ピーク情報

＜牛乳及び乳製品＞（発酵乳・乳酸菌飲料）乳酸菌飲料乳製品

pos

Peak #5399 MN MID: SE112_S130281_M90

m/z: 545.30888, RT: 44.86, 強度: 8681, ログ強度: 0.64, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 9

DB検索結果: (3 names) 13beta-Hydroxymilbemycin A3;3,14E-Implexin;Meproscillarin

DBごとのヒット数: ALL 3 KN 2 HM 1

FlavonoidSearch最大スコア MS2: -, MS3: -

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C31H44O8	544.30362	-3.695	13beta-Hydroxymilbemycin A3	KNApSAcK: C00017118
C31H44O8	544.30362	-3.695	3,14E-Implexin	KNApSAcK: C00020247, C00020248
C31H44O8	544.30362	-3.695	Meproscillarin	HMDB: HMDB0254457

MSnスペクトル情報

Level: 2, プリカーサーm/z: 545.30847

Splash: splash10-03xr-0027930000-fe7d76570a3c6bcedb50

m/z	Int.	NL	Rel.Int.
414.19	4002	131	1000
315.12	3193	230	797
298.20	1087	247	271
528.37	899	17	224
527.19	449	18	112

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.000	[2'-Hydroxychalcone]-A(2OH, 1Geranyl)-B(2OH, 1Geranyl)	2'-Hydroxychalcone	Prorepensin

Level: 3, プリカーサーm/z: 315.11865

Splash: splash10-0002-0090000000-e8c19a366e3f7275da46

m/z	Int.	NL	Rel.Int.
298.12	1913	17	1000

FlavonoidSearch結果

Symbolized Name	MSMS-Category	MSMS-Aglycone
[Flavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavone	Abrectorin
[Flavone]-A(2OH, 1OMe)-B(1OMe)	Flavone	6,8-Dihydroxy-7,4'-dimethoxyflavone
[Flavone]-A(2OH)-B(2OMe)	Flavone	Luteolin 3',4'-dimethyl ether
[Flavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavone	Luteolin 5,3'-dimethyl ether
[Flavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavone	7,3'-Dihydroxy-5,4'-dimethoxyflavone
[Flavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavone	Velutin
[Flavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavone	Pilloin
[Flavone]-A(2OH, 1OMe)-B(1OMe)	Flavone	Scutellarein 5,4'-dimethyl ether
[Flavone]-A(2OH, 1OMe)-B(1OMe)	Flavone	Pectolinarigenin
[Flavone]-A(1OH, 2OMe)-B(1OH)	Flavone	Cirsimaritin
[Flavone]-A(2OH, 1OMe)-B(1OMe)	Flavone	Ladanein
[Flavone]-A(1OH, 2OMe)-B(1OH)	Flavone	Skullcapflavone I
[Flavone]-A(2OH, 1OMe)-B(1OMe)	Flavone	5,7-Dihydroxy-8,2'-dimethoxyflavone
[Flavone]-A(2OH, 1OMe)-B(1OMe)	Flavone	5,8-dihydroxy-7,4'-dimethoxyflavone
[Flavone]-A(1OH, 2OMe)-B(1OH)	Flavone	Isoscutellarein 7,8-dimethyl ether
[Flavone]-A(2OH, 1OMe)-B(1OMe)	Flavone	Bucegin
[Flavone]-A(2OH, 2OMe)-B(none)	Flavone	5,8-Dihydroxy-6,7-dimethoxyflavone
[Flavone]-A(2OH, 2OMe)-B(none)	Flavone	5,7-Dihydroxy-6,8-dimethoxyflavone
[Anthocyanidin]-A(1OH, 1OMe)-B(1OH, 1OMe)	Anthocyanidin	Rosinidin
[Chalcone]-A(1OH, 2OMe)-B(1OMe)	Chalcone	4'-Hydroxy-2',4,6'-trimethoxychalcone
[Chalcone]-A(none)-B(1OH, 3OMe)	Chalcone	Tepanone
[Isoflavone]-A(2OH, 1OMe)-B(1OMe)	Isoflavone	Dipteryxin
[Isoflavone]-A(2OH, 1OMe)-B(1OMe)	Isoflavone	5,7-Dihydroxy-6,2'-dimethoxyisoflavone
[Isoflavone]-A(2OH, 1OMe)-B(1OMe)	Isoflavone	Irisolidone
[Isoflavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Isoflavone	Odoratin
[Isoflavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Isoflavone	7,2'-Dihydroxy-6,4'-dimethoxyisoflavone
[Isoflavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Isoflavone	3'-Hydroxy-8-O-methylretusin
[Isoflavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Isoflavone	7,3'-Dimethixyorobol
[Isoflavone]-A(1OH, 1OMe)-B(1OH, 1OMe)	Isoflavone	5,3'-Dihydroxy-7,4'-dimethoxyisoflavone
[Isoflavone]-A(1OH, 2OMe)-B(1OH)	Isoflavone	Muningin
[Isoflavone]-A(1OH, 2OMe)-B(1OH)	Isoflavone	7-O-Methyltectorigenin
[Isoflavone]-A(1OH, 2OMe)-B(1OH)	Isoflavone	5,2'-Dihydroxy-7,8-dimethoxyisoflavone
[Isoflavone]-A(2OH)-B(2OMe)	Isoflavone	Pratensein 3'-O-methyl ether
[Isoflavone]-A(2OH)-B(2OMe)	Isoflavone	2'-Methoxybiochanin A
[Isoflavone]-A(2OMe)-B(2OH)	Isoflavone	5,7-Dimethixyorobol
[Isoflavone]-A(2OMe)-B(2OH)	Isoflavone	2',4'-Dihydroxy-5,7-dimethoxyisoflavone
[Isoflavone]-A(1OH)-B(1OH, 2OMe)	Isoflavone	7,2'-Dihydroxy-3',4'-dimethoxyisoflavone
[Flavanone]-A(1OMe)-B(2OMe)	Flavanone	6,3',4'-Trimethoxyflavanone
[Flavanone]-A(2OMe)-B(1OMe)	Flavanone	Naringenin trimethyl ether
[Flavanone]-A(3OMe)-B(none)	Flavanone	5,7,8-Trimethoxyflavanone
[2'-Hydroxychalcone]-A(1OH)-B(3OMe)	2'-Hydroxychalcone	Crotaoprostrin
[2'-Hydroxychalcone]-A(1OH, 2OMe)-B(1OMe)	2'-Hydroxychalcone	2'-Hydroxy-2,4',6'-trimethoxychalcone
[2'-Hydroxychalcone]-A(1OH, 2OMe)-B(1OMe)	2'-Hydroxychalcone	Flavokawin A
[2'-Hydroxychalcone]-A(1OH, 3OMe)-B(none)	2'-Hydroxychalcone	Helilandin B
[2'-Hydroxychalcone]-A(1OH, 3OMe)-B(none)	2'-Hydroxychalcone	2'-Hydroxy-3',4',6'-trimethoxychalcone
[Coumestan]-A(1OH, 1OMe)-B(2OH)	Coumestan	Wedelolactone
[Flavonol]-A(1OH, 1OMe)-B(1OMe)	Flavonol	3,7-Dihydroxy-5,4'-dimethoxyflavone
[Flavonol]-A(1OH, 1OMe)-B(1OMe)	Flavonol	Kaempferol 7,4'-dimethyl ether
[Flavonol]-A(1OH, 2OMe)-B(none)	Flavonol	3,7-Dihydroxy-5,6-dimethoxyflavone
[Flavonol]-A(1OH, 2OMe)-B(none)	Flavonol	3,6-Dihydroxy-5,7-dimethoxyflavone
[Flavonol]-A(1OH, 2OMe)-B(none)	Flavonol	3,5-Dihydroxy-6,7-dimethoxyflavone
[Flavonol]-A(1OH, 2OMe)-B(none)	Flavonol	3,5-Dihydroxy-7,8-dimethoxyflavone
[Flavonol]-A(2OMe)-B(1OH)	Flavonol	3,4'-Dihydroxy-7,8-dimethoxyflavone
[Pterocarpan]-A(2OMe)-B(1OMe)	Pterocarpan	2-Methoxyhomopterocarpin
[Pterocarpan]-A(2OMe)-B(1OMe)	Pterocarpan	4-Methoxyhomopterocarpin
[Aurone]-A(1OH, 1OMe, 1Methyl)-B(2OH)	Aurone	6,3',4'-Trihydroxy-4-methoxy-5-methylaurone
[Aurone]-A(1OH, 1OMe, 1Methyl)-B(2OH)	Aurone	6,3',4'-Trihydroxy-4-methoxy-7-methylaurone
[2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1([@@]-Methylenedioxy))	2'-Hydroxychalcone	Prosogerin B
[2'-Hydroxychalcone]-A(1OH, 1OMe, 1([@@]-Methylenedioxy))-B(1OH)	2'-Hydroxychalcone	4,2'-Dihydroxy-6'-methoxy-3',4'-methylenedioxychalcone
[beta-Hydroxy(or Oxodihydro)chalcone]-A(3OH, 1Formyl, 1Methyl)-B(none)	beta-Hydroxy(or Oxodihydro)chalcone	3'-Formyl-2',4',6',beta-tetrahydroxy-5'-methylchalcone
[UBR-type derivative / [2',5']-Benzoquinonyl-type chalcone]-A(1OH, 2OMe)-B(none)	UBR-type derivative / [2',5']-Benzoquinonyl-type chalcone	Methylpedicinin
[UBR-type derivative / 2'-Oxocyclohexa-4',6'-dienyl-type beta-Hydroxychalcone]-A(1OH, 1OMe, 2Methyl)-B(none)	UBR-type derivative / 2'-Oxocyclohexa-4',6'-dienyl-type beta-Hydroxychalcone	Syzygiol
[Dihydrochalcone]-A(2OMe)-B(1([@@]-Methylenedioxy))	Dihydrochalcone	Ponganone VII
[Dihydrochalcone]-A(2OMe, 1([@@]-Methylenedioxy))-B(none)	Dihydrochalcone	2',6'-Dimethoxy-3',4'-methylenedioxydihydrochalcone
[UBR-type derivative / 2',4'-Dioxo-6'-cyclohexenyl-type Dihydrochalcone]-A(1OH, 4Methyl)-B(none)	UBR-type derivative / 2',4'-Dioxo-6'-cyclohexenyl-type Dihydrochalcone	Grandiflorone
[Flavanone]-A(1OH, 1OMe)-B(1([@@]-Methylenedioxy))	Flavanone	6-Hydroxy-7-methoxy-3',4'-methylenedioxyflavanone
[Flavanone]-A(1OH, 1OMe, 1Hydroxymethyl, 1Methyl)-B(none)	Flavanone	Leridol
[Flavanone]-A(2OH, 2Methyl)-B(1OMe)	Flavanone	Isomatteucinol
[Flavanone]-A(2OH, 2Methyl)-B(1OMe)	Flavanone	Matteucinol
[Flavanone]-A(1OH, 1OMe, 2Methyl)-B(1OH)	Flavanone	Angophorol
[Flavone]-A(1OH, 1OMe, 1Methyl)-B(2OH)	Flavone	5,3',4'-Trihydroxy-7-methoxy-6-methylflavone
[Dihydroflavonol]-A(2OH)-B(none)-C(1(O-Acetyl))	Dihydroflavonol	Pinobanksin 3-O-acetate
[Dihydroflavonol]-A(1OMe, 1([@@]-Methylenedioxy))-B(none)	Dihydroflavonol	3-Hydroxy-5-methoxy-6,7-methylenedioxyflavanone
[Flavonol (3-OMe)]-A(1OH, 1OMe)-B(1OH)	Flavonol	7,4'-Dihydroxy-3,6-dimethoxyflavone
[Flavonol (3-OMe)]-A(2OH, 1Methyl)-B(1OH)	Flavonol	Sylpin
[Flavonol (3-OMe)]-A(2OH)-B(1OMe)	Flavonol	Ermanin
[Flavonol (3-OMe)]-A(1OH, 1OMe)-B(1OH)	Flavonol	Kaempferol 3,5-dimethyl ether
[Flavonol (3-OMe)]-A(1OH, 1OMe)-B(1OH)	Flavonol	Kumatakenin
[Flavonol (3-OMe)]-A(2OH, 1Methyl)-B(1OH)	Flavonol	5,7,4'-Trihydroxy-3-methoxy-6-methylflavone
[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(none)	Flavonol	Alnusin 3-methyl ether
[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(none)	Flavonol	5,6-Dihydroxy-3,7-dimethoxyflavone
[Flavonol]-A(1OH, 1([@@]-Methylenedioxy))-B(1OH)	Flavonol	Gomphrenol
[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(none)	Flavonol	5,8-Dihydroxy-3,7-dimethoxyflavone
[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(none)	Flavonol	Gnaphaliin
[Flavonol (3-OMe)]-A(3OH, 1Methyl)-B(none)	Flavonol	Platanin 3-methyl ether
[Flavonol]-A(2OH, 1OMe, 1Methyl)-B(none)	Flavonol	3,5,8-Trihydroxy-7-methoxy-6-methylflavone
[Flavonol]-A(2OH, 1OMe, 1Methyl)-B(none)	Flavonol	Pityrogrammin
[CCS-type derivative / [3,2']-Epoxymethanoflavone]-A(2OH)-B(2OH)	CCS-type derivative / [3,2']-Epoxymethanoflavone	2,3,8,10-Tetrahydroxy[2]benzopyrano[4,3-b][1]benzopyran-7(5H)-one
[CCS-type derivative / [3,2']-Epoxyhydroxymethanoflavone]-A(1OH)-B(2OH)	CCS-type derivative / [3,2']-Epoxyhydroxymethanoflavone	Fasciculiferin
[Flavan]-A(1OH, 2Methyl)-B(1OH, 1([@@]-Methylenedioxy))	Flavan	7,2'-Dihydroxy-6,8-dimethyl-4',5'-methylenedioxyflavan
[Flavan]-A(1OH, 2Methyl)-B(1OH, 1([@@]-Methylenedioxy))	Flavan	7,2'-Dihydroxy-5,8-dimethyl-4',5'-methylenedioxyflavan
[3-DehydroxyAnthocyanidin]-A(2OH, 1OMe)-B(1OH, 1OMe)	3-DehydroxyAnthocyanidin	5,4'-Dimethyl-6-hydroxyluteolinidin
[UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavone]-A(2OH)-B(1OMe)	UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavone	5-Hydroxybowdichione
[Isoflavanone]-A(1OH)-B(1OMe, 1([@@]-Methylenedioxy))	Isoflavanone	Onogenin
[Pterocarpan]-A(1OH, 1OMe)-B(1([@@]-Methylenedioxy))	Pterocarpan	2-Hydroxyhomopterocarpin
[Pterocarpan]-A(1OH, 1OMe)-B(1([@@]-Methylenedioxy))	Pterocarpan	4-Methoxymaackiain
[Pterocarpan]-A(1OH, 1OMe)-B(1([@@]-Methylenedioxy))	Pterocarpan	4-Hydroxypterocarpin
[Pterocarpan-6a-ol]-A(1OMe)-B(1([@@]-Methylenedioxy))	Pterocarpan-6a-ol	Pisatin
[Pterocarpan-6-ol (6-OMe)]-A(1OH)-B(1([@@]-Methylenedioxy))	Pterocarpan-6-ol	Sophoracarpan B
[Pterocarpan-6-ol (3-OMe)]-A(1OMe)-B(1OMe)	Pterocarpan-6-ol	6-Methoxyhomopterocarpin
[4-phenylcoumarin]-A(1OH, 1OMe)-B(1OH, 1OMe)	4-phenylcoumarin	Melannein
[4-phenylcoumarin]-A(1OH, 1OMe)-B(1OH, 1OMe)	4-phenylcoumarin	7,3'-Dihydroxy-5,4'-dimethoxy-4-phenylcoumarin
[4-phenylcoumarin]-A(1OH, 1OMe)-B(1OH, 1OMe)	4-phenylcoumarin	5,3'-Dihydroxy-7,4'-dimethoxy-4-phenylcoumarin
[4-phenylcoumarin]-A(2OMe)-B(2OH)	4-phenylcoumarin	3',4'-Dihydroxy-5,7-dimethoxy-4-phenylcoumarin

Level: 3, プリカーサーm/z: 414.19336

Splash: splash10-014i-0019000000-0170c89efb5382c8f6cf

m/z	Int.	NL	Rel.Int.
315.17	1249	99	1000
397.28	223	17	178
268.16	194	146	155
396.44	177	18	141
236.98	79	177	62
380.24	74	34	59
379.22	68	35	54