ピーク情報

マカダミアナッツいり味付け

pos

Peak #6245 MN MID: SE118_S050311_M90

m/z: 467.31584, RT: 82.77, 強度: 6728, ログ強度: 0.48, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 1

DB検索結果: (17 names) Neoabieslactone D;(-)-Neoabieslactone D;Mastigophorene C;[S-(R*,R*)]-3-[[3,4-Dihydroxy-5-(1,2,2-trimethylcyclopentyl)phenyl]methyl]-4-methyl-6-(1,2,2-trimethylcyclopentyl)-1,2-benzenediol;Papyriogenin...

DBごとのヒット数: ALL 10 KN 10

FlavonoidSearch最大スコア MS2: 0.024, MS3: 0.118

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C30H42O4	466.30831	0.535	Neoabieslactone D	KNApSAcK: C00047521
C30H42O4	466.30831	0.535	Mastigophorene C	KNApSAcK: C00012549 LipidMAPS: LMPR0103160013
C30H42O4	466.30831	0.535	Papyriogenin A	KNApSAcK: C00034622
C30H42O4	466.30831	0.535	Ethyl 2â³-(5-hydroxy-3Sâ²-methyl-3â²-geranylgeranyl-2H-chromen-1-yl)acetate	LipidMAPS: LMPR02020089, LMPR02020090
C30H42O4	466.30831	0.535	Methyl 15-cinnamoyloxy-7-labden-17-oate	KNApSAcK: C00023420
C30H42O4	466.30831	0.535	[S-(R,R)]-4,4'-(1,2-Ethanediyl)bis[6-(1,2,2-trimethylcyclopentyl)-1,2-benzenediol	KNApSAcK: C00012550
C30H42O4	466.30831	0.535	Mastigophorene A	KNApSAcK: C00032002, C00032003 LipidMAPS: LMPR0103160012
C30H42O4	466.30831	0.535	Neoabieslactone E	KNApSAcK: C00047522
C30H42O4	466.30831	0.535	Stellettin K	KNApSAcK: C00041883
C30H42O4	466.30831	0.535	Lucialdehyde D	KNApSAcK: C00042706
C30H42O4	466.30831	0.535	Kuguacin O	KNApSAcK: C00048464

MSnスペクトル情報

Level: 2, プリカーサーm/z: 467.31595

Splash: splash10-05bo-0917100000-ab7701dedbee449dff8e

m/z	Int.	NL	Rel.Int.
177.12	755	290	1000
371.26	559	96	739
343.30	393	124	520
191.14	386	276	511
136.99	363	330	480
163.02	293	304	388
449.49	280	18	371
385.41	215	82	285
357.30	215	110	284
205.13	207	262	273
367.33	163	100	216
150.99	63	316	83
203.00	50	264	65
329.27	47	138	62
219.14	43	248	57
369.34	42	98	55
148.96	41	318	54
158.99	39	308	51

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.024	[Isoflavone]-A(2OH, 1(C-Prenyl))-B(1OH, 2OMe, 1(C-Prenyl))	Isoflavone	Pumilaisoflavone C
0.000	[Flavanone]-A(2OH)-B(1([2,3:@@]-(5-Hydroxymethyl-6-(p-hydroxy-m-methoxyphenyl)-dihydro[1,4]dioxinyl)))	Flavanone	Silandrin
0.000	[Flavanone]-A(2OH)-B(1OH, 1([2,3:@@]-(4-Hydroxymethyl-5-(p-hydroxy-m-methoxyphenyl)furano)))	Flavanone	Silyhermin
0.000	[Flavanone]-A(2OH)-B(1OH, 1([2,3:@@]-(4-Hydroxymethyl-5-(p-hydroxy-m-methoxyphenyl)furano)))	Flavanone	Neosilyhermin A
0.000	[UBR-type derivative / 3'-Oxocyclohexa-6'-enyl-type Flavanone]-A(2OH)-B(1OH, 1(m-((4-Hydroxy-3-methoxyphenyl)-([5,4;n,o]-tetrahydrofuran-3-yl)-methyl)))	UBR-type derivative / 3'-Oxocyclohexa-6'-enyl-type Flavanone	Silymonin
0.000	[Flavone]-A(1OMe, 1([2,3:@@]-(4-(1,2-diacetoxy-2-methylpropyl)-dihydrofurano)))-B(none)	Flavone	Polystachin (flavone)
0.000	[Dihydroflavonol]-A(2OH, 1(C-Glu))-B(2OH)	Dihydroflavonol	6-C-Glucosyltaxifolin
0.000	[Isoflavone]-A(1OH, 1(C-Prenyl), 1(1(O-(2-Hydroxyethyl))-[2,3:@@]-(5-(Hydroxyisopropanyl)dihydrofurano)))-B(1OH)	Isoflavone	Eriotriochin

Level: 3, プリカーサーm/z: 371.35812

Splash: splash10-000i-0900000000-97019af94693fee25d16

m/z	Int.	NL	Rel.Int.
137.00	194	234	1000
163.01	14	208	73
247.31	13	124	66
191.20	11	180	58
177.03	10	194	52

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.118	[Isoflavanone]-A(2OH, 1(C-Prenyl))-B(1OH, 1OMe)	Isoflavanone	4'-O-Methylkievitone
0.118	[Isoflavanone]-A(2OH, 1(C-Prenyl))-B(1OH, 1OMe)	Isoflavanone	Diphysolidone
0.111	[Flavanone]-A(1OH, 1OMe, 1(C-Prenyl))-B(2OH)	Flavanone	5,3',4'-Trihydroxy-7-methoxy-8-C-prenylflavanone
0.111	[Flavanone]-A(1OH, 1OMe, 1(C-Prenyl))-B(2OH)	Flavanone	Kenusanone I
0.053	[Flavanone]-A(2OH, 1(C-Prenyl))-B(1OH, 1OMe)	Flavanone	Exiguaflavanone K
0.037	[Flavonol]-A(2OH, 1(C-Prenyl))-B(2OH)	Flavonol	Gancaonin P
0.037	[Flavonol]-A(2OH)-B(2OH, 1(C-Prenyl))	Flavonol	2'-Prenylrhynchosin
0.037	[Flavonol]-A(2OH)-B(2OH, 1(C-Prenyl))	Flavonol	Uralenol
0.000	[Flavone]-A(2OH, 1(C-Prenyl))-B(1OH, 1OMe)	Flavone	Torosaflavone D
0.000	[Dihydroflavonol]-A(2OH, 1OMe, 1(C-Prenyl))-B(none)	Dihydroflavonol	Dioclenol
0.000	[Flavanone]-A(2OH)-B(1OH, 1OMe, 1(C-Prenyl))	Flavanone	5'-Prenylhomoeriodictyol
0.000	[Flavanone]-A(2OH)-B(1OH, 1OMe, 1(C-Prenyl))	Flavanone	4'-Methylsigmoidin B
0.000	[Flavanone]-A(2OH, 1OMe, 1(C-Prenyl))-B(1OH)	Flavanone	Dioflorin
0.000	[Isoflavanone]-A(2OH)-B(1OH, 1OMe, 1(C-Prenyl))	Isoflavanone	3S-5,7,3'-Trihydroxy-4'-methoxy-5'-prenylisoflavanone
0.000	[Isoflavanone]-A(2OH)-B(1OH, 1OMe, 1(C-Prenyl))	Isoflavanone	Sophoraisoflavanone A
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1(2-Hydroperoxy-3-methyl-3-butenyl))-B(1OH)	2'-Hydroxychalcone	Xanthoangelol E
0.000	[2'-Hydroxychalcone]-A(2OH, 1OMe, 1(2-hydroxy-3-methyl-3-butenyl))-B(1OH)	2'-Hydroxychalcone	Xanthohumol D
0.000	[2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(6,6-Dimethyl-5-hydroxydihydropyrano)))-B(1OH)	2'-Hydroxychalcone	Dehydrocycloxanthohumol hydratechalcone
0.000	[Dihydrochalcone]-A(1OH, 2OMe, 1([2,3:@@]-Furano))-B(1([@@]-Methylenedioxy))	Dihydrochalcone	2'-Hydroxy-5',6'-dimethoxy-3,4-methylenedioxyfurano[2'',3'':4',3'] dihydrochalcon
0.000	[Flavanone]-A(2OH, 1(2-hydroxy-3-methyl-3-butenyl))-B(1OMe)	Flavanone	5,7-Dihydroxy-4'-methoxy-8-C-(2-hydroxy-3-methyl-3-butenyl)flavanone
0.000	[Flavanone]-A(2OH, 1(1,1-Dimethylallyl))-B(1OH, 1OMe)	Flavanone	5,7,4'-Trihydroxy-3'-methoxy-6-(1,1-dimethylallyl)flavanone
0.000	[Flavone]-A(2OH, 1(3-Hydroxy-3-methyl-1-butenyl))-B(2OH)	Flavone	Oxidihydroartocarpesin
0.000	[Dihydroflavonol]-A(1OH, 1OMe, 1Methyl)-B(1OH)	Dihydroflavonol	5,7,4'-Trihydroxy-5-methoxy-8-prenylflavanone
0.000	[Dihydroflavonol]-A(1OH, 1([2,3:@@]-(6-Methyl-4,7-dihydrooxepino)))-B(2OH)	Dihydroflavonol	7,8-Dihydrooxepinodihydroquercetin
0.000	[Dihydroflavonol]-A(1OH, 1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(2OH)	Dihydroflavonol	Shuterone A
0.000	[Flavonol]-A(2OH)-B(1([2,3:@@]-(6,6-Dimethyl-5-hydroxydihydropyrano)))	Flavonol	Glycyrrhiza flavonol A
0.000	[Flavonol (3-OMe)]-A(1OMe, 1([@@]-Methylenedioxy))-B(1([@@]-Methylenedioxy))	Flavonol	Meliternatin
0.000	[CCS-type derivative / [3,2']-Epoxymethanoflavone]-A(1OH, 2OMe)-B(1([@@]-Methylenedioxy))	CCS-type derivative / [3,2']-Epoxymethanoflavone	6-Methoxypulcherrimin
0.000	[Flavan 3,4-diol]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1OH)	Flavan 3,4-diol	4beta-Hydroxyobovatachromene
0.000	[Flavan 3,4-diol]-A(2OMe, 1([2,3:@@]-Furano))-B(none)	Flavan 3,4-diol	3,4,5,6-Tetramethoxyfurano[2,3-h]flavan
0.000	[Flavan 3,4-diol]-A(2OMe, 1([2,3:@@]-Furano))-B(none)	Flavan 3,4-diol	Diplotropin
0.000	[Isoflavone]-A(2OH, 1((Z)-4-hydroxyprenyl))-B(2OH)	Isoflavone	2,3-Dehydrokievitol
0.000	[Isoflavone]-A(1OH, 1([2,3:@@]-(5-(Hydroxyisopropanyl)dihydrofurano)))-B(2OH)	Isoflavone	Lunatone
0.000	[Isoflavone]-A(1OH, 1([2,3:@@]-(5-(Hydroxyisopropanyl)dihydrofurano)))-B(2OH)	Isoflavone	Lupinisoflavone B
0.000	[Isoflavone]-A(2OH)-B(1OH, 1([2,3:@@]-(5-(Hydroxyisopropanyl)dihydrofurano)))	Isoflavone	Lupinisoflavone D
0.000	[Isoflavan]-A(1OH)-B(1OH, 2OMe, 1(1,1-Dimethylallyl))	Isoflavan	Unanisoflavan
0.000	[Pterocarpan-6a-ol]-A(1OH)-B(1OH, 1OMe, 1(C-Prenyl))	Pterocarpan-6a-ol	Sphenostylin B
0.000	[6-Oxodehydrorotenone]-A(1OH, 1OMe)-B(2OMe)	6-Oxodehydrorotenone	Stemonone

Level: 3, プリカーサーm/z: 177.10069

Splash: splash10-0002-0900000000-e9e96988e29f064b8599

m/z	Int.	NL	Rel.Int.
148.98	128	28	1000
159.10	22	18	175
121.09	13	56	100
162.02	11	15	89
279.01	8	-102	61
140.89	7	36	55
131.07	7	46	51