ピーク情報

イネ　葉　コシヒカリ

pos

Peak #527 MN MID: SE199_S31_M90

m/z: 305.13437, RT: 11.52, 強度: 6979, ログ強度: 0.29, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 4

DB検索結果: (4 names) Deoxyfructosazine;2-(1,2,3,4-Tetrahydroxybutyl)-6-(2,3,4-trihydroxybutyl)pyrazine;Dysiherbaine;2'-Deoxymugineic acid

DBごとのヒット数: ALL 4 KG 1 KN 1 HM 2

FlavonoidSearch最大スコア MS2: 0.250, MS3: 0.214

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C12H20O7N2	304.12705	0.136	Deoxyfructosazine	HMDB: HMDB0038696
C12H20O7N2	304.12705	0.136	2-(1,2,3,4-Tetrahydroxybutyl)-6-(2,3,4-trihydroxybutyl)pyrazine	HMDB: HMDB0034894
C12H20O7N2	304.12705	0.136	Dysiherbaine	KNApSAcK: C00028227
C12H20O7N2	304.12705	0.136	2'-Deoxymugineic acid	HMDB: HMDB0033909 KEGG: C15485

MSnスペクトル情報

Level: 2, プリカーサーm/z: 305.13391

Splash: splash10-000i-0090000000-f56cd5a1443c88e02dcd

m/z	Int.	NL	Rel.Int.
287.09	153020	18	1000

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.250	[Dihydroflavonol]-A(3OH)-B(1OH)	Dihydroflavonol	3,5,7,8,4'-Pentahydroxyflavanone
0.250	[Dihydroflavonol]-A(2OH)-B(2OH)	Dihydroflavonol	8-Hydroxyfustin
0.250	[Dihydroflavonol]-A(2OH)-B(2OH)	Dihydroflavonol	3,5,7,2',5'-Pentahydroxyflavanone
0.250	[Dihydroflavonol]-A(2OH)-B(2OH)	Dihydroflavonol	3,5,7,2',6'-Pentahydroxyflavanone
0.250	[Dihydroflavonol]-A(1OH)-B(3OH)	Dihydroflavonol	Dihydrorobinetin
0.200	[Flavan 3-ol]-A(1OH, 1OMe)-B(2OH)	Flavan 3-ol	Catechin-7-methyl ether
0.200	[Flavan 3-ol]-A(2OH)-B(1OH, 1OMe)	Flavan 3-ol	Symplocosidin
0.200	[Flavan 3-ol]-A(2OH)-B(1OH, 1OMe)	Flavan 3-ol	Catechin 4'-methyl ether
0.200	[Flavan 3-ol]-A(2OH)-B(1OH, 1OMe)	Flavan 3-ol	Catechin-3'-methyl ether
0.143	[Dihydroflavonol]-A(2OH)-B(2OH)	Dihydroflavonol	Taxifolin
0.143	[Dihydroflavonol]-A(2OH)-B(2OH)	Dihydroflavonol	Dihydromorin
0.125	[Dihydroflavonol]-A(2OH)-B(2OH)	Dihydroflavonol	3,5,7,3',5'-Pentahydroxyflavanone
0.111	[2'-Hydroxychalcone]-A(3OH)-B(3OH)	2'-Hydroxychalcone	3,4,5,2',4',6'-Hexahydroxychalcone
0.100	[Flavanone]-A(2OH)-B(3OH)	Flavanone	5,7,3',4',5'-Pentahydroxyflavanone
0.091	[Flavone]-A(1([2,3:@@]-(6,6-Dimethylpyrano)))-B(none)	Flavone	6'',6''-Dimethylpyrano[2'',3'':7,8]flavone
0.000	[Isoflavan]-A(2OH)-B(2OH, 1OMe)	Isoflavan	3',8-Dihydroxyvestitol
0.000	[Auronol]-A(2OH)-B(2OH)	Auronol	Nigrescin
0.000	[Auronol]-A(2OH)-B(2OH)	Auronol	Alphitonin
0.000	[beta-Hydroxy(or Oxodihydro)chalcone]-A(3OH)-B(2OH)	beta-Hydroxy(or Oxodihydro)chalcone	3,4,2',4',6',beta-Hexahydroxychalcone
0.000	[Dihydrochalcone alpha-ol]-A(1OH, 1OMe)-B(2OH)	Dihydrochalcone alpha-ol	3,4,4',alpha-Tetrahydroxy-2'-methoxydihydrochalcone
0.000	[Dihydrochalcone beta-ol]-A(2OH, 1OMe)-B(1OH)	Dihydrochalcone beta-ol	4,2',4',beta-Tetrahydroxy-6'-methoxydihydrochalcone
0.000	[2-Hydroxyflavanone]-A(2OH)-B(2OH)	2-Hydroxyflavanone	2,5,7,3',4'-Pentahydroxyflavanone
0.000	[Flavone]-A(2OH, 1Cl)-B(1OH)	Flavone	6-Chloroapigenin
0.000	[Flavan 3,4-diol]-A(1OH, 1OMe)-B(1OH)	Flavan 3,4-diol	Ortin-4alpha-ol 8-methyl ether

Level: 3, プリカーサーm/z: 287.09485

Splash: splash10-000i-0900000000-0f79a37672997ceea5c9

m/z	Int.	NL	Rel.Int.
186.01	81578	101	1000
197.02	13412	90	164
167.95	10345	119	126
269.10	6019	18	73
169.05	4583	118	56

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.214	[Isoflavone]-A(3OH)-B(1OH)	Isoflavone	6-Hydroxygenistein
0.158	[Flavonol]-A(3OH)-B(none)	Flavonol	6-Hydroxygalangin
0.158	[Flavonol]-A(3OH)-B(none)	Flavonol	8-Hydroxygalangin
0.143	[Flavone]-A(3OH)-B(1OH)	Flavone	5,6,7,2'-Tetrahydroxyflavone
0.143	[Flavone]-A(3OH)-B(1OH)	Flavone	Scutellarein
0.143	[Flavone]-A(3OH)-B(1OH)	Flavone	5,7,8,2'-Tetrahydroxyflavone
0.143	[Flavone]-A(3OH)-B(1OH)	Flavone	Isoscutellarein
0.133	[Isoflavone]-A(2OH)-B(2OH)	Isoflavone	7,8,2',4'-Tetrahydroxyisoflavone
0.133	[Isoflavone]-A(2OH)-B(2OH)	Isoflavone	Orobol
0.133	[Isoflavone]-A(2OH)-B(2OH)	Isoflavone	2'-Hydroxygenistein
0.133	[Isoflavone]-A(1OH)-B(3OH)	Isoflavone	Baptigenin
0.125	[Dihydroflavonol]-A(1OH)-B(1OMe)	Dihydroflavonol	Garbanzol 4'-methyl ether
0.125	[Dihydroflavonol]-A(1OH, 1OMe)-B(none)	Dihydroflavonol	3,7-Dihydroxy-6-methoxyflavanone
0.100	[Dihydroflavonol (3-OMe)]-A(2OH)-B(none)	Dihydroflavonol	Pinobanksin 3-methyl ether
0.100	[Flavonol]-A(2OH)-B(1OH)	Flavonol	Datiscetin
0.095	[Flavonol]-A(2OH)-B(1OH)	Flavonol	3,7,8,4'-Tetrahydroxyflavone
0.095	[Flavonol]-A(2OH)-B(1OH)	Flavonol	Kaempferol
0.095	[Flavonol]-A(1OH)-B(2OH)	Flavonol	Fisetin
0.091	[Dihydroflavonol]-A(1OH, 1OMe)-B(none)	Dihydroflavonol	Pinobanksin 5-methyl ether
0.091	[Dihydroflavonol]-A(1OH, 1OMe)-B(none)	Dihydroflavonol	Alpinone
0.077	[Isoflavanone]-A(2OH)-B(1OMe)	Isoflavanone	Dihydrobiochanin A
0.077	[Isoflavanone]-A(1OH)-B(1OH, 1OMe)	Isoflavanone	3'-Hydroxydihydroformononetin
0.077	[Isoflavanone]-A(1OH)-B(1OH, 1OMe)	Isoflavanone	Vestitone
0.077	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OH)	2'-Hydroxychalcone	Kukulkanin B
0.077	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OH)	2'-Hydroxychalcone	2,2',6'-Trihydroxy-4'-methoxychalcone
0.077	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OH)	2'-Hydroxychalcone	2,2',4'-Trihydroxy-6'-methoxychalcone
0.077	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OH)	2'-Hydroxychalcone	Neosakuranetin
0.077	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OH)	2'-Hydroxychalcone	Helichrysetin
0.077	[2'-Hydroxychalcone]-A(1OH, 1OMe)-B(2OH)	2'-Hydroxychalcone	Calythropsin
0.077	[2'-Hydroxychalcone]-A(3OH)-B(1OMe)	2'-Hydroxychalcone	2',4',6'-Trihydroxy-4-methoxychalcone
0.077	[2'-Hydroxychalcone]-A(3OH, 1OMe)-B(none)	2'-Hydroxychalcone	2',3',4'-dihydroxy-6'-methoxychalcone
0.077	[2'-Hydroxychalcone]-A(2OH)-B(1OH, 1OMe)	2'-Hydroxychalcone	Homobutein
0.077	[2'-Hydroxychalcone]-A(2OH)-B(1OH, 1OMe)	2'-Hydroxychalcone	3,2',4'-Trihydroxy-4-methoxychalcone
0.067	[Flavone]-A(1OH)-B(3OH)	Flavone	7,3',4',5'-Tetrahydroxyflavone
0.067	[Flavone]-A(2OH)-B(2OH)	Flavone	5,7,2',5'-Tetrahydroxyflavone
0.067	[Flavone]-A(2OH)-B(2OH)	Flavone	5,7,2',6'-Tetrahydroxyflavone
0.067	[Flavone]-A(2OH)-B(2OH)	Flavone	5,7,2',3'-Tetrahydroxyflavone
0.067	[Flavone]-A(2OH)-B(2OH)	Flavone	Luteolin
0.067	[Flavone]-A(2OH)-B(2OH)	Flavone	Norartocarpetin
0.067	[Chalcone]-A(1OH)-B(2OH, 1OMe)	Chalcone	Licochalcone B
0.067	[Chalcone]-A(1OH, 1OMe)-B(2OH)	Chalcone	Sappanchalcone
0.067	[Anthocyanidin]-A(2OH)-B(2OH)	Anthocyanidin	Cyanidin
0.067	[Anthocyanidin]-A(3OH)-B(1OH)	Anthocyanidin	Aurantinidin
0.067	[Flavanone]-A(2OH)-B(1OMe)	Flavanone	5,6-Dihydroxy-4'-methoxyflavanone
0.067	[Flavanone]-A(2OH)-B(1OMe)	Flavanone	Isosakuranetin
0.067	[Flavanone]-A(2OH, 1OMe)-B(none)	Flavanone	5-Methoxydihydrobaicalein
0.067	[Flavanone]-A(2OH, 1OMe)-B(none)	Flavanone	Dihydrooroxylin A
0.067	[Flavanone]-A(2OH, 1OMe)-B(none)	Flavanone	5,8-Dihydroxy-7-methoxyflavanone
0.067	[Flavanone]-A(2OH, 1OMe)-B(none)	Flavanone	Dihydrowogonin
0.067	[Flavanone]-A(1OH, 1OMe)-B(1OH)	Flavanone	Dihydroechioidinin
0.067	[Flavanone]-A(1OH, 1OMe)-B(1OH)	Flavanone	Naringenin 5-methyl ether
0.067	[Flavanone]-A(1OH, 1OMe)-B(1OH)	Flavanone	Sakuranetin
0.000	[Isoflavan]-A(1OH)-B(2OMe)	Isoflavan	Sativan
0.000	[Isoflavan]-A(1OMe)-B(1OH, 1OMe)	Isoflavan	Isosativan
0.000	[Isoflavan]-A(1OMe)-B(1OH, 1OMe)	Isoflavan	Arvensan
0.000	[Dihydrochalcone]-A(1OH, 2OMe)-B(none)	Dihydrochalcone	Dihydroflavokawin B
0.000	[Dihydrochalcone]-A(2OMe)-B(1OH)	Dihydrochalcone	4-Hydroxy-2',4'-dimethoxydihydrochalcone
0.000	[Dihydrochalcone]-A(1OH)-B(2OMe)	Dihydrochalcone	4'-Hydroxy-2,6-dimethoxydihydrochalcone
0.000	[Dihydrochalcone]-A(1OH)-B(2OMe)	Dihydrochalcone	Loureirin A
0.000	[Pterocarpan]-A(1OH, 1OMe)-B(1OH)	Pterocarpan	Melilotocarpan B
0.000	[Pterocarpan]-A(1OH, 1OMe)-B(1OH)	Pterocarpan	Desmocarpin
0.000	[Pterocarpan]-A(1OH)-B(1OH, 1OMe)	Pterocarpan	Nissolin
0.000	[Pterocarpan]-A(1OH)-B(1OH, 1OMe)	Pterocarpan	Vesticarpan
0.000	[Pterocarpan]-A(1OH)-B(1OH, 1OMe)	Pterocarpan	Kushenin
0.000	[Pterocarpan]-A(1OH)-B(1OH, 1OMe)	Pterocarpan	3,8-Dihydroxy-9-methoxypterocarpan
0.000	[Pterocarpan]-A(1OH)-B(1OH, 1OMe)	Pterocarpan	Nissicarpin
0.000	[Pterocarpan]-A(2OH)-B(1OMe)	Pterocarpan	4-Hydroxymedicarpin
0.000	[Aurone]-A(2OH)-B(2OH)	Aurone	Maritimetin
0.000	[Aurone]-A(2OH)-B(2OH)	Aurone	Aureusidin
0.000	[Aurone]-A(3OH)-B(1OH)	Aurone	Helmon
0.000	[beta-Hydroxy(or Oxodihydro)chalcone]-A(1OH, 1OMe)-B(1OH)	beta-Hydroxy(or Oxodihydro)chalcone	Licodione 2'-methyl ether
0.000	[beta-Hydroxy(or Oxodihydro)chalcone]-A(2OH, 1OMe)-B(none)	beta-Hydroxy(or Oxodihydro)chalcone	2',6',beta-Trihydroxy-4'-methoxychalcone
0.000	[beta-Hydroxy(or Oxodihydro)chalcone]-A(2OH, 1OMe)-B(none)	beta-Hydroxy(or Oxodihydro)chalcone	2',4',beta-Trihydroxy-6'-methoxychalcone
0.000	[UBR-type derivative / [2',5']-Benzoquinonyl-type chalcone]-A(2OH)-B(1OH)	UBR-type derivative / [2',5']-Benzoquinonyl-type chalcone	4,4',6'-Trihydroxy-[2',5']-benzoquinonechalcone
0.000	[UBR-type derivative / 2',5'-Dioxo-3'-cyclopentenyl-type Calcone]-A(2OMe)-B(none)	UBR-type derivative / 2',5'-Dioxo-3'-cyclopentenyl-type Calcone	Linderone
0.000	[Dihydrochalcone]-A(2OH)-B(1([@@]-Methylenedioxy))	Dihydrochalcone	2',4'-Dihydroxy-3,4-methylenedioxydihydrochalcone
0.000	[Dihydrochalcone]-A(2OH, 1OMe, 1Methyl)-B(none)	Dihydrochalcone	Myrigalone H
0.000	[Dihydrochalcone]-A(2OH, 1OMe, 1Methyl)-B(none)	Dihydrochalcone	2',6'-Dihydroxy-4'-methoxy-3'-methyldihydrochalcone
0.000	[Dihydrochalcone]-A(3OH, 1Formyl)-B(none)	Dihydrochalcone	3'-Formyl-2',4',6'-trihydroxydihydrochalcone
0.000	[Flavanone]-A(2OH, 1Methyl)-B(1OH)	Flavanone	Poriol
0.000	[3-substituted Flavanone (3-Methyl)]-A(2OH)-B(1OH)	3-substituted Flavanone	3-Methylnaringenin
0.000	[Dihydroflavonol]-A(2OH, 1Methyl)-B(none)	Dihydroflavonol	6-Methypinobanksin
0.000	[Flavan 3-ol]-A(1OMe, 1Methyl)-B(1OH)	Flavan 3-ol	Tupichinol A
0.000	[CCS-type derivative / [3,2']-Epoxymethanoflavan]-A(1OH)-B(2OH)	CCS-type derivative / [3,2']-Epoxymethanoflavan	Peltogynan
0.000	[Flavan]-A(1OMe)-B(1OH, 1OMe)	Flavan	4'-Hydroxy-7,3'-dimethoxyflavan
0.000	[Flavan]-A(1OH, 1Methyl)-B(1OH, 1OMe)	Flavan	7,3'-Dihydroxy-4'-methoxy-8-methylflavan
0.000	[Flavan]-A(1OH, 1Methyl)-B(1OH, 1OMe)	Flavan	7,4'-Dihydroxy-3'-methoxy-8-methylflavan
0.000	[Flavan]-A(1OH, 1OMe)-B(1OMe)	Flavan	7-Hydroxy-5,4'-dimethoxyflavan
0.000	[Flavan]-A(1OH, 1OMe)-B(1OMe)	Flavan	5-Hydroxy-7,4'-dimethoxyflavan
0.000	[Flavan]-A(2OMe)-B(1OH)	Flavan	4'-Hydroxy-5,7-dimethoxyflavan
0.000	[Flavan]-A(1OH, 1OMe, 1Methyl)-B(1OH)	Flavan	5,4'-Dihydroxy-7'-methoxy-8-methylflavan
0.000	[3-DehydroxyAnthocyanidin]-A(2OH)-B(3OH)	3-DehydroxyAnthocyanidin	Tricetinidin
0.000	[UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavan]-A(1OH)-B(1OMe)	UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavan	Claussequinone
0.000	[isoflavene]-A(1OH)-B(2OH, 1OMe)	isoflavene	Sepiol
0.000	[isoflavene]-A(1OH)-B(2OH, 1OMe)	isoflavene	Haginin C
0.000	[Pterocarpan-6a-ol]-A(1OH)-B(1OMe)	Pterocarpan-6a-ol	6a-Hydroxymedicarpin
0.000	[Pterocarpan-6a-ol]-A(1OMe)-B(1OH)	Pterocarpan-6a-ol	6a-Hydroxyisomedicarpin
0.000	[2-Phenylbenzofuran]-A(1OH, 1OMe)-B(1OH, 1OMe)	2-Phenylbenzofuran	Sainfuran
0.000	[2-Phenylbenzofuran]-A(2OMe)-B(2OH)	2-Phenylbenzofuran	2',4'-Dihydroxy-5,6-dimethoxy-2-phenylbenzofuran
0.000	[2-Phenylbenzofuran]-A(1OH)-B(1OH, 2OMe)	2-Phenylbenzofuran	Pterofuran
0.000	[2-Phenylbenzofuran]-A(1OH)-B(1OH, 2OMe)	2-Phenylbenzofuran	Isopterofuran
0.000	[alpha-Methyldeoxybenzoin]-A(1OH, 1OMe)-B(1OMe)	alpha-Methyldeoxybenzoin	2-O-Methylangolensin
0.000	[alpha-Methyldeoxybenzoin]-A(1OH, 1OMe)-B(1OMe)	alpha-Methyldeoxybenzoin	4-O-Methylangolensin
0.000	[4-phenylcoumarin]-A(2OH)-B(2OH)	4-phenylcoumarin	5,7,3',4'-Tetrahydroxy-4-phenylcoumarin
0.000	[[3,2']-Methano-4-phenylchroman (3-OH)]-A(1OH)-B(2OH)	[3,2']-Methano-4-phenylchroman	Brazilin
0.000	[Dalbergiquinol]-A(1OH, 2OMe)-B(1OH)	Dalbergiquinol	Latifolin
0.000	[Dalbergiquinol]-A(1OH, 2OMe)-B(1OH)	Dalbergiquinol	5,3'-Dihydroxy-2,4-dimethoxydalbergiquinol
0.000	[Dalbergiquinol]-A(2OH, 2OMe)-B(none)	Dalbergiquinol	2,5-Dihydroxy-3,4-dimethoxydalbergiquinol