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Peak #3970 MN MID: SE199_S41_M90

m/z: 495.13236, RT: 47.21, 強度: 337630, ログ強度: 1.94, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 2

DB検索結果: (8 names) 16-Oxonapyradiomycin A2;18-Oxonapyradiomycin A1;4'-O-Galloylsucrose;6-O-Galloylsucrose;1-Galloyl-beta-D-glucopyranosyl-(1-4)-beta-D-galactopyranoside;6'-O-Galloylsucrose;2-O-Galloylsucrose;1'-O-Galloy...

DBごとのヒット数: ALL 8 KN 3 HM 5

FlavonoidSearch最大スコア MS2: -, MS3: 0.100

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C25H28O6Cl2	494.12629	-2.447	16-Oxonapyradiomycin A2	KNApSAcK: C00038173
C25H28O6Cl2	494.12629	-2.447	18-Oxonapyradiomycin A1	KNApSAcK: C00038180
C19H26O15	494.12717	-4.218	4'-O-Galloylsucrose	HMDB: HMDB0039284
C19H26O15	494.12717	-4.218	6-O-Galloylsucrose	HMDB: HMDB0039282
C19H26O15	494.12717	-4.218	6'-O-Galloylsucrose	HMDB: HMDB0039285
C19H26O15	494.12717	-4.218	1-Galloyl-beta-D-glucopyranosyl-(1-4)-beta-D-galactopyranoside	KNApSAcK: C00050511
C19H26O15	494.12717	-4.218	2-O-Galloylsucrose	HMDB: HMDB0039281
C19H26O15	494.12717	-4.218	1'-O-Galloylsucrose	HMDB: HMDB0039283

MSnスペクトル情報

Level: 2, プリカーサーm/z: 495.13187

Splash: splash10-0ab9-0089000000-ea8d12a1c2dbd793f20a

m/z	Int.	NL	Rel.Int.
355.18	35699	140	1000
271.08	20792	224	582
219.07	14429	276	404
372.89	7329	122	205
231.12	3143	264	88

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.000	[Dihydrochalcone]-A(3OH, 1Geranyl)-B(2OH, 1(C-Prenyl))	Dihydrochalcone	2',4',6',3,4-Pentahydroxy-3'-geranyl-5-prenyldihydrochalcone

Level: 3, プリカーサーm/z: 355.19836

Splash: splash10-01q0-0349000000-32fb906edaf4ef61b803

m/z	Int.	NL	Rel.Int.
311.20	2717	44	1000
230.99	1523	124	560
337.13	1364	18	501
136.96	780	218	286
187.08	581	168	213
279.17	371	76	136

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.100	[Flavone]-A(2OH, 1(C-Prenyl))-B(2OH)	Flavone	8-C-Prenylluteolin
0.100	[Flavone]-A(2OH, 1(C-Prenyl))-B(2OH)	Flavone	6-C-Prenylluteolin
0.100	[Flavone]-A(2OH, 1(C-Prenyl))-B(2OH)	Flavone	Artocarpesin
0.100	[Chalcone]-A(2OH)-B(1OH, 1OMe, 1(C-Prenyl))	Chalcone	Licoagrochalcone C
0.095	[Isoflavone]-A(2OH, 1(C-Prenyl))-B(2OH)	Isoflavone	5,7,3',4'-Tetrahydroxy-6-prenylisoflavone
0.095	[Isoflavone]-A(2OH, 1(C-Prenyl))-B(2OH)	Isoflavone	Gancaonin L
0.095	[Isoflavone]-A(2OH, 1(C-Prenyl))-B(2OH)	Isoflavone	Luteone (isoflavone)
0.095	[Isoflavone]-A(2OH, 1(C-Prenyl))-B(2OH)	Isoflavone	2,3-Dehydrokievitone
0.095	[Isoflavone]-A(2OH)-B(2OH, 1(C-Prenyl))	Isoflavone	Licoisoflavone A
0.077	[Dihydroflavonol]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH)	Dihydroflavonol	3,5,4'-Trihydroxy-6'',6''-dimethylpyrano[2'',3'':7,8]flavanone
0.074	[Flavonol]-A(2OH)-B(1OH, 1(C-Prenyl))	Flavonol	Isolicoflavonol
0.067	[Flavanone]-A(2OH)-B(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))	Flavanone	Sigmoidin C
0.067	[Flavanone]-A(2OH)-B(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))	Flavanone	Sanggenon F
0.067	[Flavanone]-A(2OH)-B(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))	Flavanone	Sanggenon H
0.067	[Isoflavanone]-A(2OH)-B(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))	Isoflavanone	Licoisoflavanone
0.067	[Isoflavanone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OH)	Isoflavanone	Cyclokievitone
0.059	[Dihydroflavonol]-A(1OH, 1OMe, 1(C-Prenyl))-B(none)	Dihydroflavonol	Leaserone
0.053	[2'-Hydroxychalcone]-A(2OH, 1OMe, 1(C-Prenyl))-B(1OH)	2'-Hydroxychalcone	Xanthohumol
0.053	[2'-Hydroxychalcone]-A(2OH, 1OMe, 1(C-Prenyl))-B(1OH)	2'-Hydroxychalcone	Xanthogalenol
0.050	[Flavanone]-A(2OH, 1OMe, 1(C-Prenyl))-B(none)	Flavanone	Agrandol
0.050	[Flavanone]-A(2OH, 1OMe, 1(C-Prenyl))-B(none)	Flavanone	Microfolione
0.050	[Flavanone]-A(2OH, 1(C-Prenyl))-B(1OMe)	Flavanone	5,7-Dihydroxy-4'-methoxy-8-C-prenylflavanone
0.050	[Flavanone]-A(1OH, 1OMe, 1(C-Prenyl))-B(1OH)	Flavanone	5,4'-Dihydroxy-7-methoxy-6-C-prenylflavanone
0.050	[Flavanone]-A(1OH, 1OMe, 1(C-Prenyl))-B(1OH)	Flavanone	Isoxanthohumol(Sophora)
0.050	[Flavanone]-A(1OH, 1OMe, 1(C-Prenyl))-B(1OH)	Flavanone	Mundulea flavanone B
0.048	[Chalcone]-A(1OH, 1(C-Prenyl))-B(2OH, 1OMe)	Chalcone	Licochalcone D
0.037	[Flavonol]-A(3OH, 1(C-Prenyl))-B(none)	Flavonol	Platanetin
0.036	[Flavonol]-A(2OH, 1(C-Prenyl))-B(1OH)	Flavonol	6-Prenylkaempferol
0.036	[Flavonol]-A(2OH, 1(C-Prenyl))-B(1OH)	Flavonol	Noranhydroicaritin
0.000	[Pterocarpan]-A(1OH, 1OMe)-B(1OH, 1(C-Prenyl))	Pterocarpan	1-Methoxyphaseollidin
0.000	[Pterocarpan]-A(1OH, 1OMe, 1(C-Prenyl))-B(1OH)	Pterocarpan	Edudiol
0.000	[2-Benzyl-2-hydroxydihydrobenzofuran (2,3-OMe)]-A(1([2,3:@@]-Furano))-B(1([@@]-Methylenedioxy))	2-Benzyl-2-hydroxydihydrobenzofuran	Castillene C
0.000	[Chalcone]-A(1OH)-B(1OMe, 1([2,3:@@]-(5-(hydroxyisopropanyl)dihydrofurano)))	Chalcone	Licoagrochalcone D
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1(2-hydroxy-3-methyl-3-butenyl))-B(1OH)	2'-Hydroxychalcone	Xanthoangelol D
0.000	[2'-Hydroxychalcone]-A(1OMe, 1([2,3:@@]-(6,6-Dimethyl-5-hydroxydihydropyrano)))-B(1OH)	2'-Hydroxychalcone	Xanthoangelol H
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(6,6-Dimethyl-5-hydroxydihydropyrano)))-B(none)	2'-Hydroxychalcone	Helichromanochalcone
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(6,6-Dimethyl-5-hydroxydihydropyrano)))-B(none)	2'-Hydroxychalcone	2'-Methoxyhelikrausichalcone
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(6,6-Dimethyl-5-hydroxydihydropyrano)))-B(none)	2'-Hydroxychalcone	6'',6''-Dimethyl-5''-hydroxy-4'',5''-dihydropyrano[2'',3'':2',3']-4'-hydroxy-6'-methoxychalcone
0.000	[2'-Hydroxychalcone]-A(2OH, 1([2,3:@@]-(6-Methyl-4,7-dihydrooxepino)))-B(2OH)	2'-Hydroxychalcone	3',4'-Dihydrooxepino-6'-hydroxybutein
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(6,6-Dimethyldihydropyrano)))-B(1OH)	2'-Hydroxychalcone	Isodehydrocycloxanthohumol hydrate
0.000	[beta-Hydroxy(or Oxodihydro)chalcone]-A(2OH, 1OMe, 1(C-Prenyl))-B(none)	beta-Hydroxy(or Oxodihydro)chalcone	3'-Prenyl-2',6',beta-trihydroxy-4'-methoxychalcone
0.000	[Dihydrochalcone]-A(2OH, 1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(none)	Dihydrochalcone	Flemistrictin D
0.000	[Dihydrochalcone beta-ol (beta-OMe)]-A(1OMe, 1([2,3:@@]-Furano))-B(1([@@]-Methylenedioxy))	Dihydrochalcone beta-ol	Ponganone IX
0.000	[Flavanone]-A(1OH, 1OMe, 1(3-Hydroxy-3-methyl-1-butenyl))-B(none)	Flavanone	Tephroleocarpin A
0.000	[Flavanone]-A(2OH, 1(C-Prenyl), 1Methyl)-B(1OH)	Flavanone	5,7,4'-Trihydroxy-6-methyl-8-prenylflavanone
0.000	[Flavanone]-A(2OH, 1(C-Prenyl), 1Methyl)-B(1OH)	Flavanone	5,7,4'-Trihydroxy-8-methyl-6-prenylflavanone
0.000	[Flavanone]-A(1OH, 1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(2OH)	Flavanone	Velloeriodictyol
0.000	[Flavanone]-A(1OH, 1OMe, 1([2,3:@@]-Furano))-B(1([@@]-Methylenedioxy))	Flavanone	5-Hydroxy-6-methoxy-3',4'-methylenedioxyfurano[2'',3'':7,8]flavanone
0.000	[Flavone]-A(2OH, 1(2-hydroxy-3-methyl-3-butenyl))-B(1OH)	Flavone	Dinklagin C
0.000	[Flavone]-A(2OH, 1(2-hydroxy-3-methyl-3-butenyl))-B(1OH)	Flavone	Ephedroidin
0.000	[Flavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethyl-5-hydroxydihydropyrano)))-B(1OH)	Flavone	Dinklagin B
0.000	[3-substituted Flavone (3-C-Prenyl)]-A(2OH)-B(2OH)	3-substituted Flavone	Albanin A
0.000	[Dihydroflavonol]-A(1OH, 1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(1OH)	Dihydroflavonol	Shuterol
0.000	[Dihydroflavonol]-A(1OH, 1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(1OH)	Dihydroflavonol	3,5,4'-Trihydroxy-4'',5'',dihydro-5''-isopropenylfurano[2'',3'':7,8]flavanone
0.000	[Dihydroflavonol (3-OMe)]-A(2OMe, 1([2,3:@@]-Furano))-B(none)	Dihydroflavonol	3,5,6-Trimethoxy-[2'',3'':7,8]furanoflavanone
0.000	[Flavan 3-ol]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH)	Flavan 3-ol	7,8-(2,2-Dimethylpyrano)-3,4'-dihydroxy-5-methoxyflavan
0.000	[Flavan 4-ol]-A(2OMe, 1(C-Prenyl))-B(none)	Flavan 4-ol	Tephrowatsin A
0.000	[Flavan 3,4-diol]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(none)	Flavan 3,4-diol	Quercetol A
0.000	[CCS-type derivative / [2,3,4:5,4a,4]-(6-Carboxypyrano)anthocyanidin]-A(1OH)-B(2OH)	CCS-type derivative / [2,3,4:5,4a,4]-(6-Carboxypyrano)anthocyanidin	5-Carboxypyranocyanidin
0.000	[Isoflavone]-A(2OH, 1((Z)-4-hydroxyprenyl))-B(1OH)	Isoflavone	Hydroxywighteone
0.000	[Isoflavone]-A(2OH, 1((Z)-4-hydroxyprenyl))-B(1OH)	Isoflavone	Gancaonin C
0.000	[Isoflavone]-A(1OH, 1([2,3:@@]-(5-(hydroxyisopropanyl)dihydrofurano)))-B(1OH)	Isoflavone	Erythrinin C
0.000	[Isoflavone]-A(2OH)-B(1([2,3:@@]-(5-(hydroxyisopropanyl)dihydrofurano)))	Isoflavone	Lupinisoflavone C
0.000	[Isoflavone]-A(2OH)-B(2OH, 1(1,1-Dimethylallyl))	Isoflavone	Fremontin
0.000	[Isoflavanone]-A(1([2,3:@@]-Furano))-B(1OH, 1OMe, 1([@@]-Methylenedioxy))	Isoflavanone	Erosenone
0.000	[Isoflavanone]-A(1([2,3:@@]-Furano))-B(3OMe)	Isoflavanone	Nepseudin
0.000	[Isoflavanone]-A(1([2,3:@@]-Furano))-B(3OMe)	Isoflavanone	Ambonone
0.000	[Isoflavan]-A(1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OH, 1OMe)	Isoflavan	3'-Methoxyglabridin
0.000	[Isoflavan]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OH)	Isoflavan	Neorauflavane
0.000	[Pterocarpan-6a-ol]-A(1OH)-B(1OMe, 1(C-Prenyl))	Pterocarpan-6a-ol	Cristacarpin
0.000	[Pterocarpan-6a-ol]-A(1OMe, 1(C-Prenyl))-B(1OH)	Pterocarpan-6a-ol	Glyceollin IV
0.000	[Pterocarpan-6a-ol]-A(1([2,3:@@]-(5-(Hydroxyisopropanyl)furano)))-B(1OH)	Pterocarpan-6a-ol	Glyceofuran
0.000	[Rotenoid 12-ol]-A(1([2,3:@@]-Furano))-B(2OMe)	Rotenoid 12-ol	Elliptinol
0.000	[3-Hydroxy-2-phenylbenzofuran (3-OMe)]-A(1OH, 1(C-Prenyl))-B(1OH, 1OMe)	3-Hydroxy-2-phenylbenzofuran	Ambofuranol
0.000	[2-Phenylbenzofuran]-A(2OMe, 1(C-Prenyl))-B(2OH)	2-Phenylbenzofuran	Gancaonin I

Level: 3, プリカーサーm/z: 271.14655

Splash: splash10-052f-0090000000-42199c78c98101e5a604

m/z	Int.	NL	Rel.Int.
240.14	2308	31	1000
256.16	1581	15	684
239.14	906	32	392
243.19	780	28	337
211.02	451	60	195
253.07	158	18	68
213.16	152	58	66

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.385	[Chalcone]-A(1OH)-B(1OH, 1OMe)	Chalcone	Echinatin
0.385	[Chalcone]-A(1OH, 1OMe)-B(1OH)	Chalcone	Isoliquiritigenin 2'-methy ether
0.143	[Isoflavanone]-A(1OH)-B(1OMe)	Isoflavanone	Dihydroformononetin
0.143	[2'-Hydroxychalcone]-A(1OH, 1OMe)-B(1OH)	2'-Hydroxychalcone	Isoliquiritigenin 4'-methyl ether
0.143	[2'-Hydroxychalcone]-A(2OH)-B(1OMe)	2'-Hydroxychalcone	Isoliquiritigenin 4-methyl ether
0.143	[2'-Hydroxychalcone]-A(2OH)-B(1OMe)	2'-Hydroxychalcone	2',5'-Dihydroxy-4-methoxychalcone
0.143	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(none)	2'-Hydroxychalcone	Flemichapparin
0.143	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(none)	2'-Hydroxychalcone	Larrein
0.143	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(none)	2'-Hydroxychalcone	Cardamonin
0.143	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(none)	2'-Hydroxychalcone	2',6'-Dihydroxy-4'-methoxychalcone
0.125	[Flavone]-A(2OH)-B(1OH)	Flavone	5,8,2'-Trihydroxyflavone
0.125	[Flavone]-A(2OH)-B(1OH)	Flavone	5,7,2'-Trihydroxyflavone
0.125	[Flavone]-A(2OH)-B(1OH)	Flavone	Apigenin
0.125	[Flavone]-A(3OH)-B(none)	Flavone	Baicalein
0.125	[Flavone]-A(3OH)-B(none)	Flavone	Norwogonin
0.125	[Flavone]-A(1OH)-B(2OH)	Flavone	7,3',4'-Trihydroxyflavone
0.125	[Flavone]-A(1OH)-B(2OH)	Flavone	5,2',5'-Trihydroxyflavone
0.125	[Anthocyanidin]-A(2OH)-B(1OH)	Anthocyanidin	Pelargonidin
0.125	[Flavanone]-A(1OH)-B(1OMe)	Flavanone	4'-Methylliquiritigenin
0.125	[Flavanone]-A(1OMe)-B(1OH)	Flavanone	Methyl-liquiritigenin
0.125	[Flavanone]-A(1OH, 1OMe)-B(none)	Flavanone	7-Hydroxy-8-methoxyflavanone
0.125	[Flavanone]-A(1OH, 1OMe)-B(none)	Flavanone	Alpinetin
0.125	[Flavanone]-A(1OH, 1OMe)-B(none)	Flavanone	Pinostrobin
0.118	[Isoflavone]-A(2OH)-B(1OH)	Isoflavone	Demethyltexasin
0.118	[Isoflavone]-A(2OH)-B(1OH)	Isoflavone	8-Hydroxydaidzein
0.118	[Isoflavone]-A(2OH)-B(1OH)	Isoflavone	5,7,2'-Trihydroxyisoflavone
0.118	[Isoflavone]-A(2OH)-B(1OH)	Isoflavone	5,7,3'-Trihydroxyisoflavone
0.118	[Isoflavone]-A(2OH)-B(1OH)	Isoflavone	Genistein
0.118	[Isoflavone]-A(1OH)-B(2OH)	Isoflavone	3'-Hydroxydaidzein
0.118	[Isoflavone]-A(1OH)-B(2OH)	Isoflavone	2'-Hydroxydaidzein
0.091	[Flavonol]-A(2OH)-B(none)	Flavonol	Galangin
0.087	[Flavonol]-A(1OH)-B(1OH)	Flavonol	Resokaempferol
0.083	[Pterocarpan]-A(1OH)-B(1OMe)	Pterocarpan	Medicarpin
0.083	[Pterocarpan]-A(1OMe)-B(1OH)	Pterocarpan	Isomedicarpin
0.000	[Aurone]-A(1OH)-B(2OH)	Aurone	Sulfuretin
0.000	[Aurone]-A(2OH)-B(1OH)	Aurone	4,6,4'-Trihydroxyaurone
0.000	[UBR-type derivative / 2',5'-Dioxo-3'-cyclopentenyl-type Calcone (alpha-OMe)]-A(1OMe)-B(none)	UBR-type derivative / 2',5'-Dioxo-3'-cyclopentenyl-type Calcone	Methyllucidone
0.000	[UBR-type derivative / 3',5'-Dioxo-1'-cyclopentenyl-type Dihydrocalcone]-A(3Methyl)-B(none)	UBR-type derivative / 3',5'-Dioxo-1'-cyclopentenyl-type Dihydrocalcone	4-Hydrocinnamoyl-2,2,5-trimethyl-4-cyclopentene-1,3-dione
0.000	[Flavanone]-A(2OH, 1Methyl)-B(none)	Flavanone	Strobopinin
0.000	[Flavanone]-A(2OH, 1Methyl)-B(none)	Flavanone	Cryptostrobin
0.000	[Flavan]-A(1OMe, 1Methyl)-B(1OH)	Flavan	4'-Hydroxy-7-methoxy-8-methylflavan
0.000	[Flavan]-A(1OH)-B(1([@@]-Methylenedioxy))	Flavan	7-Hydroxy-3',4'-methylenedioxyflavan
0.000	[Flavan]-A(2OMe)-B(none)	Flavan	Tephrowatsin E
0.000	[Flavan]-A(1OH, 1OMe, 1Methyl)-B(none)	Flavan	7-Hydroxy-5-methoxy-6-methylflavan
0.000	[3-DehydroxyAnthocyanidin]-A(2OH)-B(2OH)	3-DehydroxyAnthocyanidin	Luteolinidin
0.000	[isoflavene]-A(1OH)-B(1OH, 1OMe)	isoflavene	Haginin B
0.000	[2-Phenylbenzofuran]-A(1OMe)-B(1OH, 1OMe)	2-Phenylbenzofuran	Vignafuran
0.000	[2-Phenylbenzofuran]-A(1([@@]-Methylenedioxy))-B(2OH)	2-Phenylbenzofuran	2',4'-Dihydroxy-5,6-methylenedioxy-2-phenylbenzofuran
0.000	[Dalbergiquinol]-A(1OH, 2OMe)-B(none)	Dalbergiquinol	5-Hydroxy-2,4-dimethoxydalbergiquinol
0.000	[UBR-type derivative / [2,5]-Benzoquinonyl-type Dalbergiquinol]-A(1OMe)-B(1OH)	UBR-type derivative / [2,5]-Benzoquinonyl-type Dalbergiquinol	4'-Hydroxy-4-methoxydalbergione