ピーク情報

細ネギ（若香）地上部

pos

Peak #4326 MN MID: SE201_S11_M90

m/z: 627.37443, RT: 42.96, 強度: 1946, ログ強度: -0.10, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 2

DB検索結果: (5 names) Ponasteroside A;Cotylenin F;(22R)-2beta,3beta,14,22-tetrahydroxy-6-oxo-5beta-cholest-7-en-25-yl D-glucopyranoside;14-epi-Ponasterone A 22-glucoside;(+)-14-epi-Ponasterone A 22-glucoside

DBごとのヒット数: ALL 4 KG 1 KN 1 LM 2

FlavonoidSearch最大スコア MS2: -, MS3: 0.125

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C33H54O11	626.36661	0.858	Ponasteroside A	HMDB: HMDB0034091 LipidMAPS: LMST01010436
C33H54O11	626.36661	0.858	Cotylenin F	KEGG: C09078 KNApSAcK: C00003418
C33H54O11	626.36661	0.858	(22R)-2beta,3beta,14,22-tetrahydroxy-6-oxo-5beta-cholest-7-en-25-yl D-glucopyranoside	LipidMAPS: LMST01010192
C33H54O11	626.36661	0.858	14-epi-Ponasterone A 22-glucoside	KNApSAcK: C00048252

MSnスペクトル情報

Level: 2, プリカーサーm/z: 627.37372

Splash: splash10-014i-0013900000-123c2de52a46b816352b

m/z	Int.	NL	Rel.Int.
465.31	3138	162	1000
321.15	969	306	308
285.24	465	342	148
303.14	267	324	85
267.23	181	360	57

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.000	[Flavone]-A(2OH, 2(C-Glu))-B(3OH)	Flavone	6,8-Di-C-glucopyranosyltricetin
0.000	[Flavone]-A(2OH, 1((O-<2,4,5-Trihydroxycinnamoyl>)-C-Glu))-B(2OH)	Flavone	Isoorientin 2''-(2,4,5-dihydroxycinnamante)

Level: 3, プリカーサーm/z: 465.32416

Splash: splash10-00dr-0049000000-61406f68279d1394bf84

m/z	Int.	NL	Rel.Int.
321.12	1268	144	1000
285.28	667	180	525
303.21	245	162	192
267.19	135	198	106
315.25	94	150	74

Symbolized Name	MSMS-Category	MSMS-Aglycone
[Flavone]-A(2OH, 1(C-Glu))-B(3OH)	Flavone	Isoaffinetin
[Flavone]-A(2OH, 1(C-Glu))-B(3OH)	Flavone	Tricetin 8-C-glucopyranoside
[Flavone]-A(2OH, 1(C-Glu))-B(3OH)	Flavone	6-C-beta-D-Glucopyranosylisoetin
[Flavonol]-A(2OH, 1(C-Glu))-B(2OH)	Flavonol	6-C-Glucosylquercetin
[Flavanone]-A(2OH, 1(C-Glu))-B(1OH, 1OMe)	Flavanone	Dihydroscoparin
[Dihydroflavonol]-A(1OH, 1OMe, 1(C-Glu))-B(1OH)	Dihydroflavonol	Keyakinol
[Flavonol]-A(2OH, 1(C-Glu))-B(2OH)	Flavonol	8-C-Glucosylquercetin
[Isoflavone]-A(2OH, 2(C-Prenyl))-B(1OMe, 1([@@]-Methylenedioxy))	Isoflavone	Euchrenone b4

Level: 3, プリカーサーm/z: 321.15637

Splash: splash10-000i-0093000000-477ad09ddac87ef5695c

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.125	[Flavan 3-ol]-A(2OH, 1OMe)-B(2OH)	Flavan 3-ol	3,5,7,3',4'-Pentahydroxy-6-methoxyflavan
0.125	[Flavan 3-ol]-A(2OH)-B(2OH, 1OMe)	Flavan 3-ol	Gallocatechin 4'-methyl ether
0.100	[Dihydroflavonol]-A(2OH)-B(3OH)	Dihydroflavonol	3,5,7,3',4',5'-Hexahydroxyflavanone
0.067	[Flavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(none)	Flavone	5-Hydroxy-6'',6''-dimethylpyrano[2'',3'':7,8]flavone
0.063	[Isoflavone]-A(1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH)	Isoflavone	Erythrinin A
0.063	[Isoflavone]-A(1OH)-B(1([2,3:@@]-(6,6-Dimethylpyrano)))	Isoflavone	Corylin
0.000	[Auronol]-A(2OH)-B(3OH)	Auronol	Amaronol A
0.000	[alpha-Hydroxychalcone]-A(4OH)-B(2OH)	alpha-Hydroxychalcone	3,4,2',3',4',6',alpha-Heptahydroxychalcone
0.000	[Dihydrochalcone beta-ol]-A(2OH)-B(2OH, 1OMe)	Dihydrochalcone beta-ol	Gliricidol
0.000	[3-substituted Flavanone (3-Methyl)]-A(2OH, 1Cl)-B(1OH)	3-substituted Flavanone	8-Chloro-5,7,4'-trihydroxy-3-C-methylflavanone
0.000	[Flavan 3,4-diol]-A(1OH, 1OMe)-B(2OH)	Flavan 3,4-diol	Mesquitol-4alpha-ol 8-methyl ether
0.000	[Flavan 3,4-diol]-A(2OH)-B(1OH, 1OMe)	Flavan 3,4-diol	Catechin-4-ol 3'-methyl ether
0.000	[Flav-3-ene]-A(1OMe, 1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(none)	Flav-3-ene	Hildgardtene
0.000	[Pterocarpene]-A(1OH)-B(1([2,3:@@]-(6,6-Dimethylpyrano)))	Pterocarpene	Anhydrotuberosin
0.000	[Coumestan]-A(1([2,3:@@]-Furano))-B(1([@@]-Methylenedioxy))	Coumestan	Erosnin

ピーク情報

DB検索結果

MSnスペクトル情報

FlavonoidSearch結果

FlavonoidSearch結果

FlavonoidSearch結果

m/z	Int.	NL	Rel.Int.
285.17	451	36	1000
303.18	194	18	430
267.21	59	54	131
239.35	23	82	50