxy-3,7-dimethoxyflavone
[Flavonol]-A(1OH, 1([@@]-Methylenedioxy))-B(1OH)	Flavonol	Gomphrenol
[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(none)	Flavonol	5,8-Dihydroxy-3,7-dimethoxyflavone
[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(none)	Flavonol	Gnaphaliin
[Flavonol (3-OMe)]-A(3OH, 1Methyl)-B(none)	Flavonol	Platanin 3-methyl ether
[Flavonol]-A(2OH, 1OMe, 1Methyl)-B(none)	Flavonol	3,5,8-Trihydroxy-7-methoxy-6-methylflavone
[Flavonol]-A(2OH, 1OMe, 1Methyl)-B(none)	Flavonol	Pityrogrammin
[CCS-type derivative / [3,2']-Epoxymethanoflavone]-A(2OH)-B(2OH)	CCS-type derivative / [3,2']-Epoxymethanoflavone	2,3,8,10-Tetrahydroxy[2]benzopyrano[4,3-b][1]benzopyran-7(5H)-one
[CCS-type derivative / [3,2']-Epoxyhydroxymethanoflavone]-A(1OH)-B(2OH)	CCS-type derivative / [3,2']-Epoxyhydroxymethanoflavone	Fasciculiferin
[Flavan]-A(1OH, 2Methyl)-B(1OH, 1([@@]-Methylenedioxy))	Flavan	7,2'-Dihydroxy-6,8-dimethyl-4',5'-methylenedioxyflavan
[Flavan]-A(1OH, 2Methyl)-B(1OH, 1([@@]-Methylenedioxy))	Flavan	7,2'-Dihydroxy-5,8-dimethyl-4',5'-methylenedioxyflavan
[3-DehydroxyAnthocyanidin]-A(2OH, 1OMe)-B(1OH, 1OMe)	3-DehydroxyAnthocyanidin	5,4'-Dimethyl-6-hydroxyluteolinidin
[UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavone]-A(2OH)-B(1OMe)	UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavone	5-Hydroxybowdichione
[Isoflavanone]-A(1OH)-B(1OMe, 1([@@]-Methylenedioxy))	Isoflavanone	Onogenin
[Pterocarpan]-A(1OH, 1OMe)-B(1([@@]-Methylenedioxy))	Pterocarpan	2-Hydroxyhomopterocarpin
[Pterocarpan]-A(1OH, 1OMe)-B(1([@@]-Methylenedioxy))	Pterocarpan	4-Methoxymaackiain
[Pterocarpan]-A(1OH, 1OMe)-B(1([@@]-Methylenedioxy))	Pterocarpan	4-Hydroxypterocarpin
[Pterocarpan-6a-ol]-A(1OMe)-B(1([@@]-Methylenedioxy))	Pterocarpan-6a-ol	Pisatin
[Pterocarpan-6-ol (6-OMe)]-A(1OH)-B(1([@@]-Methylenedioxy))	Pterocarpan-6-ol	Sophoracarpan B
[Pterocarpan-6-ol (3-OMe)]-A(1OMe)-B(1OMe)	Pterocarpan-6-ol	6-Methoxyhomopterocarpin
[4-phenylcoumarin]-A(1OH, 1OMe)-B(1OH, 1OMe)	4-phenylcoumarin	Melannein
[4-phenylcoumarin]-A(1OH, 1OMe)-B(1OH, 1OMe)	4-phenylcoumarin	7,3'-Dihydroxy-5,4'-dimethoxy-4-phenylcoumarin
[4-phenylcoumarin]-A(1OH, 1OMe)-B(1OH, 1OMe)	4-phenylcoumarin	5,3'-Dihydroxy-7,4'-dimethoxy-4-phenylcoumarin
[4-phenylcoumarin]-A(2OMe)-B(2OH)	4-phenylcoumarin	3',4'-Dihydroxy-5,7-dimethoxy-4-phenylcoumarin

Level: 3, プリカーサーm/z: 579.05255

Splash: splash10-014i-0019610000-0556a432dc32540dda46

m/z	Int.	NL	Rel.Int.
417.21	199	162	1000
381.19	95	198	478
339.24	77	240	386
399.01	76	180	380
561.25	42	18	211
459.41	25	120	127
163.09	17	416	86
261.21	15	318	76
362.98	15	216	74
535.12	15	44	73
313.17	14	266	69
278.92	13	300	66
351.10	13	228	63
265.11	12	314	60

Symbolized Name	MSMS-Category	MSMS-Aglycone
[Flavone]-A(2OH, 1(1(O-p-Coumaroyl)-C-Glu))-B(1OH)	Flavone	Vitexin 2''-O-p-coumarate
[Flavone]-A(1OH, 1OMe, 1(C-Glu), 1(C-Arabinosyl))-B(1OH)	Flavone	6-C-Glucopyranosyl-8-C-arabinopyranosylgenkwanin
[Flavone]-A(2OH, 1(C-Glu), 1(C-Rhamnosyl))-B(1OH)	Flavone	Violanthin
[Flavone]-A(2OH, 1(C-Glu), 1(C-Rhamnosyl))-B(1OH)	Flavone	Isoviolanthin
[Flavone]-A(2OH, 1(C-Glu), 1(C-Chinovosyl))-B(1OH)	Flavone	Violarvensin
[Flavone]-A(2OH, 2(C-Rhamnosyl))-B(2OH)	Flavone	6,8-Di-C-rhamnopyranosylluteolin