ピーク情報

（くり類）日本ぐり生

pos

Peak #1394 MN MID: SE123_S050101_M90

m/z: 363.10504, RT: 28.39, 強度: 2067, ログ強度: -0.10, アダクト: [M+K]+, 共有数（同様のピークを含むサンプル数）: 2

DB検索結果: (3 names) Methyl di-alpha-L-rhamnoside;Antibiotic DO 248A;Resorcinomycin A

DBごとのヒット数: ALL 2 KN 2

FlavonoidSearch最大スコア MS2: 0.107, MS3: 0.222

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C13H24O9	324.14203	-0.460	Methyl di-alpha-L-rhamnoside	KNApSAcK: C00051555
C14H20O5N4	324.14337	-4.586	Antibiotic DO 248A	KNApSAcK: C00017646

MSnスペクトル情報

Level: 2, プリカーサーm/z: 363.10464

Splash: splash10-0002-0149000000-0762ad436474dbd083eb

m/z	Int.	NL	Rel.Int.
345.23	501	18	1000
335.26	88	28	174
327.02	82	36	163
275.55	68	88	136
231.28	63	132	124
220.27	52	143	102
193.07	51	170	102
201.01	45	162	89
288.00	44	75	88
290.90	42	72	84
132.97	42	230	83
303.13	40	60	79
247.03	32	116	63
354.38	31	9	62
317.30	28	46	56

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.107	[Flavonol]-A(2OH, 1OMe)-B(2OH, 1OMe)	Flavonol	3,5,7,3',5'-Pentahydroxy-6,4'-dimethoxyflavone
0.107	[Flavonol]-A(2OH, 1OMe)-B(2OH, 1OMe)	Flavonol	Hibiscetin 8,3'-dimethyl ether
0.107	[Flavonol]-A(2OH, 2OMe)-B(2OH)	Flavonol	3,5,7,3',4'-Pentahydroxy-6,8-dimethoxyflavone
0.040	[Flavanone]-A(2OH, 1OMe)-B(1OH, 2OMe)	Flavanone	5,7,3'-Trihydroxy-6,4',5'-trimethoxyflavanone
0.000	[Isoflavan]-A(1OH, 2OMe)-B(1OH, 2OMe)	Isoflavan	Machaerol B
0.000	[Flavanone]-A(2OH, 1(2-hydroxybenzyl))-B(none)	Flavanone	Isochamanetin
0.000	[Flavanone]-A(2OH, 1(2-hydroxybenzyl))-B(none)	Flavanone	Chamanetin
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(3OH)	Flavonol	5,7,3',4',5'-Pentahydroxy-3,6-dimethoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(3OH)	Flavonol	5,7,2',3',4'-Pentahydroxy-3,6-dimethoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(3OH)	Flavonol	5,8,3',4',5'-Pentahydroxy-3,7-dimethoxyflavone
0.000	[Flavonol (3-OMe)]-A(3OH, 1OMe)-B(2OH)	Flavonol	5,7,8,3',4'-Pentahydroxy-3,6-dimethoxyflavone
0.000	[Flavan 3-ol]-A(2OH, 1OMe)-B(2OH)-C(1(O-Acetyl))	Flavan 3-ol	3,7,8,3',4'-Pentahydroxy-5-methoxyflavan 3-O-acetate

Level: 3, プリカーサーm/z: 345.22519

Splash: splash10-004i-0059000000-2324933488ed0182b30f

m/z	Int.	NL	Rel.Int.
327.19	67	18	1000
299.12	19	46	288
253.05	17	92	257
301.70	10	44	150
310.07	8	35	116
260.95	6	84	91
149.10	6	196	83
328.06	6	17	82
201.34	5	144	77
273.55	5	72	69
282.98	4	62	64
230.71	4	115	54
315.12	4	30	52

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.222	[Isoflavone]-A(1OH, 1OMe)-B(1OH, 2OMe)	Isoflavone	Derrugenin
0.222	[Isoflavone]-A(1OH, 2OMe)-B(1OH, 1OMe)	Isoflavone	5,3'-Dihydroxy-7,8,2'-trimethoxyisoflavone
0.222	[Isoflavone]-A(2OH, 1OMe)-B(2OMe)	Isoflavone	Junipegenin B
0.222	[Isoflavone]-A(2OH, 1OMe)-B(2OMe)	Isoflavone	5,7-Dihydroxy-8,3',4'-trimethoxyisoflavone
0.222	[Isoflavone]-A(2OH)-B(3OMe)	Isoflavone	Panchovillin
0.158	[2'-Hydroxychalcone]-A(2OH, 3OMe)-B(none)	2'-Hydroxychalcone	3'-Hydroxy-2',4',5',6'-tetramethoxychalcone
0.100	[2'-Hydroxychalcone]-A(1OH, 3OMe)-B(1OMe)	2'-Hydroxychalcone	6'-Hydroxy-4,2',3',4'-tetramethoxychalcone
0.100	[2'-Hydroxychalcone]-A(1OH, 4OMe)-B(none)	2'-Hydroxychalcone	Kanakugiol
0.100	[2'-Hydroxychalcone]-A(1OH, 2OMe)-B(2OMe)	2'-Hydroxychalcone	Okanin 3,4,3',4'-tetramethyl ether
0.100	[2'-Hydroxychalcone]-A(1OH, 2OMe)-B(2OMe)	2'-Hydroxychalcone	2'-Hydroxy-2,3,4',6'-tetramethoxychalcone
0.100	[2'-Hydroxychalcone]-A(1OH, 2OMe)-B(2OMe)	2'-Hydroxychalcone	2'-Hydroxy-3,4,4',6'-tetramethoxychalcone
0.100	[2'-Hydroxychalcone]-A(1OH, 2OMe)-B(2OMe)	2'-Hydroxychalcone	Cerasidin
0.091	[Flavanone]-A(4OMe)-B(none)	Flavanone	Kanakugin
0.091	[Flavanone]-A(3OMe)-B(1OMe)	Flavanone	5,6,7,4'-Tetramethoxyflavanone
0.091	[Flavanone]-A(2OMe)-B(2OMe)	Flavanone	5,7,2',5'-Tetramethoxyflavanone
0.091	[Flavanone]-A(2OMe)-B(2OMe)	Flavanone	Arjunone
0.077	[Anthocyanidin]-A(1OH, 1OMe)-B(1OH, 2OMe)	Anthocyanidin	3,7,4'-Trihydroxy-5,3',5'-trimethoxyflavylium
0.077	[Anthocyanidin]-A(1OH, 1OMe)-B(1OH, 2OMe)	Anthocyanidin	Hirsutidin
0.074	[Flavonol]-A(1OMe)-B(1OH, 2OMe)	Flavonol	3,4'-Dihydroxy-7,3',5'-trimethoxyflavone
0.074	[Flavonol]-A(1OH, 2OMe)-B(1OMe)	Flavonol	Mikanin
0.074	[Flavonol]-A(1OH, 2OMe)-B(1OMe)	Flavonol	Tambulin
0.074	[Flavonol]-A(1OH, 1OMe)-B(2OMe)	Flavonol	3,7-Dihydroxy-5,3',4'-trimethoxyflavone
0.074	[Flavonol]-A(1OH, 1OMe)-B(2OMe)	Flavonol	Quercetin 7,3',4'-trimethyl ether
0.074	[Flavonol]-A(1OH, 3OMe)-B(none)	Flavonol	3,5-Dihydroxy-6,7,8-trimethoxyflavone
0.074	[Flavonol]-A(3OMe)-B(1OH)	Flavonol	Candidol
0.000	[Flavone]-A(2OH)-B(3OMe)	Flavone	Prosogerin E
0.000	[Flavone]-A(1OH, 1OMe)-B(1OH, 2OMe)	Flavone	8,3'-Dihydroxy-7,4',5'-trimethoxyflavone
0.000	[Flavone]-A(1OH, 1OMe)-B(1OH, 2OMe)	Flavone	5,5'-Dihydroxy-8,3',4'-trimethoxyflavone
0.000	[Flavone]-A(2OH)-B(3OMe)	Flavone	Tricetin 3',4',5'-trimethyl ether
0.000	[Flavone]-A(1OH, 1OMe)-B(1OH, 2OMe)	Flavone	Lethedocin
0.000	[Flavone]-A(1OH, 1OMe)-B(1OH, 2OMe)	Flavone	5,4'-dihydroxy-7,3',5'-trimethoxyflavone
0.000	[Flavone]-A(3OMe)-B(2OH)	Flavone	3',4'-Dihydroxy-5,6,7-trimethoxyflavone
0.000	[Flavone]-A(2OH, 1OMe)-B(2OMe)	Flavone	Eupatilin
0.000	[Flavone]-A(1OH, 2OMe)-B(1OH, 1OMe)	Flavone	Cirsilineol
0.000	[Flavone]-A(1OH, 2OMe)-B(1OH, 1OMe)	Flavone	Eupatorin
0.000	[Flavone]-A(2OH, 1OMe)-B(2OMe)	Flavone	6-Hydroxyluteolin 7,3',4'-trimethyl ether
0.000	[Flavone]-A(1OH, 2OMe)-B(1OH, 1OMe)	Flavone	Wightin
0.000	[Flavone]-A(1OH, 2OMe)-B(1OH, 1OMe)	Flavone	Rivularin (flavone)
0.000	[Flavone]-A(2OH, 1OMe)-B(2OMe)	Flavone	5,7-Dihydroxy-8,2',6'-trimethoxyflavone
0.000	[Flavone]-A(2OH, 1OMe)-B(2OMe)	Flavone	5,7-Dihydroxy-8,3',5'trimethoxyflavone
0.000	[Flavone]-A(1OH, 2OMe)-B(1OH, 1OMe)	Flavone	8,3'-Dihydroxy-5,7,4'-trimethoxyflavone
0.000	[Flavone]-A(2OH, 1OMe)-B(2OMe)	Flavone	Hypolaetin 8,3',4'-trimethyl ether
0.000	[Flavone]-A(1OH, 3OMe)-B(1OH)	Flavone	Tenaxin I
0.000	[Flavone]-A(2OH, 2OMe)-B(1OMe)	Flavone	Pedunculin
0.000	[Flavone]-A(1OH, 3OMe)-B(1OH)	Flavone	Xanthomicrol
0.000	[Flavone]-A(2OH, 2OMe)-B(1OMe)	Flavone	Nevadensin
0.000	[Flavone]-A(2OH, 2OMe)-B(1OMe)	Flavone	5,6-Dihydroxy-7,8,4'-trimethoxyflavone
0.000	[Aurone]-A(3OMe)-B(2OH)	Aurone	Hamiltrone
0.000	[2'-Hydroxychalcone]-A(2OH, 2OMe)-B(1([@@]-Methylenedioxy))	2'-Hydroxychalcone	Agestricin A
0.000	[Dihydrochalcone]-A(3OMe)-B(1([@@]-Methylenedioxy))	Dihydrochalcone	2',4',6'-Trimethoxy-3,4-methylenedioxydihydrochalcone
0.000	[Dihydrochalcone beta-ol (2-OMe)]-A(1([@@]-Methylenedioxy))-B(2OMe)	Dihydrochalcone beta-ol	Dihydroisomilletenone methyl ether
0.000	[Dihydrochalcone beta-ol (beta-OMe)]-A(2OMe)-B(1([@@]-Methylenedioxy))	Dihydrochalcone beta-ol	Dihydromilletenone methyl ether
0.000	[Flavanone]-A(1OH, 1OMe, 1Methyl)-B(2OMe)	Flavanone	5-Hydroxy-7,3',4'-trimethoxy-6-C-methylflavanone
0.000	[Flavanone]-A(2OMe, 1Methyl)-B(1OH, 1OMe)	Flavanone	3'-Hydroxy-5,7,4'-trimethoxy-8-C-methylflavanone
0.000	[Flavanone]-A(1OH, 2OMe)-B(1([@@]-Methylenedioxy))	Flavanone	Agestricin B
0.000	[UBR-type derivative / [2',5']-Benzoquinonyl-type Flavanone]-A(1OH, 1OMe, 1Methyl)-B(1OMe)	UBR-type derivative / [2',5']-Benzoquinonyl-type Flavanone	Breverin
0.000	[Flavone]-A(1([2,3:@@]-(6,6-Dimethylpyrano)), 1([2,3:@@]-Furano))-B(none)	Flavone	Sanaganone
0.000	[Dihydroflavonol]-A(2OH)-B(1OMe)-C(1(O-Acetyl))	Dihydroflavonol	Aromadendrin 4'-methyl ether 3-O-acetate
0.000	[Dihydroflavonol]-A(1OH, 1OMe)-B(1OH)-C(1(O-Acetyl))	Dihydroflavonol	Aromadendrin 7-methyl ether 3-O-acetate
0.000	[Flavonol (3-OMe)]-A(1OMe)-B(2OH, 1OMe)	Flavonol	4',5'-Dihydroxy-3,7,3'-trimethoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH)-B(2OMe)	Flavonol	Quercetin 3,3',4'-trimethyl ether
0.000	[Flavonol (3-OMe)]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavonol	Quercetin 3,5,3'-trimethyl ether
0.000	[Flavonol (3-OMe)]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavonol	Pachypodol
0.000	[Flavonol (3-OMe)]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavonol	Ayanin
0.000	[Flavonol (3-OMe)]-A(2OH, 1Methyl)-B(1OH, 1OMe)	Flavonol	6-C-Methylquercetin 3,3'-dimethyl ether
0.000	[Flavonol (3-OMe)]-A(1OH, 1OMe, 1Methyl)-B(2OH)	Flavonol	2-(3,4-Dihydroxyphenyl)-5-hydroxy-3,7-dimethoxy-6-methyl-4H-1-benzopyran-4-one
0.000	[Flavonol (3-OMe)]-A(2OH, 2Methyl)-B(2OH)	Flavonol	2-(3,4-Dihydroxyphenyl)-5,7-dihydroxy-3-methoxy-6,8-dimethyl-4H-1-benzopyran-4-one
0.000	[Flavonol (3-OMe)]-A(2OH)-B(2OMe)	Flavonol	Morin 3,2',4'-trimethyl ether
0.000	[Flavonol (3-OMe)]-A(1OH, 1OMe)-B(1OH, 1OMe)	Flavonol	Morin 3,7,4'-trimethyl ether
0.000	[Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH)	Flavonol	6-Hydroxykaempferol 3,5,7-trimethyl ether
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(1OMe)	Flavonol	Santin
0.000	[Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH)	Flavonol	Penduletin
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(1OMe)	Flavonol	Tanetin
0.000	[Flavonol (3-OMe)]-A(1OH, 1([@@]-Methylenedioxy))-B(2OH)	Flavonol	5,3',4'-Trihydroxy-3-methoxy-6,7-methylenedioxyflavone
0.000	[Flavonol]-A(1OH, 1([@@]-Methylenedioxy))-B(1OH, 1OMe)	Flavonol	3,5,3'-Trihydroxy-4'-methoxy-6,7-methylenedioxyflavone
0.000	[Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH)	Flavonol	5,2'-Dihydroxy-3,7,8-trimethoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(1OMe)	Flavonol	Herbacetin 3,7,4'-trimethyl ether
0.000	[Flavonol (3-OMe)]-A(1OH, 2OMe)-B(1OH)	Flavonol	Herbacetin 3,7,8-trimethyl ether
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(1OMe)	Flavonol	Herbacetin 3,8,4'-trimethyl ether
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe, 1Methyl)-B(1OH)	Flavonol	5,8,4'-Trihydroxy-3,7-dimethoxy-6-methylflavone
0.000	[Flavonol (3-OMe)]-A(1OH, 1([@@]-Methylenedioxy))-B(2OH)	Flavonol	Wharangin
0.000	[Flavonol (3-OMe)]-A(2OH, 2OMe)-B(none)	Flavonol	5,8-Dihydroxy-3,6,7-trimethoxyflavone
0.000	[Flavonol (3-OMe)]-A(2OH, 2OMe)-B(none)	Flavonol	Araneol
0.000	[CCS-type derivative / [3,2']-Epoxymethanoflavone]-A(2OH, 1OMe)-B(2OH)	CCS-type derivative / [3,2']-Epoxymethanoflavone	Benthamianin
0.000	[Flavan]-A(1OH, 1OMe, 2Methyl)-B(1OH, 1([@@]-Methylenedioxy))	Flavan	5,2'-Dihydroxy-7-methoxy-6,8-dimethyl-4',5'-methylenedioxyflavan
0.000	[Pterocarpan]-A(1OH, 2OMe)-B(1([@@]-Methylenedioxy))	Pterocarpan	2-Hydroxy-4-methoxypterocarpin
0.000	[Pterocarpan-6a-ol]-A(2OMe)-B(1([@@]-Methylenedioxy))	Pterocarpan-6a-ol	Lathycarpin
0.000	[Pterocarpene]-A(1OH, 1OMe)-B(1OH, 2OMe)	Pterocarpene	Bryacarpene 1
0.000	[12a-Hydroxyrotenone]-A(1OH, 1OMe, 1Methyl)-B(1OH)	12a-Hydroxyrotenone	Boeravinone C
0.000	[4-phenylcoumarin]-A(1OH, 2OMe)-B(1OH, 1OMe)	4-phenylcoumarin	8,3'-Dihydroxy-5,7,4'-trimethoxy-4-phenylcoumarin

ピーク番号	保持時間 (min)	m/z	m/z差分	ログ強度	アダクト	DB検索結果	ヒット数	MSn	FS2	FS3	共有数
1394	28.39	363.10504	0.0000	-0.10	[M+K]+	(3 names) Methyl di-alpha-L-rhamnoside; Antibiotic DO 248A; Resorcinomycin A	ALL 2 KN 2	MS2 MS3	0.107	0.222	2
	28.41	342.17590	-20.9291	0.18	[M+NH4]+	(3 names) Methyl di-alpha-L-rhamnoside; Antibiotic DO 248A; Resorcinomycin A	ALL 2 KN 2	MS2 MS3			3
	28.42	325.14916	-37.9559	0.28	[M+H]+	(3 names) Methyl di-alpha-L-rhamnoside; Antibiotic DO 248A; Resorcinomycin A	ALL 2 KN 2	MS2 MS3 x 2	0.211	0.200	2

ピーク情報

DB検索結果

MSnスペクトル情報

FlavonoidSearch結果

FlavonoidSearch結果

関連ピーク情報