ピーク情報

＜牛乳及び乳製品＞（チーズ類）ナチュラルチーズパルメザン

pos

Peak #20045 MN MID: SE112_S130381_M90

m/z: 305.21427, RT: 78.61, 強度: 3727, ログ強度: -0.31, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 4

DB検索結果:

DBごとのヒット数:

FlavonoidSearch最大スコア MS2: 0.250, MS3: 0.102

MSnスペクトル情報

Level: 2, プリカーサーm/z: 305.21426

Splash: splash10-000i-0090000000-f3c34c02f6a9f389a308

m/z	Int.	NL	Rel.Int.
287.20	9600	18	1000

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.250	[Dihydroflavonol]-A(3OH)-B(1OH)	Dihydroflavonol	3,5,7,8,4'-Pentahydroxyflavanone
0.250	[Dihydroflavonol]-A(2OH)-B(2OH)	Dihydroflavonol	8-Hydroxyfustin
0.250	[Dihydroflavonol]-A(2OH)-B(2OH)	Dihydroflavonol	3,5,7,2',5'-Pentahydroxyflavanone
0.250	[Dihydroflavonol]-A(2OH)-B(2OH)	Dihydroflavonol	3,5,7,2',6'-Pentahydroxyflavanone
0.250	[Dihydroflavonol]-A(1OH)-B(3OH)	Dihydroflavonol	Dihydrorobinetin
0.200	[Flavan 3-ol]-A(1OH, 1OMe)-B(2OH)	Flavan 3-ol	Catechin-7-methyl ether
0.200	[Flavan 3-ol]-A(2OH)-B(1OH, 1OMe)	Flavan 3-ol	Symplocosidin
0.200	[Flavan 3-ol]-A(2OH)-B(1OH, 1OMe)	Flavan 3-ol	Catechin 4'-methyl ether
0.200	[Flavan 3-ol]-A(2OH)-B(1OH, 1OMe)	Flavan 3-ol	Catechin-3'-methyl ether
0.143	[Dihydroflavonol]-A(2OH)-B(2OH)	Dihydroflavonol	Taxifolin
0.143	[Dihydroflavonol]-A(2OH)-B(2OH)	Dihydroflavonol	Dihydromorin
0.125	[Dihydroflavonol]-A(2OH)-B(2OH)	Dihydroflavonol	3,5,7,3',5'-Pentahydroxyflavanone
0.111	[2'-Hydroxychalcone]-A(3OH)-B(3OH)	2'-Hydroxychalcone	3,4,5,2',4',6'-Hexahydroxychalcone
0.100	[Flavanone]-A(2OH)-B(3OH)	Flavanone	5,7,3',4',5'-Pentahydroxyflavanone
0.091	[Flavone]-A(1([2,3:@@]-(6,6-Dimethylpyrano)))-B(none)	Flavone	6'',6''-Dimethylpyrano[2'',3'':7,8]flavone
0.000	[Isoflavan]-A(2OH)-B(2OH, 1OMe)	Isoflavan	3',8-Dihydroxyvestitol
0.000	[Auronol]-A(2OH)-B(2OH)	Auronol	Nigrescin
0.000	[Auronol]-A(2OH)-B(2OH)	Auronol	Alphitonin
0.000	[beta-Hydroxy(or Oxodihydro)chalcone]-A(3OH)-B(2OH)	beta-Hydroxy(or Oxodihydro)chalcone	3,4,2',4',6',beta-Hexahydroxychalcone
0.000	[Dihydrochalcone alpha-ol]-A(1OH, 1OMe)-B(2OH)	Dihydrochalcone alpha-ol	3,4,4',alpha-Tetrahydroxy-2'-methoxydihydrochalcone
0.000	[Dihydrochalcone beta-ol]-A(2OH, 1OMe)-B(1OH)	Dihydrochalcone beta-ol	4,2',4',beta-Tetrahydroxy-6'-methoxydihydrochalcone
0.000	[2-Hydroxyflavanone]-A(2OH)-B(2OH)	2-Hydroxyflavanone	2,5,7,3',4'-Pentahydroxyflavanone
0.000	[Flavone]-A(2OH, 1Cl)-B(1OH)	Flavone	6-Chloroapigenin
0.000	[Flavan 3,4-diol]-A(1OH, 1OMe)-B(1OH)	Flavan 3,4-diol	Ortin-4alpha-ol 8-methyl ether

Level: 3, プリカーサーm/z: 287.20233

Splash: splash10-00xr-0950000000-9ecc966b34e30096979a

m/z	Int.	NL	Rel.Int.
269.33	261	18	1000
121.07	240	166	921
203.15	172	84	657
161.14	157	126	600
147.08	140	140	535
123.03	136	164	521
138.86	118	148	452
136.92	110	150	422
259.21	99	28	380
221.28	91	66	350
223.21	78	64	298
179.10	63	108	240
227.36	62	60	239
96.94	62	190	239
149.25	50	138	190
133.19	46	154	176
110.83	42	176	162
135.12	41	152	156
124.92	40	162	153
108.81	37	178	143

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.310	[Flavonol]-A(1OH)-B(2OH)	Flavonol	Fisetin
0.226	[Flavonol]-A(2OH)-B(1OH)	Flavonol	3,7,8,4'-Tetrahydroxyflavone
0.226	[Flavonol]-A(2OH)-B(1OH)	Flavonol	Kaempferol
0.194	[Flavonol]-A(2OH)-B(1OH)	Flavonol	Datiscetin
0.160	[Isoflavanone]-A(2OH)-B(1OMe)	Isoflavanone	Dihydrobiochanin A
0.160	[Isoflavanone]-A(1OH)-B(1OH, 1OMe)	Isoflavanone	3'-Hydroxydihydroformononetin
0.160	[Isoflavanone]-A(1OH)-B(1OH, 1OMe)	Isoflavanone	Vestitone
0.148	[Chalcone]-A(1OH)-B(2OH, 1OMe)	Chalcone	Licochalcone B
0.148	[Flavanone]-A(2OH)-B(1OMe)	Flavanone	5,6-Dihydroxy-4'-methoxyflavanone
0.148	[Flavanone]-A(2OH)-B(1OMe)	Flavanone	Isosakuranetin
0.148	[Flavanone]-A(1OH, 1OMe)-B(1OH)	Flavanone	Dihydroechioidinin
0.148	[Flavanone]-A(1OH, 1OMe)-B(1OH)	Flavanone	Naringenin 5-methyl ether
0.148	[Flavanone]-A(1OH, 1OMe)-B(1OH)	Flavanone	Sakuranetin
0.143	[Isoflavone]-A(2OH)-B(2OH)	Isoflavone	7,8,2',4'-Tetrahydroxyisoflavone
0.143	[Isoflavone]-A(2OH)-B(2OH)	Isoflavone	Orobol
0.143	[Isoflavone]-A(2OH)-B(2OH)	Isoflavone	2'-Hydroxygenistein
0.143	[Isoflavone]-A(1OH)-B(3OH)	Isoflavone	Baptigenin
0.121	[Flavonol]-A(3OH)-B(none)	Flavonol	6-Hydroxygalangin
0.121	[Flavonol]-A(3OH)-B(none)	Flavonol	8-Hydroxygalangin
0.115	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OH)	2'-Hydroxychalcone	Kukulkanin B
0.115	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OH)	2'-Hydroxychalcone	2,2',6'-Trihydroxy-4'-methoxychalcone
0.115	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OH)	2'-Hydroxychalcone	2,2',4'-Trihydroxy-6'-methoxychalcone
0.115	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OH)	2'-Hydroxychalcone	Neosakuranetin
0.115	[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1OH)	2'-Hydroxychalcone	Helichrysetin
0.115	[2'-Hydroxychalcone]-A(3OH)-B(1OMe)	2'-Hydroxychalcone	2',4',6'-Trihydroxy-4-methoxychalcone
0.115	[2'-Hydroxychalcone]-A(2OH)-B(1OH, 1OMe)	2'-Hydroxychalcone	Homobutein
0.115	[2'-Hydroxychalcone]-A(2OH)-B(1OH, 1OMe)	2'-Hydroxychalcone	3,2',4'-Trihydroxy-4-methoxychalcone
0.107	[Flavone]-A(1OH)-B(3OH)	Flavone	7,3',4',5'-Tetrahydroxyflavone
0.107	[Flavone]-A(2OH)-B(2OH)	Flavone	5,7,2',5'-Tetrahydroxyflavone
0.107	[Flavone]-A(2OH)-B(2OH)	Flavone	5,7,2',6'-Tetrahydroxyflavone
0.107	[Flavone]-A(2OH)-B(2OH)	Flavone	5,7,2',3'-Tetrahydroxyflavone
0.107	[Flavone]-A(2OH)-B(2OH)	Flavone	Luteolin
0.107	[Flavone]-A(2OH)-B(2OH)	Flavone	Norartocarpetin
0.107	[Flavone]-A(3OH)-B(1OH)	Flavone	5,6,7,2'-Tetrahydroxyflavone
0.107	[Flavone]-A(3OH)-B(1OH)	Flavone	Scutellarein
0.107	[Flavone]-A(3OH)-B(1OH)	Flavone	5,7,8,2'-Tetrahydroxyflavone
0.107	[Flavone]-A(3OH)-B(1OH)	Flavone	Isoscutellarein
0.107	[Anthocyanidin]-A(2OH)-B(2OH)	Anthocyanidin	Cyanidin
0.107	[Anthocyanidin]-A(3OH)-B(1OH)	Anthocyanidin	Aurantinidin
0.103	[Isoflavone]-A(3OH)-B(1OH)	Isoflavone	6-Hydroxygenistein
0.083	[Dihydroflavonol (3-OMe)]-A(2OH)-B(none)	Dihydroflavonol	Pinobanksin 3-methyl ether
0.083	[Pterocarpan]-A(1OH, 1OMe)-B(1OH)	Pterocarpan	Melilotocarpan B
0.083	[Pterocarpan]-A(1OH, 1OMe)-B(1OH)	Pterocarpan	Desmocarpin
0.083	[Pterocarpan]-A(1OH)-B(1OH, 1OMe)	Pterocarpan	Nissolin
0.083	[Pterocarpan]-A(1OH)-B(1OH, 1OMe)	Pterocarpan	Vesticarpan
0.083	[Pterocarpan]-A(1OH)-B(1OH, 1OMe)	Pterocarpan	Kushenin
0.083	[Pterocarpan]-A(1OH)-B(1OH, 1OMe)	Pterocarpan	3,8-Dihydroxy-9-methoxypterocarpan
0.083	[Pterocarpan]-A(1OH)-B(1OH, 1OMe)	Pterocarpan	Nissicarpin
0.083	[Pterocarpan]-A(2OH)-B(1OMe)	Pterocarpan	4-Hydroxymedicarpin
0.080	[Dihydroflavonol]-A(1OH, 1OMe)-B(none)	Dihydroflavonol	Pinobanksin 5-methyl ether
0.080	[Dihydroflavonol]-A(1OH, 1OMe)-B(none)	Dihydroflavonol	Alpinone
0.074	[2'-Hydroxychalcone]-A(1OH, 1OMe)-B(2OH)	2'-Hydroxychalcone	Calythropsin
0.074	[2'-Hydroxychalcone]-A(3OH, 1OMe)-B(none)	2'-Hydroxychalcone	2',3',4'-dihydroxy-6'-methoxychalcone
0.069	[Chalcone]-A(1OH, 1OMe)-B(2OH)	Chalcone	Sappanchalcone
0.069	[Flavanone]-A(2OH, 1OMe)-B(none)	Flavanone	5-Methoxydihydrobaicalein
0.069	[Flavanone]-A(2OH, 1OMe)-B(none)	Flavanone	Dihydrooroxylin A
0.069	[Flavanone]-A(2OH, 1OMe)-B(none)	Flavanone	5,8-Dihydroxy-7-methoxyflavanone
0.069	[Flavanone]-A(2OH, 1OMe)-B(none)	Flavanone	Dihydrowogonin
0.043	[Dihydroflavonol]-A(1OH)-B(1OMe)	Dihydroflavonol	Garbanzol 4'-methyl ether
0.043	[Dihydroflavonol]-A(1OH, 1OMe)-B(none)	Dihydroflavonol	3,7-Dihydroxy-6-methoxyflavanone
0.042	[Isoflavan]-A(1OH)-B(2OMe)	Isoflavan	Sativan
0.000	[Isoflavan]-A(1OMe)-B(1OH, 1OMe)	Isoflavan	Isosativan
0.000	[Isoflavan]-A(1OMe)-B(1OH, 1OMe)	Isoflavan	Arvensan
0.000	[Dihydrochalcone]-A(1OH, 2OMe)-B(none)	Dihydrochalcone	Dihydroflavokawin B
0.000	[Dihydrochalcone]-A(2OMe)-B(1OH)	Dihydrochalcone	4-Hydroxy-2',4'-dimethoxydihydrochalcone
0.000	[Dihydrochalcone]-A(1OH)-B(2OMe)	Dihydrochalcone	4'-Hydroxy-2,6-dimethoxydihydrochalcone
0.000	[Dihydrochalcone]-A(1OH)-B(2OMe)	Dihydrochalcone	Loureirin A
0.000	[Aurone]-A(2OH)-B(2OH)	Aurone	Maritimetin
0.000	[Aurone]-A(2OH)-B(2OH)	Aurone	Aureusidin
0.000	[Aurone]-A(3OH)-B(1OH)	Aurone	Helmon
0.000	[beta-Hydroxy(or Oxodihydro)chalcone]-A(1OH, 1OMe)-B(1OH)	beta-Hydroxy(or Oxodihydro)chalcone	Licodione 2'-methyl ether
0.000	[beta-Hydroxy(or Oxodihydro)chalcone]-A(2OH, 1OMe)-B(none)	beta-Hydroxy(or Oxodihydro)chalcone	2',6',beta-Trihydroxy-4'-methoxychalcone
0.000	[beta-Hydroxy(or Oxodihydro)chalcone]-A(2OH, 1OMe)-B(none)	beta-Hydroxy(or Oxodihydro)chalcone	2',4',beta-Trihydroxy-6'-methoxychalcone
0.000	[UBR-type derivative / [2',5']-Benzoquinonyl-type chalcone]-A(2OH)-B(1OH)	UBR-type derivative / [2',5']-Benzoquinonyl-type chalcone	4,4',6'-Trihydroxy-[2',5']-benzoquinonechalcone
0.000	[UBR-type derivative / 2',5'-Dioxo-3'-cyclopentenyl-type Calcone]-A(2OMe)-B(none)	UBR-type derivative / 2',5'-Dioxo-3'-cyclopentenyl-type Calcone	Linderone
0.000	[Dihydrochalcone]-A(2OH)-B(1([@@]-Methylenedioxy))	Dihydrochalcone	2',4'-Dihydroxy-3,4-methylenedioxydihydrochalcone
0.000	[Dihydrochalcone]-A(2OH, 1OMe, 1Methyl)-B(none)	Dihydrochalcone	Myrigalone H
0.000	[Dihydrochalcone]-A(2OH, 1OMe, 1Methyl)-B(none)	Dihydrochalcone	2',6'-Dihydroxy-4'-methoxy-3'-methyldihydrochalcone
0.000	[Dihydrochalcone]-A(3OH, 1Formyl)-B(none)	Dihydrochalcone	3'-Formyl-2',4',6'-trihydroxydihydrochalcone
0.000	[Flavanone]-A(2OH, 1Methyl)-B(1OH)	Flavanone	Poriol
0.000	[3-substituted Flavanone (3-Methyl)]-A(2OH)-B(1OH)	3-substituted Flavanone	3-Methylnaringenin
0.000	[Dihydroflavonol]-A(2OH, 1Methyl)-B(none)	Dihydroflavonol	6-Methypinobanksin
0.000	[Flavan 3-ol]-A(1OMe, 1Methyl)-B(1OH)	Flavan 3-ol	Tupichinol A
0.000	[CCS-type derivative / [3,2']-Epoxymethanoflavan]-A(1OH)-B(2OH)	CCS-type derivative / [3,2']-Epoxymethanoflavan	Peltogynan
0.000	[Flavan]-A(1OMe)-B(1OH, 1OMe)	Flavan	4'-Hydroxy-7,3'-dimethoxyflavan
0.000	[Flavan]-A(1OH, 1Methyl)-B(1OH, 1OMe)	Flavan	7,3'-Dihydroxy-4'-methoxy-8-methylflavan
0.000	[Flavan]-A(1OH, 1Methyl)-B(1OH, 1OMe)	Flavan	7,4'-Dihydroxy-3'-methoxy-8-methylflavan
0.000	[Flavan]-A(1OH, 1OMe)-B(1OMe)	Flavan	7-Hydroxy-5,4'-dimethoxyflavan
0.000	[Flavan]-A(1OH, 1OMe)-B(1OMe)	Flavan	5-Hydroxy-7,4'-dimethoxyflavan
0.000	[Flavan]-A(2OMe)-B(1OH)	Flavan	4'-Hydroxy-5,7-dimethoxyflavan
0.000	[Flavan]-A(1OH, 1OMe, 1Methyl)-B(1OH)	Flavan	5,4'-Dihydroxy-7'-methoxy-8-methylflavan
0.000	[3-DehydroxyAnthocyanidin]-A(2OH)-B(3OH)	3-DehydroxyAnthocyanidin	Tricetinidin
0.000	[UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavan]-A(1OH)-B(1OMe)	UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavan	Claussequinone
0.000	[isoflavene]-A(1OH)-B(2OH, 1OMe)	isoflavene	Sepiol
0.000	[isoflavene]-A(1OH)-B(2OH, 1OMe)	isoflavene	Haginin C
0.000	[Pterocarpan-6a-ol]-A(1OH)-B(1OMe)	Pterocarpan-6a-ol	6a-Hydroxymedicarpin
0.000	[Pterocarpan-6a-ol]-A(1OMe)-B(1OH)	Pterocarpan-6a-ol	6a-Hydroxyisomedicarpin
0.000	[2-Phenylbenzofuran]-A(1OH, 1OMe)-B(1OH, 1OMe)	2-Phenylbenzofuran	Sainfuran
0.000	[2-Phenylbenzofuran]-A(2OMe)-B(2OH)	2-Phenylbenzofuran	2',4'-Dihydroxy-5,6-dimethoxy-2-phenylbenzofuran
0.000	[2-Phenylbenzofuran]-A(1OH)-B(1OH, 2OMe)	2-Phenylbenzofuran	Pterofuran
0.000	[2-Phenylbenzofuran]-A(1OH)-B(1OH, 2OMe)	2-Phenylbenzofuran	Isopterofuran
0.000	[alpha-Methyldeoxybenzoin]-A(1OH, 1OMe)-B(1OMe)	alpha-Methyldeoxybenzoin	2-O-Methylangolensin
0.000	[alpha-Methyldeoxybenzoin]-A(1OH, 1OMe)-B(1OMe)	alpha-Methyldeoxybenzoin	4-O-Methylangolensin
0.000	[4-phenylcoumarin]-A(2OH)-B(2OH)	4-phenylcoumarin	5,7,3',4'-Tetrahydroxy-4-phenylcoumarin
0.000	[[3,2']-Methano-4-phenylchroman (3-OH)]-A(1OH)-B(2OH)	[3,2']-Methano-4-phenylchroman	Brazilin
0.000	[Dalbergiquinol]-A(1OH, 2OMe)-B(1OH)	Dalbergiquinol	Latifolin
0.000	[Dalbergiquinol]-A(1OH, 2OMe)-B(1OH)	Dalbergiquinol	5,3'-Dihydroxy-2,4-dimethoxydalbergiquinol
0.000	[Dalbergiquinol]-A(2OH, 2OMe)-B(none)	Dalbergiquinol	2,5-Dihydroxy-3,4-dimethoxydalbergiquinol