ピーク情報

細ネギ（若香）地下部

pos

Peak #3142 MN MID: SE201_S21_M90

m/z: 627.37463, RT: 42.03, 強度: 102173, ログ強度: 1.43, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 2

DB検索結果: (5 names) Ponasteroside A;Cotylenin F;(22R)-2beta,3beta,14,22-tetrahydroxy-6-oxo-5beta-cholest-7-en-25-yl D-glucopyranoside;14-epi-Ponasterone A 22-glucoside;(+)-14-epi-Ponasterone A 22-glucoside

DBごとのヒット数: ALL 4 KG 1 KN 1 LM 2

FlavonoidSearch最大スコア MS2: -, MS3: 0.143

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C33H54O11	626.36661	1.184	Ponasteroside A	HMDB: HMDB0034091 LipidMAPS: LMST01010436
C33H54O11	626.36661	1.184	Cotylenin F	KEGG: C09078 KNApSAcK: C00003418
C33H54O11	626.36661	1.184	(22R)-2beta,3beta,14,22-tetrahydroxy-6-oxo-5beta-cholest-7-en-25-yl D-glucopyranoside	LipidMAPS: LMST01010192
C33H54O11	626.36661	1.184	14-epi-Ponasterone A 22-glucoside	KNApSAcK: C00048252

MSnスペクトル情報

Level: 2, プリカーサーm/z: 627.37457

Splash: splash10-014i-0023900000-4a305933eb2a50ec7351

m/z	Int.	NL	Rel.Int.
465.30	57365	162	1000
321.16	19462	306	339
285.20	9181	342	160
303.18	5056	324	88
267.17	3750	360	65

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.000	[Flavone]-A(2OH, 2(C-Glu))-B(3OH)	Flavone	6,8-Di-C-glucopyranosyltricetin
0.000	[Flavone]-A(2OH, 1((O-<2,4,5-Trihydroxycinnamoyl>)-C-Glu))-B(2OH)	Flavone	Isoorientin 2''-(2,4,5-dihydroxycinnamante)

Level: 3, プリカーサーm/z: 465.29596

Splash: splash10-00dr-0059000000-87227fe72634514bf737

m/z	Int.	NL	Rel.Int.
321.24	31307	144	1000
285.28	19115	180	610
303.22	7198	162	229
267.23	3005	198	95

Symbolized Name	MSMS-Category	MSMS-Aglycone
[Flavone]-A(2OH, 1(C-Glu))-B(3OH)	Flavone	Isoaffinetin
[Flavone]-A(2OH, 1(C-Glu))-B(3OH)	Flavone	Tricetin 8-C-glucopyranoside
[Flavone]-A(2OH, 1(C-Glu))-B(3OH)	Flavone	6-C-beta-D-Glucopyranosylisoetin
[Flavonol]-A(2OH, 1(C-Glu))-B(2OH)	Flavonol	6-C-Glucosylquercetin
[Flavanone]-A(2OH, 1(C-Glu))-B(1OH, 1OMe)	Flavanone	Dihydroscoparin
[Dihydroflavonol]-A(1OH, 1OMe, 1(C-Glu))-B(1OH)	Dihydroflavonol	Keyakinol
[Flavonol]-A(2OH, 1(C-Glu))-B(2OH)	Flavonol	8-C-Glucosylquercetin
[Isoflavone]-A(2OH, 2(C-Prenyl))-B(1OMe, 1([@@]-Methylenedioxy))	Isoflavone	Euchrenone b4

Level: 3, プリカーサーm/z: 321.18558

Splash: splash10-000i-0093000000-e964a73e6ce3a4bf8384

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.143	[Flavan 3-ol]-A(2OH, 1OMe)-B(2OH)	Flavan 3-ol	3,5,7,3',4'-Pentahydroxy-6-methoxyflavan
0.143	[Flavan 3-ol]-A(2OH)-B(2OH, 1OMe)	Flavan 3-ol	Gallocatechin 4'-methyl ether
0.111	[Dihydroflavonol]-A(2OH)-B(3OH)	Dihydroflavonol	3,5,7,3',4',5'-Hexahydroxyflavanone
0.071	[Flavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(none)	Flavone	5-Hydroxy-6'',6''-dimethylpyrano[2'',3'':7,8]flavone
0.067	[Isoflavone]-A(1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH)	Isoflavone	Erythrinin A
0.067	[Isoflavone]-A(1OH)-B(1([2,3:@@]-(6,6-Dimethylpyrano)))	Isoflavone	Corylin
0.000	[Auronol]-A(2OH)-B(3OH)	Auronol	Amaronol A
0.000	[alpha-Hydroxychalcone]-A(4OH)-B(2OH)	alpha-Hydroxychalcone	3,4,2',3',4',6',alpha-Heptahydroxychalcone
0.000	[Dihydrochalcone beta-ol]-A(2OH)-B(2OH, 1OMe)	Dihydrochalcone beta-ol	Gliricidol
0.000	[3-substituted Flavanone (3-Methyl)]-A(2OH, 1Cl)-B(1OH)	3-substituted Flavanone	8-Chloro-5,7,4'-trihydroxy-3-C-methylflavanone
0.000	[Flavan 3,4-diol]-A(1OH, 1OMe)-B(2OH)	Flavan 3,4-diol	Mesquitol-4alpha-ol 8-methyl ether
0.000	[Flavan 3,4-diol]-A(2OH)-B(1OH, 1OMe)	Flavan 3,4-diol	Catechin-4-ol 3'-methyl ether
0.000	[Flav-3-ene]-A(1OMe, 1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(none)	Flav-3-ene	Hildgardtene
0.000	[Pterocarpene]-A(1OH)-B(1([2,3:@@]-(6,6-Dimethylpyrano)))	Pterocarpene	Anhydrotuberosin
0.000	[Coumestan]-A(1([2,3:@@]-Furano))-B(1([@@]-Methylenedioxy))	Coumestan	Erosnin

ピーク情報

DB検索結果

MSnスペクトル情報

FlavonoidSearch結果

FlavonoidSearch結果

FlavonoidSearch結果

m/z	Int.	NL	Rel.Int.
285.31	10622	36	1000
303.19	4494	18	423
267.27	639	54	60