ピーク情報

はつか大根　根

pos

Peak #6197 MN MID: SE202_S11_M90

m/z: 379.14005, RT: 62.43, 強度: 1736, ログ強度: -0.21, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 1

DB検索結果: (11 names) Aigialospirol;(+)-Aigialospirol;8-Hydroxy-3'',4''-dihydrocapnolactone-2',3'-diol;Syringopicrogenin C;3,4-DHPEA-EA;Cordifolia 31;2-(3,4-Dihydroxyphenylethyl)-6-epi-elenaiate;Hydroxyvernolide;Podolacton...

DBごとのヒット数: ALL 10 KG 2 KN 7 HM 1

FlavonoidSearch最大スコア MS2: -, MS3: 0.333

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C19H22O8	378.13147	3.457	8-Hydroxy-3'',4''-dihydrocapnolactone-2',3'-diol	KNApSAcK: C00036022
C19H22O8	378.13147	3.457	Syringopicrogenin C	KNApSAcK: C00010706
C19H22O8	378.13147	3.457	Aigialospirol	KNApSAcK: C00043255
C19H22O8	378.13147	3.457	Oleuropein aglycone	HMDB: HMDB0029304, HMDB0301749 KEGG: C21786
C19H22O8	378.13147	3.457	2-(3,4-Dihydroxyphenylethyl)-6-epi-elenaiate	HMDB: HMDB0039137
C19H22O8	378.13147	3.457	Cordifolia 31	KNApSAcK: C00012243
C19H22O8	378.13147	3.457	Hydroxyvernolide	KEGG: C09477 KNApSAcK: C00003301
C19H22O8	378.13147	3.457	Podolactone A	KNApSAcK: C00000263
C19H22O8	378.13147	3.457	Gibberellin A32	HMDB: HMDB0035037 KNApSAcK: C00000032
C19H22O8	378.13147	3.457	Jasmolactone A	KNApSAcK: C00010767

MSnスペクトル情報

Level: 2, プリカーサーm/z: 379.13986

Splash: splash10-0002-0009000000-1c1dbd472c9f21c91146

m/z	Int.	NL	Rel.Int.
347.18	5263	32	1000
348.29	563	31	106

FlavonoidSearch結果

Symbolized Name	MSMS-Category	MSMS-Aglycone
[Dihydrochalcone]-A(2OH, 1OMe, 1(2-hydroxybenzyl))-B(none)	Dihydrochalcone	Isouvaretin
[Dihydrochalcone]-A(2OH, 1OMe, 1(2-hydroxybenzyl))-B(none)	Dihydrochalcone	Uvaretin
[Dihydrochalcone]-A(2OH, 1OMe, 1(2-hydroxybenzyl))-B(none)	Dihydrochalcone	2',6'-Dihydroxy-4'-methoxy-3'-(2-hydroxybenzyl)dihydrochalcone
[Flavanone]-A(1OH, 1([2,3:@@]-(5,6-Dihydroxybenzofurano)))-B(1OH)	Flavanone	Anastatin A
[Flavanone]-A(1OH, 1([2,3:@@]-(5,6-Dihydroxybenzofurano)))-B(1OH)	Flavanone	Anastatin B
[Flavone]-A(1([2,3:@@]-(8,8-Dimethyl-9-hydroxy-6-oxo-1,7-dioxaspiro[4,4]non-2-ene)))-B(none)	Flavone	Glabratephrinol
[Flavone]-A(1OMe, 1([@@]-Methylenedioxy))-B(1([2,3:@@]-(6,6-Dimethylpyrano)))	Flavone	Isopongachromene
[Flavone]-A(1OMe, 1([@@]-Methylenedioxy))-B(1([2,3:@@]-(6,6-Dimethylpyrano)))	Flavone	5-Methoxy-6'',6''-dimethyl-3',4'-methylenedioxypyrano[2'',3'':7,8]flavone
[Flavonol (3-OMe)]-A(1([2,3:@@]-Furano))-B(1([@@]-Methylenedioxy))	Flavonol	Pongachromene
[Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH, 1Cl)	Flavonol	Chlorflavonin
[Isoflavone]-A(1([@@]-Methylenedioxy))-B(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))	Isoflavone	Isojamaicin
[Isoflavone]-A(1([@@]-Methylenedioxy))-B(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))	Isoflavone	Jamaicin
[Isoflavone]-A(1OMe, 1([@@]-Methylenedioxy))-B(1([2,3:@@]-(6,6-Dimethylpyrano)))	Isoflavone	Durmillone
[Isoflavone]-A(1OMe, 1([@@]-Methylenedioxy))-B(1([2,3:@@]-(6,6-Dimethylpyrano)))	Isoflavone	Robustone methyl ether
[Isoflavone]-A(1OMe, 1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(1([@@]-Methylenedioxy))	Isoflavone	Glabrescione A
[Rotenone]-A(1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(1([@@]-Methylenedioxy))	Rotenone	Isomillettone
[Rotenone]-A(1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1([@@]-Methylenedioxy))	Rotenone	Millettone

Level: 3, プリカーサーm/z: 347.18356

Splash: splash10-001i-0009000000-8c43a34179f75c45e722

m/z	Int.	NL	Rel.Int.
332.13	3239	15	1000
303.11	332	44	102
333.11	282	14	87

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.333	[Flavone]-A(2OH, 1OMe)-B(2OH, 1OMe)	Flavone	5,7,3',4'-Tetrahydroxy-6,5'-dimethoxyflavone
0.333	[Flavone]-A(1OH, 2OMe)-B(3OH)	Flavone	5,3',4',5'-Tetrahydroxy-6,7-dimethoxyflavone
0.333	[Flavone]-A(2OH, 1OMe)-B(2OH, 1OMe)	Flavone	5,7,2',4'-Tetrahydroxy-6,5'-dimethoxyflavone
0.333	[Flavone]-A(2OH, 1OMe)-B(2OH, 1OMe)	Flavone	Ganhuangenin
0.333	[Flavone]-A(2OH, 1OMe)-B(2OH, 1OMe)	Flavone	5,7,2',3'-Tetrahydroxy-8,6'-dimethoxyflavone
0.333	[Flavone]-A(2OH, 1OMe)-B(2OH, 1OMe)	Flavone	5,7,3',5'-Tetrahydroxy-8,4'-dimethoxyflavone
0.333	[Flavone]-A(2OH, 1OMe)-B(2OH, 1OMe)	Flavone	5,7,2',4'-Tetrahydroxy-8,5'-dimethoxyflavone
0.333	[Flavone]-A(2OH, 2OMe)-B(2OH)	Flavone	5,6,2',6'-Tetrahydroxy-7,8-dimethoxyflavone
0.333	[Flavone]-A(2OH, 2OMe)-B(2OH)	Flavone	Leucanthogenin
0.333	[Flavone]-A(2OH, 2OMe)-B(2OH)	Flavone	5,7,3',4'-Tetrahydroxy-6,8-dimethoxyflavone
0.333	[Flavone]-A(2OH, 2OMe)-B(2OH)	Flavone	5,6,3',4'-Tetrahydroxy-7,8-dimethoxyflavone
0.091	[2'-Hydroxychalcone]-A(1OH, 3OMe)-B(2OH)	2'-Hydroxychalcone	Hamilcone
0.077	[Flavanone]-A(1OH, 3OMe)-B(1OH)	Flavanone	5,4'-Dihydroxy-6,7,8-trimethoxyflavanone
0.077	[Flavanone]-A(1OH, 1OMe)-B(1OH, 2OMe)	Flavanone	5,2'-Dihydroxy-7,4',5'-trimethoxyflavanone
0.077	[Flavanone]-A(2OH, 2OMe)-B(1OMe)	Flavanone	5,6-Dihydroxy-7,8,4'-trimethoxyflavanone
0.077	[Flavanone]-A(1OH, 2OMe)-B(1OH, 1OMe)	Flavanone	5,2'-Dihydroxy-6,7,6'-trimethoxyflavanone
0.077	[Flavanone]-A(1OH, 2OMe)-B(1OH, 1OMe)	Flavanone	5,3'-Dihydroxy-6,7,4'-trimethoxyflavanone
0.077	[Flavanone]-A(1OH, 2OMe)-B(1OH, 1OMe)	Flavanone	Agestricin D
0.077	[Flavanone]-A(1OH, 2OMe)-B(1OH, 1OMe)	Flavanone	5,2'-Dihydroxy-7,8,6'-trimethoxyflavanone
0.077	[Flavanone]-A(1OH, 2OMe)-B(1OH, 1OMe)	Flavanone	5,3'-Dihydroxy-7,8,4'-trimethoxyflavanone
0.056	[Flavonol]-A(1OH, 1OMe)-B(2OH, 1OMe)	Flavonol	Inucrithmin
0.056	[Flavonol]-A(1OH, 1OMe)-B(2OH, 1OMe)	Flavonol	Myricetin 7,4'-dimethyl ether
0.056	[Flavonol]-A(2OH)-B(1OH, 2OMe)	Flavonol	Myricetin 3',4'-dimethyl ether
0.056	[Flavonol]-A(2OH)-B(1OH, 2OMe)	Flavonol	Syringetin
0.056	[Flavonol]-A(2OH)-B(1OH, 2OMe)	Flavonol	Viscidulin III
0.056	[Flavonol]-A(2OH, 1OMe)-B(1OH, 1OMe)	Flavonol	Spinacetin
0.056	[Flavonol]-A(2OH, 1OMe)-B(1OH, 1OMe)	Flavonol	Laciniatin
0.056	[Flavonol]-A(2OH, 1OMe)-B(1OH, 1OMe)	Flavonol	Quercetagetin 7,3'-dimethyl ether
0.056	[Flavonol]-A(2OH, 1OMe)-B(1OH, 1OMe)	Flavonol	Gossypetin 3',8-dimethyl ether
0.056	[Flavonol]-A(2OH, 1OMe)-B(1OH, 1OMe)	Flavonol	Gossypetin 7,4'-dimethyl ether
0.056	[Flavonol]-A(2OH, 1OMe)-B(1OH, 1OMe)	Flavonol	Limocitrin
0.056	[Flavonol]-A(2OH, 1OMe)-B(1OH, 1OMe)	Flavonol	Gossypetin 8,4'-dimethyl ether
0.056	[Flavonol]-A(1OH, 2OMe)-B(2OH)	Flavonol	Eupatolitin
0.056	[Flavonol]-A(1OH, 2OMe)-B(2OH)	Flavonol	Zanthoxyl flavone
0.000	[Dihydrochalcone]-A(1OH, 4OMe)-B(none)	Dihydrochalcone	Dihydrokanakugiol
0.000	[Pterocarpan]-A(1OH, 1OMe)-B(1OH, 2OMe)	Pterocarpan	2,8-Dihydroxy-3,9,10-trimethoxypterocarpan
0.000	[Dihydrochalcone]-A(2OH, 1OMe, 1([@@]-Methylenedioxy))-B(1OMe)	Dihydrochalcone	2',6'-Dihydroxy-4,3'-dimethoxy-4',5'-methylenedioxydihydrochalcone
0.000	[Dihydroflavonol]-A(2OH)-B(2OH)-C(1(O-Acetyl))	Dihydroflavonol	Taxifolin 3-O-acetate
0.000	[Flavonol (3-OMe)]-A(2OH)-B(2OH, 1OMe)	Flavonol	Myricetin 3,4'-dimethyl ether
0.000	[Flavonol (3-OMe)]-A(2OH)-B(2OH, 1OMe)	Flavonol	Artemexitin
0.000	[Flavonol]-A(2OH, 1Methyl)-B(2OH, 1OMe)	Flavonol	Dumosol
0.000	[Flavonol (3-OMe)]-A(2OH, 1Methyl)-B(3OH)	Flavonol	Alluaudiol
0.000	[Flavonol (3-OMe)]-A(2OH)-B(2OH, 1OMe)	Flavonol	5,7,4',5'-Tetrahydroxy-3,2'-dimethoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH)-B(2OH, 1OMe)	Flavonol	5,7,2',5'-Tetrahydroxy-3,4'-dimethoxyflavone
0.000	[Flavonol (3-OMe)]-A(3OH)-B(1OH, 1OMe)	Flavonol	Quercetagetin 3,3'-dimethyl ether
0.000	[Flavonol (3-OMe)]-A(3OH)-B(1OH, 1OMe)	Flavonol	Quercetagetin 3,4'-dimethyl ether
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(2OH)	Flavonol	Axillarin
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(2OH)	Flavonol	Tomentin
0.000	[Flavonol (3-OMe)]-A(3OH)-B(1OH, 1OMe)	Flavonol	Gossypetin 3,3'-dimethyl ether
0.000	[Flavonol (3-OMe)]-A(3OH)-B(1OH, 1OMe)	Flavonol	Gossypetin 3,4'-dimethyl ether
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(2OH)	Flavonol	7,8,3',4'-Trihydroxy-3,5-dimethoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(2OH)	Flavonol	Gossypetin 3,7-dimethyl ether
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(2OH)	Flavonol	Gossypetin 3,8-dimethyl ether
0.000	[Flavonol (3-OMe)]-A(3OH, 1OMe)-B(1OH)	Flavonol	5,7,8,4'-Tetrahydroxy-3,6-dimethoxyflavone
0.000	[Flavan 3,4-diol]-A(1OH, 1OMe, 2Methyl)-B(1OMe)	Flavan 3,4-diol	3,4,7-Trihydroxy-5,4'-dimethoxy-6,8-dimethylflavan
0.000	[UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavan]-A(1OH, 1OMe)-B(2OMe)	UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavan	Amorphaquinone

Level: 3, プリカーサーm/z: 348.29474

Splash: splash10-001i-0009000000-a7ef3e75743a59344d8a

m/z	Int.	NL	Rel.Int.
333.21	235	15	1000
332.23	34	16	142
304.12	23	44	96
316.20	17	32	72
348.14	13	0	54