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Peak #8214 MN MID: SE199_S31_M90

m/z: 285.22128, RT: 85.61, 強度: 5319, ログ強度: 0.17, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 2

DB検索結果: (23 names) abieta-8,11,13-trien-18-al;17-Methyl-18,19-dinor-17alpha-pregna-4,13-dien-3-one;Retinal;;19-Norpregna-4,17(20)-dien-3-one;Coronarin E;Pisiferin;6,7-Didehydroferruginol;Vitamin A2;Abieta-8,11,13-trien-...

DBごとのヒット数: ALL 20 KG 7 KN 11 LM 2

FlavonoidSearch最大スコア MS2: 0.240, MS3: -

DB検索結果

ppm

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C20H28O	284.21402	-0.025	Dehydroabietal	KNApSAcK: C00036109 LipidMAPS: LMPR0104050011
C20H28O	284.21402	-0.025	17-Methyl-18,19-dinor-17alpha-pregna-4,13-dien-3-one	KEGG: C15170
C20H28O	284.21402	-0.025	Retinal	HMDB: HMDB0001358, HMDB0002152, HMDB0006218, HMDB0006220, HMDB0244342 KEGG: C00376, C02110, C16681 LipidMAPS: LMPR01090002, LMPR01090003, LMPR01090017, LMPR01090018
C20H28O	284.21402	-0.025		LipidMAPS: LMPR0104410002
C20H28O	284.21402	-0.025	19-Norpregna-4,17(20)-dien-3-one	KEGG: C15016
C20H28O	284.21402	-0.025	Coronarin E	KNApSAcK: C00032858
C20H28O	284.21402	-0.025	Pisiferin	KNApSAcK: C00031046
C20H28O	284.21402	-0.025	6,7-Didehydroferruginol	HMDB: HMDB0035151 KNApSAcK: C00054734
C20H28O	284.21402	-0.025	Vitamin A2	HMDB: HMDB0013117 LipidMAPS: LMPR01090008, LMPR01090010
C20H28O	284.21402	-0.025	Abieta-8,11,13-trien-7-one	KNApSAcK: C00046998, C00047156
C20H28O	284.21402	-0.025	3-Methoxyestra-1,3,5(10)-trien-16beta-ol	KEGG: C15262
C20H28O	284.21402	-0.025	17,17-Dimethyl-18-norandrosta-4,13-dien-3-one	KEGG: C14655
C20H28O	284.21402	-0.025	Angustanal	KNApSAcK: C00049983
C20H28O	284.21402	-0.025	Lynestrenol	HMDB: HMDB0254258 KEGG: C13037 LipidMAPS: LMST02030127
C20H28O	284.21402	-0.025	Cespitularin B	KNApSAcK: C00045753
C20H28O	284.21402	-0.025	3-Oxo-abieta-8,11,13-triene	KNApSAcK: C00047148
C20H28O	284.21402	-0.025	Vitexifolin C	KNApSAcK: C00045446
C20H28O	284.21402	-0.025		LipidMAPS: LMPR01090035, LMPR01090036
C20H28O	284.21402	-0.025	Deoxybuddlejone	KNApSAcK: C00036112
C20H28O	284.21402	-0.025	Aikupikanyne D	KNApSAcK: C00046603

MSnスペクトル情報

Level: 2, プリカーサーm/z: 285.22122

Splash: splash10-014i-0290000000-5430ae73c06dca27e4ad

m/z	Int.	NL	Rel.Int.
267.19	16566	18	1000
211.12	2100	74	126
213.19	1856	72	112
229.11	1601	56	96
243.26	1491	42	89
257.24	1378	28	83
159.11	1348	126	81
199.18	1248	86	75
197.18	1244	88	75
147.03	1029	138	62
173.16	976	112	58
189.07	928	96	56
225.20	887	60	53
161.01	835	124	50

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.240	[Isoflavone]-A(2OH)-B(1OMe)	Isoflavone	Texasin
0.240	[Isoflavone]-A(2OH)-B(1OMe)	Isoflavone	Retusin(Dalbergia)
0.240	[Isoflavone]-A(2OH)-B(1OMe)	Isoflavone	Biochanin A
0.240	[Isoflavone]-A(2OH, 1OMe)-B(none)	Isoflavone	5,7-Dihydroxy-6-methoxyisoflavone
0.240	[Isoflavone]-A(1OH, 1OMe)-B(1OH)	Isoflavone	7,2'-Dihydroxy-6-methoxyisoflavone
0.240	[Isoflavone]-A(1OH, 1OMe)-B(1OH)	Isoflavone	Glycitein
0.240	[Isoflavone]-A(1OH, 1OMe)-B(1OH)	Isoflavone	Kakkatin
0.240	[Isoflavone]-A(1OH, 1OMe)-B(1OH)	Isoflavone	5-O-Methylgenistein
0.240	[Isoflavone]-A(1OH, 1OMe)-B(1OH)	Isoflavone	Prunetin
0.240	[Isoflavone]-A(1OH)-B(1OH, 1OMe)	Isoflavone	3'-Methoxydaidzein
0.240	[Isoflavone]-A(1OH)-B(1OH, 1OMe)	Isoflavone	Calycosin
0.240	[Isoflavone]-A(1OH)-B(1OH, 1OMe)	Isoflavone	Xenognosin B
0.240	[Isoflavone]-A(1OH)-B(1OH, 1OMe)	Isoflavone	Teralin
0.190	[Chalcone]-A(1OMe)-B(1OH, 1OMe)	Chalcone	Glypallichalcone
0.167	[Flavonol]-A(1OH, 1OMe)-B(none)	Flavonol	Zuccagin
0.167	[Flavonol]-A(1OH, 1OMe)-B(none)	Flavonol	Galangin 5-methyl ether
0.167	[Flavonol]-A(1OH, 1OMe)-B(none)	Flavonol	Izalpinin
0.167	[Flavonol]-A(1OMe)-B(1OH)	Flavonol	5-Deoxyrhamnocitrin
0.125	[Coumestan]-A(1OH)-B(2OH)	Coumestan	7,10,12-Trihydroxycoumestan
0.125	[Coumestan]-A(2OH)-B(1OH)	Coumestan	Lucernol
0.125	[Coumestan]-A(2OH)-B(1OH)	Coumestan	Aureol
0.095	[2'-Hydroxychalcone]-A(1OH, 2OMe)-B(none)	2'-Hydroxychalcone	Flavokawin B
0.095	[2'-Hydroxychalcone]-A(1OH, 1OMe)-B(1OMe)	2'-Hydroxychalcone	Isoliquiritigenin 4,4'-dimethyl ether
0.087	[Flavanone]-A(2OMe)-B(none)	Flavanone	7,8-Dimethoxyflavanone
0.087	[Flavanone]-A(2OMe)-B(none)	Flavanone	Pinocembrin 5,7-dimethyl ether
0.053	[Pterocarpan]-A(1OMe)-B(1OMe)	Pterocarpan	Baphinitone
0.000	[Flavone]-A(1OH)-B(1OH, 1OMe)	Flavone	Geraldone
0.000	[Flavone]-A(1OH)-B(1OH, 1OMe)	Flavone	Farnisin
0.000	[Flavone]-A(1OH, 1OMe)-B(1OH)	Flavone	7,2'-Dihydroxy-5-methoxyflavone
0.000	[Flavone]-A(1OH, 1OMe)-B(1OH)	Flavone	Echioidinin
0.000	[Flavone]-A(2OH)-B(1OMe)	Flavone	Acacetin
0.000	[Flavone]-A(1OH, 1OMe)-B(1OH)	Flavone	Thevetiaflavone
0.000	[Flavone]-A(1OH, 1OMe)-B(1OH)	Flavone	Genkwanin
0.000	[Flavone]-A(2OH, 1OMe)-B(none)	Flavone	Baicalein 5-methyl ether
0.000	[Flavone]-A(2OH, 1OMe)-B(none)	Flavone	Oroxylin A
0.000	[Flavone]-A(2OH, 1OMe)-B(none)	Flavone	Negletein
0.000	[Flavone]-A(2OH, 1OMe)-B(none)	Flavone	5,8-Dihydroxy-7-methoxyflavone
0.000	[Flavone]-A(2OH, 1OMe)-B(none)	Flavone	Wogonin
0.000	[Aurone]-A(2OH, 1Methyl)-B(1OH)	Aurone	4,6,4'-Trihydroxy-7-methylaurone
0.000	[2'-Hydroxychalcone]-A(2OH, 1OMe, 1Methyl)-B(none)	2'-Hydroxychalcone	Aurentiacin A
0.000	[2'-Hydroxychalcone]-A(2OH, 1OMe, 1Methyl)-B(none)	2'-Hydroxychalcone	Triangularin
0.000	[2'-Hydroxychalcone]-A(2OH, 1OMe, 1Methyl)-B(none)	2'-Hydroxychalcone	Stercurensin
0.000	[Flavanone]-A(1OH, 1OMe, 1Methyl)-B(none)	Flavanone	Comptonin
0.000	[Flavanone]-A(1OH, 1OMe, 1Methyl)-B(none)	Flavanone	7-O-Methylstrobopinin
0.000	[Flavanone]-A(1OH, 1OMe, 1Methyl)-B(none)	Flavanone	5-Hydroxy-7-methoxy-8-C-methylflavanone
0.000	[Flavanone]-A(2OH, 2Methyl)-B(none)	Flavanone	5,7-Dihydroxy-6,8-dimethylflavanone
0.000	[Flavone]-A(2OH, 1Methyl)-B(1OH)	Flavone	6-Methylapigenin
0.000	[3-substituted Flavone (3-Methyl)]-A(2OH)-B(1OH)	3-substituted Flavone	3-C-Methylapigenin
0.000	[Flavone]-A(2OH)-B(1OH, 1Methyl)	Flavone	5,7,4'-Trihydroxy-3'-C-methylflavone
0.000	[Flavonol (3-OMe)]-A(2OH)-B(none)	Flavonol	Galangin 3-methyl ether
0.000	[Flavonol]-A(2OH, 1Methyl)-B(none)	Flavonol	8-C-Methylgalangin
0.000	[CCS-type derivative / [3,2']-Epoxy-3-Dehydroxyanthocyanidin]-A(2OH)-B(2OH)	CCS-type derivative / [3,2']-Epoxy-3-Dehydroxyanthocyanidin	Riccionidin A
0.000	[3-DehydroxyAnthocyanidin]-A(2OH, 1OMe)-B(1OH)	3-DehydroxyAnthocyanidin	Carajuron
0.000	[Pterocarpan]-A(1OH)-B(1([@@]-Methylenedioxy))	Pterocarpan	Maackiain
0.000	[Coumaranochromon]-A(2OH)-B(1OH)	Coumaranochromon	Lupinalbin A
0.000	[3-Phenylcoumarin]-A(1OH)-B(1OH, 1OMe)	3-Phenylcoumarin	7,2'-Dihydroxy-4'-methoxy-3-phenylcoumarin
0.000	[2-Phenylbenzofuran]-A(1([@@]-Methylenedioxy))-B(1OH, 1OMe)	2-Phenylbenzofuran	2'-Hydroxy-4'-methoxy-5,6-methylenedioxy-2-phenylbenzofuran
0.000	[4-phenylcoumarin]-A(1OH)-B(1OH, 1OMe)	4-phenylcoumarin	7,3'-Dihydroxy-4'-methoxy-4-phenylcoumarin
0.000	[4-phenylcoumarin]-A(1OH, 1OMe)-B(1OH)	4-phenylcoumarin	Stevenin
0.000	[4-phenylcoumarin]-A(1OH, 1OMe)-B(1OH)	4-phenylcoumarin	Melannin
0.000	[4-phenylcoumarin]-A(2OH)-B(1OMe)	4-phenylcoumarin	5,7-Dihydroxy-4'-methoxy-4-phenylcoumarin
0.000	[4-phenylcoumarin]-A(1OH, 1OMe)-B(1OH)	4-phenylcoumarin	5,4'-Dihydroxy-7-methoxy-4-phenylcoumarin
0.000	[CCS-type derivative / [5,2']-Epoxy-4-phenylcoumarin]-A(1OH)-B(2OH)	CCS-type derivative / [5,2']-Epoxy-4-phenylcoumarin	7,4',5'-Trihydroxy-5,2'-oxido-4-phenylcoumarin
0.000	[Dalbergiquinol]-A(3OMe)-B(none)	Dalbergiquinol	2,4,5-Trimethoxydalbergiquinol
0.000	[UBR-type derivative / [2,5]-Benzoquinonyl-type Dalbergiquinol]-A(2OMe)-B(none)	UBR-type derivative / [2,5]-Benzoquinonyl-type Dalbergiquinol	3,4-Dimethoxydalbergione
0.000	[UBR-type derivative / [2,5]-Benzoquinonyl-type Dalbergiquinol]-A(1OMe)-B(1OMe)	UBR-type derivative / [2,5]-Benzoquinonyl-type Dalbergiquinol	4,4'-Dimethoxydalbergione
0.000	[Neoflavene]-A(1OH, 2OMe)-B(none)	Neoflavene	Kuhlmannene

Level: 3, プリカーサーm/z: 267.20013

Splash: splash10-03ds-0960000000-906dce933fbb627a7ebd

m/z	Int.	NL	Rel.Int.
211.17	1896	56	1000
197.09	1140	70	601
225.18	757	42	399
239.21	538	28	283
182.98	475	84	250
185.17	445	82	234
171.11	374	96	197
159.13	374	108	197
252.19	354	15	186
173.09	317	94	167
169.03	291	98	153
199.11	210	68	111
155.02	207	112	109
157.16	190	110	100
145.08	187	122	98
119.02	135	148	71
161.09	122	106	64
109.00	113	158	59
94.93	113	172	59
187.14	111	80	58

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.000	[2-substituted Isoflavone (2-Methyl)]-A(1OMe)-B(none)	2-substituted Isoflavone	7-Methoxy-2-methylisoflavone

Level: 3, プリカーサーm/z: 211.10364

Splash: splash10-014i-0900000000-5141b70dcc244dbcd73c

m/z	Int.	NL	Rel.Int.
169.11	425	42	1000
196.11	220	15	516
155.05	148	56	347
183.15	140	28	329
168.47	46	43	107
182.25	28	29	64
143.11	25	68	58