ピーク情報

＜香辛料類＞にんにくおろし

pos

Peak #3781 MN MID: SE122_S170761_M90

m/z: 329.14948, RT: 37.85, 強度: 39538, ログ強度: 0.84, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 13

DB検索結果: (8 names) Phe-Tyr;Tyrosyl-Phenylalanine;(+)-Megistosarcimine;Dichotomine D;Dictyoquinazol B;(2S)-2-Amino-3-[4-[(2S)-2-amino-3-phenylpropanoyl]oxyphenyl]propanoic acid;(2S)-2-Amino-3-[3-[(2S)-2-amino-3-phenylpro...

DBごとのヒット数: ALL 8 KN 3 HM 5

FlavonoidSearch最大スコア MS2: 0.048, MS3: -

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C18H20O4N2	328.14231	-0.331	Phe-Tyr	HMDB: HMDB0029007, HMDB0256384
C18H20O4N2	328.14231	-0.331	Tyrosyl-Phenylalanine	HMDB: HMDB0029112
C18H20O4N2	328.14231	-0.331	(+)-Megistosarcimine	KNApSAcK: C00026357
C18H20O4N2	328.14231	-0.331	Dichotomine D	KNApSAcK: C00026655
C18H20O4N2	328.14231	-0.331	Dictyoquinazol B	HMDB: HMDB0040441 KNApSAcK: C00045853
C18H20O4N2	328.14231	-0.331	(2S)-2-Amino-3-[4-[(2S)-2-amino-3-phenylpropanoyl]oxyphenyl]propanoic acid	HMDB: HMDB0257556
C18H20O4N2	328.14231	-0.331	(2S)-2-Amino-3-[3-[(2S)-2-amino-3-phenylpropanoyl]oxyphenyl]propanoic acid	HMDB: HMDB0257687
C18H20O4N2	328.14231	-0.331	Bis(3-methoxysalicylidene)ethylenediamine	HMDB: HMDB0252126

MSnスペクトル情報

Level: 2, プリカーサーm/z: 329.14886

Splash: splash10-000i-0903000000-d300b7f75eb1e72b5da3

m/z	Int.	NL	Rel.Int.
135.99	158950	193	1000
312.09	74020	17	465
166.06	24132	163	151
206.06	11755	123	73
118.93	8559	210	53
283.05	8371	46	52

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.048	[Flavonol]-A(3OMe)-B(none)	Flavonol	3-Hydroxy-5,7,8-trimethoxyflavone
0.048	[Flavonol]-A(2OMe)-B(1OMe)	Flavonol	3-Hydroxy-7,8,4'-trimethoxyflavone
0.048	[Flavonol]-A(1OMe)-B(2OMe)	Flavonol	Fisetin 7,3',4'-trimethyl ether
0.040	[Isoflavone]-A(1OMe)-B(1OH, 2OMe)	Isoflavone	2'-Hydroxy-7,3',4'-trimethoxyisoflavone
0.040	[Isoflavone]-A(1OH, 2OMe)-B(1OMe)	Isoflavone	5-Methoxyafrormosin
0.040	[Isoflavone]-A(1OH, 2OMe)-B(1OMe)	Isoflavone	7,4'-Di-O-methyltectorigenin
0.040	[Isoflavone]-A(1OH, 2OMe)-B(1OMe)	Isoflavone	Iso-5-methoxyafrormosin
0.040	[Isoflavone]-A(1OH)-B(3OMe)	Isoflavone	7-Hydroxy-2',4',5'-trimethoxyisoflavone
0.040	[Isoflavone]-A(1OH, 1OMe)-B(2OMe)	Isoflavone	Cladrastin
0.040	[Isoflavone]-A(1OH, 1OMe)-B(2OMe)	Isoflavone	7-Hydroxy-8,3',4'-trimethoxyisoflavone
0.000	[Flavone]-A(1OH, 1OMe)-B(2OMe)	Flavone	Grantionin
0.000	[Flavone]-A(1OH, 1OMe)-B(2OMe)	Flavone	Zapotinin
0.000	[Flavone]-A(1OH, 1OMe)-B(2OMe)	Flavone	5-Hydroxy-7,2',5'-trimethoxyflavone
0.000	[Flavone]-A(1OH, 1OMe)-B(2OMe)	Flavone	5-Hydroxy-7,2',6'-trimethoxyflavone
0.000	[Flavone]-A(1OH, 1OMe)-B(2OMe)	Flavone	Luteolin 5,3',4'-trimethyl ether
0.000	[Flavone]-A(1OH, 1OMe)-B(2OMe)	Flavone	Luteolin 7,3',4'-trimethyl ether
0.000	[Flavone]-A(1OH, 1OMe)-B(2OMe)	Flavone	Noratocarpetin 7,2',4'-trimethyl ether
0.000	[Flavone]-A(1OH, 2OMe)-B(1OMe)	Flavone	6-Hydroxy-5,7,4'-trimethoxyflavone
0.000	[Flavone]-A(1OH, 2OMe)-B(1OMe)	Flavone	Salvigenin
0.000	[Flavone]-A(1OH, 2OMe)-B(1OMe)	Flavone	7-Hydroxy-5,8,2'-trimethoxyflavone
0.000	[Flavone]-A(1OH, 2OMe)-B(1OMe)	Flavone	Andrographin
0.000	[Flavone]-A(1OH, 2OMe)-B(1OMe)	Flavone	Isoscutellarein 7,8,4'-trimethyl ether
0.000	[Flavone]-A(1OH, 3OMe)-B(none)	Flavone	8-Hydroxy-5,6,7-trimethoxyflavone
0.000	[Flavone]-A(1OH, 3OMe)-B(none)	Flavone	Alnetin
0.000	[Chalcone]-A(4OMe)-B(none)	Chalcone	2',3',4',6'-Tetramethoxychalcone
0.000	[Aurone]-A(1OH, 1OMe, 1Methyl)-B(1OH, 1OMe)	Aurone	6,3'-Dihydroxy-4,4'-dimethoxy-5-methylaurone
0.000	[Aurone]-A(1OH, 2OMe)-B(1OMe)	Aurone	5-Hydroxy-4,6,4'-trimethoxyaurone
0.000	[2'-Hydroxychalcone]-A(1OH, 2OMe)-B(1([@@]-Methylenedioxy))	2'-Hydroxychalcone	Tephrone
0.000	[beta-Hydroxy(or Oxodihydro)chalcone]-A(2OH, 1OMe, 1Formyl, 1Methyl)-B(none)	beta-Hydroxy(or Oxodihydro)chalcone	3'-Formyl-2',6',beta-trihydroxy-4'-methoxy-5'-methylchalcone
0.000	[beta-Hydroxy(or Oxodihydro)chalcone]-A(2OMe)-B(1([@@]-Methylenedioxy))	beta-Hydroxy(or Oxodihydro)chalcone	Milletenone
0.000	[UBR-type derivative / 2',4'-Dioxo-6'-cyclohexenyl-type Chalcone]-A(1OH, 4Methyl)-B(1OH)	UBR-type derivative / 2',4'-Dioxo-6'-cyclohexenyl-type Chalcone	2-Hydroxy-7,8-dehydrograndiflorone
0.000	[Flavanone]-A(1OMe)-B(1OMe, 1([@@]-Methylenedioxy))	Flavanone	7,2'-Dimethoxy-4',5'-methylenedioxyflavanone
0.000	[Flavanone]-A(2OMe)-B(1([@@]-Methylenedioxy))	Flavanone	6,7-Dimethoxy-3',4'-methylenedioxyflavanone
0.000	[Flavanone]-A(2OMe, 1Hydroxymethyl, 1Methyl)-B(none)	Flavanone	5-O-Methylleridol
0.000	[Flavanone]-A(1OH, 1OMe, 2Methyl)-B(1OMe)	Flavanone	5-Hydroxy-7,4'-dimethoxy-6,8-di-C-methylflavanone
0.000	[Flavanone]-A(2OMe)-B(1([@@]-Methylenedioxy))	Flavanone	5,7-Dimethoxy-3',4'-methylenedioxyflavanone
0.000	[Flavanone]-A(1OMe, 1([@@]-Methylenedioxy))-B(1OMe)	Flavanone	Betagarin
0.000	[Flavanone]-A(1OMe, 1([@@]-Methylenedioxy))-B(1OMe)	Flavanone	5,4'-Dimethoxy-6,7-methylenedioxyflavanone
0.000	[Flavone]-A(1OH, 1OMe, 2Methyl)-B(2OH)	Flavone	5,3',4'-Trihydroxy-7-methoxy-6,8-dimethylflavone
0.000	[Flavone]-A(2OH, 1([@@]-Methylenedioxy))-B(1OMe)	Flavone	Kanzakiflavone 1
0.000	[Dihydroflavonol]-A(2OH)-B(none)-C(1(O-Propionyl))	Dihydroflavonol	Pinobanksin 3-O-propionate
0.000	[Dihydroflavonol]-A(1OH, 1OMe)-B(none)-C(1(O-Acetyl))	Dihydroflavonol	3,5-Dihydroxy-7-methoxyflavanone 3-O-acetate
0.000	[Dihydroflavonol]-A(2OH, 1Methyl)-B(none)-C(1(O-Acetyl))	Dihydroflavonol	6-Methypinobanksin 3-O-acetate
0.000	[Flavonol (3-OMe)]-A(2OMe)-B(1OH)	Flavonol	Kaempferol 3,5,7-trimethyl ether
0.000	[Flavonol (3-OMe)]-A(1OH, 1OMe)-B(1OMe)	Flavonol	Kaempferol 3,7,4'-trimethyl ether
0.000	[Flavonol (3-OMe)]-A(1OH, 1OMe, 1Methyl)-B(1OH)	Flavonol	8-Demethyllatifolin
0.000	[Flavonol]-A(1OH, 1OMe, 2Methyl)-B(1OH)	Flavonol	6,8-Di-C-methylkaempferol 7-methyl ether
0.000	[Flavonol (3-OMe)]-A(2OH, 2Methyl)-B(1OH)	Flavonol	5,7-Dihydroxy-2-(4-hydroxyphenyl)-3-methoxy-6,8-dimethyl-4H-1-benzopyran-4-one
0.000	[Flavonol (3-OMe)]-A(1OH, 2OMe)-B(none)	Flavonol	Alnustin
0.000	[Flavonol (3-OMe)]-A(1OH, 1([@@]-Methylenedioxy))-B(1OH)	Flavonol	5,4'-Dihydrox-3-methoxy-6,7-methylenedioxyflavone
0.000	[Flavonol (3-OMe)]-A(1OH, 2OMe)-B(none)	Flavonol	7-Hydroxy-3,5,8-trimethoxyflavone
0.000	[Flavonol (3-OMe)]-A(1OH, 2OMe)-B(none)	Flavonol	Methylgnaphaliin
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe, 1Methyl)-B(none)	Flavonol	Platanin 3,7-dimethyl ether
0.000	[CCS-type derivative / [3,2']-Epoxymethanoflavan 4-ol (4-OMe)]-A(1OH)-B(1([@@]-Methylenedioxy))	CCS-type derivative / [3,2']-Epoxymethanoflavan 4-ol	4-O-Methyl-3',4'-methylenedioxymopanan-4alpha-ol
0.000	[Isoflavone]-A(1OH, 1([@@]-Methylenedioxy))-B(1OH, 1OMe)	Isoflavone	5,3'-Dihydroxy-2'-methoxy-6,7-methylenedioxyisoflavone
0.000	[Isoflavone]-A(2OH, 1OMe)-B(1([@@]-Methylenedioxy))	Isoflavone	Dalspinin
0.000	[Isoflavone]-A(1OH, 1([@@]-Methylenedioxy))-B(1OH, 1OMe)	Isoflavone	5,4'-Trihydroxy-3'-methoxy-6,7-methylenedioxyisoflavone
0.000	[Isoflavanone]-A(2OMe)-B(1([@@]-Methylenedioxy))	Isoflavanone	6,7-Dimethoxy-3',4'-methylenedioxyisoflavanone
0.000	[Pterocarpan]-A(2OMe)-B(1([@@]-Methylenedioxy))	Pterocarpan	2-Methoxypterocarpin
0.000	[Pterocarpan]-A(2OMe)-B(1([@@]-Methylenedioxy))	Pterocarpan	4-Methoxypterocarpin
0.000	[Pterocarpan-6a-ol]-A(1([@@]-Methylenedioxy))-B(1([@@]-Methylenedioxy))	Pterocarpan-6a-ol	Acanthocarpan
0.000	[Pterocarpan-6-ol (3-OMe)]-A(1OMe)-B(1([@@]-Methylenedioxy))	Pterocarpan-6-ol	6-Methoxypterocarpin
0.000	[UBR-type derivative / [9,10]-Benzoquinonyl-type Pterocarpene]-A(1OH, 1OMe)-B(1OMe)	UBR-type derivative / [9,10]-Benzoquinonyl-type Pterocarpene	Bryaquinone
0.000	[Pterocarpene]-A(1OMe)-B(1OH, 2OMe)	Pterocarpene	Bryacarpene 2
0.000	[Pterocarpene]-A(1OH, 1OMe)-B(2OMe)	Pterocarpene	Bryacarpene 4
0.000	[4-phenylcoumarin]-A(2OMe)-B(1OH, 1OMe)	4-phenylcoumarin	3'-Hydroxy-5,7,4'-trimethoxy-4-phenylcoumarin
0.000	[4-phenylcoumarin]-A(1OH, 2OMe)-B(1OMe)	4-phenylcoumarin	Exostemin

Level: 3, プリカーサーm/z: 312.08530

Splash: splash10-0a4i-0090000000-deacc4c8efc39ec45734

m/z	Int.	NL	Rel.Int.
206.13	49042	106	1000
284.15	14174	28	289
106.97	3793	205	77
121.05	2472	191	50

Level: 3, プリカーサーm/z: 135.98653

Splash: splash10-014i-0900000000-f965e688492d7bc8fc63

m/z	Int.	NL	Rel.Int.
118.98	29795	17	1000
135.92	3060	0	102
90.89	1939	45	65