ピーク情報

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pos

Peak #5027 MN MID: SE199_S21_M90

m/z: 373.25849, RT: 81.82, 強度: 14948, ログ強度: 0.77, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 2

DB検索結果: (9 names) 8,8a-Deoxyoleandolide;9S,11,15S-trihydroxy-thrombox-13E-enoic acid;14-Hydroxy-12,13-dihydrosesquiterpineol-14-O-xylopyranoside;Polyrhacitide B;(+)-Polyrhacitide B;14-(3,6-dideoxy-alpha-L-arabino-hexop...

DBごとのヒット数: ALL 8 KG 1 KN 2 LM 5

FlavonoidSearch最大スコア MS2: 0.067, MS3: 0.176

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C20H36O6	372.25119	0.059	8,8a-Deoxyoleandolide	KEGG: C11989 LipidMAPS: LMPK04000030
C20H36O6	372.25119	0.059	9S,11,15S-trihydroxy-thrombox-13E-enoic acid	LipidMAPS: LMFA03030008
C20H36O6	372.25119	0.059	Polyrhacitide B	KNApSAcK: C00040048
C20H36O6	372.25119	0.059	14-Hydroxy-12,13-dihydrosesquiterpineol-14-O-xylopyranoside	KNApSAcK: C00022459
C20H36O6	372.25119	0.059	14-(3,6-dideoxy-alpha-L-arabino-hexopyranosyloxy)-2E-tetradecenoic acid	LipidMAPS: LMFA13040079
C20H36O6	372.25119	0.059	13R-(3,6-dideoxy-alpha-L-arabino-hexopyranosyloxy)-2E-tetradecenoic acid	LipidMAPS: LMFA13040030
C20H36O6	372.25119	0.059	9-oxo-11R,15S,19R-trihydroxy-prostanoic acid	LipidMAPS: LMFA03010165
C20H36O6	372.25119	0.059	9S,11R,15S,19R-tetrahydroxy-13E-prostaenoic acid	LipidMAPS: LMFA03010038

MSnスペクトル情報

Level: 2, プリカーサーm/z: 373.25848

Splash: splash10-0a4i-0129000000-cbba82ea7e23baff80e7

m/z	Int.	NL	Rel.Int.
355.17	4182	18	1000
211.12	971	162	232
127.04	417	246	99
144.96	237	228	56

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.067	[Dihydroflavonol]-A(2OH, 1(C-Prenyl))-B(2OH)	Dihydroflavonol	6-Prenyltaxifolin
0.043	[Isoflavone]-A(2OMe)-B(3OMe)	Isoflavone	6,7,3',4',5'-Pentamethoxyisoflavone
0.043	[Isoflavone]-A(2OMe)-B(3OMe)	Isoflavone	6,7,2',3',4'-Pentamethoxyisoflavone
0.043	[Isoflavone]-A(2OMe)-B(3OMe)	Isoflavone	6,7,2',4',5'-Pentamethoxyisoflavone
0.043	[Isoflavone]-A(2OMe)-B(3OMe)	Isoflavone	Robustigenin methyl ether
0.000	[Flavone]-A(2OMe)-B(3OMe)	Flavone	Prosogerin C
0.000	[Flavone]-A(2OMe)-B(3OMe)	Flavone	7,8,3',4',5'-Pentamethoxyflavone
0.000	[Flavone]-A(2OMe)-B(3OMe)	Flavone	5,6,2',3',6'-Pentamethoxyflavone
0.000	[Flavone]-A(2OMe)-B(3OMe)	Flavone	Cerosilin B
0.000	[Flavone]-A(2OMe)-B(3OMe)	Flavone	5,6,2',3',4'-Pentamethoxyflavone
0.000	[Flavone]-A(2OMe)-B(3OMe)	Flavone	Tricetin 5,7,3',4',5'-pentamethyl ether
0.000	[Flavone]-A(2OMe)-B(3OMe)	Flavone	5,7,2',3',4'-Pentamethoxyflavone
0.000	[Flavone]-A(2OMe)-B(3OMe)	Flavone	5,7,2',4',6'-Pentamethoxyflavone
0.000	[Flavone]-A(3OMe)-B(2OMe)	Flavone	Sinensetin
0.000	[Flavone]-A(3OMe)-B(2OMe)	Flavone	Isosinensetin
0.000	[Flavone]-A(4OMe)-B(1OMe)	Flavone	Tangeretin
0.000	[2'-Hydroxychalcone]-A(2OH)-B(1([2,3:@@]-(5-(p-Hydroxyphenyl)furano)))	2'-Hydroxychalcone	Lophirone E
0.000	[beta-Hydroxy(or Oxodihydro)chalcone (2-OMe)]-A(1([@@]-Methylenedioxy))-B(3OMe)	beta-Hydroxy(or Oxodihydro)chalcone	3',4'-Methylenedioxy-2,4,6,beta-tetramethoxychalcone
0.000	[Flavanone]-A(1OH)-B(1([2,3:@@]-(5-(p-Hydroxyphenyl)furano)))	Flavanone	7-Hydroxy-(5-(p-Hydroxyphenyl)furano)[2,3:4',3'])flavanone
0.000	[Flavanone]-A(2OH, 1((E)-4-Hydroxyprenyl))-B(2OH)	Flavanone	Licoleafol
0.000	[Flavanone]-A(2OH)-B(1OH, 1([2,3:@@]-(6,6-Dimethyl-5-hydroxydihydropyrano)))	Flavanone	Sigmoidin D
0.000	[3-substituted Flavone (3-(3-Methylbutyl))]-A(2OH)-B(3OH)	3-substituted Flavone	Asplenetin
0.000	[Flavonol (3-OMe)]-A(3OMe)-B(1OMe)	Flavonol	Auranetin
0.000	[Flavonol (3-OMe)]-A(2OMe)-B(2OMe)	Flavonol	3,5,7,2',6'-Pentamethoxyflavone
0.000	[Flavonol]-A(2OH, 1(3-hydroxy-3-methylbutyl))-B(1OH)	Flavonol	6-(3-hydroxy-3-methylbutyl)kaempferol
0.000	[Flavonol]-A(2OH, 1(3-hydroxy-3-methylbutyl))-B(1OH)	Flavonol	Noricaritin
0.000	[Flavonol (3-OMe)]-A(2OMe)-B(2OMe)	Flavonol	Quercetin pentamethyl ether
0.000	[Flavonol (3-OMe)]-A(1OH, 1OMe, 1Methyl)-B(2OMe)	Flavonol	2-(3,4-Dimethoxyphenyl)-5-hydroxy-3,7-dimethoxy-6-methyl-4H-1-benzopyran-4-one
0.000	[Flavonol (3-OMe)]-A(1OH, 1OMe, 2Methyl)-B(1OH, 1OMe)	Flavonol	5,4'-Dihydroxy-3,7,3'-trimethoxy-6,8-dimethylflavone
0.000	[Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1([@@]-Methylenedioxy))	Flavonol	Melisimplin
0.000	[Flavonol (3-OMe)]-A(3OMe)-B(1OMe)	Flavonol	Herbacetin pentamethyl ether
0.000	[Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1([@@]-Methylenedioxy))	Flavonol	7-Hydroxy-3,5,8-trimethoxy-3',4'-methylenedioxyflavone
0.000	[Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1([@@]-Methylenedioxy))	Flavonol	5-Hydroxy-3,7,8-trimethoxy-3',4'-methylenedioxyflavone
0.000	[Flavonol (3-OMe)]-A(4OMe)-B(none)	Flavonol	3,5,6,7,8-Pentamethoxyflavone
0.000	[Flavan 3,4-diol]-A(1OH, 1OMe, 1(C-Prenyl))-B(1OH)	Flavan 3,4-diol	3,4,7,4'-Tetrahydroxy-5-methoxy-8-prenylflavan
0.000	[Isoflavone]-A(2OH, 1(3-hydroxy-3-methylbutyl))-B(2OH)	Isoflavone	2,3-Dehydrokievitone hydrate
0.000	[Isoflavanone]-A(2OH, 1((Z)-4-hydroxyprenyl))-B(2OH)	Isoflavanone	Kievitol
0.000	[6-Hydroxydehydrorotenone]-A(3OH)-B(1OH)-C(1(O-Acetyl))	6-Hydroxydehydrorotenone	3,6,9,10,11-Pentahydroxydehydrorotenone 6-O-acetate
0.000	[6-Hydroxydehydrorotenone]-A(1OH, 1OMe)-B(2OMe)	6-Hydroxydehydrorotenone	Stemonal

Level: 3, プリカーサーm/z: 355.18277

Splash: splash10-03di-0790000000-823f667c3d558bac7a62

m/z	Int.	NL	Rel.Int.
211.11	354	144	1000
127.01	150	228	424
109.01	103	246	290
137.00	40	218	113
122.96	37	232	104
294.87	34	60	95
229.17	27	126	76
208.93	27	146	75
111.12	24	244	66
327.19	20	28	55

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.176	[Isoflavanone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OH)	Isoflavanone	Cyclokievitone
0.105	[Pterocarpan]-A(1OH, 1OMe, 1(C-Prenyl))-B(1OH)	Pterocarpan	Edudiol
0.083	[Flavone]-A(2OH, 1(C-Prenyl))-B(2OH)	Flavone	8-C-Prenylluteolin
0.083	[Flavone]-A(2OH, 1(C-Prenyl))-B(2OH)	Flavone	6-C-Prenylluteolin
0.083	[Flavone]-A(2OH, 1(C-Prenyl))-B(2OH)	Flavone	Artocarpesin
0.083	[Chalcone]-A(2OH)-B(1OH, 1OMe, 1(C-Prenyl))	Chalcone	Licoagrochalcone C
0.080	[Isoflavone]-A(2OH)-B(2OH, 1(C-Prenyl))	Isoflavone	Licoisoflavone A
0.065	[Flavonol]-A(2OH)-B(1OH, 1(C-Prenyl))	Flavonol	Isolicoflavonol
0.053	[Flavanone]-A(2OH)-B(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))	Flavanone	Sigmoidin C
0.053	[Flavanone]-A(2OH)-B(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))	Flavanone	Sanggenon F
0.053	[Flavanone]-A(2OH)-B(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))	Flavanone	Sanggenon H
0.053	[Isoflavanone]-A(2OH)-B(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))	Isoflavanone	Licoisoflavanone
0.050	[Pterocarpan]-A(1OH, 1OMe)-B(1OH, 1(C-Prenyl))	Pterocarpan	1-Methoxyphaseollidin
0.040	[Chalcone]-A(1OH, 1(C-Prenyl))-B(2OH, 1OMe)	Chalcone	Licochalcone D
0.038	[Isoflavone]-A(2OH, 1(C-Prenyl))-B(2OH)	Isoflavone	5,7,3',4'-Tetrahydroxy-6-prenylisoflavone
0.038	[Isoflavone]-A(2OH, 1(C-Prenyl))-B(2OH)	Isoflavone	Gancaonin L
0.038	[Isoflavone]-A(2OH, 1(C-Prenyl))-B(2OH)	Isoflavone	Luteone (isoflavone)
0.038	[Isoflavone]-A(2OH, 1(C-Prenyl))-B(2OH)	Isoflavone	2,3-Dehydrokievitone
0.032	[Flavonol]-A(3OH, 1(C-Prenyl))-B(none)	Flavonol	Platanetin
0.031	[Flavonol]-A(2OH, 1(C-Prenyl))-B(1OH)	Flavonol	6-Prenylkaempferol
0.031	[Flavonol]-A(2OH, 1(C-Prenyl))-B(1OH)	Flavonol	Noranhydroicaritin
0.000	[Dihydroflavonol]-A(1OH, 1OMe, 1(C-Prenyl))-B(none)	Dihydroflavonol	Leaserone
0.000	[Dihydroflavonol]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH)	Dihydroflavonol	3,5,4'-Trihydroxy-6'',6''-dimethylpyrano[2'',3'':7,8]flavanone
0.000	[Flavanone]-A(2OH, 1OMe, 1(C-Prenyl))-B(none)	Flavanone	Agrandol
0.000	[Flavanone]-A(2OH, 1OMe, 1(C-Prenyl))-B(none)	Flavanone	Microfolione
0.000	[Flavanone]-A(2OH, 1(C-Prenyl))-B(1OMe)	Flavanone	5,7-Dihydroxy-4'-methoxy-8-C-prenylflavanone
0.000	[Flavanone]-A(1OH, 1OMe, 1(C-Prenyl))-B(1OH)	Flavanone	5,4'-Dihydroxy-7-methoxy-6-C-prenylflavanone
0.000	[Flavanone]-A(1OH, 1OMe, 1(C-Prenyl))-B(1OH)	Flavanone	Isoxanthohumol(Sophora)
0.000	[Flavanone]-A(1OH, 1OMe, 1(C-Prenyl))-B(1OH)	Flavanone	Mundulea flavanone B
0.000	[2'-Hydroxychalcone]-A(2OH, 1OMe, 1(C-Prenyl))-B(1OH)	2'-Hydroxychalcone	Xanthohumol
0.000	[2'-Hydroxychalcone]-A(2OH, 1OMe, 1(C-Prenyl))-B(1OH)	2'-Hydroxychalcone	Xanthogalenol
0.000	[2-Benzyl-2-hydroxydihydrobenzofuran (2,3-OMe)]-A(1([2,3:@@]-Furano))-B(1([@@]-Methylenedioxy))	2-Benzyl-2-hydroxydihydrobenzofuran	Castillene C
0.000	[Chalcone]-A(1OH)-B(1OMe, 1([2,3:@@]-(5-(hydroxyisopropanyl)dihydrofurano)))	Chalcone	Licoagrochalcone D
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1(2-hydroxy-3-methyl-3-butenyl))-B(1OH)	2'-Hydroxychalcone	Xanthoangelol D
0.000	[2'-Hydroxychalcone]-A(1OMe, 1([2,3:@@]-(6,6-Dimethyl-5-hydroxydihydropyrano)))-B(1OH)	2'-Hydroxychalcone	Xanthoangelol H
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(6,6-Dimethyl-5-hydroxydihydropyrano)))-B(none)	2'-Hydroxychalcone	Helichromanochalcone
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(6,6-Dimethyl-5-hydroxydihydropyrano)))-B(none)	2'-Hydroxychalcone	2'-Methoxyhelikrausichalcone
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(6,6-Dimethyl-5-hydroxydihydropyrano)))-B(none)	2'-Hydroxychalcone	6'',6''-Dimethyl-5''-hydroxy-4'',5''-dihydropyrano[2'',3'':2',3']-4'-hydroxy-6'-methoxychalcone
0.000	[2'-Hydroxychalcone]-A(2OH, 1([2,3:@@]-(6-Methyl-4,7-dihydrooxepino)))-B(2OH)	2'-Hydroxychalcone	3',4'-Dihydrooxepino-6'-hydroxybutein
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(6,6-Dimethyldihydropyrano)))-B(1OH)	2'-Hydroxychalcone	Isodehydrocycloxanthohumol hydrate
0.000	[beta-Hydroxy(or Oxodihydro)chalcone]-A(2OH, 1OMe, 1(C-Prenyl))-B(none)	beta-Hydroxy(or Oxodihydro)chalcone	3'-Prenyl-2',6',beta-trihydroxy-4'-methoxychalcone
0.000	[Dihydrochalcone]-A(2OH, 1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(none)	Dihydrochalcone	Flemistrictin D
0.000	[Dihydrochalcone beta-ol (beta-OMe)]-A(1OMe, 1([2,3:@@]-Furano))-B(1([@@]-Methylenedioxy))	Dihydrochalcone beta-ol	Ponganone IX
0.000	[Flavanone]-A(1OH, 1OMe, 1(3-Hydroxy-3-methyl-1-butenyl))-B(none)	Flavanone	Tephroleocarpin A
0.000	[Flavanone]-A(2OH, 1(C-Prenyl), 1Methyl)-B(1OH)	Flavanone	5,7,4'-Trihydroxy-6-methyl-8-prenylflavanone
0.000	[Flavanone]-A(2OH, 1(C-Prenyl), 1Methyl)-B(1OH)	Flavanone	5,7,4'-Trihydroxy-8-methyl-6-prenylflavanone
0.000	[Flavanone]-A(1OH, 1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(2OH)	Flavanone	Velloeriodictyol
0.000	[Flavanone]-A(1OH, 1OMe, 1([2,3:@@]-Furano))-B(1([@@]-Methylenedioxy))	Flavanone	5-Hydroxy-6-methoxy-3',4'-methylenedioxyfurano[2'',3'':7,8]flavanone
0.000	[Flavone]-A(2OH, 1(2-hydroxy-3-methyl-3-butenyl))-B(1OH)	Flavone	Dinklagin C
0.000	[Flavone]-A(2OH, 1(2-hydroxy-3-methyl-3-butenyl))-B(1OH)	Flavone	Ephedroidin
0.000	[Flavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethyl-5-hydroxydihydropyrano)))-B(1OH)	Flavone	Dinklagin B
0.000	[3-substituted Flavone (3-C-Prenyl)]-A(2OH)-B(2OH)	3-substituted Flavone	Albanin A
0.000	[Dihydroflavonol]-A(1OH, 1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(1OH)	Dihydroflavonol	Shuterol
0.000	[Dihydroflavonol]-A(1OH, 1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(1OH)	Dihydroflavonol	3,5,4'-Trihydroxy-4'',5'',dihydro-5''-isopropenylfurano[2'',3'':7,8]flavanone
0.000	[Dihydroflavonol (3-OMe)]-A(2OMe, 1([2,3:@@]-Furano))-B(none)	Dihydroflavonol	3,5,6-Trimethoxy-[2'',3'':7,8]furanoflavanone
0.000	[Flavan 3-ol]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH)	Flavan 3-ol	7,8-(2,2-Dimethylpyrano)-3,4'-dihydroxy-5-methoxyflavan
0.000	[Flavan 4-ol]-A(2OMe, 1(C-Prenyl))-B(none)	Flavan 4-ol	Tephrowatsin A
0.000	[Flavan 3,4-diol]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(none)	Flavan 3,4-diol	Quercetol A
0.000	[CCS-type derivative / [2,3,4:5,4a,4]-(6-Carboxypyrano)anthocyanidin]-A(1OH)-B(2OH)	CCS-type derivative / [2,3,4:5,4a,4]-(6-Carboxypyrano)anthocyanidin	5-Carboxypyranocyanidin
0.000	[Isoflavone]-A(2OH, 1((Z)-4-hydroxyprenyl))-B(1OH)	Isoflavone	Hydroxywighteone
0.000	[Isoflavone]-A(2OH, 1((Z)-4-hydroxyprenyl))-B(1OH)	Isoflavone	Gancaonin C
0.000	[Isoflavone]-A(1OH, 1([2,3:@@]-(5-(hydroxyisopropanyl)dihydrofurano)))-B(1OH)	Isoflavone	Erythrinin C
0.000	[Isoflavone]-A(2OH)-B(1([2,3:@@]-(5-(hydroxyisopropanyl)dihydrofurano)))	Isoflavone	Lupinisoflavone C
0.000	[Isoflavone]-A(2OH)-B(2OH, 1(1,1-Dimethylallyl))	Isoflavone	Fremontin
0.000	[Isoflavanone]-A(1([2,3:@@]-Furano))-B(1OH, 1OMe, 1([@@]-Methylenedioxy))	Isoflavanone	Erosenone
0.000	[Isoflavanone]-A(1([2,3:@@]-Furano))-B(3OMe)	Isoflavanone	Nepseudin
0.000	[Isoflavanone]-A(1([2,3:@@]-Furano))-B(3OMe)	Isoflavanone	Ambonone
0.000	[Isoflavan]-A(1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OH, 1OMe)	Isoflavan	3'-Methoxyglabridin
0.000	[Isoflavan]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OH)	Isoflavan	Neorauflavane
0.000	[Pterocarpan-6a-ol]-A(1OH)-B(1OMe, 1(C-Prenyl))	Pterocarpan-6a-ol	Cristacarpin
0.000	[Pterocarpan-6a-ol]-A(1OMe, 1(C-Prenyl))-B(1OH)	Pterocarpan-6a-ol	Glyceollin IV
0.000	[Pterocarpan-6a-ol]-A(1([2,3:@@]-(5-(Hydroxyisopropanyl)furano)))-B(1OH)	Pterocarpan-6a-ol	Glyceofuran
0.000	[Rotenoid 12-ol]-A(1([2,3:@@]-Furano))-B(2OMe)	Rotenoid 12-ol	Elliptinol
0.000	[3-Hydroxy-2-phenylbenzofuran (3-OMe)]-A(1OH, 1(C-Prenyl))-B(1OH, 1OMe)	3-Hydroxy-2-phenylbenzofuran	Ambofuranol
0.000	[2-Phenylbenzofuran]-A(2OMe, 1(C-Prenyl))-B(2OH)	2-Phenylbenzofuran	Gancaonin I

Level: 3, プリカーサーm/z: 211.02536

Splash: splash10-074j-4900000000-3180a8f2baa104731cf2

m/z	Int.	NL	Rel.Int.
123.21	11	88	1000
97.16	8	114	764
108.78	6	102	551
110.91	6	100	542
137.14	3	74	310
80.89	3	130	242
67.01	3	144	242
193.03	3	18	242