ピーク情報

（かんきつ類）グレープフルーツ白肉種砂じょう生

pos

Peak #758 MN MID: SE118_S070621_M90

m/z: 337.07637, RT: 12.80, 強度: 11212, ログ強度: 0.68, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 21

DB検索結果:

DBごとのヒット数:

FlavonoidSearch最大スコア MS2: 0.158, MS3: 0.333

MSnスペクトル情報

Level: 2, プリカーサーm/z: 337.07590

Splash: splash10-014i-0619000000-a84bd222d66facb9a326

m/z	Int.	NL	Rel.Int.
319.15	7787	18	1000
192.87	2335	144	299
127.00	1360	210	174
301.01	1272	36	163
174.84	1248	162	160
290.99	1201	46	154
146.75	748	190	96
254.90	645	82	82
145.02	585	192	75

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.158	[Isoflavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH)	Isoflavone	Alpinumisoflavone
0.158	[Isoflavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH)	Isoflavone	Derrone
0.107	[Isoflavone]-A(1OH)-B(1OMe, 1(C-Prenyl))	Isoflavone	4'-O-Methylneobavaisoflavone
0.105	[Flavone]-A(2OH)-B(1([2,3:@@]-(6,6-Dimethylpyrano)))	Flavone	Yinyanghuo C
0.105	[Flavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH)	Flavone	Atalantoflavone
0.105	[Flavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH)	Flavone	Carpachromene
0.105	[Chalcone]-A(1OH)-B(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))	Chalcone	Licoagrochalcone B
0.100	[Isoflavone]-A(2OH)-B(1([2,3:@@]-(6,6-Dimethylpyrano)))	Isoflavone	Isoderrone
0.100	[Isoflavone]-A(1OH)-B(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))	Isoflavone	Glabrone
0.100	[Isoflavone]-A(1OH)-B(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))	Isoflavone	Puerarone
0.056	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(none)	2'-Hydroxychalcone	Oaxacacin
0.056	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(none)	2'-Hydroxychalcone	Pongachalcone I
0.056	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(none)	2'-Hydroxychalcone	Cedreprenone
0.056	[2'-Hydroxychalcone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OMe)	2'-Hydroxychalcone	4-Methoxylonchocarpin
0.053	[Flavanone]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(none)	Flavanone	Ovalichromene
0.053	[Flavanone]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(none)	Flavanone	Obovatin methyl ether
0.053	[Flavanone]-A(1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OMe)	Flavanone	Dorspoinsettifolin
0.000	[Coumestan]-A(1OH, 1(C-Prenyl))-B(1OH)	Coumestan	Psoralidin
0.000	[Coumestan]-A(1OH)-B(1OH, 1(C-Prenyl))	Coumestan	Isosojagol
0.000	[Coumestan]-A(1OH, 1(C-Prenyl))-B(1OH)	Coumestan	Phaseol
0.000	[Pterocarpan]-A(1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OMe)	Pterocarpan	Hemileiocarpin
0.000	[2-(alpha-oxobenzyl)benzofuran (3-OMe)]-A(1([2,3:@@]-Furano))-B(1([@@]-Methylenedioxy))	2-(alpha-oxobenzyl)benzofuran	Derriobtusone B
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(none)	2'-Hydroxychalcone	Crassichalcone
0.000	[2'-Hydroxychalcone]-A(2OH, 1([2,3:@@]-(6,6-Dimethylpyrano)), 1Methyl)-B(none)	2'-Hydroxychalcone	2',4'-Dihydroxy-3',6'',6''-trimethylpyrano[2'',3'':6',5']chalcone
0.000	[beta-Hydroxy(or Oxodihydro)chalcone]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(none)	beta-Hydroxy(or Oxodihydro)chalcone	6'-Demethoxypraecansone B
0.000	[Flavanone]-A(1OH, 1OMe, 1(3-Methylbutadienyl))-B(none)	Flavanone	Tephroleocarpin B
0.000	[Flavanone]-A(1OMe, 1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(none)	Flavanone	Emoroidenone
0.000	[Flavone]-A(1OMe, 1(3-Hydroxy-3-methyl-1-butenyl))-B(none)	Flavone	Lanceolatin A(flavonoid)
0.000	[Flavone]-A(1OH, 1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(1OH)	Flavone	Ciliatin A
0.000	[Flavonol (3-OMe)]-A(1([2,3:@@]-Furano))-B(1([@@]-Methylenedioxy))	Flavonol	Pongapin
0.000	[Flav-3-ene]-A(2OMe, 1(C-Prenyl))-B(none)	Flav-3-ene	Tephrowatsin B
0.000	[Isoflavone]-A(1([2,3:@@]-Furano))-B(1OMe, 1([@@]-Methylenedioxy))	Isoflavone	Dehydroneotenone
0.000	[Isoflavone]-A(1OMe, 1([2,3:@@]-Furano))-B(1([@@]-Methylenedioxy))	Isoflavone	Garhwalin
0.000	[Pterocarpan-6a-ol]-A(1([2,3:@@]-(5-(Hydroxyisopropanyl)furano)))-B(1OH)	Pterocarpan-6a-ol	Clandestacarpin
0.000	[Coumestan]-A(1OH)-B(1([2,3:@@]-(6,6-Dimethyldihydropyrano)))	Coumestan	Sojagol
0.000	[Coumestan]-A(1([2,3:@@]-(6,6-Dimethyldihydropyrano)))-B(1OH)	Coumestan	Isopsoralidin
0.000	[Rotenone]-A(1([2,3:@@]-Furano))-B(1([@@]-Methylenedioxy))	Rotenone	Dolineone
0.000	[3-Phenylcoumarin]-A(1([2,3:@@]-Furano))-B(1OMe, 1([@@]-Methylenedioxy))	3-Phenylcoumarin	Pachyrrhizin

Level: 3, プリカーサーm/z: 319.14664

Splash: splash10-0udi-0029000000-b434e606c35e47200c01

m/z	Int.	NL	Rel.Int.
301.16	1064	18	1000
273.06	173	46	162
291.10	112	28	105
126.96	90	192	84

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.333	[Dihydroflavonol]-A(2OH, 1OMe)-B(1OH)	Dihydroflavonol	3,5,7,4'-Tetrahydroxy-8-methoxyflavanone
0.333	[Dihydroflavonol]-A(1OH, 1OMe)-B(2OH)	Dihydroflavonol	8-Methoxyfustin
0.333	[Dihydroflavonol]-A(1OH, 1OMe)-B(2OH)	Dihydroflavonol	3,5,2',3'-Tetrahydroxy-7-methoxyflavanone
0.333	[Dihydroflavonol]-A(1OH, 1OMe)-B(2OH)	Dihydroflavonol	Taxifolin 5-methyl ether
0.333	[Dihydroflavonol]-A(1OH, 1OMe)-B(2OH)	Dihydroflavonol	Padmatin
0.333	[Dihydroflavonol]-A(2OH)-B(1OH, 1OMe)	Dihydroflavonol	3,5,7,2'-Tetrahydroxy-5'-methoxyflavanone
0.333	[Dihydroflavonol]-A(2OH)-B(1OH, 1OMe)	Dihydroflavonol	Taxifolin 4'-methyl ether
0.333	[Dihydroflavonol]-A(1OH)-B(2OH, 1OMe)	Dihydroflavonol	Sepinol
0.250	[Flavone]-A(3OH)-B(3OH)	Flavone	5,6,7,3',4',5'-Hexahydroxyflavone
0.250	[Flavone]-A(3OH)-B(3OH)	Flavone	5,7,8,3',4',5'-Hexahydroxyflavone
0.250	[Flavone]-A(4OH)-B(2OH)	Flavone	Bitalgenin
0.250	[Anthocyanidin]-A(3OH)-B(3OH)	Anthocyanidin	6-Hydroxydelphinidin
0.222	[Dihydroflavonol]-A(2OH, 1OMe)-B(1OH)	Dihydroflavonol	3,5,7,4'-Tetrahydroxy-6-methoxyflavanone
0.222	[Dihydroflavonol]-A(2OH)-B(1OH, 1OMe)	Dihydroflavonol	Dihydroisorhamnetin
0.167	[Dihydroflavonol (3-OMe)]-A(2OH)-B(2OH)	Dihydroflavonol	Taxifolin 3-methyl ether
0.158	[Flavonol]-A(4OH)-B(1OH)	Flavonol	3,5,6,7,8,4'-Hexahydroxyflavone
0.158	[Flavonol]-A(3OH)-B(2OH)	Flavonol	Quercetagetin
0.158	[Flavonol]-A(3OH)-B(2OH)	Flavonol	Gossypetin
0.158	[Flavonol]-A(2OH)-B(3OH)	Flavonol	3,5,8,3',4',5'-Hexahydroxyflavone
0.158	[Flavonol]-A(2OH)-B(3OH)	Flavonol	Myricetin
0.158	[Flavonol]-A(2OH)-B(3OH)	Flavonol	5'-Hydroxymorin
0.158	[Flavonol]-A(2OH)-B(3OH)	Flavonol	3,5,7,2',3',4'-Hexahydroxyflavone
0.125	[Flavan 3-ol]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavan 3-ol	Catechin 5,3'-dimethyl ether
0.125	[Flavan 3-ol]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavan 3-ol	Catechin 7,4'-dimethyl ether
0.125	[Flavan 3-ol]-A(2OH)-B(2OMe)	Flavan 3-ol	Catechin 3',4'-dimethyl ether
0.071	[Flavanone]-A(3OH)-B(1OH, 1OMe)	Flavanone	8-Hydroxyhesperetin
0.071	[Flavanone]-A(2OH, 1OMe)-B(2OH)	Flavanone	5,7,2',5'-Tetrahydroxy-6-methoxyflavanone
0.071	[Flavanone]-A(2OH, 1OMe)-B(2OH)	Flavanone	6-Methoxyeriodictyol
0.071	[Flavanone]-A(2OH, 1OMe)-B(2OH)	Flavanone	8-Methoxyeriodictyol
0.000	[Isoflavan]-A(2OH)-B(1OH, 2OMe)	Isoflavan	Bryaflavan
0.000	[Isoflavan]-A(2OH)-B(1OH, 2OMe)	Isoflavan	8-Demethylduartin
0.000	[UBR-type derivative / 4'-Oxocyclohexa-2'-enyl-type Flavanone]-A(2OH, 2Methyl)-B(1OH)	UBR-type derivative / 4'-Oxocyclohexa-2'-enyl-type Flavanone	Protofarrerol
0.000	[Dihydroflavonol]-A(2OH, 1Methyl)-B(2OH)	Dihydroflavonol	6-Methyltaxifolin
0.000	[Dihydroflavonol]-A(2OH, 1Methyl)-B(2OH)	Dihydroflavonol	Deodarin
0.000	[Flavan 4-ol]-A(2OH, 1Hydroxymethyl, 1Methyl)-B(1OH)	Flavan 4-ol	4,5,7,4'-Tetrahydroxy-6-hydroxymethyl-8-methylflavan
0.000	[Isoflavanone-3-ol]-A(2OH)-B(1OH, 1OMe)	Isoflavanone-3-ol	Bolusanthin
0.000	[3-substituted 2-Phenylbenzofuran (3-COOH)]-A(2OH)-B(3OH)	3-substituted 2-Phenylbenzofuran	Norwedelic acid

Level: 3, プリカーサーm/z: 192.86989

Splash: splash10-00di-0900000000-8f002e0a02fd75e28bcb