ピーク情報
|
イネ 葉 コシヒカリ
pos
|
| Peak #8032 MN MID: SE199_S31_M90 |
| m/z: 287.23735, RT: 80.27, 強度: 4410, ログ強度: 0.09, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 1 |
| DB検索結果: (46 names) cis-Communal;Dehydroambliol A;Labda-7,12(E),14-triene-17-al;(+)-Labda-7,12(E),14-triene-17-al;Pimarinal;Oxo-12E-Biformene;ent-19-Trachylobanal;abieta-8,11,13-trien-18-ol;ent-Cassa-12,15-dien-2-one;Sta... |
| DBごとのヒット数: ALL 37 KG 9 KN 24 HM 2 LM 2 |
| FlavonoidSearch最大スコア MS2: 0.167, MS3: - |
DB検索結果
ppm
| 組成式 | 分子量 | 誤差(Δppm） | 候補化合物名（代表で最短名を記載） | 化合物ID |
|---|---|---|---|---|
| C20H30O | 286.22967 | 1.438 | cis-Communal | KNApSAcK: C00023282, C00055014 |
| C20H30O | 286.22967 | 1.438 | Dehydroambliol A | KNApSAcK: C00022176 |
| C20H30O | 286.22967 | 1.438 | Labda-7,12(E),14-triene-17-al | KNApSAcK: C00041028 |
| C20H30O | 286.22967 | 1.438 | Pimarinal | KNApSAcK: C00031284, C00053684 |
| C20H30O | 286.22967 | 1.438 | Oxo-12E-Biformene | KNApSAcK: C00023279 |
| C20H30O | 286.22967 | 1.438 | ent-19-Trachylobanal | HMDB: HMDB0036841 |
| C20H30O | 286.22967 | 1.438 | Dehydroabietinol | KNApSAcK: C00034167 LipidMAPS: LMPR0104050010 |
| C20H30O | 286.22967 | 1.438 | Ambliofuran | KNApSAcK: C00022031 |
| C20H30O | 286.22967 | 1.438 | Stachenone | KNApSAcK: C00034689 LipidMAPS: LMPR0104140002 |
| C20H30O | 286.22967 | 1.438 | LipidMAPS: LMPR0104110003 |
|
| C20H30O | 286.22967 | 1.438 | (x)-p-Menth-1-en-4-yl 5-isopropyl-2-methylphenyl ether | HMDB: HMDB0030403 |
| C20H30O | 286.22967 | 1.438 | LipidMAPS: LMPR01090067 |
|
| C20H30O | 286.22967 | 1.438 | Neocrotocembranal | KNApSAcK: C00037543 |
| C20H30O | 286.22967 | 1.438 | Retinol | HMDB: HMDB0000305, HMDB0006216, HMDB0006217, HMDB0006221, HMDB0247586 KEGG: C00473, C17276, C00899, C19962, C16682 KNApSAcK: C00031437 LipidMAPS: LMPR01090001, LMPR01090005, LMPR01090009, LMPR01090011 |
| C20H30O | 286.22967 | 1.438 | Isopimara-7,15-dien-3-one | KNApSAcK: C00034865 |
| C20H30O | 286.22967 | 1.438 | Sempervirol | KNApSAcK: C00040276 |
| C20H30O | 286.22967 | 1.438 | Totarol | KNApSAcK: C00040508 LipidMAPS: LMPR0104070001 |
| C20H30O | 286.22967 | 1.438 | Isopimaradienal | KEGG: C18222, C20148 KNApSAcK: C00053375 LipidMAPS: LMPR0104080009 |
| C20H30O | 286.22967 | 1.438 | Helicallen-16-al | KNApSAcK: C00022168 LipidMAPS: LMPR0104020001 |
| C20H30O | 286.22967 | 1.438 | LipidMAPS: LMPR0104240014 |
|
| C20H30O | 286.22967 | 1.438 | Ferruginol | KEGG: C09092 KNApSAcK: C00003426 |
| C20H30O | 286.22967 | 1.438 | Pumiloxide | KNApSAcK: C00022308 |
| C20H30O | 286.22967 | 1.438 | Kaur-16-en-18-al | HMDB: HMDB0036728, HMDB0304347 KEGG: C11873 KNApSAcK: C00055814 LipidMAPS: LMPR0104130005 |
| C20H30O | 286.22967 | 1.438 | Neoabietal | KEGG: C11885 KNApSAcK: C00053539 |
| C20H30O | 286.22967 | 1.438 | Gibberosin L | KNApSAcK: C00030380 |
| C20H30O | 286.22967 | 1.438 | Cyanthiwigin F | KNApSAcK: C00048672 |
| C20H30O | 286.22967 | 1.438 | Palustradienal | HMDB: HMDB0038709 KEGG: C18220 KNApSAcK: C00053624 |
| C20H30O | 286.22967 | 1.438 | Mikanifuran | KNApSAcK: C00022073 |
| C20H30O | 286.22967 | 1.438 | ent-15,16-Epoxy-7,13(16),14-labdatriene | KNApSAcK: C00022310 |
| C20H30O | 286.22967 | 1.438 | Valpara-3,15-dien-2-one | KNApSAcK: C00049322 |
| C20H30O | 286.22967 | 1.438 | Deoxyhypoestenone | KNApSAcK: C00048971 |
| C20H30O | 286.22967 | 1.438 | Abietal | HMDB: HMDB0034735, HMDB0304254 KEGG: C11887 KNApSAcK: C00000869 |
| C20H30O | 286.22967 | 1.438 | Tagalsin E | KNApSAcK: C00035400 |
| C20H30O | 286.22967 | 1.438 | Levopimarinal | KEGG: C11886 LipidMAPS: LMPR0104050009 |
| C20H30O | 286.22967 | 1.438 | pregna-5,20-dien-3beta-ol | LipidMAPS: LMST02030210 |
| C20H30O | 286.22967 | 1.438 | ent-Trachyloban-3-one | KNApSAcK: C00035605 |
| C20H30O | 286.22967 | 1.438 | ent-3,13(16),14-Clerodatrien-17-al | KNApSAcK: C00023508 |
| C20H30O | 286.22967 | 1.438 | 3-Oxo-labda-8(17),13(16),14-triene | KNApSAcK: C00036563 |
MSnスペクトル情報
| Level: 2, プリカーサーm/z: 287.23703 |
| Splash: splash10-014i-0090000000-0546c56cc23dd83d198c |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 269.26 | 4207 | 18 | 1000 |
| 287.16 | 535 | 0 | 127 |
| 227.11 | 251 | 60 | 59 |
| 213.06 | 225 | 74 | 53 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.167 | [Flavone]-A(1OH)-B(3OH) | Flavone | 7,3',4',5'-Tetrahydroxyflavone |
| 0.167 | [Flavone]-A(2OH)-B(2OH) | Flavone | 5,7,2',5'-Tetrahydroxyflavone |
| 0.167 | [Flavone]-A(2OH)-B(2OH) | Flavone | 5,7,2',6'-Tetrahydroxyflavone |
| 0.167 | [Flavone]-A(2OH)-B(2OH) | Flavone | 5,7,2',3'-Tetrahydroxyflavone |
| 0.167 | [Flavone]-A(2OH)-B(2OH) | Flavone | Luteolin |
| 0.167 | [Flavone]-A(2OH)-B(2OH) | Flavone | Norartocarpetin |
| 0.167 | [Flavone]-A(3OH)-B(1OH) | Flavone | 5,6,7,2'-Tetrahydroxyflavone |
| 0.167 | [Flavone]-A(3OH)-B(1OH) | Flavone | Scutellarein |
| 0.167 | [Flavone]-A(3OH)-B(1OH) | Flavone | 5,7,8,2'-Tetrahydroxyflavone |
| 0.167 | [Flavone]-A(3OH)-B(1OH) | Flavone | Isoscutellarein |
| 0.167 | [Dihydroflavonol]-A(1OH)-B(1OMe) | Dihydroflavonol | Garbanzol 4'-methyl ether |
| 0.167 | [Dihydroflavonol]-A(1OH, 1OMe)-B(none) | Dihydroflavonol | 3,7-Dihydroxy-6-methoxyflavanone |
| 0.167 | [Chalcone]-A(1OH)-B(2OH, 1OMe) | Chalcone | Licochalcone B |
| 0.167 | [Chalcone]-A(1OH, 1OMe)-B(2OH) | Chalcone | Sappanchalcone |
| 0.167 | [Anthocyanidin]-A(2OH)-B(2OH) | Anthocyanidin | Cyanidin |
| 0.167 | [Anthocyanidin]-A(3OH)-B(1OH) | Anthocyanidin | Aurantinidin |
| 0.154 | [Isoflavone]-A(2OH)-B(2OH) | Isoflavone | 7,8,2',4'-Tetrahydroxyisoflavone |
| 0.154 | [Isoflavone]-A(2OH)-B(2OH) | Isoflavone | Orobol |
| 0.154 | [Isoflavone]-A(2OH)-B(2OH) | Isoflavone | 2'-Hydroxygenistein |
| 0.154 | [Isoflavone]-A(1OH)-B(3OH) | Isoflavone | Baptigenin |
| 0.154 | [Isoflavone]-A(3OH)-B(1OH) | Isoflavone | 6-Hydroxygenistein |
| 0.125 | [Dihydroflavonol (3-OMe)]-A(2OH)-B(none) | Dihydroflavonol | Pinobanksin 3-methyl ether |
| 0.111 | [Dihydroflavonol]-A(1OH, 1OMe)-B(none) | Dihydroflavonol | Pinobanksin 5-methyl ether |
| 0.111 | [Dihydroflavonol]-A(1OH, 1OMe)-B(none) | Dihydroflavonol | Alpinone |
| 0.111 | [Flavonol]-A(2OH)-B(1OH) | Flavonol | Datiscetin |
| 0.111 | [Flavonol]-A(3OH)-B(none) | Flavonol | 6-Hydroxygalangin |
| 0.111 | [Flavonol]-A(3OH)-B(none) | Flavonol | 8-Hydroxygalangin |
| 0.105 | [Flavonol]-A(2OH)-B(1OH) | Flavonol | 3,7,8,4'-Tetrahydroxyflavone |
| 0.105 | [Flavonol]-A(2OH)-B(1OH) | Flavonol | Kaempferol |
| 0.105 | [Flavonol]-A(1OH)-B(2OH) | Flavonol | Fisetin |
| 0.091 | [Isoflavanone]-A(2OH)-B(1OMe) | Isoflavanone | Dihydrobiochanin A |
| 0.091 | [Isoflavanone]-A(1OH)-B(1OH, 1OMe) | Isoflavanone | 3'-Hydroxydihydroformononetin |
| 0.091 | [Isoflavanone]-A(1OH)-B(1OH, 1OMe) | Isoflavanone | Vestitone |
| 0.091 | [2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OH) | 2'-Hydroxychalcone | Kukulkanin B |
| 0.091 | [2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OH) | 2'-Hydroxychalcone | 2,2',6'-Trihydroxy-4'-methoxychalcone |
| 0.091 | [2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OH) | 2'-Hydroxychalcone | 2,2',4'-Trihydroxy-6'-methoxychalcone |
| 0.091 | [2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OH) | 2'-Hydroxychalcone | Neosakuranetin |
| 0.091 | [2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OH) | 2'-Hydroxychalcone | Helichrysetin |
| 0.091 | [2'-Hydroxychalcone]-A(1OH, 1OMe)-B(2OH) | 2'-Hydroxychalcone | Calythropsin |
| 0.091 | [2'-Hydroxychalcone]-A(3OH)-B(1OMe) | 2'-Hydroxychalcone | 2',4',6'-Trihydroxy-4-methoxychalcone |
| 0.091 | [2'-Hydroxychalcone]-A(3OH, 1OMe)-B(none) | 2'-Hydroxychalcone | 2',3',4'-dihydroxy-6'-methoxychalcone |
| 0.091 | [2'-Hydroxychalcone]-A(2OH)-B(1OH, 1OMe) | 2'-Hydroxychalcone | Homobutein |
| 0.091 | [2'-Hydroxychalcone]-A(2OH)-B(1OH, 1OMe) | 2'-Hydroxychalcone | 3,2',4'-Trihydroxy-4-methoxychalcone |
| 0.077 | [Flavanone]-A(2OH)-B(1OMe) | Flavanone | 5,6-Dihydroxy-4'-methoxyflavanone |
| 0.077 | [Flavanone]-A(2OH)-B(1OMe) | Flavanone | Isosakuranetin |
| 0.077 | [Flavanone]-A(2OH, 1OMe)-B(none) | Flavanone | 5-Methoxydihydrobaicalein |
| 0.077 | [Flavanone]-A(2OH, 1OMe)-B(none) | Flavanone | Dihydrooroxylin A |
| 0.077 | [Flavanone]-A(2OH, 1OMe)-B(none) | Flavanone | 5,8-Dihydroxy-7-methoxyflavanone |
| 0.077 | [Flavanone]-A(2OH, 1OMe)-B(none) | Flavanone | Dihydrowogonin |
| 0.077 | [Flavanone]-A(1OH, 1OMe)-B(1OH) | Flavanone | Dihydroechioidinin |
| 0.077 | [Flavanone]-A(1OH, 1OMe)-B(1OH) | Flavanone | Naringenin 5-methyl ether |
| 0.077 | [Flavanone]-A(1OH, 1OMe)-B(1OH) | Flavanone | Sakuranetin |
| 0.000 | [Isoflavan]-A(1OH)-B(2OMe) | Isoflavan | Sativan |
| 0.000 | [Isoflavan]-A(1OMe)-B(1OH, 1OMe) | Isoflavan | Isosativan |
| 0.000 | [Isoflavan]-A(1OMe)-B(1OH, 1OMe) | Isoflavan | Arvensan |
| 0.000 | [Dihydrochalcone]-A(1OH, 2OMe)-B(none) | Dihydrochalcone | Dihydroflavokawin B |
| 0.000 | [Dihydrochalcone]-A(2OMe)-B(1OH) | Dihydrochalcone | 4-Hydroxy-2',4'-dimethoxydihydrochalcone |
| 0.000 | [Dihydrochalcone]-A(1OH)-B(2OMe) | Dihydrochalcone | 4'-Hydroxy-2,6-dimethoxydihydrochalcone |
| 0.000 | [Dihydrochalcone]-A(1OH)-B(2OMe) | Dihydrochalcone | Loureirin A |
| 0.000 | [Pterocarpan]-A(1OH, 1OMe)-B(1OH) | Pterocarpan | Melilotocarpan B |
| 0.000 | [Pterocarpan]-A(1OH, 1OMe)-B(1OH) | Pterocarpan | Desmocarpin |
| 0.000 | [Pterocarpan]-A(1OH)-B(1OH, 1OMe) | Pterocarpan | Nissolin |
| 0.000 | [Pterocarpan]-A(1OH)-B(1OH, 1OMe) | Pterocarpan | Vesticarpan |
| 0.000 | [Pterocarpan]-A(1OH)-B(1OH, 1OMe) | Pterocarpan | Kushenin |
| 0.000 | [Pterocarpan]-A(1OH)-B(1OH, 1OMe) | Pterocarpan | 3,8-Dihydroxy-9-methoxypterocarpan |
| 0.000 | [Pterocarpan]-A(1OH)-B(1OH, 1OMe) | Pterocarpan | Nissicarpin |
| 0.000 | [Pterocarpan]-A(2OH)-B(1OMe) | Pterocarpan | 4-Hydroxymedicarpin |
| 0.000 | [Aurone]-A(2OH)-B(2OH) | Aurone | Maritimetin |
| 0.000 | [Aurone]-A(2OH)-B(2OH) | Aurone | Aureusidin |
| 0.000 | [Aurone]-A(3OH)-B(1OH) | Aurone | Helmon |
| 0.000 | [beta-Hydroxy(or Oxodihydro)chalcone]-A(1OH, 1OMe)-B(1OH) | beta-Hydroxy(or Oxodihydro)chalcone | Licodione 2'-methyl ether |
| 0.000 | [beta-Hydroxy(or Oxodihydro)chalcone]-A(2OH, 1OMe)-B(none) | beta-Hydroxy(or Oxodihydro)chalcone | 2',6',beta-Trihydroxy-4'-methoxychalcone |
| 0.000 | [beta-Hydroxy(or Oxodihydro)chalcone]-A(2OH, 1OMe)-B(none) | beta-Hydroxy(or Oxodihydro)chalcone | 2',4',beta-Trihydroxy-6'-methoxychalcone |
| 0.000 | [UBR-type derivative / [2',5']-Benzoquinonyl-type chalcone]-A(2OH)-B(1OH) | UBR-type derivative / [2',5']-Benzoquinonyl-type chalcone | 4,4',6'-Trihydroxy-[2',5']-benzoquinonechalcone |
| 0.000 | [UBR-type derivative / 2',5'-Dioxo-3'-cyclopentenyl-type Calcone]-A(2OMe)-B(none) | UBR-type derivative / 2',5'-Dioxo-3'-cyclopentenyl-type Calcone | Linderone |
| 0.000 | [Dihydrochalcone]-A(2OH)-B(1([@@]-Methylenedioxy)) | Dihydrochalcone | 2',4'-Dihydroxy-3,4-methylenedioxydihydrochalcone |
| 0.000 | [Dihydrochalcone]-A(2OH, 1OMe, 1Methyl)-B(none) | Dihydrochalcone | Myrigalone H |
| 0.000 | [Dihydrochalcone]-A(2OH, 1OMe, 1Methyl)-B(none) | Dihydrochalcone | 2',6'-Dihydroxy-4'-methoxy-3'-methyldihydrochalcone |
| 0.000 | [Dihydrochalcone]-A(3OH, 1Formyl)-B(none) | Dihydrochalcone | 3'-Formyl-2',4',6'-trihydroxydihydrochalcone |
| 0.000 | [Flavanone]-A(2OH, 1Methyl)-B(1OH) | Flavanone | Poriol |
| 0.000 | [3-substituted Flavanone (3-Methyl)]-A(2OH)-B(1OH) | 3-substituted Flavanone | 3-Methylnaringenin |
| 0.000 | [Dihydroflavonol]-A(2OH, 1Methyl)-B(none) | Dihydroflavonol | 6-Methypinobanksin |
| 0.000 | [Flavan 3-ol]-A(1OMe, 1Methyl)-B(1OH) | Flavan 3-ol | Tupichinol A |
| 0.000 | [CCS-type derivative / [3,2']-Epoxymethanoflavan]-A(1OH)-B(2OH) | CCS-type derivative / [3,2']-Epoxymethanoflavan | Peltogynan |
| 0.000 | [Flavan]-A(1OMe)-B(1OH, 1OMe) | Flavan | 4'-Hydroxy-7,3'-dimethoxyflavan |
| 0.000 | [Flavan]-A(1OH, 1Methyl)-B(1OH, 1OMe) | Flavan | 7,3'-Dihydroxy-4'-methoxy-8-methylflavan |
| 0.000 | [Flavan]-A(1OH, 1Methyl)-B(1OH, 1OMe) | Flavan | 7,4'-Dihydroxy-3'-methoxy-8-methylflavan |
| 0.000 | [Flavan]-A(1OH, 1OMe)-B(1OMe) | Flavan | 7-Hydroxy-5,4'-dimethoxyflavan |
| 0.000 | [Flavan]-A(1OH, 1OMe)-B(1OMe) | Flavan | 5-Hydroxy-7,4'-dimethoxyflavan |
| 0.000 | [Flavan]-A(2OMe)-B(1OH) | Flavan | 4'-Hydroxy-5,7-dimethoxyflavan |
| 0.000 | [Flavan]-A(1OH, 1OMe, 1Methyl)-B(1OH) | Flavan | 5,4'-Dihydroxy-7'-methoxy-8-methylflavan |
| 0.000 | [3-DehydroxyAnthocyanidin]-A(2OH)-B(3OH) | 3-DehydroxyAnthocyanidin | Tricetinidin |
| 0.000 | [UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavan]-A(1OH)-B(1OMe) | UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavan | Claussequinone |
| 0.000 | [isoflavene]-A(1OH)-B(2OH, 1OMe) | isoflavene | Sepiol |
| 0.000 | [isoflavene]-A(1OH)-B(2OH, 1OMe) | isoflavene | Haginin C |
| 0.000 | [Pterocarpan-6a-ol]-A(1OH)-B(1OMe) | Pterocarpan-6a-ol | 6a-Hydroxymedicarpin |
| 0.000 | [Pterocarpan-6a-ol]-A(1OMe)-B(1OH) | Pterocarpan-6a-ol | 6a-Hydroxyisomedicarpin |
| 0.000 | [2-Phenylbenzofuran]-A(1OH, 1OMe)-B(1OH, 1OMe) | 2-Phenylbenzofuran | Sainfuran |
| 0.000 | [2-Phenylbenzofuran]-A(2OMe)-B(2OH) | 2-Phenylbenzofuran | 2',4'-Dihydroxy-5,6-dimethoxy-2-phenylbenzofuran |
| 0.000 | [2-Phenylbenzofuran]-A(1OH)-B(1OH, 2OMe) | 2-Phenylbenzofuran | Pterofuran |
| 0.000 | [2-Phenylbenzofuran]-A(1OH)-B(1OH, 2OMe) | 2-Phenylbenzofuran | Isopterofuran |
| 0.000 | [alpha-Methyldeoxybenzoin]-A(1OH, 1OMe)-B(1OMe) | alpha-Methyldeoxybenzoin | 2-O-Methylangolensin |
| 0.000 | [alpha-Methyldeoxybenzoin]-A(1OH, 1OMe)-B(1OMe) | alpha-Methyldeoxybenzoin | 4-O-Methylangolensin |
| 0.000 | [4-phenylcoumarin]-A(2OH)-B(2OH) | 4-phenylcoumarin | 5,7,3',4'-Tetrahydroxy-4-phenylcoumarin |
| 0.000 | [[3,2']-Methano-4-phenylchroman (3-OH)]-A(1OH)-B(2OH) | [3,2']-Methano-4-phenylchroman | Brazilin |
| 0.000 | [Dalbergiquinol]-A(1OH, 2OMe)-B(1OH) | Dalbergiquinol | Latifolin |
| 0.000 | [Dalbergiquinol]-A(1OH, 2OMe)-B(1OH) | Dalbergiquinol | 5,3'-Dihydroxy-2,4-dimethoxydalbergiquinol |
| 0.000 | [Dalbergiquinol]-A(2OH, 2OMe)-B(none) | Dalbergiquinol | 2,5-Dihydroxy-3,4-dimethoxydalbergiquinol |