ピーク情報
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わらび 生わらび 生
pos
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| Peak #4782 MN MID: SE116_S063241_M90 |
| m/z: 365.15965, RT: 54.30, 強度: 21990, ログ強度: 0.85, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 4 |
| DB検索結果: (42 names) Nagilactone B;Gibberellin A91;L 783277;9alpha-Acetoxycumambrin A;(+)-9alpha-Acetoxycumambrin A;Gibberellin A50;6alpha-Hydroxyeurycomalactone;(7R*,8R*)-3-Methoxy-3',4,7,9,9'-pentahydroxy-8,4'-oxyneolig... |
| DBごとのヒット数: ALL 32 KG 3 KN 26 HM 3 |
| FlavonoidSearch最大スコア MS2: 0.045, MS3: 0.125 |
DB検索結果
ppm
| 組成式 | 分子量 | 誤差(Δppm） | 候補化合物名（代表で最短名を記載） | 化合物ID |
|---|---|---|---|---|
| C19H24O7 | 364.15220 | 0.475 | Nagilactone B | KNApSAcK: C00000269 |
| C19H24O7 | 364.15220 | 0.475 | Gibberellin A91 | HMDB: HMDB0040651 KNApSAcK: C00000216 |
| C19H24O7 | 364.15220 | 0.475 | L 783277 | KNApSAcK: C00015456, C00015457 |
| C19H24O7 | 364.15220 | 0.475 | 9alpha-Acetoxycumambrin A | KNApSAcK: C00033605 |
| C19H24O7 | 364.15220 | 0.475 | Gibberellin A48 | HMDB: HMDB0035038, HMDB0035052 KNApSAcK: C00000048, C00000049 |
| C19H24O7 | 364.15220 | 0.475 | (7R*,8R*)-3-Methoxy-3',4,7,9,9'-pentahydroxy-8,4'-oxyneolignan | HMDB: HMDB0040324 |
| C19H24O7 | 364.15220 | 0.475 | 6alpha-Hydroxyeurycomalactone | KNApSAcK: C00047684 |
| C19H24O7 | 364.15220 | 0.475 | Gibberellin A55 | HMDB: HMDB0033420 KNApSAcK: C00000055, C00000057 |
| C19H24O7 | 364.15220 | 0.475 | Gibberellin A78 | HMDB: HMDB0039623 KNApSAcK: C00000078, C00000079 |
| C19H24O7 | 364.15220 | 0.475 | Achillolide B | KNApSAcK: C00012250 |
| C19H24O7 | 364.15220 | 0.475 | Gibberellin A8 | HMDB: HMDB0303450 KEGG: C03579 KNApSAcK: C00000008, C00000056 LipidMAPS: LMPR0104170005 |
| C19H24O7 | 364.15220 | 0.475 | Gibberellin A50 | KNApSAcK: C00000050 |
| C19H24O7 | 364.15220 | 0.475 | Gibberellin A72 | HMDB: HMDB0036890 KNApSAcK: C00000072 |
| C19H24O7 | 364.15220 | 0.475 | Hydruntinolide A | KNApSAcK: C00033933 |
| C19H24O7 | 364.15220 | 0.475 | Zempoalin C | KNApSAcK: C00011996 |
| C19H24O7 | 364.15220 | 0.475 | 3,15-Di-O-acetyl-9beta-hydroxyamphoricarpolide | KNApSAcK: C00035790 |
| C19H24O7 | 364.15220 | 0.475 | 1beta,2alpha-Epoxytagitinin C | KNApSAcK: C00033537 |
| C19H24O7 | 364.15220 | 0.475 | Acrorepiolide | KNApSAcK: C00020850 |
| C19H24O7 | 364.15220 | 0.475 | Christinine | KNApSAcK: C00020601 |
| C19H24O7 | 364.15220 | 0.475 | Zexbrevin B | KEGG: C09607 KNApSAcK: C00003398 |
| C19H24O7 | 364.15220 | 0.475 | [7S-(5Z,7R*,9R*,10E,11aS*)]-9-(acetyloxy)-3-[(acetyloxy)methyl]-7,8,9,11a-tetrahydro-7-hydroxy-6,10-dimethylcyclodeca[b]furan-2(4H)-one | KNApSAcK: C00012247 |
| C19H24O7 | 364.15220 | 0.475 | Gibberellin A76 | HMDB: HMDB0036898 KNApSAcK: C00000076 |
| C19H24O7 | 364.15220 | 0.475 | [7R-(7R*,9S*,10E,11aR*)]-9-(Acetyloxy)-3-[(acetyloxy)methyl]-5,6,7,8,9,11a-hexahydro-7-hydroxy-10-methyl-6-methylenecyclodeca[b]furan-2(4H)-one | KNApSAcK: C00012249, C00012254 |
| C19H24O7 | 364.15220 | 0.475 | Eudesmaafraglaucolide | KNApSAcK: C00013089 |
| C19H24O7 | 364.15220 | 0.475 | Vernomygdin | KEGG: C09585 KNApSAcK: C00003390 |
| C19H24O7 | 364.15220 | 0.475 | [3S-(3R*,8R*,9R*,11E)]-3,4,5,6,9,10-Hexahydro-8,9,16-trihydroxy-14-methoxy-3-methyl-1H-2-benzoxacyclotetradecin-1,7(8H)-dione | KNApSAcK: C00015458 |
| C19H24O7 | 364.15220 | 0.475 | Gibberellin A85 | HMDB: HMDB0303670 KNApSAcK: C00000085 |
| C19H24O7 | 364.15220 | 0.475 | Inumakilactone E | KNApSAcK: C00050844 |
| C19H24O7 | 364.15220 | 0.475 | Cedronin | KNApSAcK: C00035558 |
| C19H24O7 | 364.15220 | 0.475 | Ailanquassin A | KNApSAcK: C00047701 |
| C20H20O3N4 | 364.15354 | -3.197 | N'-Methoxy-4-[5-[4-(N'-methoxycarbamimidoyl)phenyl]furan-2-yl]benzenecarboximidamide | HMDB: HMDB0244823 |
| C20H20O3N4 | 364.15354 | -3.197 | Ganetespib | HMDB: HMDB0252628 |
MSnスペクトル情報
| Level: 2, プリカーサーm/z: 365.15915 |
| Splash: splash10-001i-0090000000-b5b48bbbd3413b6c3b77 |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 231.06 | 71007 | 134 | 1000 |
| 347.17 | 3612 | 18 | 50 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.045 | [Isoflavone]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OMe) | Isoflavone | Alpinumisoflavone dimethyl ether |
| 0.000 | [Flavone]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OMe) | Flavone | Carpachromene dimethyl ether |
| 0.000 | [Coumestan]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH) | Coumestan | Gancaonin F |
| 0.000 | [Flavonol (3-OMe)]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(none) | Flavonol | 3,6-Dimethoxy-6'',6''-dimethylpyrano[2,3:7,8]flavone |
| 0.000 | [Flavonol (3-OMe)]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(none) | Flavonol | 3,5-Dimethoxy-8,8-dimethyl-2-phenyl-4H,8H-benzo[1,2-b:3,4-b']dipyran-4-one |
| 0.000 | [Isoflavone]-A(1OH, 1([@@]-Methylenedioxy))-B(1([2,3:@@]-(6,6-Dimethylpyrano))) | Isoflavone | Robustone |
| 0.000 | [Isoflavone]-A(1OH, 1([@@]-Methylenedioxy))-B(1([2,3:@@]-(6,6-Dimethylpyrano))) | Isoflavone | 5-Hydroxy-3',4'-methylenedioxy-6'',6''-dimethylpyrano[2'',3'':7,8]isoflavone |
| 0.000 | [Dehydrorotenone]-A(1OMe, 1([2,3:@@]-Furano))-B(1([@@]-Methylenedioxy)) | Dehydrorotenone | Dehydropachyrrhizone |
| Level: 3, プリカーサーm/z: 231.05872 |
| Splash: splash10-03dr-0790000000-8e81166b0c713bb7e620 |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 213.16 | 27160 | 18 | 1000 |
| 185.03 | 23576 | 46 | 868 |
FlavonoidSearch結果
ヒットなし
| Level: 3, プリカーサーm/z: 347.16867 |
| Splash: splash10-03di-0090000000-aa1c378ecb09a52e8bcb |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 213.18 | 2252 | 134 | 1000 |
| 231.18 | 811 | 116 | 360 |
| 319.06 | 129 | 28 | 57 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.125 | [Pterocarpan]-A(1OH, 1OMe)-B(1OH, 2OMe) | Pterocarpan | 2,8-Dihydroxy-3,9,10-trimethoxypterocarpan |
| 0.077 | [Flavanone]-A(2OH, 2OMe)-B(1OMe) | Flavanone | 5,6-Dihydroxy-7,8,4'-trimethoxyflavanone |
| 0.000 | [Flavone]-A(2OH, 1OMe)-B(2OH, 1OMe) | Flavone | 5,7,3',4'-Tetrahydroxy-6,5'-dimethoxyflavone |
| 0.000 | [Flavone]-A(1OH, 2OMe)-B(3OH) | Flavone | 5,3',4',5'-Tetrahydroxy-6,7-dimethoxyflavone |
| 0.000 | [Flavone]-A(2OH, 1OMe)-B(2OH, 1OMe) | Flavone | 5,7,2',4'-Tetrahydroxy-6,5'-dimethoxyflavone |
| 0.000 | [Flavone]-A(2OH, 1OMe)-B(2OH, 1OMe) | Flavone | Ganhuangenin |
| 0.000 | [Flavone]-A(2OH, 1OMe)-B(2OH, 1OMe) | Flavone | 5,7,2',3'-Tetrahydroxy-8,6'-dimethoxyflavone |
| 0.000 | [Flavone]-A(2OH, 1OMe)-B(2OH, 1OMe) | Flavone | 5,7,3',5'-Tetrahydroxy-8,4'-dimethoxyflavone |
| 0.000 | [Flavone]-A(2OH, 1OMe)-B(2OH, 1OMe) | Flavone | 5,7,2',4'-Tetrahydroxy-8,5'-dimethoxyflavone |
| 0.000 | [Flavone]-A(2OH, 2OMe)-B(2OH) | Flavone | 5,6,2',6'-Tetrahydroxy-7,8-dimethoxyflavone |
| 0.000 | [Flavone]-A(2OH, 2OMe)-B(2OH) | Flavone | Leucanthogenin |
| 0.000 | [Flavone]-A(2OH, 2OMe)-B(2OH) | Flavone | 5,7,3',4'-Tetrahydroxy-6,8-dimethoxyflavone |
| 0.000 | [Flavone]-A(2OH, 2OMe)-B(2OH) | Flavone | 5,6,3',4'-Tetrahydroxy-7,8-dimethoxyflavone |
| 0.000 | [Flavanone]-A(1OH, 3OMe)-B(1OH) | Flavanone | 5,4'-Dihydroxy-6,7,8-trimethoxyflavanone |
| 0.000 | [Flavanone]-A(1OH, 1OMe)-B(1OH, 2OMe) | Flavanone | 5,2'-Dihydroxy-7,4',5'-trimethoxyflavanone |
| 0.000 | [Flavanone]-A(1OH, 2OMe)-B(1OH, 1OMe) | Flavanone | 5,2'-Dihydroxy-6,7,6'-trimethoxyflavanone |
| 0.000 | [Flavanone]-A(1OH, 2OMe)-B(1OH, 1OMe) | Flavanone | 5,3'-Dihydroxy-6,7,4'-trimethoxyflavanone |
| 0.000 | [Flavanone]-A(1OH, 2OMe)-B(1OH, 1OMe) | Flavanone | Agestricin D |
| 0.000 | [Flavanone]-A(1OH, 2OMe)-B(1OH, 1OMe) | Flavanone | 5,2'-Dihydroxy-7,8,6'-trimethoxyflavanone |
| 0.000 | [Flavanone]-A(1OH, 2OMe)-B(1OH, 1OMe) | Flavanone | 5,3'-Dihydroxy-7,8,4'-trimethoxyflavanone |
| 0.000 | [Dihydrochalcone]-A(1OH, 4OMe)-B(none) | Dihydrochalcone | Dihydrokanakugiol |
| 0.000 | [2'-Hydroxychalcone]-A(1OH, 3OMe)-B(2OH) | 2'-Hydroxychalcone | Hamilcone |
| 0.000 | [Flavonol]-A(1OH, 1OMe)-B(2OH, 1OMe) | Flavonol | Inucrithmin |
| 0.000 | [Flavonol]-A(1OH, 1OMe)-B(2OH, 1OMe) | Flavonol | Myricetin 7,4'-dimethyl ether |
| 0.000 | [Flavonol]-A(2OH)-B(1OH, 2OMe) | Flavonol | Myricetin 3',4'-dimethyl ether |
| 0.000 | [Flavonol]-A(2OH)-B(1OH, 2OMe) | Flavonol | Syringetin |
| 0.000 | [Flavonol]-A(2OH)-B(1OH, 2OMe) | Flavonol | Viscidulin III |
| 0.000 | [Flavonol]-A(2OH, 1OMe)-B(1OH, 1OMe) | Flavonol | Spinacetin |
| 0.000 | [Flavonol]-A(2OH, 1OMe)-B(1OH, 1OMe) | Flavonol | Laciniatin |
| 0.000 | [Flavonol]-A(2OH, 1OMe)-B(1OH, 1OMe) | Flavonol | Quercetagetin 7,3'-dimethyl ether |
| 0.000 | [Flavonol]-A(2OH, 1OMe)-B(1OH, 1OMe) | Flavonol | Gossypetin 3',8-dimethyl ether |
| 0.000 | [Flavonol]-A(2OH, 1OMe)-B(1OH, 1OMe) | Flavonol | Gossypetin 7,4'-dimethyl ether |
| 0.000 | [Flavonol]-A(2OH, 1OMe)-B(1OH, 1OMe) | Flavonol | Limocitrin |
| 0.000 | [Flavonol]-A(2OH, 1OMe)-B(1OH, 1OMe) | Flavonol | Gossypetin 8,4'-dimethyl ether |
| 0.000 | [Flavonol]-A(1OH, 2OMe)-B(2OH) | Flavonol | Eupatolitin |
| 0.000 | [Flavonol]-A(1OH, 2OMe)-B(2OH) | Flavonol | Zanthoxyl flavone |
| 0.000 | [Dihydrochalcone]-A(2OH, 1OMe, 1([@@]-Methylenedioxy))-B(1OMe) | Dihydrochalcone | 2',6'-Dihydroxy-4,3'-dimethoxy-4',5'-methylenedioxydihydrochalcone |
| 0.000 | [Dihydroflavonol]-A(2OH)-B(2OH)-C(1(O-Acetyl)) | Dihydroflavonol | Taxifolin 3-O-acetate |
| 0.000 | [Flavonol (3-OMe)]-A(2OH)-B(2OH, 1OMe) | Flavonol | Myricetin 3,4'-dimethyl ether |
| 0.000 | [Flavonol (3-OMe)]-A(2OH)-B(2OH, 1OMe) | Flavonol | Artemexitin |
| 0.000 | [Flavonol]-A(2OH, 1Methyl)-B(2OH, 1OMe) | Flavonol | Dumosol |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1Methyl)-B(3OH) | Flavonol | Alluaudiol |
| 0.000 | [Flavonol (3-OMe)]-A(2OH)-B(2OH, 1OMe) | Flavonol | 5,7,4',5'-Tetrahydroxy-3,2'-dimethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(2OH)-B(2OH, 1OMe) | Flavonol | 5,7,2',5'-Tetrahydroxy-3,4'-dimethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(3OH)-B(1OH, 1OMe) | Flavonol | Quercetagetin 3,3'-dimethyl ether |
| 0.000 | [Flavonol (3-OMe)]-A(3OH)-B(1OH, 1OMe) | Flavonol | Quercetagetin 3,4'-dimethyl ether |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1OMe)-B(2OH) | Flavonol | Axillarin |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1OMe)-B(2OH) | Flavonol | Tomentin |
| 0.000 | [Flavonol (3-OMe)]-A(3OH)-B(1OH, 1OMe) | Flavonol | Gossypetin 3,3'-dimethyl ether |
| 0.000 | [Flavonol (3-OMe)]-A(3OH)-B(1OH, 1OMe) | Flavonol | Gossypetin 3,4'-dimethyl ether |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1OMe)-B(2OH) | Flavonol | 7,8,3',4'-Trihydroxy-3,5-dimethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1OMe)-B(2OH) | Flavonol | Gossypetin 3,7-dimethyl ether |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1OMe)-B(2OH) | Flavonol | Gossypetin 3,8-dimethyl ether |
| 0.000 | [Flavonol (3-OMe)]-A(3OH, 1OMe)-B(1OH) | Flavonol | 5,7,8,4'-Tetrahydroxy-3,6-dimethoxyflavone |
| 0.000 | [Flavan 3,4-diol]-A(1OH, 1OMe, 2Methyl)-B(1OMe) | Flavan 3,4-diol | 3,4,7-Trihydroxy-5,4'-dimethoxy-6,8-dimethylflavan |
| 0.000 | [UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavan]-A(1OH, 1OMe)-B(2OMe) | UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavan | Amorphaquinone |