ピーク情報
|
イネ 葉 ニッポンバレ
pos
|
| Peak #4017 MN MID: SE199_S41_M90 |
| m/z: 655.18805, RT: 47.43, 強度: 31204, ログ強度: 0.90, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 4 |
| DB検索結果: (24 names) Syringetin 3-rutinoside;Malvin;5,7,4'-Trihydroxy-6,3'-dimethoxyisoflavone 7-O-(6''-glucosylglucoside);Rhamnazin 3-galactoside-4'-glucoside;Iristectorigenin A 7-O-gentiobioside;Rhamnazin 3-sophoroside;... |
| DBごとのヒット数: ALL 20 KG 1 KN 16 HM 3 |
| FlavonoidSearch最大スコア MS2: -, MS3: 0.600 |
DB検索結果
ppm
| 組成式 | 分子量 | 誤差(Δppm） | 候補化合物名（代表で最短名を記載） | 化合物ID |
|---|---|---|---|---|
| C29H34O17 | 654.17960 | 1.793 | 5,7,4'-Trihydroxy-6,3'-dimethoxyisoflavone 7-O-(6''-glucosylglucoside) | KNApSAcK: C00019131 |
| C29H34O17 | 654.17960 | 1.793 | Rhamnazin 3-sophoroside | HMDB: HMDB0038235 |
| C29H34O17 | 654.17960 | 1.793 | Clemochinenoside B | KNApSAcK: C00038808 |
| C29H34O17 | 654.17960 | 1.793 | Monoxerutin | HMDB: HMDB0254873 |
| C29H34O17 | 654.17960 | 1.793 | Spinacetin 3-rutinoside | HMDB: HMDB0037470 |
| C29H34O17 | 654.17960 | 1.793 | Syringetin 3-rutinoside | FlavonoidViewer: FL5FAIGL0002, FL5FAIGS0005 KNApSAcK: C00005780, C00013985 LipidMAPS: LMPK12112489, LMPK12112497 |
| C29H34O17 | 654.17960 | 1.793 | Malvin | FlavonoidViewer: [1]FL7AAIGO0001 HMDB: [1]HMDB0038009, [1f]HMDB0302848 KEGG: [1]C08718 KNApSAcK: [1]C00002384, [1]C00051451 |
| C29H34O17 | 654.17960 | 1.793 | Rhamnazin 3-galactoside-4'-glucoside | FlavonoidViewer: FL5FCDGA0002 KNApSAcK: C00005610 LipidMAPS: LMPK12112630 |
| C29H34O17 | 654.17960 | 1.793 | Iristectorigenin A 7-O-gentiobioside | FlavonoidViewer: FLIAECGS0005 KNApSAcK: C00010148 LipidMAPS: LMPK12050397 |
| C29H34O17 | 654.17960 | 1.793 | Tricin 5,7-diglucoside | FlavonoidViewer: FL3FAIGS0009 KNApSAcK: C00004467 LipidMAPS: LMPK12110867 |
| C29H34O17 | 654.17960 | 1.793 | 6,8-Di-C-glucopyranosyltricin | FlavonoidViewer: FL3FAICS0005 KNApSAcK: C00006295 LipidMAPS: LMPK12110857 |
| C29H34O17 | 654.17960 | 1.793 | Limocitrin 7-neohesperidoside | FlavonoidViewer: FL5FFCGS0018 KNApSAcK: C00005721 LipidMAPS: LMPK12113211 |
| C29H34O17 | 654.17960 | 1.793 | Malvidin 3-laminaribioside | FlavonoidViewer: [1]FL7AAIGL0003 HMDB: [1]HMDB0038033 KNApSAcK: [1]C00006738 LipidMAPS: [1]LMPK12010374 |
| C29H34O17 | 654.17960 | 1.793 | Limocitrin 3-rutinoside | FlavonoidViewer: FL5FFCGL0012 HMDB: HMDB0037579 KNApSAcK: C00005719 LipidMAPS: LMPK12113191 |
| C29H34O17 | 654.17960 | 1.793 | Malvidin 3-diglucoside | FlavonoidViewer: [1]FL7AAIGL0002 KNApSAcK: [1]C00006737 LipidMAPS: [1]LMPK12010373 |
| C29H34O17 | 654.17960 | 1.793 | Dillenetin 3,7-diglucoside | FlavonoidViewer: FL5FAFGL0003 KNApSAcK: C00005621 LipidMAPS: LMPK12110610 |
| C29H34O17 | 654.17960 | 1.793 | Isopyrenin 7-O-glucoside | FlavonoidViewer: FL3FAIDS0001 KNApSAcK: C00006297 LipidMAPS: LMPK12110858 |
| C29H34O17 | 654.17960 | 1.793 | Malvidin 3-gentiobiside | FlavonoidViewer: [1]FL7AAIGL0004 KNApSAcK: [1]C00006739 LipidMAPS: [1]LMPK12010375 |
| C29H34O17 | 654.17960 | 1.793 | Malvidin 3,7-diglucoside | FlavonoidViewer: [1]FL7AAIGL0006 KNApSAcK: [1]C00006742 LipidMAPS: [1]LMPK12010377 |
| C29H34O17 | 654.17960 | 1.793 | 6-Hydroxytricetin 6,3',5'-trimethyl eter 7-alpha-L-arabinosyl-(1->6)-glucoside | FlavonoidViewer: FL3FEGGS0003 KNApSAcK: C00013723 LipidMAPS: LMPK12111262 |
MSnスペクトル情報
| Level: 2, プリカーサーm/z: 655.18774 |
| Splash: splash10-001i-0009000000-fe294400510753b96697 |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 331.15 | 26721 | 324 | 1000 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.000 | [Flavone]-A(2OH, 2(C-Glu))-B(1OH, 2OMe) | Flavone | 6,8-Di-C-glucopyranosyltricin |
| Level: 3, プリカーサーm/z: 331.13287 |
| Splash: splash10-014i-0019000000-af610328203b0461ca9b |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 315.10 | 2077 | 16 | 1000 |
| 316.13 | 1343 | 15 | 646 |
| 270.13 | 506 | 61 | 243 |
| 331.21 | 161 | -0 | 77 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.600 | [Flavone]-A(2OH)-B(1OH, 2OMe) | Flavone | 6,7,4'-Trihydroxy-3',5'-dimethoxyflavone |
| 0.600 | [Flavone]-A(1OH, 1OMe)-B(2OH, 1OMe) | Flavone | 5,4',5'-Trihydroxy-6,2'-dimethoxyflavone |
| 0.600 | [Flavone]-A(2OH)-B(1OH, 2OMe) | Flavone | Apometzgerin |
| 0.600 | [Flavone]-A(2OH)-B(1OH, 2OMe) | Flavone | Tricin |
| 0.600 | [Flavone]-A(2OMe)-B(3OH) | Flavone | Isoetin 5,7-dimethyl ether |
| 0.600 | [Flavone]-A(1OH, 2OMe)-B(2OH) | Flavone | 5,2',6'-Trihydroxy-6,7-dimethoxyflavone |
| 0.600 | [Flavone]-A(1OH, 2OMe)-B(2OH) | Flavone | 6-Hydroxyluteolin 5,6-dimethyl ether |
| 0.600 | [Flavone]-A(2OH, 1OMe)-B(1OH, 1OMe) | Flavone | Jaceosidin |
| 0.600 | [Flavone]-A(2OH, 1OMe)-B(1OH, 1OMe) | Flavone | Desmethoxycentaureidin |
| 0.600 | [Flavone]-A(1OH, 2OMe)-B(2OH) | Flavone | Cirsiliol |
| 0.600 | [Flavone]-A(2OH, 1OMe)-B(1OH, 1OMe) | Flavone | 6-Hydroxyluteolin 7,3'-dimethyl ether |
| 0.600 | [Flavone]-A(2OH, 1OMe)-B(1OH, 1OMe) | Flavone | Nuchensin |
| 0.600 | [Flavone]-A(2OH, 1OMe)-B(1OH, 1OMe) | Flavone | Tamaridone |
| 0.600 | [Flavone]-A(1OH, 2OMe)-B(2OH) | Flavone | 5,2',3'-Trihydroxy-7,8-dimethoxyflavone |
| 0.600 | [Flavone]-A(1OH, 2OMe)-B(2OH) | Flavone | Rehderianin I |
| 0.600 | [Flavone]-A(1OH, 2OMe)-B(2OH) | Flavone | Viscidulin II |
| 0.600 | [Flavone]-A(2OH, 1OMe)-B(1OH, 1OMe) | Flavone | 5,7,2'-Trihydroxy-8,6'-dimethoxyflavone |
| 0.600 | [Flavone]-A(2OH, 1OMe)-B(1OH, 1OMe) | Flavone | Hypolaetin 7,3'-dimethyl ether |
| 0.600 | [Flavone]-A(2OH, 1OMe)-B(1OH, 1OMe) | Flavone | Hypolaetin 8,3'-dimethyl ether |
| 0.600 | [Flavone]-A(2OH, 2OMe)-B(1OH) | Flavone | 5,8,2'-Trihydroxy-6,7-dimethoxyflavone |
| 0.600 | [Flavone]-A(2OH, 2OMe)-B(1OH) | Flavone | 5,7,2'-trihydroxy-6,8-dimethoxyflavone |
| 0.600 | [Flavone]-A(2OH, 2OMe)-B(1OH) | Flavone | Isothymusin |
| 0.600 | [Flavone]-A(2OH, 2OMe)-B(1OH) | Flavone | Desmethoxysudachitin |
| 0.600 | [Flavone]-A(3OH, 1OMe)-B(1OMe) | Flavone | 5,6,8-Trihydroxy-7,4'-dimethoxyflavone |
| 0.600 | [Flavone]-A(2OH, 2OMe)-B(1OH) | Flavone | Thymusin |
| 0.600 | [Flavone]-A(3OH, 1OMe)-B(1OMe) | Flavone | 5,6,7-Trihydroxy-8,4'-dimethoxyflavone |
| 0.200 | [Anthocyanidin]-A(1OH, 1OMe)-B(2OH, 1OMe) | Anthocyanidin | Europinidin |
| 0.200 | [Anthocyanidin]-A(2OH)-B(1OH, 2OMe) | Anthocyanidin | Malvidin |
| 0.150 | [Isoflavone]-A(2OH, 1OMe)-B(1OH, 1OMe) | Isoflavone | Podospicatin |
| 0.150 | [Isoflavone]-A(2OH, 1OMe)-B(1OH, 1OMe) | Isoflavone | Iristectorigenin B |
| 0.150 | [Isoflavone]-A(2OH, 1OMe)-B(1OH, 1OMe) | Isoflavone | Iristectorigenin A |
| 0.150 | [Isoflavone]-A(2OH, 1OMe)-B(1OH, 1OMe) | Isoflavone | 5,7,4'-Trihydroxy-8,3'-dimethoxyisoflavone |
| 0.150 | [Isoflavone]-A(2OH, 1OMe)-B(1OH, 1OMe) | Isoflavone | 5,7,3'-Trihydroxy-8,4'-dimethoxyisoflavone |
| 0.150 | [Isoflavone]-A(1OH, 2OMe)-B(2OH) | Isoflavone | 6-Methoxyorobol 7-methyl ether |
| 0.150 | [Isoflavone]-A(2OH)-B(1OH, 2OMe) | Isoflavone | 2'-Hydroxy-5'-methoxybiochanin A |
| 0.118 | [Flavonol]-A(2OH, 2OMe)-B(none) | Flavonol | 3,5,7-Trihydroxy-6,8-dimethoxyflavone |
| 0.118 | [Flavonol]-A(2OH, 1OMe)-B(1OMe) | Flavonol | Betuletol |
| 0.118 | [Flavonol]-A(2OH, 1OMe)-B(1OMe) | Flavonol | 3,5,6-Trihydroxy-7,4'-dimethoxyflavone |
| 0.118 | [Flavonol]-A(2OH, 1OMe)-B(1OMe) | Flavonol | Herbacetin 7,4'-dimethyl ether |
| 0.118 | [Flavonol]-A(2OH, 1OMe)-B(1OMe) | Flavonol | Prudomestin |
| 0.118 | [Flavonol]-A(1OH, 2OMe)-B(1OH) | Flavonol | 6-Hydroxykaempferol 5,6-dimethyl ether |
| 0.118 | [Flavonol]-A(1OH, 2OMe)-B(1OH) | Flavonol | Herbacetin 7,8-dimethyl ether |
| 0.118 | [Flavonol]-A(1OH)-B(1OH, 2OMe) | Flavonol | Laurentinol |
| 0.118 | [Flavonol]-A(1OH, 1OMe)-B(1OH, 1OMe) | Flavonol | 3,5,2'-Trihydroxy-7,5'-dimethoxyflavone |
| 0.118 | [Flavonol]-A(1OH, 1OMe)-B(1OH, 1OMe) | Flavonol | Quercetin 5,3'-dimethyl ether |
| 0.118 | [Flavonol]-A(1OH, 1OMe)-B(1OH, 1OMe) | Flavonol | Quercetin 5,4'-dimethyl ether |
| 0.118 | [Flavonol]-A(1OH, 1OMe)-B(1OH, 1OMe) | Flavonol | Rhamnazin |
| 0.118 | [Flavonol]-A(1OH, 1OMe)-B(1OH, 1OMe) | Flavonol | Ombuin |
| 0.118 | [Flavonol]-A(2OH)-B(2OMe) | Flavonol | Morelosin |
| 0.118 | [Flavonol]-A(2OH)-B(2OMe) | Flavonol | Dillenetin |
| 0.091 | [2'-Hydroxychalcone]-A(1OH, 3OMe)-B(1OH) | 2'-Hydroxychalcone | 4,6'-Dihydroxy-2',3',4'-trimethoxychalcone |
| 0.091 | [2'-Hydroxychalcone]-A(1OH, 3OMe)-B(1OH) | 2'-Hydroxychalcone | 4,2'-Dihydroxy-3',4',6'-trimethoxychalcone |
| 0.091 | [2'-Hydroxychalcone]-A(2OH, 2OMe)-B(1OMe) | 2'-Hydroxychalcone | 2',4'-Dihydroxy-2,3',6'-trimethoxychalcone |
| 0.091 | [2'-Hydroxychalcone]-A(2OH, 1OMe)-B(2OMe) | 2'-Hydroxychalcone | Okanin 3,4,3'-trimethyl ether |
| 0.091 | [2'-Hydroxychalcone]-A(2OH, 1OMe)-B(2OMe) | 2'-Hydroxychalcone | Cerasin |
| 0.091 | [2'-Hydroxychalcone]-A(1OH, 2OMe)-B(1OH, 1OMe) | 2'-Hydroxychalcone | 4,2'-Dihydroxy-3,4',6'-trimethoxychalcone |
| 0.091 | [2'-Hydroxychalcone]-A(1OH, 2OMe)-B(1OH, 1OMe) | 2'-Hydroxychalcone | 3,2'-Dihydroxy-4,4',6'-trimethoxychalcone |
| 0.091 | [2'-Hydroxychalcone]-A(2OH, 3OMe)-B(none) | 2'-Hydroxychalcone | Pedicin |
| 0.077 | [Chalcone]-A(1OH, 4OMe)-B(none) | Chalcone | Isodidymocarpin |
| 0.077 | [Flavanone]-A(1OH, 3OMe)-B(none) | Flavanone | Isopedicin |
| 0.077 | [Flavanone]-A(1OH, 3OMe)-B(none) | Flavanone | 5-Hydroxy-6,7,8-trimethoxyflavanone |
| 0.077 | [Flavanone]-A(1OH, 3OMe)-B(none) | Flavanone | Kwangsienin A |
| 0.077 | [Flavanone]-A(2OMe)-B(1OH, 1OMe) | Flavanone | 4'-Hydroxy-5,7,2'-trimethoxyflavanone |
| 0.077 | [Flavanone]-A(3OMe)-B(1OH) | Flavanone | 4'-Hydroxy-5,6,7-trimethoxyflavanone |
| 0.077 | [Flavanone]-A(1OH, 2OMe)-B(1OMe) | Flavanone | 5-Hydroxy-6,7,4'-trimethoxyflavanone |
| 0.077 | [Flavanone]-A(1OH, 2OMe)-B(1OMe) | Flavanone | 7-Hydroxy-5,8,2'-trimethoxyflavanone |
| 0.077 | [Flavanone]-A(1OH, 2OMe)-B(1OMe) | Flavanone | 5-Hydroxy-7,8,4'-trimethoxyflavanone |
| 0.077 | [Flavanone]-A(1OH, 1OMe)-B(2OMe) | Flavanone | 5-Hydroxy-7,2',3'-trimethoxyflavanone |
| 0.077 | [Flavanone]-A(1OH, 1OMe)-B(2OMe) | Flavanone | Eriodictyol 7,3',4'-trimethyl ether |
| 0.077 | [Flavanone]-A(1OH, 1OMe)-B(2OMe) | Flavanone | Cerasinone |
| 0.000 | [Dihydroflavonol (3-OMe)]-A(1OH, 1OMe)-B(1OMe) | Dihydroflavonol | 7-Hydroxy-3,5,4'-trimethoxyflavanone |
| 0.000 | [Dihydroflavonol]-A(2OMe)-B(1OMe) | Dihydroflavonol | 3-Hydroxy-5,7,4'-trimethoxyflavanone |
| 0.000 | [Pterocarpan]-A(1OH, 2OMe)-B(1OMe) | Pterocarpan | 4-Hydroxy-2,3,9-trimethoxypterocarpan |
| 0.000 | [Pterocarpan]-A(1OH, 1OMe)-B(2OMe) | Pterocarpan | Melilotocarpan C |
| 0.000 | [Pterocarpan]-A(1OH)-B(3OMe) | Pterocarpan | 9-O-Methylphilenopteran |
| 0.000 | [Pterocarpan]-A(2OMe)-B(1OH, 1OMe) | Pterocarpan | Odoricarpan |
| 0.000 | [Isoflavanone]-A(1OH)-B(3OMe) | Isoflavanone | 3'-O-Methylviolanone |
| 0.000 | [Isoflavanone]-A(1OMe)-B(1OH, 2OMe) | Isoflavanone | 3'-Methoxyisosativanone |
| 0.000 | [Dihydrochalcone beta-ol]-A(2OMe, 1([@@]-Methylenedioxy))-B(none) | Dihydrochalcone beta-ol | beta-Hydroxy-2',6'-dimethoxy-3',4'-methylenedioxydihydrochalcone |
| 0.000 | [Flavanone]-A(2OH, 2Methyl)-B(1OH, 1OMe) | Flavanone | 5,7,4'-Trihydroxy-3'-methoxy-6,8-di-C-methylflavanone |
| 0.000 | [Flavanone]-A(2OH, 2Methyl)-B(1OH, 1OMe) | Flavanone | 2'-Hydroxymatteucinol |
| 0.000 | [UBR-type derivative / [2',5']-Benzoquinonyl-type Flavanone]-A(1OH, 1OMe)-B(1OMe) | UBR-type derivative / [2',5']-Benzoquinonyl-type Flavanone | Remerin |
| 0.000 | [Dihydroflavonol]-A(2OH)-B(1OH)-C(1(O-Acetyl)) | Dihydroflavonol | Aromadendrin 3-O-acetate |
| 0.000 | [CCS-type derivative / [3,2']-Epoxymethanodihydroflavanone]-A(1OH, 1OMe)-B(2OH) | CCS-type derivative / [3,2']-Epoxymethanodihydroflavanone | 5-Methoxypeltogynone |
| 0.000 | [CCS-type derivative / [3,2']-Epoxymethanodihydroflavanone]-A(1OH, 1OMe)-B(2OH) | CCS-type derivative / [3,2']-Epoxymethanodihydroflavanone | 5-Methoxymopanone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 1OMe)-B(2OH) | Flavonol | 7,3',4'-Trihydroxy-3,8-dimethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(2OH)-B(1OH, 1OMe) | Flavonol | 7,8,4'-Trihydroxy-3,3'-dimethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(2OH)-B(1OH, 1OMe) | Flavonol | Quercetin 3,3'-dimethyl ether |
| 0.000 | [Flavonol (3-OMe)]-A(2OH)-B(1OH, 1OMe) | Flavonol | Quercetin 3,4'-dimethyl ether |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 1OMe)-B(2OH) | Flavonol | Caryatin |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 1OMe)-B(2OH) | Flavonol | Quercetin 3,7-dimethyl ether |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1Methyl)-B(2OH) | Flavonol | 6-C-Methylquercetin 3-methyl ether |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1Methyl)-B(2OH) | Flavonol | 8-C-Methylquercetin 3-methyl ether |
| 0.000 | [Flavonol (3-OMe)]-A(3OH)-B(1OMe) | Flavonol | 6-Hydroxykaempferol 3,4'-dimethyl ether |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1OMe)-B(1OH) | Flavonol | 6-Methoxykaempferol 3-methyl ether |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1OMe)-B(1OH) | Flavonol | 6-Hydroxykaempferol 3,7-dimethyl ether |
| 0.000 | [Flavonol (3-OMe)]-A(3OH)-B(1OMe) | Flavonol | 5,7,8-Trihydroxy-3,4'-dimethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1OMe)-B(1OH) | Flavonol | 3,7-Dimethylherbacetin |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1OMe)-B(1OH) | Flavonol | Herbacetin 3,8-dimethyl ether |
| 0.000 | [Flavonol (3-OMe)]-A(3OH, 1OMe)-B(none) | Flavonol | 5,7,8-Trihydroxy-3,6-dimethoxyflavone |
| 0.000 | [Flavan 3-ol]-A(2OMe)-B(1([@@]-Methylenedioxy)) | Flavan 3-ol | 3',4'-Methylenedioxy catechin 5,7-dimethyl ether |
| 0.000 | [CCS-type derivative / [2,3,4:5,4a,4]-(6-oxodihydropyrano)-Flavan 3-ol]-A(1OH)-B(2OH) | CCS-type derivative / [2,3,4:5,4a,4]-(6-oxodihydropyrano)-Flavan 3-ol | Dryopterin |
| 0.000 | [CCS-type derivative / [3,2']-Epoxydimethylmethanoflavan]-A(2OH)-B(2OH) | CCS-type derivative / [3,2']-Epoxydimethylmethanoflavan | 8-Hydroxy-5,5-dimethylpeltogynan |
| 0.000 | [Flavan 4-ol (4-OMe)]-A(2OH, 2Methyl)-B(1OMe) | Flavan 4-ol | 5,7-Dihydroxy-4,4'-dimethoxy-6,8-dimethylflavan |
| 0.000 | [Pterocarpan]-A(2OH, 1OMe)-B(1([@@]-Methylenedioxy)) | Pterocarpan | Trifolian |
| 0.000 | [Pterocarpan-6a-ol]-A(1OH, 1OMe)-B(1([@@]-Methylenedioxy)) | Pterocarpan-6a-ol | Hildecarpin |
| 0.000 | [Pterocarpan-6a-ol]-A(1OH, 1OMe)-B(1([@@]-Methylenedioxy)) | Pterocarpan-6a-ol | Tephrocarpin |
| 0.000 | [12a-Hydroxyrotenone]-A(1OH, 1OMe)-B(1OH) | 12a-Hydroxyrotenone | 4,11,12a-Trihydroxy-9-methoxyrotenone |
| 0.000 | [4-phenylcoumarin]-A(1OH, 2OMe)-B(2OH) | 4-phenylcoumarin | 8,3',4'-Trihydroxy-5,7-dimethoxy-4-phenylcoumarin |