ピーク情報

だいず［納豆類］糸引き納豆

pos

Peak #12799 MN MID: SE112_S040461_M90

m/z: 625.39296, RT: 43.15, 強度: 488447, ログ強度: 1.74, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 1

DB検索結果: (3 names) Linckoside F;(-)-Linckoside F;23-O-beta-D-Glucopyranosyl-25-methyldolichosterone

DBごとのヒット数: ALL 2 KN 2

FlavonoidSearch最大スコア MS2: -, MS3: 0.069

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C34H56O10	624.38735	-2.668	Linckoside F	KNApSAcK: C00030666 LipidMAPS: LMST05050040
C34H56O10	624.38735	-2.668	23-O-beta-D-Glucopyranosyl-25-methyldolichosterone	KNApSAcK: C00036255
C34H56O10	624.38735	-2.668	1alpha,3beta,7alpha,22R,26-tetrahydroxy- ergost-5,24E-diene 27-O-beta-D-glucopyranoside	LipidMAPS: LMST01031286
C34H56O10	624.38735	-2.668	1alpha,7alpha,22R,26-tetrahydroxy- ergost-5,24Z-diene 3-O-beta-D-glucopyranoside	LipidMAPS: LMST01031285

MSnスペクトル情報

Level: 2, プリカーサーm/z: 625.39301

Splash: splash10-03fr-0011901000-88baabbf37aaa5c52745

m/z	Int.	NL	Rel.Int.
411.24	97895	214	1000
425.27	68277	200	697
383.28	28564	242	291
607.41	23067	18	235
215.09	21886	410	223
412.26	18337	213	187
426.26	14111	199	144
608.43	10861	17	110
298.12	10070	327	102
384.28	6082	241	62
508.36	5076	117	51
393.27	5051	232	51

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.059	[Flavone]-A(2OH, 2(C-Glu))-B(1OH, 1OMe)	Flavone	Stellarin 2
0.059	[Flavone]-A(2OH, 2(C-Glu))-B(1OH, 1OMe)	Flavone	6,8-Di-C-glucopyranosyldiosmetin
0.000	[Flavone]-A(2OH, 1(1(O-(E)-Feruloyl)-C-Glu))-B(2OH)	Flavone	Isoorientin 2''-O-(E)-ferulate
0.000	[Flavone]-A(2OH, 1(1(O-Feruloyl)-C-Glu))-B(2OH)	Flavone	2''-O-Feruloylorientin
0.000	[Flavone]-A(2OH, 1(1(O-Feruloyl)-C-Glu))-B(2OH)	Flavone	Orientin 6''-O-ferulate
0.000	[3-substituted Flavone (3-C-Glu)]-A(2OH, 1(C-Glu))-B(1OH, 1OMe)	3-substituted Flavone	3,8-Di-C-glucopyranosyldiosmetin
0.000	[Flavone]-A(2OH, 1(C-Glu), 1(C-Arabinosyl))-B(1OH, 2OMe)	Flavone	6-C-Glucopyranosyl-8-C-arabinopyranosyltricin
0.000	[Flavone]-A(2OH, 1(C-Glu), 1(C-Arabinosyl))-B(1OH, 2OMe)	Flavone	6-C-Arabinopyranosyl-8-C-glucopyranosyltricin

Level: 3, プリカーサーm/z: 425.27039

Splash: splash10-014i-0090000000-8724215d297dd45ad280

m/z	Int.	NL	Rel.Int.
215.11	19496	210	1000

FlavonoidSearch結果

Symbolized Name	MSMS-Category	MSMS-Aglycone
[Flavanone]-A(2OH, 2(C-Prenyl))-B(2OH)	Flavanone	Monotesone B
[Flavanone]-A(2OH, 2(C-Prenyl))-B(2OH)	Flavanone	6,8-Diprenyleriodictyol
[Flavanone]-A(2OH, 2(C-Prenyl))-B(2OH)	Flavanone	Kushenol E
[Flavanone]-A(2OH)-B(2OH, 2(C-Prenyl))	Flavanone	Sigmoidin A
[Flavanone]-A(2OH)-B(2OH, 2(C-Prenyl))	Flavanone	Abyssinin III
[Isoflavanone]-A(2OH, 1(C-Prenyl))-B(2OH, 1(C-Prenyl))	Isoflavanone	3'-Dimethylallylkievitone
[Flavanone]-A(2OH, 1(C-Prenyl))-B(2OH, 1(C-Prenyl))	Flavanone	Gancaonin E
[Flavanone]-A(2OH, 1(C-Prenyl))-B(2OH, 1(C-Prenyl))	Flavanone	5,7,3',4'-Tetrahydroxy-6,5'-di-C-prenylflavanone
[Flavanone]-A(2OH, 1(C-Prenyl))-B(2OH, 1(C-Prenyl))	Flavanone	Lespedezaflavanone D
[Dihydroflavonol]-A(2OH, 2(C-Prenyl))-B(1OH)	Dihydroflavonol	6,8-diprenylaromadendrin
[Dihydroflavonol]-A(2OH, 1(C-Prenyl))-B(1OH, 1(C-Prenyl))	Dihydroflavonol	Lespedezaflavanone C
[Flavone]-A(2OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OMe)	Flavone	7,8,3',4'-Tetramethoxy-6'',6''-dimethylpyrano[2'',3'':5,6]flavone
[2'-Hydroxychalcone]-A(2OH, 1(2-hydroxy-3-methyl-3-butenyl))-B(1OH, 1(2-hydroxy-3-methyl-3-butenyl))	2'-Hydroxychalcone	Angusticornin B
[2'-Hydroxychalcone]-A(2OH, 1(C-Prenyl))-B(1([2,3:@@]-(4-Hydroxy-5-(hydroxyisopropanyl)dihydrofurano)))	2'-Hydroxychalcone	Paratocarpin G
[2'-Hydroxychalcone]-A(1OH, 1OMe, 1([2,3:@@]-(5,5-Dimethyl-4-acetoxy-4,5,3a,6a-tetrahydro-furo[2,3-b]furano)))-B(none)	2'-Hydroxychalcone	Tephropurpurin
[beta-Hydroxy(or Oxodihydro)chalcone]-A(2OH, 1(C-Prenyl))-B(1OH, 1(2-hydroxy-3-methyl-3-butenyl))	beta-Hydroxy(or Oxodihydro)chalcone	Glyinflanin E
[beta-Hydroxy(or Oxodihydro)chalcone]-A(1OH, 1([2,3:@@]-(5-(hydroxyisopropanyl)dihydrofurano)))-B(1OH, 1(C-Prenyl))	beta-Hydroxy(or Oxodihydro)chalcone	Glyinflanin F
[Dihydrochalcone]-A(1OH, 1OMe, 1([2,3:@@]-(4-Ispropyl-7-methyl-7-hydroxy-3a,4,5,6,7,7a-hexahydrobenzofurano)))-B(none)	Dihydrochalcone	Adunctin E
[UBR-type derivative / 2'-Oxocyclohexa-4',6'-dienyl-type Dihydrochalcone]-A(2OH, 1OMe, 2(C-Prenyl))-B(none)	UBR-type derivative / 2'-Oxocyclohexa-4',6'-dienyl-type Dihydrochalcone	Helihumulone
[Flavanone]-A(2OH, 1Lavandulyl)-B(2OH)	Flavanone	Exiguaflavanone A
[Flavanone]-A(1OH, 1([2,3:@@]-(6,6-Dimethyl-5-prenyl-4,5-dihydropyrano)))-B(2OH)	Flavanone	Exiguaflavanone L
[Flavanone]-A(2OH, 1(C-Prenyl), 1(2-hydroxy-3-methyl-3-butenyl))-B(1OH)	Flavanone	Lupiniol A1
[Flavanone]-A(2OH, 1(C-Prenyl))-B(1OH, 1(2-hydroxy-3-methyl-3-butenyl))	Flavanone	Lupiniol B
[Flavanone]-A(2OH, 1(C-Prenyl))-B(1OH, 1(3-Methyl-2,3-epoxybutyl))	Flavanone	Flemiflavanone D
[Flavanone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(5-(hydroxyisopropanyl)dihydrofurano)))-B(1OH)	Flavanone	Lonchocarpol C
[Flavanone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(5-(hydroxyisopropanyl)dihydrofurano)))-B(1OH)	Flavanone	Lonchocarpol D
[Flavanone]-A(2OH, 1Geranyl)-B(2OH)	Flavanone	Diplacone
[Flavanone]-A(2OH)-B(2OH, 1Geranyl)	Flavanone	Propolin D
[Flavanone]-A(2OH)-B(2OH, 1Geranyl)	Flavanone	Isonymphaeol B
[Flavanone]-A(1OH, 1(C-Prenyl), 1([2,3:@@]-(6,6-Dimethyldihydropyrano)))-B(2OH)	Flavanone	Dorsmanin J
[Flavanone]-A(2([2,3:@@]-(6,6-Dimethyldihydropyrano)))-B(2OH)	Flavanone	Dorsmanin E
[Flavanone]-A(2OH, 1(C-Prenyl))-B(2OH, 1(1,1-Dimethylallyl))	Flavanone	2',4'-Dihydroxy-5'-(1'',1''-dimethylallyl)-6-C-prenylpinocembrin
[Flavanone]-A(2OH, 1(C-Prenyl))-B(2OH, 1(1,1-Dimethylallyl))	Flavanone	5,7,2',4'-Tetrahydroxy-8-prenyl-5'-(1,1-dimethylallyl)flavanone
[Flavanone]-A(2OH)-B(2OH, 1Geranyl)	Flavanone	Sanggenol A
[Flavanone]-A(2OH)-B(2OH, 1Geranyl)	Flavanone	5'-Geranylsteppogenin
[Flavanone]-A(2OH, 1Geranyl)-B(2OH)	Flavanone	Sophoraflavanone C
[Flavanone]-A(2OH, 1Lavandulyl)-B(2OH)	Flavanone	Kushenol F
[Flavanone]-A(2OH, 1Lavandulyl)-B(2OH)	Flavanone	Sophoraflavanone G
[Flavanone]-A(2OH, 1(2-Isopropenyl-5-methyl-5-hexenyl))-B(2OH)	Flavanone	Remangiflavanone B
[Flavanone]-A(1OH, 1([2,3:@@]-(6,6-Dimethyl-5-prenyl-4,5-dihydropyrano)))-B(2OH)	Flavanone	Leachianone F
[Dihydroflavonol]-A(2OH, 1Geranyl)-B(1OH)	Dihydroflavonol	Bonanniol A
[Dihydroflavonol]-A(2OH)-B(1OH, 1(5-Carboxy-2-hydroxyphenyl))	Dihydroflavonol	Hypnum acid
[Flavonol (3-OMe)]-A(1OMe, 1Methyl, 1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(1OH, 1OMe)	Flavonol	8-C-Methylvelloquercetin 3,5,3'-trimethyl ether
[Flavan 3-ol]-A(1OH)-B(2OH)	Flavan 3-ol	6-(3,4-Dihydroxyphenyl)-6a,12b-dihydro-3,10,11,12-tetrahydroxy-[2]benzopyrano[3,4-c]benzopyran-8(6H)-one
[Isoflavanone]-A(2OH, 1Geranyl)-B(2OH)	Isoflavanone	6-Geranyldalbergioidin
[Isoflavan]-A(1OH, 1OMe, 1(C-Prenyl))-B(2OH, 1(C-Prenyl))	Isoflavan	Licoricidin
[Rotenone]-A(1OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OMe)	Rotenone	Erythynone
[12a-Hydroxyrotenone (3-OMe)]-A(1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(2OMe)	12a-Hydroxyrotenone	12a-Methoxyrotenone
[6-Hydroxydehydrorotenone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OMe)	6-Hydroxydehydrorotenone	6-Hydroxy-6a,12a-dehydro-alpha-toxicarol

Level: 3, プリカーサーm/z: 411.23682

Splash: splash10-001l-0039000000-43fb434f6f48d8039c59

m/z	Int.	NL	Rel.Int.
383.25	16406	28	1000
393.29	11200	18	682
298.18	7906	113	481
280.29	2696	131	164
324.30	1474	87	89
326.20	1439	85	87
211.15	1399	200	85
201.19	1330	210	81
348.22	990	63	60
366.40	982	45	59

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.069	[Isoflavone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(3OMe)	Isoflavone	Toxicarolisoflavone
0.061	[Isoflavone]-A(1OMe, 1(C-Prenyl))-B(3OMe)	Isoflavone	Prebarbigerone
0.000	[Flavan 3-ol]-A(2OH)-B(2OH)-C(1(O-p-Hydroxybenzoyl))	Flavan 3-ol	Catechin 3-O-p-hydroxybenzoate
0.000	[beta-Hydroxy(or Oxodihydro)chalcone]-A(2OMe, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(1([@@]-Methylenedioxy))	beta-Hydroxy(or Oxodihydro)chalcone	Pongapinone A
0.000	[Dihydrochalcone]-A(2OH)-B(2OH, 1Geranyl)	Dihydrochalcone	2-Geranyl-3,4,2',4'-tetrahydroxydihydrochalcone
0.000	[Dihydrochalcone]-A(3OH)-B(1OH, 2(C-Prenyl))	Dihydrochalcone	4,2',4',6'-Tetrahydroxy-3,5-diprenyldihydrochalcone
0.000	[Dihydrochalcone alpha-ol]-A(2OH, 1(C-Prenyl))-B(1OH, 1(C-Prenyl))	Dihydrochalcone alpha-ol	Kanzonol Y
0.000	[UBR-type derivative / 2'-Oxocyclohexa-4',6'-dienyl-type Dihydrochalcone]-A(3OH, 2(C-Prenyl))-B(none)	UBR-type derivative / 2'-Oxocyclohexa-4',6'-dienyl-type Dihydrochalcone	3',4',6'-Trihydroxy-2'-oxo-3',5'-diprenyldihydrochalcone
0.000	[Dihydroflavonol]-A(2OH, 1(p-Hydroxybenzyl))-B(2OH)	Dihydroflavonol	Gericudranin C
0.000	[Dihydroflavonol]-A(2OH, 1(p-Hydroxybenzyl))-B(2OH)	Dihydroflavonol	Gericudranin B
0.000	[Flavonol (3-OMe)]-A(1OH, 1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(2OMe)	Flavonol	Velloquercetin 3,3',4'-trimethyl ether
0.000	[Flavonol (3-OMe)]-A(1OMe, 1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(1OH, 1OMe)	Flavonol	Velloquercetin 3,5,3'-trimethyl ether
0.000	[Isoflavone]-A(1OH, 1(C-Prenyl))-B(2OMe, 1([@@]-Methylenedioxy))	Isoflavone	Preferrugone
0.000	[Isoflavone]-A(1OH, 2OMe, 1(C-Prenyl))-B(1([@@]-Methylenedioxy))	Isoflavone	Pre-5-methoxydurmillone
0.000	[Rotenone]-A(1([2,3:@@]-(5-(1-Hydroxymethylvinyl)dihydrofurano)))-B(2OMe)	Rotenone	Amorphigenin
0.000	[Rotenone]-A(1OH, 1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(2OMe)	Rotenone	Sumatrol
0.000	[Rotenone]-A(1OH, 1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OMe)	Rotenone	Toxicarol
0.000	[6-Hydroxyrotenone]-A(1([2,3:@@]-(5-Isopropenyldihydrofurano)))-B(2OH)	6-Hydroxyrotenone	2,3,6-Trihydroxy-5''-isopropenyldihydrofurano[2'',3'':9,8]rotenone
0.000	[12a-Hydroxyrotenone]-A(1([2,3:@@]-(6,6-Dimethylpyrano)))-B(2OMe)	12a-Hydroxyrotenone	Tephrosin
0.000	[Dehydrorotenone]-A(1([2,3:@@]-(5-(Hydroxyisopropanyl)dihydrofurano)))-B(2OMe)	Dehydrorotenone	Dehydrodalpanol