ピーク情報

細ネギ（若香）地下部

pos

Peak #5519 MN MID: SE201_S21_M90

m/z: 609.36345, RT: 53.22, 強度: 94906, ログ強度: 1.39, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 3

DB検索結果: (3 names) 3-O-(beta-D-glucopyranosyl)-2beta,3beta,20,22R-tetrahydroxy-5beta-cholest-7,14-dien-6-one;3alpha-Angeloyloxy-2beta,15,16-trihydroxy-ent-labda-7,13E-dien-2-O-beta-[fucopyranoside-4'-O-acetate];3alpha-A...

DBごとのヒット数: ALL 3 KN 2 LM 1

FlavonoidSearch最大スコア MS2: -, MS3: 0.176

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C33H52O10	608.35605	0.201	3-O-(beta-D-glucopyranosyl)-2beta,3beta,20,22R-tetrahydroxy-5beta-cholest-7,14-dien-6-one	LipidMAPS: LMST01010433
C33H52O10	608.35605	0.201	3alpha-Angeloyloxy-2beta,15,16-trihydroxy-ent-labda-7,13E-dien-2-O-beta-[fucopyranoside-4'-O-acetate]	KNApSAcK: C00023196
C33H52O10	608.35605	0.201	3alpha-Angeloyloxy-2beta,15,16-trihydroxy-ent-labda-7,13E-dien-2-O-beta-[fucopyranoside-4'-O-acetate]	KNApSAcK: C00023195

MSnスペクトル情報

Level: 2, プリカーサーm/z: 609.36267

Splash: splash10-0002-0022900000-e0f3672704c58b39310d

m/z	Int.	NL	Rel.Int.
447.31	42890	162	1000
303.16	10525	306	245
243.14	4999	366	116
225.16	3934	384	91
285.24	2789	324	65
429.33	2564	180	59

Symbolized Name	MSMS-Category	MSMS-Aglycone
[Flavone]-A(1OH, 1OMe, 2(C-Glu))-B(1OH)	Flavone	6,8-Di-C-glucopyranosylgenkwanin
[Flavone]-A(2OH, 1(1(O-(E)-Feruloyl)-C-Glu))-B(1OH)	Flavone	Vitexin 2''-O-(E)-ferulate
[Flavone]-A(2OH, 1(1(O-(E)-Feruloyl)-C-Glu))-B(1OH)	Flavone	Isovitexin 2''-O-(E)-ferulate
[3-substituted Flavone (3-C-Glu)]-A(2OH, 1(C-Glu))-B(1OMe)	3-substituted Flavone	3,6-Di-C-glucopyranosylacacetin
[Flavone]-A(1OH, 1OMe, 1(C-Glu), 1(C-Galactosyl))-B(1OH)	Flavone	6-C-Glucopyranosyl-8-C-galactopyranosylgenkwanin

Level: 3, プリカーサーm/z: 447.28485

Splash: splash10-0udl-0095000000-e9f442eb8a431c509070

m/z	Int.	NL	Rel.Int.
303.16	10933	144	1000
243.14	8321	204	761
225.15	5149	222	471
285.29	3922	162	358
259.12	2187	188	200
201.23	762	246	69
429.27	670	18	61
315.28	588	132	53
369.40	548	78	50

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.071	[Flavone]-A(2OH, 1(C-Glu))-B(1OMe)	Flavone	Cytisoside
0.071	[Flavone]-A(1OH, 1OMe, 1(C-Glu))-B(1OH)	Flavone	Isoswertisin
0.071	[Flavone]-A(2OH, 1(C-Glu))-B(1OMe)	Flavone	Isocytisoside
0.071	[Flavone]-A(1OH, 1OMe, 1(C-Glu))-B(1OH)	Flavone	Swertisin
0.071	[Isoflavone]-A(1OH, 1(C-Glu))-B(1OH, 1OMe)	Isoflavone	Pueraria glycoside 3
0.071	[Isoflavone]-A(1OH, 1OMe, 1(C-Glu))-B(1OH)	Isoflavone	Prunetin 8-C-glucoside
0.000	[Dihydrochalcone]-A(1OH, 1OMe, 1([2,3:@@]-(5-(2-Hydroxy-5-methoxycarbonylphenyl)furano)))-B(none)	Dihydrochalcone	Longicaudatin
0.000	[Flavone]-A(2OH, 1(C-Fucosyl))-B(1OH, 1OMe)	Flavone	6-C-fucosyl-3'-methoxyluteoiin
0.000	[CCS-type derivative / [2,3,4:5,4a,4]-(6-Phenylpyrano)anthocyanidin (4'-Hydroxy)]-A(1OH)-B(1OH, 2OMe)	CCS-type derivative / [2,3,4:5,4a,4]-(6-Phenylpyrano)anthocyanidin	Malvidin 4-vinylphenol

Level: 3, プリカーサーm/z: 303.12030

Splash: splash10-000l-0090000000-cec1f86791f4504c9ae5

m/z	Int.	NL	Rel.Int.
285.27	2189	18	1000
243.24	1453	60	663
225.09	901	78	411
216.07	403	87	184
259.25	386	44	176
215.04	207	88	94
267.31	174	36	79
257.24	162	46	73
217.18	146	86	66

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.231	[Dihydroflavonol]-A(2OH, 1OMe)-B(none)	Dihydroflavonol	Alnustinol
0.182	[Dihydroflavonol]-A(2OH, 1OMe)-B(none)	Dihydroflavonol	3,5,8-Trihydroxy-7-methoxyflavanone
0.176	[Anthocyanidin]-A(2OH)-B(3OH)	Anthocyanidin	Delphinidin
0.176	[Anthocyanidin]-A(3OH)-B(2OH)	Anthocyanidin	6-Hydroxycyanidin
0.167	[Isoflavone]-A(3OH)-B(2OH)	Isoflavone	5,7,8,2',4'-Pentahydroxyisoflavone
0.143	[Dihydroflavonol]-A(2OH)-B(1OMe)	Dihydroflavonol	Aromadendrin 4'-methyl ether
0.125	[Isoflavanone]-A(1OH)-B(2OH, 1OMe)	Isoflavanone	7,2',3'-Trihydroxy-4'-methoxyisoflavanone
0.125	[Isoflavanone]-A(2OH)-B(1OH, 1OMe)	Isoflavanone	Ferreirin
0.125	[Isoflavanone]-A(2OH)-B(1OH, 1OMe)	Isoflavanone	Isoferreirin
0.111	[Flavone]-A(3OH)-B(2OH)	Flavone	6-Hydroxyluteolin
0.111	[Flavone]-A(3OH)-B(2OH)	Flavone	Hypolaetin
0.111	[Flavone]-A(2OH)-B(3OH)	Flavone	Tricetin
0.111	[Flavone]-A(2OH)-B(3OH)	Flavone	Isoetin
0.111	[Flavanone]-A(3OH, 1OMe)-B(none)	Flavanone	Oresbiusin
0.091	[Dihydroflavonol (3-OMe)]-A(1OH)-B(2OH)	Dihydroflavonol	3-O-Methyl-2,3-trans-fustin
0.083	[Dihydroflavonol]-A(1OH, 1OMe)-B(1OH)	Dihydroflavonol	Aromadendrin 5-methyl ether
0.083	[Dihydroflavonol]-A(1OH, 1OMe)-B(1OH)	Dihydroflavonol	Aromadendrin 7-methyl ether
0.083	[Flavonol]-A(2OH)-B(2OH)	Flavonol	3,5,7,2',5'-Pentahydroxyflavone
0.083	[Flavonol]-A(2OH)-B(2OH)	Flavonol	Viscidulin I
0.080	[Flavonol]-A(3OH)-B(1OH)	Flavonol	6-Hydroxykaempferol
0.080	[Flavonol]-A(3OH)-B(1OH)	Flavonol	Herbacetin
0.080	[Flavonol]-A(2OH)-B(2OH)	Flavonol	Rhynchosin
0.080	[Flavonol]-A(2OH)-B(2OH)	Flavonol	Melanoxetin
0.080	[Flavonol]-A(2OH)-B(2OH)	Flavonol	Quercetin
0.080	[Flavonol]-A(2OH)-B(2OH)	Flavonol	Morin
0.080	[Flavonol]-A(1OH)-B(3OH)	Flavonol	Robinetin
0.080	[Flavonol]-A(1OH)-B(3OH)	Flavonol	3,7,2',3',4'-Pentahydroxyflavone
0.077	[Flavan 3-ol]-A(1OH, 1OMe)-B(1OMe)	Flavan 3-ol	Afzelechin 5,4'-dimethyl ether
0.071	[Dihydroflavonol (3-OMe)]-A(2OH)-B(1OH)	Dihydroflavonol	Aromadendrin 3-methyl ether
0.059	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(2OH)	2'-Hydroxychalcone	Lanceoletin
0.059	[2'-Hydroxychalcone]-A(3OH)-B(1OH, 1OMe)	2'-Hydroxychalcone	Okanin 4-methyl ether
0.059	[2'-Hydroxychalcone]-A(3OH)-B(1OH, 1OMe)	2'-Hydroxychalcone	4,2',4',6'-Tetrahydroxy-3-methoxychalcone
0.053	[Chalcone]-A(2OH)-B(2OH, 1OMe)	Chalcone	3,4,3',4'-Tetrahydroxy-2-methoxychalcone
0.053	[Flavanone]-A(2OH, 1OMe)-B(1OH)	Flavanone	5,7,4'-Trihydroxy-6-methoxyflavanone
0.053	[Flavanone]-A(2OH, 1OMe)-B(1OH)	Flavanone	5,8,2'-Trihydroxy-7-methoxyflavanone
0.053	[Flavanone]-A(2OH, 1OMe)-B(1OH)	Flavanone	5,7,4'-Trihydroxy-8-methoxyflavanone
0.053	[Flavanone]-A(2OH)-B(1OH, 1OMe)	Flavanone	Alysifolinone
0.053	[Flavanone]-A(2OH)-B(1OH, 1OMe)	Flavanone	Homoeriodictyol
0.053	[Flavanone]-A(2OH)-B(1OH, 1OMe)	Flavanone	Hesperetin
0.053	[Flavanone]-A(1OH, 1OMe)-B(2OH)	Flavanone	8-Methoxybutin
0.053	[Flavanone]-A(1OH, 1OMe)-B(2OH)	Flavanone	7,2',6'-Trihydroxy-5-methoxyflavanone
0.053	[Flavanone]-A(1OH, 1OMe)-B(2OH)	Flavanone	Scutamoenin
0.053	[Flavanone]-A(1OH, 1OMe)-B(2OH)	Flavanone	5,2',3'-Trihydroxy-7-methoxyflavanone
0.053	[Flavanone]-A(1OH, 1OMe)-B(2OH)	Flavanone	Eriodictyol 5-methyl ether
0.053	[Flavanone]-A(1OH, 1OMe)-B(2OH)	Flavanone	Sternbin
0.053	[Flavanone]-A(1OH, 1OMe)-B(2OH)	Flavanone	Artocarpanone
0.053	[Flavanone]-A(3OH)-B(1OMe)	Flavanone	4'-O-Methylcarthamidin
0.053	[Flavanone]-A(3OH)-B(1OMe)	Flavanone	5,7,8-Trihydroxy-4'-methoxyflavanone
0.000	[Isoflavan]-A(1OH, 1OMe)-B(1OH, 1OMe)	Isoflavan	5-Methoxyvestitol
0.000	[Isoflavan]-A(2OMe)-B(2OH)	Isoflavan	Lotisoflavan
0.000	[Isoflavan]-A(1OH)-B(1OH, 2OMe)	Isoflavan	Sphaerosin
0.000	[Isoflavan]-A(1OH)-B(1OH, 2OMe)	Isoflavan	4',7-Dihydroxy-2',3'-dimethoxyisoflavan (+-)
0.000	[Isoflavan]-A(1OH)-B(1OH, 2OMe)	Isoflavan	Mucronulatol
0.000	[Isoflavan]-A(1OH)-B(1OH, 2OMe)	Isoflavan	Isomucronulatol
0.000	[Isoflavan]-A(1OH)-B(1OH, 2OMe)	Isoflavan	Methoxyvestitol
0.000	[Dihydrochalcone]-A(1OH, 2OMe)-B(1OH)	Dihydrochalcone	Dihydroflavokawain C
0.000	[Dihydrochalcone]-A(1OH)-B(1OH, 2OMe)	Dihydrochalcone	2,4'-Dihydroxy-4,6-dimethoxydihydrochalcone
0.000	[Dihydrochalcone]-A(1OH)-B(1OH, 2OMe)	Dihydrochalcone	4,4'-Dihydroxy-2,6-dimethoxydihydrochalcone
0.000	[Dihydrochalcone]-A(2OH, 1OMe)-B(1OMe)	Dihydrochalcone	Lusianin
0.000	[Dihydrochalcone]-A(2OH, 1OMe)-B(1OMe)	Dihydrochalcone	Calomelanone
0.000	[Dihydrochalcone]-A(2OH, 1OMe)-B(1OMe)	Dihydrochalcone	2',4'-Dihydroxy-4,6'-dimethoxydihydrochalcone
0.000	[Dihydrochalcone]-A(2OH, 2OMe)-B(none)	Dihydrochalcone	Dihydropashanone
0.000	[Dihydrochalcone]-A(2OH, 2OMe)-B(none)	Dihydrochalcone	2',4'-Dihydroxy-3',6'-dimethoxydihydrochalcone
0.000	[Dihydrochalcone]-A(2OH, 2OMe)-B(none)	Dihydrochalcone	2',3'-Dihydroxy-4',6'-dimethoxydihydrochalcone
0.000	[Aurone]-A(2OH)-B(3OH)	Aurone	Bracteatin
0.000	[Auronol]-A(1OH)-B(1OH, 1OMe)	Auronol	2,6,3'-Trihydroxy-4'-methoxy-2-benzylcoumaranone
0.000	[Auronol]-A(1OH, 1OMe)-B(1OH)	Auronol	Carpusin
0.000	[Dihydrochalcone]-A(2OH, 1OMe, 1Methyl)-B(1OH)	Dihydrochalcone	4,2',6'-Trihydroxy-4'-methoxy-3'-methyldihydrochalcone
0.000	[Dihydrochalcone alpha-ol]-A(1OH, 1OMe)-B(1OMe)	Dihydrochalcone alpha-ol	Odoratol
0.000	[UBR-type derivative / 2'-Oxocyclohexa-4',6'-dienyl-type Dihydrochalcone]-A(3OH, 2Methyl)-B(none)	UBR-type derivative / 2'-Oxocyclohexa-4',6'-dienyl-type Dihydrochalcone	Ceratiolin
0.000	[Flavanone]-A(2OH, 1Methyl)-B(2OH)	Flavanone	5,7,3',5'-Tetrahydroxy-6-methylflavanone
0.000	[Flavanone]-A(2OH, 1Methyl)-B(2OH)	Flavanone	6-C-Methyleriodictylol
0.000	[Flavanone]-A(2OH)-B(2OH, 1Methyl)	Flavanone	5'-C-Methyleriodictylol
0.000	[Dihydroflavonol]-A(2OH, 1Methyl)-B(1OH)	Dihydroflavonol	6-Methylaromadendrin
0.000	[Flavan 4-ol]-A(2OH, 1Hydroxymethyl, 1Methyl)-B(none)	Flavan 4-ol	4,5,7-Trihydroxy-6-hydroxymethyl-8-methylflavan
0.000	[CCS-type derivative / [3,2']-Epoxymethanoflavan 4-ol]-A(1OH)-B(2OH)	CCS-type derivative / [3,2']-Epoxymethanoflavan 4-ol	Peltogynan-4-alpha-ol
0.000	[CCS-type derivative / [3,2']-Epoxymethanoflavan 4-ol]-A(1OH)-B(2OH)	CCS-type derivative / [3,2']-Epoxymethanoflavan 4-ol	Mopanan-4-alpha-ol
0.000	[Flavan]-A(2OH)-B(2OMe)	Flavan	Diffutidin
0.000	[Flavan]-A(2OMe)-B(2OH)	Flavan	3',4'-Dihydroxy-5,7-dimethoxyflavan
0.000	[Pterocarpan-6a-ol]-A(1OH)-B(1OH, 1OMe)	Pterocarpan-6a-ol	6a,7-Dihydroxymedicarpin
0.000	[[3,2']-Methano-4-phenylchroman (3-OH)]-A(2OH)-B(2OH)	[3,2']-Methano-4-phenylchroman	Haematoxylin