ピーク情報
|
きく 花びら 生 黄色
pos
|
| Peak #6070 MN MID: SE123_S060581_M90 |
| m/z: 315.15902, RT: 93.20, 強度: 15264, ログ強度: 0.75, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 1 |
| DB検索結果: (38 names) (+)-7-(3-Methylbut-2-enyloxy)-8-(2-hydroxy-3-methylbut-3-enyl)coumarin;Gibberellin A103;GA103;Auraptenol;Lupichromone;Eriosematin C;(+)-7-(3-Methylbut-2-enyloxy)-8-(4-hydroxy-3-methylbut-2-enyl)coumar... |
| DBごとのヒット数: ALL 33 KG 5 KN 27 HM 1 |
| FlavonoidSearch最大スコア MS2: 0.083, MS3: - |
DB検索結果
ppm
| 組成式 | 分子量 | 誤差(Δppm） | 候補化合物名（代表で最短名を記載） | 化合物ID |
|---|---|---|---|---|
| C19H22O4 | 314.15181 | -0.219 | (+)-7-(3-Methylbut-2-enyloxy)-8-(2-hydroxy-3-methylbut-3-enyl)coumarin | KNApSAcK: C00019960 |
| C19H22O4 | 314.15181 | -0.219 | Gibberellin A103 | KNApSAcK: C00000431 |
| C19H22O4 | 314.15181 | -0.219 | Auraptenol | KNApSAcK: C00036786 |
| C19H22O4 | 314.15181 | -0.219 | Lupichromone | KNApSAcK: C00019593 |
| C19H22O4 | 314.15181 | -0.219 | Drypetenone B | KNApSAcK: C00045869 |
| C19H22O4 | 314.15181 | -0.219 | (+)-7-(3-Methylbut-2-enyloxy)-8-(4-hydroxy-3-methylbut-2-enyl)coumarin | KNApSAcK: C00019961 |
| C19H22O4 | 314.15181 | -0.219 | Anisocoumarin H | KNApSAcK: C00019788 |
| C19H22O4 | 314.15181 | -0.219 | (-)-Rel-(pR,9S,9'S)-maximowicziol A | KNApSAcK: C00000680 |
| C19H22O4 | 314.15181 | -0.219 | 8-Geranylesculetin | KEGG: C21496 |
| C19H22O4 | 314.15181 | -0.219 | Doitungbiphenyl B | KNApSAcK: C00055805 |
| C19H22O4 | 314.15181 | -0.219 | Perrottetin B | KNApSAcK: C00015841 |
| C19H22O4 | 314.15181 | -0.219 | (-)-(aS,9S,9'S)-Alnusdiol | KNApSAcK: C00000679 |
| C19H22O4 | 314.15181 | -0.219 | Gibberellin A120 | HMDB: HMDB0038013 KNApSAcK: C00007332 |
| C19H22O4 | 314.15181 | -0.219 | Ferulagol B | KNApSAcK: C00037142 |
| C19H22O4 | 314.15181 | -0.219 | O-Methyloctandrenolone | KNApSAcK: C00046839 |
| C19H22O4 | 314.15181 | -0.219 | Menadiol dibutyrate | HMDB: HMDB0032726 |
| C19H22O4 | 314.15181 | -0.219 | 6beta-(2-Methylacryloyloxy)-9-oxoeuryopsin | KNApSAcK: C00017426 |
| C19H22O4 | 314.15181 | -0.219 | Anisocoumarin E | KNApSAcK: C00019785 |
| C19H22O4 | 314.15181 | -0.219 | Anisocoumarin F | KNApSAcK: C00019786 |
| C19H22O4 | 314.15181 | -0.219 | 7-(6R-Hydroxy-3,7-dimethylocta-2,5-dienyl)-7-hydroxycoumarin | HMDB: HMDB0039063 KNApSAcK: C00019896 |
| C19H22O4 | 314.15181 | -0.219 | Heliettin | KEGG: C09267 KNApSAcK: C00002475, C00035561 |
| C19H22O4 | 314.15181 | -0.219 | Cryptomoscatone E1 | KNApSAcK: C00036946, C00036948 |
| C19H22O4 | 314.15181 | -0.219 | 8-Geranyl-5,7-dihydroxycoumarin | KNApSAcK: C00019877 |
| C19H22O4 | 314.15181 | -0.219 | 2,3-Dehydro-gibberellin A9 | KEGG: C11866 KNApSAcK: C00000866 LipidMAPS: LMPR0104170023 |
| C19H22O4 | 314.15181 | -0.219 | Gibberellin A73 | KNApSAcK: C00000073 |
| C19H22O4 | 314.15181 | -0.219 | cis-Dehydrocrotonin | HMDB: HMDB0250947 KNApSAcK: C00036908, C00037929 |
| C19H22O4 | 314.15181 | -0.219 | Karnatakafuran A | KNApSAcK: C00043631 |
| C19H22O4 | 314.15181 | -0.219 | Grandiflorone | FlavonoidViewer: FL1DQUNM0002 KNApSAcK: C00007980 LipidMAPS: LMPK12120595 |
| C19H22O4 | 314.15181 | -0.219 | Epoxyaurapten | KNApSAcK: C00053040 |
| C19H22O4 | 314.15181 | -0.219 | Ferulagol A | KNApSAcK: C00037141 |
| C19H22O4 | 314.15181 | -0.219 | (E)-6-Hydroxy-7-(3-methyl-2-butenyl)-2-(3-oxobut-1-enyl)chroman-5-carbaldehyde | KNApSAcK: C00029333 |
| C18H26OSi2 | 314.15222 | -1.525 | 1,3-Dibenzyltetramethyldisiloxane | KEGG: C14252 |
| C20H18N4 | 314.15315 | -4.476 | Safranin | KEGG: [1f]C19919 |
MSnスペクトル情報
| Level: 2, プリカーサーm/z: 315.15903 |
| Splash: splash10-03di-0290000000-668e1576475d64baa71f |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 213.01 | 37041 | 102 | 1000 |
| 159.06 | 4569 | 156 | 123 |
| 195.06 | 2854 | 120 | 77 |
| 185.02 | 2326 | 130 | 62 |
FlavonoidSearch結果
| Score | Symbolized Name | MSMS-Category | MSMS-Aglycone |
|---|---|---|---|
| 0.083 | [2'-Hydroxychalcone]-A(1OH)-B(3OMe) | 2'-Hydroxychalcone | Crotaoprostrin |
| 0.083 | [2'-Hydroxychalcone]-A(1OH, 2OMe)-B(1OMe) | 2'-Hydroxychalcone | 2'-Hydroxy-2,4',6'-trimethoxychalcone |
| 0.083 | [2'-Hydroxychalcone]-A(1OH, 2OMe)-B(1OMe) | 2'-Hydroxychalcone | Flavokawin A |
| 0.083 | [2'-Hydroxychalcone]-A(1OH, 3OMe)-B(none) | 2'-Hydroxychalcone | Helilandin B |
| 0.083 | [2'-Hydroxychalcone]-A(1OH, 3OMe)-B(none) | 2'-Hydroxychalcone | 2'-Hydroxy-3',4',6'-trimethoxychalcone |
| 0.071 | [Chalcone]-A(1OH, 2OMe)-B(1OMe) | Chalcone | 4'-Hydroxy-2',4,6'-trimethoxychalcone |
| 0.071 | [Chalcone]-A(none)-B(1OH, 3OMe) | Chalcone | Tepanone |
| 0.071 | [Flavanone]-A(1OMe)-B(2OMe) | Flavanone | 6,3',4'-Trimethoxyflavanone |
| 0.071 | [Flavanone]-A(2OMe)-B(1OMe) | Flavanone | Naringenin trimethyl ether |
| 0.071 | [Flavanone]-A(3OMe)-B(none) | Flavanone | 5,7,8-Trimethoxyflavanone |
| 0.000 | [Flavone]-A(1OH, 1OMe)-B(1OH, 1OMe) | Flavone | Abrectorin |
| 0.000 | [Flavone]-A(2OH, 1OMe)-B(1OMe) | Flavone | 6,8-Dihydroxy-7,4'-dimethoxyflavone |
| 0.000 | [Flavone]-A(2OH)-B(2OMe) | Flavone | Luteolin 3',4'-dimethyl ether |
| 0.000 | [Flavone]-A(1OH, 1OMe)-B(1OH, 1OMe) | Flavone | Luteolin 5,3'-dimethyl ether |
| 0.000 | [Flavone]-A(1OH, 1OMe)-B(1OH, 1OMe) | Flavone | 7,3'-Dihydroxy-5,4'-dimethoxyflavone |
| 0.000 | [Flavone]-A(1OH, 1OMe)-B(1OH, 1OMe) | Flavone | Velutin |
| 0.000 | [Flavone]-A(1OH, 1OMe)-B(1OH, 1OMe) | Flavone | Pilloin |
| 0.000 | [Flavone]-A(2OH, 1OMe)-B(1OMe) | Flavone | Scutellarein 5,4'-dimethyl ether |
| 0.000 | [Flavone]-A(2OH, 1OMe)-B(1OMe) | Flavone | Pectolinarigenin |
| 0.000 | [Flavone]-A(1OH, 2OMe)-B(1OH) | Flavone | Cirsimaritin |
| 0.000 | [Flavone]-A(2OH, 1OMe)-B(1OMe) | Flavone | Ladanein |
| 0.000 | [Flavone]-A(1OH, 2OMe)-B(1OH) | Flavone | Skullcapflavone I |
| 0.000 | [Flavone]-A(2OH, 1OMe)-B(1OMe) | Flavone | 5,7-Dihydroxy-8,2'-dimethoxyflavone |
| 0.000 | [Flavone]-A(2OH, 1OMe)-B(1OMe) | Flavone | 5,8-dihydroxy-7,4'-dimethoxyflavone |
| 0.000 | [Flavone]-A(1OH, 2OMe)-B(1OH) | Flavone | Isoscutellarein 7,8-dimethyl ether |
| 0.000 | [Flavone]-A(2OH, 1OMe)-B(1OMe) | Flavone | Bucegin |
| 0.000 | [Flavone]-A(2OH, 2OMe)-B(none) | Flavone | 5,8-Dihydroxy-6,7-dimethoxyflavone |
| 0.000 | [Flavone]-A(2OH, 2OMe)-B(none) | Flavone | 5,7-Dihydroxy-6,8-dimethoxyflavone |
| 0.000 | [Anthocyanidin]-A(1OH, 1OMe)-B(1OH, 1OMe) | Anthocyanidin | Rosinidin |
| 0.000 | [Isoflavone]-A(2OH, 1OMe)-B(1OMe) | Isoflavone | Dipteryxin |
| 0.000 | [Isoflavone]-A(2OH, 1OMe)-B(1OMe) | Isoflavone | 5,7-Dihydroxy-6,2'-dimethoxyisoflavone |
| 0.000 | [Isoflavone]-A(2OH, 1OMe)-B(1OMe) | Isoflavone | Irisolidone |
| 0.000 | [Isoflavone]-A(1OH, 1OMe)-B(1OH, 1OMe) | Isoflavone | Odoratin |
| 0.000 | [Isoflavone]-A(1OH, 1OMe)-B(1OH, 1OMe) | Isoflavone | 7,2'-Dihydroxy-6,4'-dimethoxyisoflavone |
| 0.000 | [Isoflavone]-A(1OH, 1OMe)-B(1OH, 1OMe) | Isoflavone | 3'-Hydroxy-8-O-methylretusin |
| 0.000 | [Isoflavone]-A(1OH, 1OMe)-B(1OH, 1OMe) | Isoflavone | 7,3'-Dimethixyorobol |
| 0.000 | [Isoflavone]-A(1OH, 1OMe)-B(1OH, 1OMe) | Isoflavone | 5,3'-Dihydroxy-7,4'-dimethoxyisoflavone |
| 0.000 | [Isoflavone]-A(1OH, 2OMe)-B(1OH) | Isoflavone | Muningin |
| 0.000 | [Isoflavone]-A(1OH, 2OMe)-B(1OH) | Isoflavone | 7-O-Methyltectorigenin |
| 0.000 | [Isoflavone]-A(1OH, 2OMe)-B(1OH) | Isoflavone | 5,2'-Dihydroxy-7,8-dimethoxyisoflavone |
| 0.000 | [Isoflavone]-A(2OH)-B(2OMe) | Isoflavone | Pratensein 3'-O-methyl ether |
| 0.000 | [Isoflavone]-A(2OH)-B(2OMe) | Isoflavone | 2'-Methoxybiochanin A |
| 0.000 | [Isoflavone]-A(2OMe)-B(2OH) | Isoflavone | 5,7-Dimethixyorobol |
| 0.000 | [Isoflavone]-A(2OMe)-B(2OH) | Isoflavone | 2',4'-Dihydroxy-5,7-dimethoxyisoflavone |
| 0.000 | [Isoflavone]-A(1OH)-B(1OH, 2OMe) | Isoflavone | 7,2'-Dihydroxy-3',4'-dimethoxyisoflavone |
| 0.000 | [Coumestan]-A(1OH, 1OMe)-B(2OH) | Coumestan | Wedelolactone |
| 0.000 | [Flavonol]-A(1OH, 1OMe)-B(1OMe) | Flavonol | 3,7-Dihydroxy-5,4'-dimethoxyflavone |
| 0.000 | [Flavonol]-A(1OH, 1OMe)-B(1OMe) | Flavonol | Kaempferol 7,4'-dimethyl ether |
| 0.000 | [Flavonol]-A(1OH, 2OMe)-B(none) | Flavonol | 3,7-Dihydroxy-5,6-dimethoxyflavone |
| 0.000 | [Flavonol]-A(1OH, 2OMe)-B(none) | Flavonol | 3,6-Dihydroxy-5,7-dimethoxyflavone |
| 0.000 | [Flavonol]-A(1OH, 2OMe)-B(none) | Flavonol | 3,5-Dihydroxy-6,7-dimethoxyflavone |
| 0.000 | [Flavonol]-A(1OH, 2OMe)-B(none) | Flavonol | 3,5-Dihydroxy-7,8-dimethoxyflavone |
| 0.000 | [Flavonol]-A(2OMe)-B(1OH) | Flavonol | 3,4'-Dihydroxy-7,8-dimethoxyflavone |
| 0.000 | [Pterocarpan]-A(2OMe)-B(1OMe) | Pterocarpan | 2-Methoxyhomopterocarpin |
| 0.000 | [Pterocarpan]-A(2OMe)-B(1OMe) | Pterocarpan | 4-Methoxyhomopterocarpin |
| 0.000 | [Aurone]-A(1OH, 1OMe, 1Methyl)-B(2OH) | Aurone | 6,3',4'-Trihydroxy-4-methoxy-5-methylaurone |
| 0.000 | [Aurone]-A(1OH, 1OMe, 1Methyl)-B(2OH) | Aurone | 6,3',4'-Trihydroxy-4-methoxy-7-methylaurone |
| 0.000 | [2'-Hydroxychalcone]-A(2OH, 1OMe)-B(1([@@]-Methylenedioxy)) | 2'-Hydroxychalcone | Prosogerin B |
| 0.000 | [2'-Hydroxychalcone]-A(1OH, 1OMe, 1([@@]-Methylenedioxy))-B(1OH) | 2'-Hydroxychalcone | 4,2'-Dihydroxy-6'-methoxy-3',4'-methylenedioxychalcone |
| 0.000 | [beta-Hydroxy(or Oxodihydro)chalcone]-A(3OH, 1Formyl, 1Methyl)-B(none) | beta-Hydroxy(or Oxodihydro)chalcone | 3'-Formyl-2',4',6',beta-tetrahydroxy-5'-methylchalcone |
| 0.000 | [UBR-type derivative / [2',5']-Benzoquinonyl-type chalcone]-A(1OH, 2OMe)-B(none) | UBR-type derivative / [2',5']-Benzoquinonyl-type chalcone | Methylpedicinin |
| 0.000 | [UBR-type derivative / 2'-Oxocyclohexa-4',6'-dienyl-type beta-Hydroxychalcone]-A(1OH, 1OMe, 2Methyl)-B(none) | UBR-type derivative / 2'-Oxocyclohexa-4',6'-dienyl-type beta-Hydroxychalcone | Syzygiol |
| 0.000 | [Dihydrochalcone]-A(2OMe)-B(1([@@]-Methylenedioxy)) | Dihydrochalcone | Ponganone VII |
| 0.000 | [Dihydrochalcone]-A(2OMe, 1([@@]-Methylenedioxy))-B(none) | Dihydrochalcone | 2',6'-Dimethoxy-3',4'-methylenedioxydihydrochalcone |
| 0.000 | [UBR-type derivative / 2',4'-Dioxo-6'-cyclohexenyl-type Dihydrochalcone]-A(1OH, 4Methyl)-B(none) | UBR-type derivative / 2',4'-Dioxo-6'-cyclohexenyl-type Dihydrochalcone | Grandiflorone |
| 0.000 | [Flavanone]-A(1OH, 1OMe)-B(1([@@]-Methylenedioxy)) | Flavanone | 6-Hydroxy-7-methoxy-3',4'-methylenedioxyflavanone |
| 0.000 | [Flavanone]-A(1OH, 1OMe, 1Hydroxymethyl, 1Methyl)-B(none) | Flavanone | Leridol |
| 0.000 | [Flavanone]-A(2OH, 2Methyl)-B(1OMe) | Flavanone | Isomatteucinol |
| 0.000 | [Flavanone]-A(2OH, 2Methyl)-B(1OMe) | Flavanone | Matteucinol |
| 0.000 | [Flavanone]-A(1OH, 1OMe, 2Methyl)-B(1OH) | Flavanone | Angophorol |
| 0.000 | [Flavone]-A(1OH, 1OMe, 1Methyl)-B(2OH) | Flavone | 5,3',4'-Trihydroxy-7-methoxy-6-methylflavone |
| 0.000 | [Dihydroflavonol]-A(2OH)-B(none)-C(1(O-Acetyl)) | Dihydroflavonol | Pinobanksin 3-O-acetate |
| 0.000 | [Dihydroflavonol]-A(1OMe, 1([@@]-Methylenedioxy))-B(none) | Dihydroflavonol | 3-Hydroxy-5-methoxy-6,7-methylenedioxyflavanone |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 1OMe)-B(1OH) | Flavonol | 7,4'-Dihydroxy-3,6-dimethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1Methyl)-B(1OH) | Flavonol | Sylpin |
| 0.000 | [Flavonol (3-OMe)]-A(2OH)-B(1OMe) | Flavonol | Ermanin |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 1OMe)-B(1OH) | Flavonol | Kaempferol 3,5-dimethyl ether |
| 0.000 | [Flavonol (3-OMe)]-A(1OH, 1OMe)-B(1OH) | Flavonol | Kumatakenin |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1Methyl)-B(1OH) | Flavonol | 5,7,4'-Trihydroxy-3-methoxy-6-methylflavone |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1OMe)-B(none) | Flavonol | Alnusin 3-methyl ether |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1OMe)-B(none) | Flavonol | 5,6-Dihydroxy-3,7-dimethoxyflavone |
| 0.000 | [Flavonol]-A(1OH, 1([@@]-Methylenedioxy))-B(1OH) | Flavonol | Gomphrenol |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1OMe)-B(none) | Flavonol | 5,8-Dihydroxy-3,7-dimethoxyflavone |
| 0.000 | [Flavonol (3-OMe)]-A(2OH, 1OMe)-B(none) | Flavonol | Gnaphaliin |
| 0.000 | [Flavonol (3-OMe)]-A(3OH, 1Methyl)-B(none) | Flavonol | Platanin 3-methyl ether |
| 0.000 | [Flavonol]-A(2OH, 1OMe, 1Methyl)-B(none) | Flavonol | 3,5,8-Trihydroxy-7-methoxy-6-methylflavone |
| 0.000 | [Flavonol]-A(2OH, 1OMe, 1Methyl)-B(none) | Flavonol | Pityrogrammin |
| 0.000 | [CCS-type derivative / [3,2']-Epoxymethanoflavone]-A(2OH)-B(2OH) | CCS-type derivative / [3,2']-Epoxymethanoflavone | 2,3,8,10-Tetrahydroxy[2]benzopyrano[4,3-b][1]benzopyran-7(5H)-one |
| 0.000 | [CCS-type derivative / [3,2']-Epoxyhydroxymethanoflavone]-A(1OH)-B(2OH) | CCS-type derivative / [3,2']-Epoxyhydroxymethanoflavone | Fasciculiferin |
| 0.000 | [Flavan]-A(1OH, 2Methyl)-B(1OH, 1([@@]-Methylenedioxy)) | Flavan | 7,2'-Dihydroxy-6,8-dimethyl-4',5'-methylenedioxyflavan |
| 0.000 | [Flavan]-A(1OH, 2Methyl)-B(1OH, 1([@@]-Methylenedioxy)) | Flavan | 7,2'-Dihydroxy-5,8-dimethyl-4',5'-methylenedioxyflavan |
| 0.000 | [3-DehydroxyAnthocyanidin]-A(2OH, 1OMe)-B(1OH, 1OMe) | 3-DehydroxyAnthocyanidin | 5,4'-Dimethyl-6-hydroxyluteolinidin |
| 0.000 | [UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavone]-A(2OH)-B(1OMe) | UBR-type derivative / [2',5']-Benzoquinonyl-type Isoflavone | 5-Hydroxybowdichione |
| 0.000 | [Isoflavanone]-A(1OH)-B(1OMe, 1([@@]-Methylenedioxy)) | Isoflavanone | Onogenin |
| 0.000 | [Pterocarpan]-A(1OH, 1OMe)-B(1([@@]-Methylenedioxy)) | Pterocarpan | 2-Hydroxyhomopterocarpin |
| 0.000 | [Pterocarpan]-A(1OH, 1OMe)-B(1([@@]-Methylenedioxy)) | Pterocarpan | 4-Methoxymaackiain |
| 0.000 | [Pterocarpan]-A(1OH, 1OMe)-B(1([@@]-Methylenedioxy)) | Pterocarpan | 4-Hydroxypterocarpin |
| 0.000 | [Pterocarpan-6a-ol]-A(1OMe)-B(1([@@]-Methylenedioxy)) | Pterocarpan-6a-ol | Pisatin |
| 0.000 | [Pterocarpan-6-ol (6-OMe)]-A(1OH)-B(1([@@]-Methylenedioxy)) | Pterocarpan-6-ol | Sophoracarpan B |
| 0.000 | [Pterocarpan-6-ol (3-OMe)]-A(1OMe)-B(1OMe) | Pterocarpan-6-ol | 6-Methoxyhomopterocarpin |
| 0.000 | [4-phenylcoumarin]-A(1OH, 1OMe)-B(1OH, 1OMe) | 4-phenylcoumarin | Melannein |
| 0.000 | [4-phenylcoumarin]-A(1OH, 1OMe)-B(1OH, 1OMe) | 4-phenylcoumarin | 7,3'-Dihydroxy-5,4'-dimethoxy-4-phenylcoumarin |
| 0.000 | [4-phenylcoumarin]-A(1OH, 1OMe)-B(1OH, 1OMe) | 4-phenylcoumarin | 5,3'-Dihydroxy-7,4'-dimethoxy-4-phenylcoumarin |
| 0.000 | [4-phenylcoumarin]-A(2OMe)-B(2OH) | 4-phenylcoumarin | 3',4'-Dihydroxy-5,7-dimethoxy-4-phenylcoumarin |
| Level: 3, プリカーサーm/z: 213.02628 |
| Splash: splash10-014i-0900000000-de9d49d2dd8d4437411e |
| m/z | Int. | NL | Rel.Int. |
|---|---|---|---|
| 168.97 | 14225 | 44 | 1000 |
FlavonoidSearch結果
ヒットなし