ピーク情報
|
＜調味料類＞（だし類）昆布だし
pos
|
| Peak #1376 MN MID: SE119_S170201_M90 |
| m/z: 283.15392, RT: 70.56, 強度: 3130, ログ強度: 0.14, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 2 |
| DB検索結果: (66 names) (+)-Cheimonophyllal;Cheimonophyllal;Lactarolide B;12-Hydroxyalliacolide;11-Hydroxyalliacolide;Strobilol A;(+)-Strobilol A;Pestafolide A;(-)-Pestafolide A;Wasabidienone B0;6-Deoxypseudoanisatin;11,13-D... |
| DBごとのヒット数: ALL 52 KG 3 KN 42 HM 3 LM 4 |
| FlavonoidSearch最大スコア MS2: 0.095, MS3: 0.133 |
DB検索結果
ppm
| 組成式 | 分子量 | 誤差(Δppm） | 候補化合物名（代表で最短名を記載） | 化合物ID |
|---|---|---|---|---|
| C15H22O5 | 282.14672 | -0.278 | (+)-Cheimonophyllal | KNApSAcK: C00016699 |
| C15H22O5 | 282.14672 | -0.278 | Lactarolide B | KNApSAcK: C00021543 |
| C15H22O5 | 282.14672 | -0.278 | 12-Hydroxyalliacolide | KNApSAcK: C00020207 |
| C15H22O5 | 282.14672 | -0.278 | 11-Hydroxyalliacolide | KNApSAcK: C00020206 |
| C15H22O5 | 282.14672 | -0.278 | Pestafolide A | KNApSAcK: C00039969 |
| C15H22O5 | 282.14672 | -0.278 | Wasabidienone B0 | KNApSAcK: C00046962 |
| C15H22O5 | 282.14672 | -0.278 | Strobilol A | KNApSAcK: C00034698 |
| C15H22O5 | 282.14672 | -0.278 | 6-Deoxypseudoanisatin | KNApSAcK: C00021775 |
| C15H22O5 | 282.14672 | -0.278 | 11,13-Dihydrosilostachyin | KNApSAcK: C00021195 |
| C15H22O5 | 282.14672 | -0.278 | 3,6-Dideoxy-10-hydroxypseudoanisatin | KNApSAcK: C00036519 |
| C15H22O5 | 282.14672 | -0.278 | Pseudomajucin | KNApSAcK: C00047338 |
| C15H22O5 | 282.14672 | -0.278 | 1alpha-Hydroxyalliacolide | KNApSAcK: C00020205 |
| C15H22O5 | 282.14672 | -0.278 | G1 | KNApSAcK: C00000290, C00000291 |
| C15H22O5 | 282.14672 | -0.278 | 6alpha-Hydroxypulchellin | KNApSAcK: C00021169 |
| C15H22O5 | 282.14672 | -0.278 | [3S-(3R*,3aS*,4R*,7S*,10E,11aS*)]-3a,4,5,6,7,8,9,11a-octahydro-7-hydroperoxy-4-hydroxy-3,10-dimethyl-6-methylene-Cyclodeca[b]furan-2(3H)-one | KNApSAcK: C00011774 |
| C15H22O5 | 282.14672 | -0.278 | (1R,2R,2'E)-2-(5'-methoxy-5'-oxo-2-penten-1-yl)-3-oxo-cyclopentane acetic acid ethyl ester | LipidMAPS: LMFA02020214 |
| C15H22O5 | 282.14672 | -0.278 | 5-(3-carboxypropyl)-3,4-dimethyl-furan-2-yl-pentanoic acid | LipidMAPS: LMFA01150063 |
| C15H22O5 | 282.14672 | -0.278 | 6-O-Methylpapyracon B | KNApSAcK: C00016225, C00016226 |
| C15H22O5 | 282.14672 | -0.278 | Hysterone B | KNApSAcK: C00036125 |
| C15H22O5 | 282.14672 | -0.278 | Strobilactone B | KNApSAcK: C00048153 |
| C15H22O5 | 282.14672 | -0.278 | Zedoarolide B | KNApSAcK: C00032549 |
| C15H22O5 | 282.14672 | -0.278 | (1R,2R,2'E)-2-(5'-ethoxy-5'-oxo-2-penten-1-yl)-3-oxo-cyclopentane acetic acid methyl ester | LipidMAPS: LMFA02020213 |
| C15H22O5 | 282.14672 | -0.278 | Spiropinguisanin | KNApSAcK: C00021346 |
| C15H22O5 | 282.14672 | -0.278 | Bisbynin | HMDB: HMDB0041324 KNApSAcK: C00053002 |
| C15H22O5 | 282.14672 | -0.278 | Biennin A | KNApSAcK: C00021182 |
| C15H22O5 | 282.14672 | -0.278 | Hymenoxon | HMDB: HMDB0253305 KEGG: C09482 KNApSAcK: C00003304, C00021188, C00021189 |
| C15H22O5 | 282.14672 | -0.278 | Vestolide | KNApSAcK: C00020873 |
| C15H22O5 | 282.14672 | -0.278 | Oxyhumulinic acid | HMDB: HMDB0038989 |
| C15H22O5 | 282.14672 | -0.278 | dihydrophaseic acid | HMDB: HMDB0038660, HMDB0038661, [-1]HMDB0304338 KEGG: C15971 KNApSAcK: C00033819, C00053080 LipidMAPS: LMPR0103050005, LMPR0103050007 |
| C15H22O5 | 282.14672 | -0.278 | 5-(2-carboxyethyl)-3,4-dimethyl-furan-2-yl-hexanoic acid | LipidMAPS: LMFA01150061 |
| C15H22O5 | 282.14672 | -0.278 | Lactarorufin B | KNApSAcK: C00021546 |
| C15H22O5 | 282.14672 | -0.278 | 3beta,10beta-Epoxy-1alpha,3beta-dihydroxy-4Z-germacren-12,6alpha-olide | KNApSAcK: C00011754 |
| C15H22O5 | 282.14672 | -0.278 | [1S-[1alpha(E),5beta,6beta]]-5-hydroxy-3-(hydroxymethyl)-6-(1-methylethyl)-2-oxo-3-cyclohexen-1-yl ester | KNApSAcK: C00010965 |
| C15H22O5 | 282.14672 | -0.278 | 11-O-Debenzoyltashironin | KNApSAcK: C00045511 |
| C15H22O5 | 282.14672 | -0.278 | Octyl gallate | HMDB: HMDB0033375 |
| C15H22O5 | 282.14672 | -0.278 | Hydroxysydonic acid | KNApSAcK: C00011666 |
| C15H22O5 | 282.14672 | -0.278 | Mairetolide H | KNApSAcK: C00041648 |
| C15H22O5 | 282.14672 | -0.278 | Illudin H | KNApSAcK: C00049726 |
| C15H22O5 | 282.14672 | -0.278 | Wasabidienone B1 | KNApSAcK: C00046963 |
| C15H22O5 | 282.14672 | -0.278 | Decipienin H | KNApSAcK: C00013092 |
| C15H22O5 | 282.14672 | -0.278 | Cynaratriol | HMDB: HMDB0034983 KNApSAcK: C00020855 |
| C15H22O5 | 282.14672 | -0.278 | Strobilol D | KNApSAcK: C00034701 |
| C15H22O5 | 282.14672 | -0.278 | Merrillianone | KNApSAcK: C00046133 |
| C15H22O5 | 282.14672 | -0.278 | Decipienin E | KNApSAcK: C00013095 |
| C15H22O5 | 282.14672 | -0.278 | Porellapinguisanolide | KNApSAcK: C00021343 |
| C15H22O5 | 282.14672 | -0.278 | Anguidol | HMDB: HMDB0035846 KNApSAcK: C00012642 |
| C15H22O5 | 282.14672 | -0.278 | Hysterone C | KNApSAcK: C00031863 |
| C15H22O5 | 282.14672 | -0.278 | Qing Hau Sau | HMDB: HMDB0242246 KEGG: C09538 KNApSAcK: C00003359 LipidMAPS: LMPR0103190003 |
| C15H22O5 | 282.14672 | -0.278 | Carolenalol | KNApSAcK: C00020955 |
| C15H22O5 | 282.14672 | -0.278 | Artabsinolide C | HMDB: HMDB0034941 KNApSAcK: C00020869, C00020871 |
| C15H22O5 | 282.14672 | -0.278 | Lactarolide A | KNApSAcK: C00021541 |
| C15H22O5 | 282.14672 | -0.278 | Pisumic acid | HMDB: HMDB0039241 |
MSnスペクトル情報
| Level: 2, プリカーサーm/z: 283.15378 |
| Splash: splash10-00di-0090000000-95987746579282902aca |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 223.01 | 4563 | 60 | 1000 |
| 205.10 | 1650 | 78 | 361 |
| 265.03 | 1093 | 18 | 239 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.095 | [Isoflavone]-A(1OMe)-B(1OMe) | Isoflavone | 7,4'-Di-O-methyldaidzein |
| 0.095 | [Isoflavone]-A(2OMe)-B(none) | Isoflavone | 5,7-Dimethoxyisoflavone |
| 0.000 | [Flavone]-A(2OMe)-B(none) | Flavone | 7,8-Dimethoxyflavone |
| 0.000 | [Flavone]-A(2OMe)-B(none) | Flavone | 5,6-Dimethoxyflavone |
| 0.000 | [Flavone]-A(1OMe)-B(1OMe) | Flavone | 6,3'-Dimethoxyflavone |
| 0.000 | [Flavone]-A(2OMe)-B(none) | Flavone | chrysin 5,7-dimethyl ether |
| 0.000 | [Coumestan]-A(1OH)-B(1OMe) | Coumestan | 9-O-Methylcoumestrol |
| 0.000 | [Aurone]-A(1OH, 1([@@]-Methylenedioxy))-B(none) | Aurone | 4,5-Methylenedioxy-6-hydroxyaurone |
| 0.000 | [UBR-type derivative / 2'-Oxocyclohexa-4',6'-dienyl-type Chalcone]-A(1OH, 3Methyl)-B(none) | UBR-type derivative / 2'-Oxocyclohexa-4',6'-dienyl-type Chalcone | Ohobanin |
| 0.000 | [UBR-type derivative / 2'-Oxo-3'-enyl-0-hydroxy-type Chalcone]-A(1([2,3:@@]-(5-Oxotetrahydrofurano)))-B(none) | UBR-type derivative / 2'-Oxo-3'-enyl-0-hydroxy-type Chalcone | Cryptocaryone |
| 0.000 | [Dihydrochalcone alpha-ol]-A(1OH, 1([2,3:@@]-Furano))-B(none) | Dihydrochalcone alpha-ol | Castillene E |
| 0.000 | [Flavone]-A(1OH, 1Methyl)-B(1OMe) | Flavone | Saltillin |
| 0.000 | [Flavone]-A(1OH, 1OMe, 1Methyl)-B(none) | Flavone | 6-Methyltectochrysin |
| 0.000 | [Flavone]-A(2OH, 2Methyl)-B(none) | Flavone | Matteuorien |
| 0.000 | [Flavonol (3-OMe)]-A(1OMe)-B(none) | Flavonol | 3,7-Dimethoxyflavone |
| 0.000 | [Isoflavone]-A(1OH)-B(1OH, 1Formyl) | Isoflavone | Corylinal |
| 0.000 | [Isoflavone]-A(1OH)-B(1([@@]-Methylenedioxy)) | Isoflavone | Pseudobaptigenin |
| 0.000 | [Pterocarpene]-A(1OMe)-B(1OMe) | Pterocarpene | Anhydrovariabilin |
| 0.000 | [Pterocarpene]-A(1OH)-B(1([@@]-Methylenedioxy)) | Pterocarpene | 3-Hydroxy-8,9-methylenedioxypterocarp-6a-ene |
| 0.000 | [Coumestan]-A(1Methyl)-B(2OH) | Coumestan | 8,9-Dihydroxy-1-methylcoumestan |
| 0.000 | [4-phenylcoumarin]-A(2OMe)-B(none) | 4-phenylcoumarin | Methyldalbergin |
| Level: 3, プリカーサーm/z: 223.01288 |
| Splash: splash10-003r-0900000000-cf50b4db2d087fa0bd42 |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 181.08 | 842 | 42 | 1000 |
| 125.01 | 592 | 98 | 702 |
| 205.00 | 157 | 18 | 186 |
| 165.01 | 114 | 58 | 135 |
| 106.97 | 111 | 116 | 131 |
| 163.03 | 77 | 60 | 91 |
| 139.04 | 73 | 84 | 87 |
| 158.96 | 69 | 64 | 81 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.133 | [Flavone]-A(none)-B(none) | Flavone | Flavone |