ピーク情報

＜香辛料類＞にんにくおろし

pos

Peak #3128 MN MID: SE122_S170761_M90

m/z: 435.14310, RT: 34.56, 強度: 51805, ログ強度: 0.96, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 2

DB検索結果: (15 names) Euchretin H;Artoindonesianin D;Haplopappin;7-Demethylartonol E;Artelastoxanthone;Kraussianone 4;Artobiloxanthone;Formosanatin D;Euchretin G;Haplopappin A;5'-Hydroxycudraflavone A;Cycloartobiloxanthone...

DBごとのヒット数: ALL 13 KN 12 HM 1

FlavonoidSearch最大スコア MS2: 0.154, MS3: 0.125

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C25H22O7	434.13655	-1.691	Euchretin H	KNApSAcK: C00019414
C25H22O7	434.13655	-1.691	Artoindonesianin D	KNApSAcK: C00029729
C25H22O7	434.13655	-1.691	Haplopappin	FlavonoidViewer: FL5FDBNC0001 KNApSAcK: C00005036 LipidMAPS: LMPK12112693
C25H22O7	434.13655	-1.691	7-Demethylartonol E	KNApSAcK: C00029588
C25H22O7	434.13655	-1.691	Kraussianone 4	KNApSAcK: C00019087
C25H22O7	434.13655	-1.691	Artobiloxanthone	FlavonoidViewer: FL3FALNR0009 HMDB: HMDB0034021 KNApSAcK: C00004104 LipidMAPS: LMPK12110939
C25H22O7	434.13655	-1.691	Euchretin G	KNApSAcK: C00019170
C25H22O7	434.13655	-1.691	Formosanatin D	KNApSAcK: C00019168
C25H22O7	434.13655	-1.691	Haplopappin A	FlavonoidViewer: FL5FCBNC0001 KNApSAcK: C00005037 LipidMAPS: LMPK12112594
C25H22O7	434.13655	-1.691	5'-Hydroxycudraflavone A	KNApSAcK: C00029567
C25H22O7	434.13655	-1.691	Cycloartobiloxanthone	FlavonoidViewer: FL3FRNND0001 KNApSAcK: C00013485 LipidMAPS: LMPK12111514
C25H22O7	434.13655	-1.691	Gnetumontanin C	KNApSAcK: C00030414
C18H22O5N6S	434.13724	-3.270	6-(D-alpha-(3-Guanylureido)phenylacetamido)penicillanic acid	HMDB: HMDB0247826

MSnスペクトル情報

Level: 2, プリカーサーm/z: 435.14270

Splash: splash10-0gb9-0093600000-92d9292be005944be519

m/z	Int.	NL	Rel.Int.
417.15	52426	18	1000
251.04	39836	184	759
306.07	21863	129	417
288.06	17771	147	338
270.04	15046	165	286
399.15	3939	36	75

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.154	[2'-Hydroxychalcone]-A(1OH, 3OMe)-B(4OMe)	2'-Hydroxychalcone	6'-Hydroxy-2,3,4,5,2',3',4'-heptamethoxychalcone
0.133	[Flavanone]-A(3OMe)-B(4OMe)	Flavanone	5,6,7,2',3',4',5'-Heptamethoxyflavanone
0.063	[Flavanone]-A(4OMe)-B(3OMe)	Flavanone	5,6,7,8,3',4',5'-Heptamethoxyflavanone
0.000	[Flavone]-A(1OH, 3OMe)-B(1OH, 3OMe)	Flavone	Agehoustin D
0.000	[beta-Hydroxy(or Oxodihydro)chalcone]-A(3OMe)-B(4OMe)	beta-Hydroxy(or Oxodihydro)chalcone	beta-Hydroxy-2,3,4,5,2',4',5'-heptamethoxychalcone
0.000	[Flavanone]-A(1OH, 1(C-Galactosyl))-B(2OH)	Flavanone	Palodulcin B
0.000	[Flavanone]-A(2OH, 1(C-Glu))-B(1OH)	Flavanone	Hemiphloin
0.000	[Flavanone]-A(2OH, 1(C-Glu))-B(1OH)	Flavanone	Isohemiphloin
0.000	[Flavone]-A(2OH)-B(1([2,3:@@]-(5-Hydroxymethyl-6-(p-hydroxyphenyl)-dihydro[1,4]dioxinyl)))	Flavone	Sinaticin
0.000	[CCS-type derivative / [2',3]-Prenyloxidoflavone]-A(2OH, 1(3-Methyl-1-butenyl))-B(1OMe)	CCS-type derivative / [2',3]-Prenyloxidoflavone	Cycloartocarpin A
0.000	[CCS-type derivative / [2',3]-Prenyloxidoflavone]-A(1OH, 1OMe, 1(C-Prenyl))-B(1OH)	CCS-type derivative / [2',3]-Prenyloxidoflavone	Cycloartocarpin
0.000	[CCS-type derivative / [2',3]-Isopropenylethanoflavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(3OH)	CCS-type derivative / [2',3]-Isopropenylethanoflavone	Artobiloxanthone
0.000	[CCS-type derivative / [2,2a,5:3',2',3]-7,7-Dimethyltetrahydroisobenzofuranoflavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OH)	CCS-type derivative / [2,2a,5:3',2',3]-7,7-Dimethyltetrahydroisobenzofuranoflavone	Cycloartobiloxanthone
0.000	[Flavonol (3-OMe)]-A(1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OH)	Flavonol	Macaflavone II
0.000	[Flavonol (3-OMe)]-A(2OH, 1(1-(p-Hydroxyphenyl)ethyl))-B(1OMe)	Flavonol	Haplopappin
0.000	[Flavonol]-A(1OH, 1OMe, 1(1-(p-Hydroxyphenyl)ethyl))-B(1OMe)	Flavonol	Haplopappin A
0.000	[Flavonol (3-OMe)]-A(4OMe)-B(2OH, 1OMe)	Flavonol	3',5'-Dihydroxy-3,5,6,7,8,4'-hexamethoxyflavone
0.000	[Flavonol (3-OMe)]-A(1OH, 3OMe)-B(1OH, 2OMe)	Flavonol	Digicitrin
0.000	[Flavonol (3-OMe)]-A(2OH, 2OMe)-B(3OMe)	Flavonol	5,7-Dihydroxy-3,6,8,3',4',5'-hexamethoxyflavone
0.000	[Flavonol (3-OMe)]-A(1OH, 3OMe)-B(1OH, 2OMe)	Flavonol	5,2'-Dihydroxy-3,6,7,8,4',5'-hexamethoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH, 2OMe)-B(3OMe)	Flavonol	5,7-Dihydroxy-3,6,8,2',4',5'-hexamethoxyflavone
0.000	[Isoflavone]-A(1([2,3:@@]-(6,6-Dimethyl-5-hydroxydihydropyrano)))-B(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))	Isoflavone	Mundulone
0.000	[Isoflavone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH, 1OMe)	Isoflavone	Auriculin
0.000	[4-Hydroxy-3-phenylcoumarin]-A(1OMe, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH)	4-Hydroxy-3-phenylcoumarin	Scandenin
0.000	[4-Hydroxy-3-phenylcoumarin]-A(1OMe, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH)	4-Hydroxy-3-phenylcoumarin	Lonchocarpic acid

Level: 3, プリカーサーm/z: 417.15079

Splash: splash10-00dr-0091000000-bb35e8e31e12165fe170

m/z	Int.	NL	Rel.Int.
270.09	24406	147	1000
288.01	14773	129	605
399.16	7203	18	295

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.125	[Flavone]-A(1OH, 1(C-Glu))-B(1OH)	Flavone	Bayin
0.125	[Flavone]-A(2OH, 1(C-Glu))-B(none)	Flavone	Chrysin 6-C-beta-D-glucopyranoside
0.125	[Flavone]-A(2OH, 1(C-Glu))-B(none)	Flavone	Chrysin 8-C-beta-D-glucopyranoside
0.125	[Isoflavone]-A(1OH, 1(C-Glu))-B(1OH)	Isoflavone	8-Glucosyldaidzein
0.050	[Isoflavone]-A(1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))	Isoflavone	Munetone
0.000	[Flavone]-A(1OH, 1OMe, 1(C-Arabinosyl))-B(1OH)	Flavone	Isomolludistin
0.000	[Flavone]-A(1OH, 1OMe, 1(C-Arabinosyl))-B(1OH)	Flavone	Molludistin
0.000	[Flavone]-A(2OH, 1(C-Rhamnosyl))-B(1OH)	Flavone	Isofurcatain
0.000	[Flavone]-A(4OMe)-B(1OMe, 1([@@]-Methylenedioxy))	Flavone	Eupalestin
0.000	[Flavonol]-A(1OH, 1([2,3:@@]-(4-(p-Hydroxyphenyl)-6-oxodihydropyrano)))-B(1OH)	Flavonol	Calomelanol D
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(1OH, 1(3-hydroxy-3-methylbutyl))	Flavonol	Aliarin
0.000	[Flavonol]-A(1OH, 2OMe)-B(1OH, 1(4-hydroxy-3-methylbutyl))	Flavonol	3,7-Dihydroxy-2-[4-hydroxy-3-(4-hydroxy-3-methylbutyl)phenyl]-5,6-dimethoxy-4H-1-benzopyran-4-one
0.000	[Flavonol (3-OMe)]-A(4OMe)-B(1([@@]-Methylenedioxy))	Flavonol	Melibentin
0.000	[Flavonol (3-OMe)]-A(2OMe, 1([@@]-Methylenedioxy))-B(2OMe)	Flavonol	Melicophyllin
0.000	[6-Hydroxyrotenone]-A(1OH, 1OMe)-B(2OMe)-C(1(O-Acetyl))	6-Hydroxyrotenone	Dihydrostemonal 6-O-acetate
0.000	[4-phenylcoumarin]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)), 1Tiglyl)-B(none)	4-phenylcoumarin	Apetalolide

Level: 3, プリカーサーm/z: 251.03748

Splash: splash10-00di-0920000000-46a7e95df881b51a433f

m/z	Int.	NL	Rel.Int.
121.99	14110	129	1000
234.01	2917	17	206
129.98	1761	121	124
232.95	1335	18	94