ピーク情報

＜牛乳及び乳製品＞（チーズ類）プロセスチーズ

pos

Peak #1435 MN MID: SE112_S130401_M90

m/z: 373.17150, RT: 12.39, 強度: 8988, ログ強度: 0.03, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 7

DB検索結果: Clavamycin F

DBごとのヒット数: ALL 1 KG 1

FlavonoidSearch最大スコア MS2: 0.027, MS3: 0.091

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C15H24O7N4	372.16450	-0.736	Clavamycin F	KEGG: C17395 KNApSAcK: C00017766

MSnスペクトル情報

Level: 2, プリカーサーm/z: 373.17136

Splash: splash10-0a6r-0629000000-4326ad51c5dd81670554

m/z	Int.	NL	Rel.Int.
355.23	2139	18	1000
147.00	1252	226	585
130.08	987	243	461
356.41	932	17	435
129.01	684	244	319
328.29	606	45	283
226.14	596	147	278
174.95	506	198	236
338.34	478	35	223
337.32	393	36	183
311.26	356	62	166
257.91	325	115	151
227.22	227	146	105
318.68	165	54	77
199.16	147	174	68
209.12	124	164	57
367.54	118	6	55
208.51	112	165	52

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.034	[Dihydroflavonol]-A(2OH, 1(C-Prenyl))-B(2OH)	Dihydroflavonol	6-Prenyltaxifolin
0.027	[Isoflavone]-A(2OMe)-B(3OMe)	Isoflavone	6,7,3',4',5'-Pentamethoxyisoflavone
0.027	[Isoflavone]-A(2OMe)-B(3OMe)	Isoflavone	6,7,2',3',4'-Pentamethoxyisoflavone
0.027	[Isoflavone]-A(2OMe)-B(3OMe)	Isoflavone	6,7,2',4',5'-Pentamethoxyisoflavone
0.027	[Isoflavone]-A(2OMe)-B(3OMe)	Isoflavone	Robustigenin methyl ether
0.000	[Flavone]-A(2OMe)-B(3OMe)	Flavone	Prosogerin C
0.000	[Flavone]-A(2OMe)-B(3OMe)	Flavone	7,8,3',4',5'-Pentamethoxyflavone
0.000	[Flavone]-A(2OMe)-B(3OMe)	Flavone	5,6,2',3',6'-Pentamethoxyflavone
0.000	[Flavone]-A(2OMe)-B(3OMe)	Flavone	Cerosilin B
0.000	[Flavone]-A(2OMe)-B(3OMe)	Flavone	5,6,2',3',4'-Pentamethoxyflavone
0.000	[Flavone]-A(2OMe)-B(3OMe)	Flavone	Tricetin 5,7,3',4',5'-pentamethyl ether
0.000	[Flavone]-A(2OMe)-B(3OMe)	Flavone	5,7,2',3',4'-Pentamethoxyflavone
0.000	[Flavone]-A(2OMe)-B(3OMe)	Flavone	5,7,2',4',6'-Pentamethoxyflavone
0.000	[Flavone]-A(3OMe)-B(2OMe)	Flavone	Sinensetin
0.000	[Flavone]-A(3OMe)-B(2OMe)	Flavone	Isosinensetin
0.000	[Flavone]-A(4OMe)-B(1OMe)	Flavone	Tangeretin
0.000	[2'-Hydroxychalcone]-A(2OH)-B(1([2,3:@@]-(5-(p-Hydroxyphenyl)furano)))	2'-Hydroxychalcone	Lophirone E
0.000	[beta-Hydroxy(or Oxodihydro)chalcone (2-OMe)]-A(1([@@]-Methylenedioxy))-B(3OMe)	beta-Hydroxy(or Oxodihydro)chalcone	3',4'-Methylenedioxy-2,4,6,beta-tetramethoxychalcone
0.000	[Flavanone]-A(1OH)-B(1([2,3:@@]-(5-(p-Hydroxyphenyl)furano)))	Flavanone	7-Hydroxy-(5-(p-Hydroxyphenyl)furano)[2,3:4',3'])flavanone
0.000	[Flavanone]-A(2OH, 1((E)-4-Hydroxyprenyl))-B(2OH)	Flavanone	Licoleafol
0.000	[Flavanone]-A(2OH)-B(1OH, 1([2,3:@@]-(6,6-Dimethyl-5-hydroxydihydropyrano)))	Flavanone	Sigmoidin D
0.000	[3-substituted Flavone (3-(3-Methylbutyl))]-A(2OH)-B(3OH)	3-substituted Flavone	Asplenetin
0.000	[Flavonol (3-OMe)]-A(3OMe)-B(1OMe)	Flavonol	Auranetin
0.000	[Flavonol (3-OMe)]-A(2OMe)-B(2OMe)	Flavonol	3,5,7,2',6'-Pentamethoxyflavone
0.000	[Flavonol]-A(2OH, 1(3-hydroxy-3-methylbutyl))-B(1OH)	Flavonol	6-(3-hydroxy-3-methylbutyl)kaempferol
0.000	[Flavonol]-A(2OH, 1(3-hydroxy-3-methylbutyl))-B(1OH)	Flavonol	Noricaritin
0.000	[Flavonol (3-OMe)]-A(2OMe)-B(2OMe)	Flavonol	Quercetin pentamethyl ether
0.000	[Flavonol (3-OMe)]-A(1OH, 1OMe, 1Methyl)-B(2OMe)	Flavonol	2-(3,4-Dimethoxyphenyl)-5-hydroxy-3,7-dimethoxy-6-methyl-4H-1-benzopyran-4-one
0.000	[Flavonol (3-OMe)]-A(1OH, 1OMe, 2Methyl)-B(1OH, 1OMe)	Flavonol	5,4'-Dihydroxy-3,7,3'-trimethoxy-6,8-dimethylflavone
0.000	[Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1([@@]-Methylenedioxy))	Flavonol	Melisimplin
0.000	[Flavonol (3-OMe)]-A(3OMe)-B(1OMe)	Flavonol	Herbacetin pentamethyl ether
0.000	[Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1([@@]-Methylenedioxy))	Flavonol	7-Hydroxy-3,5,8-trimethoxy-3',4'-methylenedioxyflavone
0.000	[Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1([@@]-Methylenedioxy))	Flavonol	5-Hydroxy-3,7,8-trimethoxy-3',4'-methylenedioxyflavone
0.000	[Flavonol (3-OMe)]-A(4OMe)-B(none)	Flavonol	3,5,6,7,8-Pentamethoxyflavone
0.000	[Flavan 3,4-diol]-A(1OH, 1OMe, 1(C-Prenyl))-B(1OH)	Flavan 3,4-diol	3,4,7,4'-Tetrahydroxy-5-methoxy-8-prenylflavan
0.000	[Isoflavone]-A(2OH, 1(3-hydroxy-3-methylbutyl))-B(2OH)	Isoflavone	2,3-Dehydrokievitone hydrate
0.000	[Isoflavanone]-A(2OH, 1((Z)-4-hydroxyprenyl))-B(2OH)	Isoflavanone	Kievitol
0.000	[6-Hydroxydehydrorotenone]-A(3OH)-B(1OH)-C(1(O-Acetyl))	6-Hydroxydehydrorotenone	3,6,9,10,11-Pentahydroxydehydrorotenone 6-O-acetate
0.000	[6-Hydroxydehydrorotenone]-A(1OH, 1OMe)-B(2OMe)	6-Hydroxydehydrorotenone	Stemonal

Level: 3, プリカーサーm/z: 147.04303

Splash: splash10-001i-0900000000-81816ac5055f60f10da8

m/z	Int.	NL	Rel.Int.
130.01	275	17	1000
129.27	40	18	145

Level: 3, プリカーサーm/z: 355.21634

Splash: splash10-01t9-0098000000-68c9597e1f216222fd16

m/z	Int.	NL	Rel.Int.
226.21	116	129	1000
337.27	57	18	492
310.22	55	45	472
311.17	52	44	445
291.43	31	64	270
275.00	31	80	266
320.30	31	35	265
345.77	30	9	262
459.38	29	-104	249
309.50	22	46	192
128.83	20	226	173
209.29	18	146	157
264.30	17	91	148
284.23	17	71	146
227.23	17	128	143
254.15	17	101	143
338.27	8	17	71
328.45	8	27	67
292.11	6	63	54

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.091	[Isoflavone]-A(2OH, 1(C-Prenyl))-B(2OH)	Isoflavone	5,7,3',4'-Tetrahydroxy-6-prenylisoflavone
0.091	[Isoflavone]-A(2OH, 1(C-Prenyl))-B(2OH)	Isoflavone	Gancaonin L
0.091	[Isoflavone]-A(2OH, 1(C-Prenyl))-B(2OH)	Isoflavone	Luteone (isoflavone)
0.091	[Isoflavone]-A(2OH, 1(C-Prenyl))-B(2OH)	Isoflavone	2,3-Dehydrokievitone
0.091	[Isoflavone]-A(2OH)-B(2OH, 1(C-Prenyl))	Isoflavone	Licoisoflavone A
0.079	[Flavonol]-A(3OH, 1(C-Prenyl))-B(none)	Flavonol	Platanetin
0.077	[Flavonol]-A(2OH)-B(1OH, 1(C-Prenyl))	Flavonol	Isolicoflavonol
0.077	[Flavonol]-A(2OH, 1(C-Prenyl))-B(1OH)	Flavonol	6-Prenylkaempferol
0.077	[Flavonol]-A(2OH, 1(C-Prenyl))-B(1OH)	Flavonol	Noranhydroicaritin
0.074	[Isoflavanone]-A(2OH)-B(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))	Isoflavanone	Licoisoflavanone
0.074	[Isoflavanone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OH)	Isoflavanone	Cyclokievitone
0.069	[Dihydroflavonol]-A(1OH, 1OMe, 1(C-Prenyl))-B(none)	Dihydroflavonol	Leaserone
0.061	[Flavone]-A(2OH, 1(C-Prenyl))-B(2OH)	Flavone	8-C-Prenylluteolin
0.061	[Flavone]-A(2OH, 1(C-Prenyl))-B(2OH)	Flavone	6-C-Prenylluteolin
0.061	[Flavone]-A(2OH, 1(C-Prenyl))-B(2OH)	Flavone	Artocarpesin
0.038	[Dihydroflavonol]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH)	Dihydroflavonol	3,5,4'-Trihydroxy-6'',6''-dimethylpyrano[2'',3'':7,8]flavanone
0.036	[Flavanone]-A(2OH)-B(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))	Flavanone	Sigmoidin C
0.036	[Flavanone]-A(2OH)-B(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))	Flavanone	Sanggenon F
0.036	[Flavanone]-A(2OH)-B(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))	Flavanone	Sanggenon H
0.031	[2'-Hydroxychalcone]-A(2OH, 1OMe, 1(C-Prenyl))-B(1OH)	2'-Hydroxychalcone	Xanthohumol
0.031	[2'-Hydroxychalcone]-A(2OH, 1OMe, 1(C-Prenyl))-B(1OH)	2'-Hydroxychalcone	Xanthogalenol
0.030	[Flavanone]-A(2OH, 1OMe, 1(C-Prenyl))-B(none)	Flavanone	Agrandol
0.030	[Flavanone]-A(2OH, 1OMe, 1(C-Prenyl))-B(none)	Flavanone	Microfolione
0.030	[Flavanone]-A(2OH, 1(C-Prenyl))-B(1OMe)	Flavanone	5,7-Dihydroxy-4'-methoxy-8-C-prenylflavanone
0.030	[Flavanone]-A(1OH, 1OMe, 1(C-Prenyl))-B(1OH)	Flavanone	5,4'-Dihydroxy-7-methoxy-6-C-prenylflavanone
0.030	[Flavanone]-A(1OH, 1OMe, 1(C-Prenyl))-B(1OH)	Flavanone	Isoxanthohumol(Sophora)
0.030	[Flavanone]-A(1OH, 1OMe, 1(C-Prenyl))-B(1OH)	Flavanone	Mundulea flavanone B
0.029	[Chalcone]-A(2OH)-B(1OH, 1OMe, 1(C-Prenyl))	Chalcone	Licoagrochalcone C
0.029	[Chalcone]-A(1OH, 1(C-Prenyl))-B(2OH, 1OMe)	Chalcone	Licochalcone D
0.000	[Pterocarpan]-A(1OH, 1OMe)-B(1OH, 1(C-Prenyl))	Pterocarpan	1-Methoxyphaseollidin
0.000	[Pterocarpan]-A(1OH, 1OMe, 1(C-Prenyl))-B(1OH)	Pterocarpan	Edudiol
0.000	[2-Benzyl-2-hydroxydihydrobenzofuran (2,3-OMe)]-A(1([2,3:@@]-Furano))-B(1([@@]-Methylenedioxy))	2-Benzyl-2-hydroxydihydrobenzofuran	Castillene C
0.000	[Chalcone]-A(1OH)-B(1OMe, 1([2,3:@@]-(5-(hydroxyisopropanyl)dihydrofurano)))	Chalcone	Licoagrochalcone D
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1(2-hydroxy-3-methyl-3-butenyl))-B(1OH)	2'-Hydroxychalcone	Xanthoangelol D
0.000	[2'-Hydroxychalcone]-A(1OMe, 1([2,3:@@]-(6,6-Dimethyl-5-hydroxydihydropyrano)))-B(1OH)	2'-Hydroxychalcone	Xanthoangelol H
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(6,6-Dimethyl-5-hydroxydihydropyrano)))-B(none)	2'-Hydroxychalcone	Helichromanochalcone
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(6,6-Dimethyl-5-hydroxydihydropyrano)))-B(none)	2'-Hydroxychalcone	2'-Methoxyhelikrausichalcone
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(6,6-Dimethyl-5-hydroxydihydropyrano)))-B(none)	2'-Hydroxychalcone	6'',6''-Dimethyl-5''-hydroxy-4'',5''-dihydropyrano[2'',3'':2',3']-4'-hydroxy-6'-methoxychalcone
0.000	[2'-Hydroxychalcone]-A(2OH, 1([2,3:@@]-(6-Methyl-4,7-dihydrooxepino)))-B(2OH)	2'-Hydroxychalcone	3',4'-Dihydrooxepino-6'-hydroxybutein
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(6,6-Dimethyldihydropyrano)))-B(1OH)	2'-Hydroxychalcone	Isodehydrocycloxanthohumol hydrate
0.000	[beta-Hydroxy(or Oxodihydro)chalcone]-A(2OH, 1OMe, 1(C-Prenyl))-B(none)	beta-Hydroxy(or Oxodihydro)chalcone	3'-Prenyl-2',6',beta-trihydroxy-4'-methoxychalcone
0.000	[Dihydrochalcone]-A(2OH, 1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(none)	Dihydrochalcone	Flemistrictin D
0.000	[Dihydrochalcone beta-ol (beta-OMe)]-A(1OMe, 1([2,3:@@]-Furano))-B(1([@@]-Methylenedioxy))	Dihydrochalcone beta-ol	Ponganone IX
0.000	[Flavanone]-A(1OH, 1OMe, 1(3-Hydroxy-3-methyl-1-butenyl))-B(none)	Flavanone	Tephroleocarpin A
0.000	[Flavanone]-A(2OH, 1(C-Prenyl), 1Methyl)-B(1OH)	Flavanone	5,7,4'-Trihydroxy-6-methyl-8-prenylflavanone
0.000	[Flavanone]-A(2OH, 1(C-Prenyl), 1Methyl)-B(1OH)	Flavanone	5,7,4'-Trihydroxy-8-methyl-6-prenylflavanone
0.000	[Flavanone]-A(1OH, 1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(2OH)	Flavanone	Velloeriodictyol
0.000	[Flavanone]-A(1OH, 1OMe, 1([2,3:@@]-Furano))-B(1([@@]-Methylenedioxy))	Flavanone	5-Hydroxy-6-methoxy-3',4'-methylenedioxyfurano[2'',3'':7,8]flavanone
0.000	[Flavone]-A(2OH, 1(2-hydroxy-3-methyl-3-butenyl))-B(1OH)	Flavone	Dinklagin C
0.000	[Flavone]-A(2OH, 1(2-hydroxy-3-methyl-3-butenyl))-B(1OH)	Flavone	Ephedroidin
0.000	[Flavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethyl-5-hydroxydihydropyrano)))-B(1OH)	Flavone	Dinklagin B
0.000	[3-substituted Flavone (3-C-Prenyl)]-A(2OH)-B(2OH)	3-substituted Flavone	Albanin A
0.000	[Dihydroflavonol]-A(1OH, 1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(1OH)	Dihydroflavonol	Shuterol
0.000	[Dihydroflavonol]-A(1OH, 1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(1OH)	Dihydroflavonol	3,5,4'-Trihydroxy-4'',5'',dihydro-5''-isopropenylfurano[2'',3'':7,8]flavanone
0.000	[Dihydroflavonol (3-OMe)]-A(2OMe, 1([2,3:@@]-Furano))-B(none)	Dihydroflavonol	3,5,6-Trimethoxy-[2'',3'':7,8]furanoflavanone
0.000	[Flavan 3-ol]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH)	Flavan 3-ol	7,8-(2,2-Dimethylpyrano)-3,4'-dihydroxy-5-methoxyflavan
0.000	[Flavan 4-ol]-A(2OMe, 1(C-Prenyl))-B(none)	Flavan 4-ol	Tephrowatsin A
0.000	[Flavan 3,4-diol]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(none)	Flavan 3,4-diol	Quercetol A
0.000	[CCS-type derivative / [2,3,4:5,4a,4]-(6-Carboxypyrano)anthocyanidin]-A(1OH)-B(2OH)	CCS-type derivative / [2,3,4:5,4a,4]-(6-Carboxypyrano)anthocyanidin	5-Carboxypyranocyanidin
0.000	[Isoflavone]-A(2OH, 1((Z)-4-hydroxyprenyl))-B(1OH)	Isoflavone	Hydroxywighteone
0.000	[Isoflavone]-A(2OH, 1((Z)-4-hydroxyprenyl))-B(1OH)	Isoflavone	Gancaonin C
0.000	[Isoflavone]-A(1OH, 1([2,3:@@]-(5-(hydroxyisopropanyl)dihydrofurano)))-B(1OH)	Isoflavone	Erythrinin C
0.000	[Isoflavone]-A(2OH)-B(1([2,3:@@]-(5-(hydroxyisopropanyl)dihydrofurano)))	Isoflavone	Lupinisoflavone C
0.000	[Isoflavone]-A(2OH)-B(2OH, 1(1,1-Dimethylallyl))	Isoflavone	Fremontin
0.000	[Isoflavanone]-A(1([2,3:@@]-Furano))-B(1OH, 1OMe, 1([@@]-Methylenedioxy))	Isoflavanone	Erosenone
0.000	[Isoflavanone]-A(1([2,3:@@]-Furano))-B(3OMe)	Isoflavanone	Nepseudin
0.000	[Isoflavanone]-A(1([2,3:@@]-Furano))-B(3OMe)	Isoflavanone	Ambonone
0.000	[Isoflavan]-A(1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OH, 1OMe)	Isoflavan	3'-Methoxyglabridin
0.000	[Isoflavan]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OH)	Isoflavan	Neorauflavane
0.000	[Pterocarpan-6a-ol]-A(1OH)-B(1OMe, 1(C-Prenyl))	Pterocarpan-6a-ol	Cristacarpin
0.000	[Pterocarpan-6a-ol]-A(1OMe, 1(C-Prenyl))-B(1OH)	Pterocarpan-6a-ol	Glyceollin IV
0.000	[Pterocarpan-6a-ol]-A(1([2,3:@@]-(5-(Hydroxyisopropanyl)furano)))-B(1OH)	Pterocarpan-6a-ol	Glyceofuran
0.000	[Rotenoid 12-ol]-A(1([2,3:@@]-Furano))-B(2OMe)	Rotenoid 12-ol	Elliptinol
0.000	[3-Hydroxy-2-phenylbenzofuran (3-OMe)]-A(1OH, 1(C-Prenyl))-B(1OH, 1OMe)	3-Hydroxy-2-phenylbenzofuran	Ambofuranol
0.000	[2-Phenylbenzofuran]-A(2OMe, 1(C-Prenyl))-B(2OH)	2-Phenylbenzofuran	Gancaonin I