ピーク情報

＜牛乳及び乳製品＞（チーズ類）ナチュラルチーズカマンベール

pos

Peak #14240 MN MID: SE120_S130341_M90

m/z: 507.29656, RT: 83.70, 強度: 4352, ログ強度: -0.45, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 2

DB検索結果: (9 names) Hemsine D;Mucronine A;Sordarin-1-methyl ester;Baconipyrone B;Baconipyrone D;(24R,25R)-6-oxo-2beta,3beta,14alpha 20R-tetrahydroxy-witha-7-enolide;14-O-(alpha-L-rhamnopyranosyl)-7S,14R-dihydroxy-7,9,13,...

DBごとのヒット数: ALL 9 KG 1 KN 4 HM 2 LM 2

FlavonoidSearch最大スコア MS2: 0.033, MS3: -

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C29H38O4N4	506.28931	-0.047	Hemsine D	KNApSAcK: C00027215
C29H38O4N4	506.28931	-0.047	Mucronine A	KEGG: C10009 KNApSAcK: C00002004
C28H42O8	506.28797	2.595	Sordarin-1-methyl ester	KNApSAcK: C00015134
C28H42O8	506.28797	2.595	Baconipyrone B	KNApSAcK: C00038572
C28H42O8	506.28797	2.595	Baconipyrone D	KNApSAcK: C00038574
C28H42O8	506.28797	2.595	(24R,25R)-6-oxo-2beta,3beta,14alpha 20R-tetrahydroxy-witha-7-enolide	LipidMAPS: LMST01160030
C28H42O8	506.28797	2.595	14-O-(alpha-L-rhamnopyranosyl)-7S,14R-dihydroxy-7,9,13,17-tetramethyl-2E,4E,8E,10E,12E,16E-octadecahexaenoic acid	LipidMAPS: LMFA13030009
C28H42O8	506.28797	2.595	(5alpha,6beta,14alpha,20R,22R)-5,6,14,20,27-Pentahydroxy-1-oxowith-24-enolide	HMDB: HMDB0033198
C30H34N8	506.29064	-2.688	Bemcentinib	HMDB: HMDB0244307

MSnスペクトル情報

Level: 2, プリカーサーm/z: 507.29755

Splash: splash10-004i-0004900000-f1b45cf730ba05ca4017

m/z	Int.	NL	Rel.Int.
479.21	1913	28	1000
408.08	866	99	452
394.24	557	113	291
360.21	528	147	275
462.25	204	45	106
294.98	186	212	97
315.14	156	192	81
363.25	144	144	75

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.033	[Flavonol]-A(2OH, 1(C-Prenyl))-B(2OH, 2(C-Prenyl))	Flavonol	Broussoflavonol G
0.033	[Flavonol]-A(2OH, 1(C-Prenyl))-B(2OH, 2(C-Prenyl))	Flavonol	Petalostemumol G
0.000	[Flavanone]-A(2OH, 2(C-Prenyl))-B(1OH, 1OMe, 1(C-Prenyl))	Flavanone	Amoritin
0.000	[Flavanone]-A(2OH, 2(C-Prenyl))-B(1OH, 1OMe, 1(C-Prenyl))	Flavanone	Isoamoritin
0.000	[Dihydrochalcone]-A(1OH, 1OMe, 1([2,3:@@]-(5-(hydroxyisopropyl)-4-(5-methoxycarbonyl-2-hydroxyPhenyl)-4,5-dihydrofurano)))-B(none)	Dihydrochalcone	Piperaduncin B
0.000	[Flavanone]-A(1OH, 1Methyl, 1([2,3:@@]-(8a-Hydroxy-4-Isopropyl-6,6,8,8-tetramethyl-5,7-dioxy-4,4a,8,8a-tetrahydrochromeno)))-B(none)	Flavanone	Lumaflavanone C
0.000	[Flavanone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH, 1([2,3:@@]-(6,6-Dimethyl-5-hydroxydihydropyrano)))	Flavanone	Flemichin E
0.000	[Flavanone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)), 1Lavandulyl)-B(3OH)	Flavanone	Exiguaflavanone H
0.000	[Flavanone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)), 1Lavandulyl)-B(3OH)	Flavanone	Exiguaflavanone I
0.000	[3-substituted Flavone (3-C-Prenyl)]-A(2OH, 1(C-Prenyl), 1(2-hydroxy-3-methyl-3-butenyl))-B(2OH)	3-substituted Flavone	Dorsilurin D
0.000	[Flavone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(5-(hydroxyisopropanyl)dihydrofurano)))-B(2OH)	Flavone	Artelastofuran
0.000	[Flavone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethyl-5-hydroxydihydropyrano)))-B(2OH)	Flavone	Dorsilurin B
0.000	[CCS-type derivative / [2',3]-(Epoxy-1-hydroxyisopropanylethano)flavone]-A(2OH, 2(C-Prenyl))-B(1OH)	CCS-type derivative / [2',3]-(Epoxy-1-hydroxyisopropanylethano)flavone	Artelastocarpin
0.000	[CCS-type derivative / [3,2']-Epoxy-2-prenyl-3-hydroxyflavanone]-A(none)-B(1Geranyl)	CCS-type derivative / [3,2']-Epoxy-2-prenyl-3-hydroxyflavanone	Sanggenol G
0.000	[CCS-type derivative / [3,2']-Epoxy-2-farnesylflavanone]-A(2OH)-B(1OH)	CCS-type derivative / [3,2']-Epoxy-2-farnesylflavanone	Sanggenol H
0.000	[CCS-type derivative / [3,2']-Epoxy-2-prenyl-3-hydroxyflavanone]-A(1Geranyl)-B(none)	CCS-type derivative / [3,2']-Epoxy-2-prenyl-3-hydroxyflavanone	Sanggenol I
0.000	[CCS-type derivative / [3,2']-Epoxy-2-prenyl-3-hydroxyflavanone]-A(2OH, 1(C-Prenyl))-B(1OH, 1(C-Prenyl))	CCS-type derivative / [3,2']-Epoxy-2-prenyl-3-hydroxyflavanone	Sorocein F
0.000	[CCS-type derivative / [3,2']-Epoxy-2-prenyl-3-hydroxyflavanone]-A(2OH, 2(C-Prenyl))-B(1OH)	CCS-type derivative / [3,2']-Epoxy-2-prenyl-3-hydroxyflavanone	Sorocein G
0.000	[Flavonol]-A(2OH, 1(1,1-Dimethylallyl))-B(2OH, 2(C-Prenyl))	Flavonol	Broussoflavonol C
0.000	[Flavonol]-A(2OH, 1(1,1-Dimethylallyl))-B(1OH, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethyldihydropyrano)))	Flavonol	Broussoflavonol E

Level: 3, プリカーサーm/z: 408.07584

Splash: splash10-0002-0092000000-2dae101129214e3cfae3

m/z	Int.	NL	Rel.Int.
295.03	426	113	1000
363.13	144	45	339
261.10	49	147	115
267.21	41	141	95

Level: 3, プリカーサーm/z: 479.21152

Splash: splash10-03xr-0029400000-d1642df2554f07911404

m/z	Int.	NL	Rel.Int.
462.33	328	17	1000
315.11	323	164	983
363.18	175	116	531
287.21	130	192	395
394.13	115	85	351
349.12	105	130	318
408.04	82	71	250
219.31	49	260	150
295.18	36	184	109
360.09	29	119	89
321.29	21	158	64
335.33	21	144	64
188.23	17	291	51

Symbolized Name	MSMS-Category	MSMS-Aglycone
[Flavonol]-A(1OH, 1OMe, 1(C-Glu))-B(2OH)	Flavonol	Keyakinin B
[Dihydrochalcone]-A(3OH)-B(1OH, 1(C-Prenyl), 1Geranyl)	Dihydrochalcone	3-Geranyl-4,2',4',6'-tetrahydroxy-5-prenyldihydrochalcone
[Flavonol]-A(1OH, 1OMe, 1(C-Rhamnosyl))-B(3OH)	Flavonol	8-C-Rhamnosyleuropetin