ピーク情報

（その他）はちみつ

pos

Peak #2969 MN MID: SE112_S030221_M90

m/z: 477.21406, RT: 38.77, 強度: 45281, ログ強度: 1.26, アダクト: [M+H]+, 共有数（同様のピークを含むサンプル数）: 3

DB検索結果: (24 names) Caudatol;Norcaesalpinin D;(+)-Norcaesalpinin D;Sudachinoid B;(+)-Sudachinoid B;Luzonoid E;(+)-Luzonoid E;Toonaciliatin G;(+)-Toonaciliatin G;Platyphylloside;Luzonoid G;(-)-Luzonoid G;Kadsuphilol I;2-M...

DBごとのヒット数: ALL 14 KG 1 KN 13

FlavonoidSearch最大スコア MS2: 0.111, MS3: 0.333

組成式	分子量	誤差(Δppm）	候補化合物名（代表で最短名を記載）	化合物ID
C25H32O9	476.20463	4.514	Norcaesalpinin D	KNApSAcK: C00042791
C25H32O9	476.20463	4.514	Caudatol	KNApSAcK: C00012189
C25H32O9	476.20463	4.514	Sudachinoid B	KNApSAcK: C00033394
C25H32O9	476.20463	4.514	Toonaciliatin G	KNApSAcK: C00040503
C25H32O9	476.20463	4.514	Luzonoid E	KNApSAcK: C00043682, C00043683
C25H32O9	476.20463	4.514	Platyphylloside	KNApSAcK: C00034641
C25H32O9	476.20463	4.514	Luzonoid G	KNApSAcK: C00043684
C25H32O9	476.20463	4.514	Kadsuphilol I	KNApSAcK: C00048444
C25H32O9	476.20463	4.514	2-Methoxyestrone 3-glucuronide	HMDB: HMDB0004482 KEGG: C11132 LipidMAPS: LMST05010010
C25H32O9	476.20463	4.514	Aurovertin D	KNApSAcK: C00038536
C25H32O9	476.20463	4.514	Norcaesalpinin MB	KNApSAcK: C00043781
C25H32O9	476.20463	4.514	Norcaesalpinin MC	KNApSAcK: C00043782
C25H32O9	476.20463	4.514	4-methoxyestrone 3-O-(beta-D-glucuronide)	LipidMAPS: LMST05010071
C25H32O9	476.20463	4.514	Caesalpinin J	KNApSAcK: C00029874
C25H32O9	476.20463	4.514	Kadangustin A	KNApSAcK: C00039510

MSnスペクトル情報

Level: 2, プリカーサーm/z: 477.21411

Splash: splash10-001i-0000900000-874ec7c9978fcb0d3c38

m/z	Int.	NL	Rel.Int.
431.19	11192	46	1000

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.111	[Dihydroflavonol]-A(1OH, 1(C-Prenyl))-B(1OH, 2(C-Prenyl))	Dihydroflavonol	8,3',5'-Triprenylgarbanzol
0.000	[Flavanone]-A(2OH, 1(C-Prenyl))-B(1OH, 2(C-Prenyl))	Flavanone	Hydroxysophoranone
0.000	[Flavanone]-A(2OH, 2(C-Prenyl))-B(1OH, 1(C-Prenyl))	Flavanone	Amorilin
0.000	[Flavone]-A(1OH, 1OMe, 1(C-Glu))-B(1OH, 1OMe)	Flavone	Isoorientin 7,3'-dimethyl ether
0.000	[Flavone]-A(1OH, 1OMe, 1(C-Glu))-B(1OH, 1OMe)	Flavone	6-C-Glucopyranosylpilloin
0.000	[Flavone]-A(2OMe, 1(C-Glu))-B(2OH)	Flavone	Parkinsonin B
0.000	[Flavone]-A(1OH, 1OMe, 1(C-Glu))-B(1OH, 1OMe)	Flavone	Orientin 7,3'-dimethyl ether
0.000	[Flavone]-A(1OH, 2OMe, 1(C-Glu))-B(1OH)	Flavone	Abrusin
0.000	[Flavone]-A(1OH, 2OMe, 1(C-Glu))-B(1OH)	Flavone	Precatorin I
0.000	[Isoflavone]-A(2OH, 1OMe, 1(C-Glu))-B(1OMe)	Isoflavone	Volubilinin
0.000	[Flavonol (3-OMe)]-A(2OH, 1(C-Rhamnosyl))-B(1OH, 1OMe)	Flavonol	5,7,3'-Trihydroxy-3,4'-dimethoxyflavone 8-C-rhamnopyranoside
0.000	[CCS-type derivative / [2,3,4:5,4a,4]-(6-Phenylpyrano)anthocyanidin (4'-Hydroxy-3'-methoxy)]-A(1OH)-B(1OH, 2OMe)	CCS-type derivative / [2,3,4:5,4a,4]-(6-Phenylpyrano)anthocyanidin	Malvidin 4-vinylguaiacol
0.000	[Isoflavanone]-A(2OH, 1(C-Prenyl))-B(1OH, 1Geranyl)	Isoflavanone	Sophoraisoflavanone C
0.000	[UBR-type derivative / 7-Oxocyclohexa-5,8a-dienyl-type 4-Phenylcoumarin]-A(1OH, 2(C-Prenyl), 1(2-Methylbutyroyl))-B(none)	UBR-type derivative / 7-Oxocyclohexa-5,8a-dienyl-type 4-Phenylcoumarin	Calofloride

Level: 3, プリカーサーm/z: 431.18875

Splash: splash10-03dj-0049700000-b958e109f432dcb4ddfe

m/z	Int.	NL	Rel.Int.
413.21	1863	18	1000
395.23	1369	36	734
377.11	780	54	418
224.97	534	206	286
242.98	385	188	206
260.92	109	170	58

ピーク情報

DB検索結果

MSnスペクトル情報

FlavonoidSearch結果

FlavonoidSearch結果

Score	Symbolized Name	MSMS-Category	MSMS-Aglycone
0.333	[Flavone]-A(1OH, 1OMe, 1(C-Glu))-B(none)	Flavone	Kaplanin
0.333	[Isoflavone]-A(1OH, 1(C-Glu))-B(1OMe)	Isoflavone	Puerarin 4'-methyl ether
0.000	[Flavone]-A(1OH, 1OMe, 1(C-Arabinosyl))-B(1OMe)	Flavone	Isomollupentin 7,4'-dimethyl ether
0.000	[Flavone]-A(1OH, 1OMe, 1(C-Arabinosyl))-B(1OMe)	Flavone	7,4'-Di-O-Methylisomollupentin
0.000	[Flavone]-A(1OH, 1OMe, 1(C-Rhamnosyl))-B(1OH)	Flavone	8-C-Rhamnosylgenkwanin
0.000	[Flavone]-A(2OH, 1(3,4-Dihydroxy-6-methyl-5-oxotetrahydro-2-pyranyl))-B(2OH)	Flavone	Derhamnosylmaysin
0.000	[Flavone]-A(2OH, 1(6-Deoxy-beta-L-ribo-hexopyranos-3-ulos-1-yl))-B(2OH)	Flavone	6-C-(6-Deoxy-beta-L-ribo-hexopyranos-3-ulos-1-yl)luteolin
0.000	[Flavone]-A(2OH, 1(2,6-Dideoxy-beta-L-xylo-hexopyranosyl))-B(1OH, 1OMe)	Flavone	Alternanthin
0.000	[Flavonol (3-OMe)]-A(2OH, 1OMe)-B(1OMe, 1(3-hydroxy-3-methylbutyl))	Flavonol	Aliarin 4'-methyl ether
0.000	[Flavonol]-A(1OH, 2OMe)-B(1OMe, 1(4-hydroxy-3-methylbutyl))	Flavonol	3,7-Dihydroxy-2-[3-(4-hydroxy-3-methylbutyl)-4-methoxyphenyl]-5,6-dimethoxy-4H-1-benzopyran-4-one
0.000	[Flavonol (3-OMe)]-A(2OMe, 1([@@]-Methylenedioxy))-B(1OMe, 1([@@]-Methylenedioxy))	Flavonol	3,5,8,3'-Tetramethoxy-6,7:4',5'-bis(methylenedioxy)flavone
0.000	[Flavan 3-ol]-A(2OH)-B(2OH)-C(1(O-<1,6-Dihydroxy-2-cyclohexene-1-carbonyl>))	Flavan 3-ol	Catechin 3-O-(1,6-dihydroxy-2-cyclohexene-1-carboxylate)