ピーク情報

細ネギ（若香）地上部

pos

Peak #7708 MN MID: SE201_S11_M90

m/z: 579.31635, RT: 61.87, 強度: 1737, ログ強度: -0.15, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 2

DB検索結果: (5 names) 3alpha-Angeloyloxy-18beta-glucopyranosyloxy-ent-labd-8(17),13-dien-15,16-olide;Oscillatoxin A;Macrolactin P;(-)-Macrolactin P;3beta-O-(d-2-O-methyldigitalosyl)-5beta,14beta-dihydroxy-19-oxo-card-20(22...

DBごとのヒット数: ALL 4 KG 1 KN 2 LM 1

FlavonoidSearch最大スコア MS2: -, MS3: 0.211

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C31H46O10	578.30910	-0.041	3alpha-Angeloyloxy-18beta-glucopyranosyloxy-ent-labd-8(17),13-dien-15,16-olide	KNApSAcK: C00023413
C31H46O10	578.30910	-0.041	Oscillatoxin A	KEGG: C16771 KNApSAcK: C00046842
C31H46O10	578.30910	-0.041	Macrolactin P	KNApSAcK: C00039694 LipidMAPS: LMFA07040106
C31H46O10	578.30910	-0.041	3beta-O-(d-2-O-methyldigitalosyl)-5beta,14beta-dihydroxy-19-oxo-card-20(22)-enolide	LipidMAPS: LMST01120035, LMST01120036

MSnスペクトル情報

Level: 2, プリカーサーm/z: 579.31628

Splash: splash10-0udj-0058900000-7d90cff64ee90e983f26

m/z	Int.	NL	Rel.Int.
301.14	600	278	1000
445.30	335	134	557
283.18	266	296	442
435.26	206	144	342
265.12	80	314	133
313.35	64	266	106
427.36	63	152	105
409.33	43	170	72
561.37	42	18	69
237.14	38	342	63
417.40	34	162	56

Symbolized Name	MSMS-Category	MSMS-Aglycone
[Flavone]-A(2OH, 1(1(O-p-Coumaroyl)-C-Glu))-B(1OH)	Flavone	Vitexin 2''-O-p-coumarate
[Flavone]-A(1OH, 1OMe, 1(C-Glu), 1(C-Arabinosyl))-B(1OH)	Flavone	6-C-Glucopyranosyl-8-C-arabinopyranosylgenkwanin
[Flavone]-A(2OH, 1(C-Glu), 1(C-Rhamnosyl))-B(1OH)	Flavone	Violanthin
[Flavone]-A(2OH, 1(C-Glu), 1(C-Rhamnosyl))-B(1OH)	Flavone	Isoviolanthin
[Flavone]-A(2OH, 1(C-Glu), 1(C-Chinovosyl))-B(1OH)	Flavone	Violarvensin
[Flavone]-A(2OH, 2(C-Rhamnosyl))-B(2OH)	Flavone	6,8-Di-C-rhamnopyranosylluteolin

Level: 3, プリカーサーm/z: 301.13354

Splash: splash10-00lr-0090000000-6b5a138a92a1f5f66359

m/z	Int.	NL	Rel.Int.
283.15	304	18	1000
265.11	161	36	528
213.08	37	88	122
255.22	22	46	72
208.95	18	92	60
237.13	18	64	59

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.211	[Isoflavone]-A(2OH, 1OMe)-B(1OH)	Isoflavone	7,8,4'-Trihydroxy-6-methoxyisoflavone
0.211	[Isoflavone]-A(2OH, 1OMe)-B(1OH)	Isoflavone	Tectorigenin
0.211	[Isoflavone]-A(2OH, 1OMe)-B(1OH)	Isoflavone	Isotectorigenin
0.182	[Dihydroflavonol]-A(2OMe)-B(none)	Dihydroflavonol	5,7-Di-O-methylpinobanksin
0.154	[Isoflavanone]-A(1OH)-B(2OMe)	Isoflavanone	3'-Methoxydihydroformononetin
0.154	[Isoflavanone]-A(1OH)-B(2OMe)	Isoflavanone	Sativanone
0.154	[Isoflavanone]-A(1OMe)-B(1OH, 1OMe)	Isoflavanone	Isosativanone
0.150	[Isoflavone]-A(1OH)-B(2OH, 1OMe)	Isoflavone	Gliricidin
0.150	[Isoflavone]-A(1OH)-B(2OH, 1OMe)	Isoflavone	7,2',4'-Trihydroxy-3'-methoxyisoflavone
0.150	[Isoflavone]-A(1OH)-B(2OH, 1OMe)	Isoflavone	Koparin
0.150	[Isoflavone]-A(1OH, 1OMe)-B(2OH)	Isoflavone	Santal
0.150	[Isoflavone]-A(1OH, 1OMe)-B(2OH)	Isoflavone	Cajanin
0.150	[Isoflavone]-A(2OH)-B(1OH, 1OMe)	Isoflavone	7,8,3'-Trihydroxy-4'-methoxyisoflavone
0.150	[Isoflavone]-A(2OH)-B(1OH, 1OMe)	Isoflavone	3'-O-Methylorobol
0.150	[Isoflavone]-A(2OH)-B(1OH, 1OMe)	Isoflavone	Pratensein
0.150	[Isoflavone]-A(2OH)-B(1OH, 1OMe)	Isoflavone	2'-Hydroxybiochanin A
0.125	[Anthocyanidin]-A(2OH)-B(1OH, 1OMe)	Anthocyanidin	Peonidin
0.125	[Anthocyanidin]-A(1OH, 1OMe)-B(2OH)	Anthocyanidin	5-Methoxycyanidin
0.111	[Flavonol]-A(1OH, 1OMe)-B(1OH)	Flavonol	Datin
0.111	[Flavonol]-A(1OH, 1OMe)-B(1OH)	Flavonol	Kaempferol 5-methyl ether
0.111	[Flavonol]-A(1OH, 1OMe)-B(1OH)	Flavonol	Rhamnocitrin
0.111	[Flavonol]-A(2OH, 1OMe)-B(none)	Flavonol	Alnusin
0.111	[Flavonol]-A(2OH, 1OMe)-B(none)	Flavonol	8-Hydroxygalangin 7-methyl ether
0.111	[Flavonol]-A(2OH, 1OMe)-B(none)	Flavonol	8-Methoxygalangin
0.111	[Flavonol]-A(1OH)-B(1OH, 1OMe)	Flavonol	Geraldol
0.111	[Flavonol]-A(1OH)-B(1OH, 1OMe)	Flavonol	Fisetin 4'-methyl ether
0.111	[Flavonol]-A(2OH)-B(1OMe)	Flavonol	3,6,7-Trihydroxy-4'-methoxyflavone
0.111	[Flavonol]-A(2OH)-B(1OMe)	Flavonol	Ptaeroxylol
0.111	[Flavonol]-A(2OH)-B(1OMe)	Flavonol	Kaempferide
0.071	[2'-Hydroxychalcone]-A(2OH, 2OMe)-B(none)	2'-Hydroxychalcone	Pashanone
0.071	[2'-Hydroxychalcone]-A(2OH, 2OMe)-B(none)	2'-Hydroxychalcone	2',4'-Dihydroxy-3',6'-dimethoxychalcone
0.071	[2'-Hydroxychalcone]-A(2OH, 2OMe)-B(none)	2'-Hydroxychalcone	2',3'-Dihydroxy-4',6'-dimethoxychalcone
0.071	[2'-Hydroxychalcone]-A(2OH)-B(2OMe)	2'-Hydroxychalcone	2',4'-Dihydroxy-3,4-dimethoxychalcone
0.071	[2'-Hydroxychalcone]-A(1OH, 2OMe)-B(1OH)	2'-Hydroxychalcone	Heliannone A
0.071	[2'-Hydroxychalcone]-A(1OH, 2OMe)-B(1OH)	2'-Hydroxychalcone	Flavokawin C
0.071	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OMe)	2'-Hydroxychalcone	Kukulkanin A
0.071	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OMe)	2'-Hydroxychalcone	Gymnogrammene
0.071	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OMe)	2'-Hydroxychalcone	2',4'-Dihydroxy-4,6'-dimethoxychalcone
0.063	[Chalcone]-A(1OH, 2OMe)-B(1OH)	Chalcone	4,4'-Dihydroxy-2',6'-dimethoxychalcone
0.063	[Chalcone]-A(1OMe)-B(2OH, 1OMe)	Chalcone	2,4-Dihydroxy-6,4'-dimethoxychalcone
0.063	[Flavanone]-A(2OMe)-B(1OH)	Flavanone	Naringenin 5,7-dimethyl ether
0.063	[Flavanone]-A(1OH, 2OMe)-B(none)	Flavanone	6-Hydroxy-5,7-dimethoxyflavanone
0.063	[Flavanone]-A(1OH, 2OMe)-B(none)	Flavanone	Onysilin
0.063	[Flavanone]-A(1OH, 2OMe)-B(none)	Flavanone	8-Hydroxy-5,7-dimethoxyflavanone
0.063	[Flavanone]-A(1OH, 2OMe)-B(none)	Flavanone	5-Hydroxy-7,8-dimethoxyflavanone
0.063	[Flavanone]-A(1OH, 1OMe)-B(1OMe)	Flavanone	Tsugafolin
0.063	[Flavanone]-A(1OH, 1OMe)-B(1OMe)	Flavanone	Naringenin 7,4'-dimethyl ether
0.000	[Flavone]-A(1OH, 1OMe)-B(2OH)	Flavone	7,3',4'-Trihydroxy-6-methoxyflavone
0.000	[Flavone]-A(2OH)-B(1OH, 1OMe)	Flavone	5,7,2'-Trihydroxy-6'-methoxyflavone
0.000	[Flavone]-A(1OH, 1OMe)-B(2OH)	Flavone	5,2',6'-Trihydroxy-7-methoxyflavone
0.000	[Flavone]-A(2OH)-B(1OH, 1OMe)	Flavone	Chrysoeriol
0.000	[Flavone]-A(2OH)-B(1OH, 1OMe)	Flavone	Diosmetin
0.000	[Flavone]-A(1OH, 1OMe)-B(2OH)	Flavone	Luteolin 5-methyl ether
0.000	[Flavone]-A(1OH, 1OMe)-B(2OH)	Flavone	Luteolin 7-methyl ether
0.000	[Flavone]-A(1OH, 1OMe)-B(2OH)	Flavone	Artocarpetin
0.000	[Flavone]-A(2OH, 1OMe)-B(1OH)	Flavone	5,7,2'-Trihydroxy-6-methoxyflavone
0.000	[Flavone]-A(3OH)-B(1OMe)	Flavone	Scutellarein 4'-methyl ether
0.000	[Flavone]-A(2OH, 1OMe)-B(1OH)	Flavone	Hispidulin
0.000	[Flavone]-A(2OH, 1OMe)-B(1OH)	Flavone	Sorbifolin
0.000	[Flavone]-A(2OH, 1OMe)-B(1OH)	Flavone	5,8,2'-Trihydroxy-7-methoxyflavone
0.000	[Flavone]-A(2OH, 1OMe)-B(1OH)	Flavone	Scutevulin
0.000	[Flavone]-A(3OH)-B(1OMe)	Flavone	Takakin
0.000	[Flavone]-A(2OH, 1OMe)-B(1OH)	Flavone	Isocutellarein 7-methyl ether
0.000	[Flavone]-A(2OH, 1OMe)-B(1OH)	Flavone	Isoscutellarein 8-methyl ether
0.000	[Coumestan]-A(2OH)-B(2OH)	Coumestan	Demethylwedelolactone
0.000	[Pterocarpan]-A(1OH, 1OMe)-B(1OMe)	Pterocarpan	2-Methoxymedicarpin
0.000	[Pterocarpan]-A(1OH, 1OMe)-B(1OMe)	Pterocarpan	Melilotocarpan A
0.000	[Pterocarpan]-A(1OH, 1OMe)-B(1OMe)	Pterocarpan	4-Methoxymedicarpin
0.000	[Pterocarpan]-A(1OH)-B(2OMe)	Pterocarpan	Methylnissolin
0.000	[Pterocarpan]-A(2OMe)-B(1OH)	Pterocarpan	Sparticarpin
0.000	[Pterocarpan]-A(1OMe)-B(1OH, 1OMe)	Pterocarpan	8-Hydroxy-3,9-dimethoxypterocarpan
0.000	[Pterocarpan]-A(1OMe)-B(1OH, 1OMe)	Pterocarpan	Fruticarpin
0.000	[Aurone]-A(1OH, 1OMe)-B(2OH)	Aurone	Leptosidin
0.000	[Aurone]-A(1OH, 1OMe)-B(2OH)	Aurone	Rengasin
0.000	[Aurone]-A(2OH, 1Methyl)-B(2OH)	Aurone	4,6,3',4'-Tetrahydroxy-5-methylaurone
0.000	[Aurone]-A(2OH, 1Methyl)-B(2OH)	Aurone	4,6,3',4'-Tetrahydroxy-7-methylaurone
0.000	[CCS-type derivative / [alpha,2]-Epoxymethanochalcone]-A(2OH)-B(2OH)	CCS-type derivative / [alpha,2]-Epoxymethanochalcone	Peltochalcone
0.000	[CCS-type derivative / [alpha,2]-Epoxymethanochalcone]-A(2OH)-B(2OH)	CCS-type derivative / [alpha,2]-Epoxymethanochalcone	Mopachalcone
0.000	[UBR-type derivative / [2',5']-Benzoquinonyl-type chalcone]-A(2OH, 1OMe)-B(none)	UBR-type derivative / [2',5']-Benzoquinonyl-type chalcone	Pedicinin
0.000	[UBR-type derivative / 2',5'-Dioxo-3'-cyclopentenyl-type Calcone (alpha-OMe)]-A(2OMe)-B(none)	UBR-type derivative / 2',5'-Dioxo-3'-cyclopentenyl-type Calcone	Methylliderone
0.000	[Dihydrochalcone]-A(1OH, 2OMe, 1Methyl)-B(none)	Dihydrochalcone	2'-Hydroxy-4',6'-dimethoxy-3'-methyldihydrochalcone
0.000	[Dihydrochalcone]-A(2OH, 1OMe, 2Methyl)-B(none)	Dihydrochalcone	Myrigalon B
0.000	[Dihydrochalcone]-A(2OH, 1OMe, 2Methyl)-B(none)	Dihydrochalcone	Angoletin
0.000	[Dihydrochalcone]-A(3OH, 1Formyl, 1Methyl)-B(none)	Dihydrochalcone	3'-Formyl-2',4',6'-trihydroxy-5'-methyldihydrochalcone
0.000	[UBR-type derivative / 2',4',6'-trioxocyclohexanyl-type Dihydrochalcone]-A(3Methyl)-B(none)	UBR-type derivative / 2',4',6'-trioxocyclohexanyl-type Dihydrochalcone	2,2,4-Trimethyl-6-(1-oxo-3-phenylpropyl)-1,3,5-cyclohexanetrione
0.000	[Flavanone]-A(1OH, 1OMe, 1Methyl)-B(1OH)	Flavanone	5,4'-Dihydroxy-7-methoxy-6-methylflavanone
0.000	[Flavanone]-A(2OH, 1Methyl)-B(1OMe)	Flavanone	5,7-Dihydroxy-4'-methoxy-8-methylflavanone
0.000	[Flavanone]-A(1OH, 1OMe, 1Methyl)-B(1OH)	Flavanone	5,4'-Dihydroxy-7-methoxy-8-methylflavanone
0.000	[Flavanone]-A(2OH, 2Methyl)-B(1OH)	Flavanone	Farrerol
0.000	[Flavanone]-A(1OH, 1([@@]-Methylenedioxy))-B(1OH)	Flavanone	5,2'-Dihydroxy-6,7-methylenedioxyflavanone
0.000	[2-Hydroxyflavanone]-A(1OH, 1OMe, 1Methyl)-B(none)	2-Hydroxyflavanone	2,5-Dihydroxy-7-methoxy-6-methylflavanone
0.000	[2-Hydroxyflavanone]-A(1OH, 1OMe, 1Methyl)-B(none)	2-Hydroxyflavanone	2,5-Dihydroxy-7-methoxy-8-methylflavanone
0.000	[3-substituted Flavone (3-Methyl)]-A(2OH)-B(2OH)	3-substituted Flavone	3-C-Methylluteolin
0.000	[Flavone]-A(2OH, 1Methyl)-B(2OH)	Flavone	6-Methylluteolin
0.000	[Dihydroflavonol]-A(1OH, 1([@@]-Methylenedioxy))-B(none)	Dihydroflavonol	3,5-Dihydroxy-6,7-methylenedioxyflavanone
0.000	[CCS-type derivative / [3,2']-Epoxymethanodihydroflavanone]-A(1OH)-B(2OH)	CCS-type derivative / [3,2']-Epoxymethanodihydroflavanone	Peltogynone
0.000	[CCS-type derivative / [3,2']-Epoxymethanodihydroflavanone]-A(1OH)-B(2OH)	CCS-type derivative / [3,2']-Epoxymethanodihydroflavanone	Mopanone
0.000	[Flavonol (3-OMe)]-A(1OH)-B(2OH)	Flavonol	Fisetin 3-methyl ether
0.000	[Flavonol (3-OMe)]-A(2OH)-B(1OH)	Flavonol	6,7,4'-Trihydroxy-3-methoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH)-B(1OH)	Flavonol	7,8,4'-Trihydroxy-3-methoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH)-B(1OH)	Flavonol	Isokaempferide
0.000	[Flavonol]-A(2OH, 1Methyl)-B(1OH)	Flavonol	6-C-Methylkaempferol
0.000	[Flavonol]-A(2OH, 1Methyl)-B(1OH)	Flavonol	8-C-Methylkaempferol
0.000	[Flavonol]-A(3OH, 1Methyl)-B(none)	Flavonol	Isoplatanin
0.000	[Flavonol (3-OMe)]-A(3OH)-B(none)	Flavonol	8-Hydroxygalangin 3-methyl ether
0.000	[Flavonol]-A(3OH, 1Methyl)-B(none)	Flavonol	Platanin
0.000	[Flavan]-A(1OMe)-B(1OH, 1([@@]-Methylenedioxy))	Flavan	2'-Hydroxy-7-methoxy-4',5'-methylenedioxyflavan
0.000	[Flavan]-A(2OMe)-B(1OMe)	Flavan	5,7,4'-Trimethoxyflavan
0.000	[Flavan]-A(2OMe, 1Methyl)-B(1OH)	Flavan	4'-Hydroxy-5,7-dimethoxy-8-methylflavan
0.000	[3-DehydroxyAnthocyanidin]-A(2OH, 1OMe)-B(2OH)	3-DehydroxyAnthocyanidin	5-Methyl-6-hydroxyluteolinidin
0.000	[Isoflavanone]-A(1OH)-B(1OH, 1([@@]-Methylenedioxy))	Isoflavanone	Sophorol
0.000	[Isoflavan]-A(1OH)-B(1OMe, 1([@@]-Methylenedioxy))	Isoflavan	Astraciceran
0.000	[isoflavene]-A(1OH)-B(1OH, 2OMe)	isoflavene	2'-O-Methylsepiol
0.000	[isoflavene]-A(1OH)-B(1OH, 2OMe)	isoflavene	Haginin A
0.000	[isoflavene]-A(1OH)-B(1OH, 2OMe)	isoflavene	Odoriflavene
0.000	[isoflavene]-A(1OH, 1OMe)-B(1OH, 1OMe)	isoflavene	7,2'-Dihydroxy-8,4'-dimethoxyisoflav-3-ene
0.000	[Pterocarpan]-A(2OH)-B(1([@@]-Methylenedioxy))	Pterocarpan	2-Hydroxymaackiain
0.000	[Pterocarpan]-A(2OH)-B(1([@@]-Methylenedioxy))	Pterocarpan	4-Hydroxymaackiain
0.000	[Pterocarpan-6a-ol]-A(1OMe)-B(1OMe)	Pterocarpan-6a-ol	Homopisatin
0.000	[Pterocarpan-6a-ol]-A(1OH)-B(1([@@]-Methylenedioxy))	Pterocarpan-6a-ol	6a-Hydroxymaackiain
0.000	[Pterocarpan-6-ol (6-OMe)]-A(1OH)-B(1OMe)	Pterocarpan-6-ol	Sophoracarpan A
0.000	[2-Phenylbenzofuran]-A(1OH, 1OMe)-B(2OMe)	2-Phenylbenzofuran	Methylsainfuran
0.000	[2-Phenylbenzofuran]-A(1([@@]-Methylenedioxy))-B(2OH, 1OMe)	2-Phenylbenzofuran	Sophorafuran A
0.000	[4-phenylcoumarin]-A(1OH, 1OMe)-B(2OH)	4-phenylcoumarin	5,3',4'-Trihydroxy-7-methoxy-4-phenylcoumarin
0.000	[4-phenylcoumarin]-A(1OH, 1OMe)-B(2OH)	4-phenylcoumarin	7,3',4'-Trihydroxy-5-methoxy-4-phenylcoumarin
0.000	[Dalbergiquinol]-A(3OMe)-B(1OH)	Dalbergiquinol	5-O-Methyllatifolin
0.000	[UBR-type derivative / [2,5]-Benzoquinonyl-type Dalbergiquinol]-A(1OH)-B(2OMe)	UBR-type derivative / [2,5]-Benzoquinonyl-type Dalbergiquinol	4'-Hydroxy-3,4-dimethoxydalbergione
0.000	[UBR-type derivative / [2,5]-Benzoquinonyl-type Dalbergiquinol]-A(1OMe)-B(1OH, 1OMe)	UBR-type derivative / [2,5]-Benzoquinonyl-type Dalbergiquinol	3'-Hydroxy-4,4'-dimethoxydalbergione